U.S. patent number 3,790,431 [Application Number 05/220,152] was granted by the patent office on 1974-02-05 for light-transmissive retroreflective sheeting.
This patent grant is currently assigned to Minnesota Mining and Manufacturing Company. Invention is credited to Chi Fang Tung.
United States Patent |
3,790,431 |
Tung |
February 5, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
LIGHT-TRANSMISSIVE RETROREFLECTIVE SHEETING
Abstract
Light-transmissive retroreflective sheeting comprising an open
web of filaments that are encased around their whole circumference
at least over those parts of their length that define open spaces
of the web by a monolayer of minute retroreflective microspheres.
One use of the sheeting is in internally illuminated signs, where
the light-transmissive retroreflective sheeting is incorporated
between the internal illumination source and the sign face so as to
retroreflect light beamed against the sign face and make the signs
retroreflective.
Inventors: |
Tung; Chi Fang (Lincoln,
MN) |
Assignee: |
Minnesota Mining and Manufacturing
Company (St. Paul, MN)
|
Family
ID: |
22822283 |
Appl.
No.: |
05/220,152 |
Filed: |
January 24, 1972 |
Current U.S.
Class: |
442/44; 40/564;
359/540; 428/414; 40/615; 428/338; 442/73 |
Current CPC
Class: |
F21V
11/14 (20130101); G02B 5/128 (20130101); Y10T
442/2115 (20150401); Y10T 428/268 (20150115); G09F
13/0472 (20210501); Y10T 428/31515 (20150401); Y10T
442/174 (20150401) |
Current International
Class: |
F21V
11/00 (20060101); G02B 5/128 (20060101); G02B
5/12 (20060101); F21V 11/14 (20060101); G09F
13/04 (20060101); G09f 013/16 (); G09f
013/06 () |
Field of
Search: |
;40/13B,13J,132R,134
;161/3.5,4,83,92,408-410,DIG.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Ansher; Harold
Attorney, Agent or Firm: Kinney, Alexander, Sell, Steldt
& Delahunt
Claims
1. Light-transmissive retroreflective sheeting comprising an open
web of filaments that are encased around their whole circumference
at least over those parts of their length that define open spaces
of the web by a monolayer of minute retroreflective microspheres,
the spaces between the encased filaments occupying between 20 and
80 percent of the area covered
2. Sheeting of claim 1 in which the spaces between the encased
filaments
3. Sheeting of claim 1 in which the encased filaments have a
diameter less
4. Sheeting of claim 1 in which the smallest dimension of the
spaces
5. Sheeting of claim 1 in which the web is a fabric of
interwoven
6. Sheeting of claim 1 in which the retroreflective microspheres
are partially embedded in a layer of binder material coated on the
filaments and comprise glass microspheres covered over their
partially embedded
7. Sheeting of claim 1 in which the microspheres are held to the
filaments
8. Sheeting of claim 7 in which the elastomeric material comprises
epoxy resin and a water-insoluble polyether polyamine of high
amine
9. Light-transmissive retroreflective sheeting comprising an open
fabric of interwoven filaments that are encased around their whole
circumference over those parts of their length that define open
spaces of the fabric by a monolayer of minute retroreflective
microspheres, the microspheres being partially embedded in a layer
of elastomeric binder material coated on the filaments after the
filaments have been woven into a fabric, the encased filaments
having a diameter less than 500 microns, the spaces between the
encased filaments occupying between 20 and 80 percent of the area
covered by the fabric, and the smallest dimension of the spaces
being less than
10. Sheeting of claim 9 in which the elastomeric material comprises
epoxy resin and a water-insoluble polyether polyamine of high
amine
11. Sheeting of claim 9 in which the retroreflective microspheres
comprise glass microspheres covered over their partially embedded
surface with
12. Sheeting of claim 9 in which the spaces between the encased
filaments
13. Light-transmissive retroreflective sheeting comprising an
open-mesh fabric of interwoven filaments that are encased around
their whole circumference over those parts of their length that
define open spaces of the fabric by a monolayer of minute
retroreflective microspheres, the microspheres being partially
embedded in a layer of binder material coated on the filaments
after the filaments have been woven into a fabric, the spaces
between the encased filaments occupying between 20 and 80 percent
of the area covered by the fabric.
Description
BACKGROUND OF THE INVENTION
A principal advantage asserted for internally illuminated roadway
signs is that they can be seen at night even when out of reach of
headlights of approaching vehicles. But this internal illumination
also becomes a serious disadvantage when the light source within
the sign fails or when there is a general electric power failure.
Under such circumstances the sign may become partially or wholly
illegible or inconspicuous, especially to motorists traveling at
highway speeds at night.
Others have suggested ways for imparting retroreflectivity to
internally illuminated signs. For example, in U.S. Pat. No.
3,510,976, it is suggested that a sign face be formed by partially
embedding, as a monolayer in an adhesive layer coated on a
transparent plate, a mixture of metallized glass microspheres and
non-metallized microspheres. The metal on the protruding portions
of the metallized microspheres is then removed, a clear material
coated over the microspheres, and an opaque sign image painted over
the clear layer. The non-metallized microspheres are said to
transmit light from the internal source, while the metallized
microspheres retroreflect light beamed against the front of the
sign.
A major difficulty with a sign as described in U.S. Pat. No.
3,510,976 is that light is poorly transmitted through the
non-metallized microspheres, and thus the internal illumination of
the sign is greatly reduced. Further, it would be expensive to make
existing signs retroreflective using the technique taught in the
patent, since that would require replacement of the sign faces.
Insofar as is known, signs such as taught in U.S. Pat. No.
3,510,976 have never become commercial.
SUMMARY OF THE INVENTION
The present invention provides a new light-transmissive
retroreflective sheeting, and among other uses for the sheeting, it
may be used to make internally illuminated signs retroreflective
while retaining good light-transmission properties for the sign.
When incorporated in internally illuminated signs, the sheeting is
disposed between the sign image and the light source for the sign.
The sign is normally illuminated by the light source, but in the
event that the light source wholly or partially fails, the sign can
still be read by light beamed at the front of the sign and
retroreflected by the retroreflective sheeting that is behind the
sign image.
Briefly, a preferred light-transmissive retroreflective sheeting of
the invention comprises an open web of filaments encased by minute
retroreflective microspheres ("open" means that the filaments are
separated from one another so that there are significant
light-transmitting spaces between the encased filaments).
Typically, the web of filaments is a fabric of interwoven
filaments. Such open webs provide good light transmission, and in
addition, they have good "angularity," meaning that they will
retroreflect light striking them on a line that forms a substantial
angle with a line normal to the web.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is an "exploded" schematic perspective view of a
representative internally illuminated sign of the invention;
and
FIG. 2 is a greatly enlarged perspective view of a
light-transmissive retroreflective fabric of the invention, shown
with the layer of microspheres broken away to reveal the base
fabric.
DETAILED DESCRIPTION
FIG. 1 shows in an "exploded" schematic representation an
illustrative back-lighted or internally illuminated sign 10, which
comprises a box-like enclosure 11; a light source that comprises a
set of tubular light bulbs 12 and a diffuser panel 13; a
light-transmissive retroreflective sheeting 14 of the invention;
and a transparent sign face 15 carrying a sign image 16 visible
from the front of the sign when illuminated from the back by the
light source. A diffuser panel is not necessary, but is preferred
so that light traveling through the sign face is substantially
uniform over the whole area of the sign face. The sign image is
almost always supported on a transparent sign face, through for
special effects it could be supported in some other way (as by
suspension on wires) and could be in front of or behind the sign
face.
As previously noted, light-transmissive retroreflective sheeting
comprising an open web of filaments encased by minute
retroreflective microspheres is especially useful in an internally
illuminated sign, because such a sheeting provides good light
transmission and also has good "angularity." For example, some
light-transmissive retro-reflective fabrics of the invention can
retroreflect, with 50 percent of original brightness, light
striking the sheeting at an angle of 70.degree.-80.degree. to the
normal to the sheeting. Open webs are further advantageous in that
they permit movement of air within the sign, and light is better
transmitted through open spaces than through transparent structure
such as a transparent film. Instead of being woven as a fabric,
only parallel filaments supported in an exterior frame may be used
as a retroreflective sheeting of the invention. And in some
embodiments, the base filaments of the sheeting are electrical
conductors that generate heat when carrying a current, making the
sheeting useful to keep the sign warm and free from
condensation.
A light-transmissive retroreflective fabric useful as the
light-transmissive sheeting 14 is illustrated in closeup in FIG. 2,
and comprises a base fabric of woven filaments 17, a layer of
binder material (not shown) coated on the filaments, and a
monolayer of microspheres or beads 18 each partially embedded and
adhered in the layer of binder material (the layer of microspheres
is partially broken away to show the base fabric); the embedded
surfaces of the microspheres are preferably covered with a
reflective material such as vapor-coated aluminum. A typical method
for preparing such a light-transmissive retroreflective fabric
includes the steps of coating binder material on a base fabric
having filaments of the desired denier and the desired percentage
of open area; applying microspheres completely covered with a
reflective material to the coated fabric while the binder material
is in a tacky state so that the microspheres become partially
embedded in the layer of binder material; drying or curing the
binder material to advance it to a non-tacky durable adherent
condition; and removing the layer of reflective material that
covers the exposed surfaces of the microspheres, as by etching.
Light-transmissive retroreflective sheeting can also be prepared by
weaving or otherwise grouping into an integral whole a web of
filaments that have been previously coated with retroreflective
elements, but such a method is much more difficult than preparing
the light-transmissive retroreflective fabric from an already
prepared base fabric, and such precoated filaments cause
substantial wear on weaving equipment.
The filaments in a fabric of the invention are made from a variety
of materials, such as natural cellulose-based fibers, synthetic
polymeric fibers, or metal filaments. And they are sometimes made
of a material that can be heat-formed, whereby the fabric is given
a non-planar configuration. Such a configuration is useful, for
example, when the sign face is three-dimensional.
The binder material on a light-transmissive retroreflective
sheeting of the invention is preferably elastomeric to permit the
sheeting to be rolled, as for shipment, and to facilitate an
otherwise easy handling of the sheeting. One such useful
elastomer-forming binder material comprises a polyether polyamine
of high amine functionality, such as poly(tetramethyleneoxide)
diamine taught in Hubin et al., U.S. Pat. No. 3,436,359, and
diglycidyl ether of bisphenol A. This material cures to form a very
strong bond with partially embedded silver- or aluminum-coated
glass microspheres. Other useful binder materials include natural
rubber, acrylic resins, and polyvinyl butyral resins.
A light-transmissive retroreflective fabric of the invention has
other uses besides in an internally illuminated sign. For example,
it can be incorporated in a perforate retroreflective traffic or
advertising sign for use in situations where it is desired to
permit viewers to see in back of the sign or to permit wind to blow
through the sign and thus keep it from being blown over, or it can
be incorporated in a cool retroreflective over-garment, for
example, a retroreflective vest or jacket worn by highway or street
crews.
The light-transmissive retroreflective sheeting in a sign of the
invention is chosen so as to provide a desired balance of
transmission and reflection. Preferably, the light-transmissive
retroreflective sheeting transmits at least 20 percent, and more
preferably at least 40 percent, of the light impinging on the
sheeting from the light source. On the other hand, so that the
light-transmissive retroreflective sheeting will provide good
retroreflection if the light source fails, the light-transmissive
retroreflective sheeting preferably transmits no more than 80
percent, and more preferably no more than 60 percent, of the light
from the light source (the percent-transmission numbers are assumed
to describe the percent open area of the area occupied by the
sheeting, and the non-transmitting portions of the sheeting are
assumed to be retroreflective). Adequate light-transmission and
reflection can also be obtained with sheeting having a percentage
of open area outside these ranges; for example, by increasing the
brightness of the light bulbs in the sign, a sheeting transmitting
as little as 5 percent of the light impinging on it may be used,
and sheeting transmitting as much as 90 or 95 percent of light has
useful reflection characteristics.
The light-transmissive retroreflective sheeting is usually not in
contact with the sign face in the assembled condition of the sign,
since the microspheres touching the sign face might not
retroreflect. Desirably, the sheeting is spaced far enough from the
sign face so that light from the light source transmitted through
the sheeting will spread sufficiently to eliminate or minimize any
shadow cast by the sheeting on the sign face by the light
source.
Also, a light-transmissive retroreflective sheeting is least
noticeable in an internally illuminated sign when the
light-transmissive spaces and the densely packed areas of
microspheres are very fine or small. Thus, a light-transmissive
retroreflective fabric is least noticeable when the diameter of the
retroreflective-microsphere-encased filaments is less than 500
microns and preferably less than 250 microns, and the smallest
dimension of the spaces between the encased filaments is less than
one millimeter, and preferably less than 500 microns. The glass
microspheres or beads are of a size such that a dense monolayer of
them can be coated on the filament without unduly reducing the size
of the spaces between the filaments.
The invention will be further illustrated by the following example.
A fabric of 200-micron-diameter nylon filaments woven in a straight
"Leno" weave using 20 threads per inch was first roller coated with
a primer to fill up all crevices in the filament. The primer
material was a 10-weight-percent-solids solution in toluene of the
following ingredients:
Parts by Weight Poly(tetramethyleneoxide) diamine that has a
number-average molecular weight of 10,000, an amine equivalent
weight of 4610, and a viscosity at 65.degree.C of 49,500
centipoises, and that was prepared according to the procedures of
Examples 1-4 of Hubin et al., U.S. Pat. No. 3,436,359 100
2,4,6-tris-dimethylaminomethylphenyl catalyst (DMP-30) 2.5
Diglycidyl ether of bisphenol A having an epoxide equivalent weight
of 180-195 (Epon 828) 50 Stannous octoate catalyst 5
This primer coating was then cured at 150.degree.F for 30 minutes.
After the fabric had cooled to room temperature, a binder material
of the same ingredients listed above but dissolved at
30-weight-percent solids in toluene was coated on the fabric, after
which the coated fabric was exposed to jets of compressed air to
remove excess binder material and keep the spaces between filaments
open. While the layer of binder material was still wet and tacky,
the fabric was passed through a "fluidized bed" of
aluminum-vapor-coated glass microspheres 37 to 88 microns in
diameter (the fabric passed over a trough containing microspheres
that were shot upward by a set of compressed air nozzles at the
bottom of the trough, with a canopy above the fabric returning the
microspheres toward the fabric), whereupon the filaments of the
fabric became individually encased by a densely packed monolayer of
microspheres adhered to and partially embedded in the coating of
binder material. The layer of binder material was then cured at
150.degree.F for one hour, after which the aluminum on the exposed
portions of the microspheres was removed by etching with an alkali
solution.
The resulting light-transmissive retroreflective sheeting had an
open area of about 50 percent (determined by measuring the light in
photovolt units (PV) returned by an assembly that comprised the
sheeting before the aluminum was removed (which is known to have a
PV of zero) over a standard sheeting known to have a PV of 57 using
a photometer that had been calibrated with the standard 57 PV
sheeting; the assembly was measured as having a PV of 30, meaning
that the percent open area of the light-transmissive sheeting of
this example was 30/57 times 100 percent, or about 50 percent). The
sheeting was disposed in a sign having a 24-inch-by-24-inch
transparent glass-plate sign face carrying no image; the sign was
lighted by a bank of four 40-watt fluorescent light bulbs through a
diffuser panel of white translucent plastic sheeting spaced 4
inches in front of the bulbs. The light from the sign was then
measured under various combinations of the following conditions:
with the light-transmissive retroreflective sheeting ("screen" in
the table below) in place and not in place between the sign face
and diffuser panel; with the sign illuminated by a headlight
(having 3950 candle power at 12.5 feet) and not illuminated; and
with the internal lights on and not on. The light was measured
through a photocell and galvanometer 50 feet away from the sign,
and the headlight was adjacent the photocell. The sign was turned
so that the angle of incidence of light on the sign from the
headlight was varied between 0.degree. and 60.degree. from the
normal of the sign face. The results were as follows, the numbers
given being readings on the galvanometer: ##SPC1##
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