U.S. patent number 3,790,332 [Application Number 05/218,248] was granted by the patent office on 1974-02-05 for liquid candles.
This patent grant is currently assigned to Price's Patent Candle Company Limited. Invention is credited to Ronald Brian Woollard.
United States Patent |
3,790,332 |
Woollard |
February 5, 1974 |
LIQUID CANDLES
Abstract
A liquid candle capable of burning with a coloured flame is
formed by floating a wick holder comprising a float and a wick on a
body of combustible liquid within an open-top, for example, glass
container, the liquid having a high flash point and containing in
solution a flame-colouring amount of at least one flame-colouring
additive. The float portion of the wick holder holds the wick with
its lower part within the liquid and its upper part, which forms a
burning end, spaced from the surface of the body of liquid to an
extent which prevents ignition thereof during use. The liquid can
contain a dye to enhance its appearance, and optionally also a
perfume.
Inventors: |
Woollard; Ronald Brian (Hook,
EN) |
Assignee: |
Price's Patent Candle Company
Limited (London, EN)
|
Family
ID: |
9763304 |
Appl.
No.: |
05/218,248 |
Filed: |
January 17, 1972 |
Foreign Application Priority Data
Current U.S.
Class: |
431/126; 44/318;
44/445; 431/291; D26/6; 44/385; 44/457; 431/298 |
Current CPC
Class: |
F21S
13/12 (20130101); F21V 37/0095 (20130101) |
Current International
Class: |
F21V
37/00 (20060101); F23q 002/32 () |
Field of
Search: |
;431/126,298,291
;44/59 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Dority, Jr.; Carroll B.
Claims
1. A liquid candle capable of burning with a coloured flame which
comprises
a. an open top container containing a body of combustible liquid of
high flash point therein,
b. said liquid consisting essentially of an alcohol having a
minimum flash point of 100.degree. C. and the ability to burn on a
wick with free burning characteristics and
c. said liquid containing, in solution, a flame-coloring amount of
an ash producing flame coloring additive containing a metal salt,
and
d. floating on said liquid, a wick holder comprising a float and a
wick,
e. the float having a dished-base portion floating with its
uppermost surface clear of said liquid, said base portion including
an upstanding wall portion extending therefrom and an upstanding
tubular portion holding said wick with the lower part of said wick
within said liquid and the upper part of said wick projecting about
said float to form an exposed burning end of said wick which is
spaced from the surface of said liquid
2. A liquid candle as claimed in claim 1, wherein said liquid also
contains
3. A liquid candle as claimed in claim 1, wherein said liquid also
contains
4. A liquid candle as claimed in claim 1, wherein said liquid
contains at
5. A liquid candle, as in claim 1, wherein the combustible liquid
is ethane
6. A liquid candle, as in claim 5, wherein the ethane diol contains
from 1.3 to 1.7 percent by weight of boric acid as a flame-coloring
additive.
7. A liquid candle, as in claim 5, wherein the ethane diol contains
from 0.2 to 0.4 percent by weight of lithium acetate as a
flame-coloring
8. A liquid candle, as in claim 7, wherein the ethane diol contains
from 0.2 to 0.4 percent by weight of potassium chloride as an
additional
9. A liquid candle, as in claim 5, wherein the ethane diol contains
from 0.2 to 0.5 percent by weight of potassium chloride as a
flame-coloring
10. A liquid candle, as in claim 1, wherein the float has a
sidewall upstanding from the base portion to a height greater than
the tubular
11. A liquid candle, as in claim 1, wherein the base of the float
is a convex conical form.
Description
BACKGROUND OF THE INVENTION
With conventional solid candles containing flame-colouring
additives in the solid combustible material constituting the body
of the candle tne natural luminosity of the flame produced by
combustion of the solid material itself overwhelms to a greater or
lesser extent the colouring action of the additive(s). For example,
a conventional wax candle burns with a pronounced yellow flame, and
the introduction of any flame-colouring additives into the wax
(other than yellow or golden flame-colouring additives) results in
little more than a coloured edge to the flame. Other solid
combustible materials, for example, solid polyethylene glycols, as
are potentially suitable for the commercial production of coloured
flame candles of acceptable cost, albeit of relatively high cost
compared with wax, have been found to have other disadvantages such
as difficulty of moulding, poor flame colours - yellow still tends
to predominate, and hydroscopisity, which latter gives rise to very
poor storage properties.
SUMMARY OF THE INVENTION
The present invention provides a new approach to the problem of
providing, in a straight forward and aesthetically acceptable
manner, a candle-like device capable of burning with a truly
coloured flame. This approach is based on the concept of using a
combustible liquid instead of a solid, the liquid being burned with
the aid of a floating wick. The resulting combination is termed a
"liquid candle." It has now been found that such a liquid candle
capable of burning with a coloured flame can be formed by providing
in combination an open-top container, a body of combustible liquid
disposed therein, said liquid consisting essentially of an alcohol
having a high flash point and the ability to burn on a wick with
free burning characteristics and said liquid containing in solution
a flame-colouring amount of at least one flame-colouring additive,
and, floating on said liquid, a wick holder comprising a float and
a wick, the float holding said wick with the lower part of said
wick within said liquid and the upper part thereof projecting above
said float to form an exposed burning end of said wick which is
spaced from the surface of said liquid to prevent ignition thereof
during use. Advantageously, said combustible liquid is coloured by
the incorporation of a light-stable colouring matter such as one or
more dyes therein, the colour of the liquid being chosen, for
example, in relation to the colour of the flame produced when the
liquid candle is burned so as to provide an attractive
combination.
Surprisingly, it has been found that liquid candles can be formed
in accordance with the invention which are pleasing in appearance
and which burn with an intense, attractively coloured flame having
none of the disadvantages hitherto associated with the known,
so-called coloured flame candles. By employing alcohols of high
flash point as the basis of the combustible liquids, the liquids
can be stored easily under conditions in which they remain stable
until required for use; and an attractive, safe candle-like device
can be formed by pouring the liquid into an open-top, glass or
transparent plastics container and floating the wick holder on the
surface of the liquid. The novel and attractive appearance of such
a liquid candle, coupled with its safety and high functional
efficiency in operation, constitutes an important advance in the
candle-manufacturing art and enables the latter to meet the large
demand for coloured flame candles which has existed for many
years.
The open-top containers used in forming liquid candles in
accordance with the invention can be of any suitable size or shape
as dictated by appearance considerations, and, whilst containers of
transparent or translucent plastics material can be used, glass
containers are preferred. The wick holder can also be of any
suitable size or shape, and it can comprise a float of tray - or
cup-like form, for example, of circular shape, having a central,
upstanding tubular portion through which the wick passes and within
which the upper part of the wick is held, which can be floated on
the surface of the combustible liquid either way up depending on
its shape.
The combustible liquid used in carrying out the present invention
contains in solution an appropriate amount of one or more additives
which render it capable of burning on a wick with a coloured flame.
In addition the liquid has the following critical
characteristics:
1. A high flash point which renders the liquid safe to use in a
liquid candle under any normal ambient temperature conditions
likely to be encountered by users, the term "high flash point"
being defined herein as a flash point which is such that the liquid
does not ignite and burn when a small flame is applied directly
(i.e., in the absence of a wick) to a body of said liquid under
said ambient temperature conditions. In practice, a minimum flash
point (open cup) of 100.degree. C provides ample safeguards in this
respect, and accordingly liquids having a minimum flash point (open
cup) of 100.degree. are preferred. 2. An ability to burn on a wick
with free burning characteristics. The latter is a term well
understood in the art, but to avoid any misunderstanding the term
is used herein to mean an ability to continue burning for at least
one-half hour from initial ignition.
By forming said combustible liquid from an alcohol one can ensure
that it will burn on a wick in the absence of said flame-colouring
additive(s) with a flame having no pronounced luminosity,
particularly in the yellow part of the spectrum. As will be known
by those in the art a yellow luminous emission can be difficult to
suppress completely, but unless a liquid candle capable of burning
with an intense yellow or golden flame, is desired, the combustible
material should be such that the yellow content of the flame when
it burns should be appreciably less intense than that of the flame
of a conventional hydrocarbon wax candle if a truly coloured flame
is to be obtained. Hitherto, however, no satisfactory way of
achieving this desideratum has been found which is satisfactory,
straightforward in practical application and pleasing to the
user.
DETAILED DESCRIPTION OF THE INVENTION
The liquid candles of the present invention are formed from
combustible liquids which consist of or include as the major
component thereof an alcohol of high flash point, for example,
ethylene glycol (ethane diol), glycerol, diethylene glycol,
carbital and butyl carbitol or a mixture of alcohols. Commercial
ethylene glycol sold by Shell Chemical Company has been found to be
eminently satisfactory from the point of view of performance and
cost. It is advantageous for the combustible liquid to have a
significant water tolerance before burning properties are
noticeably affected, and this is another advantage of ethylene
glycol. In fact, surprisingly, ethylene glycol has been found to
have outstanding properties as a combustible liquid for carrying
out the present invention since it combines excellent burning
characteristics on a wick with the ability to give attractive,
intensely coloured flames, and it also possesses high satisfactory
float-support characteristics which facilitate the use of a
floating wick holder as required to form the liquid candles of the
invention. Glycerol and diethylene glycol can also be used to form
acceptable liquid candles, although these liquids do not appear to
have the unique balance of properties of ethylene glycol (ethane
diol).
Any suitable liquid - soluble substances capable of imparting a
desired flame colouration may be used in carrying out the present
invention, particularly the metal salts which are known in the art
as flame-colouring additives for solid candles, provided they are
soluble in said liquid. Preferably one or more light-stables dyes
are incorporates in the combustible liquid in order to make the
liquid candle more attractive to the user, especially when it is
formed, as is preferred, with the aid of an open top glass
container for the liquid. Such dyes should, of course, be soluble
in the liquid and not all conventional candle body colourants are
suitable in this respect. Suitability can be determined readily by
simple experiment, but by way of illustration it is noted that the
dyes marketed by Williams (Hounslow) Limited of Hounslow,
Middlesex, England under the trade name "Alcovar" have been found
to be particularly suitable for use in ethylene glycol. Such dyes,
in the colours green, red and violet, can be used in concentrations
of from 0.0025 percent to 0.01 percent, by weight, depending on the
colour intensity required; and they are stable to light for long
periods and are without appreciable effect on the flame colours.
The glass container may be of any desired shape consistent with the
purpose it serves, and liquid candles formed in this way are
particularly advantageous for household decorative purposes and
like uses. The combustible liquid can also be perfumed, if desired;
any suitable perfume of acceptable cost may be used providing it is
soluble in the combustible liquid and has no deleterious affect on
the burning characteristics thereof, and does not give rise to any
objectionable end products, for example, odourwise when burned. By
way of illustration it can be mentioned that a perfume marketed by
Dragoca (Great Britain) Ltd., of Lady Lane Industrial Estate,
Hadleigh, Essex, England, under the trade designation ER 0/0098 has
given satisfactory results in ethylene glycol based combustible
liquids.
Many flame-colouring chemicals are known in the art in connection
with prior proposals for making conventional (solid) candles for
burning with a coloured flame, and the nature and characteristics
of such chemicals and the flame colourations achievable with
various metals are well known in the art. However, the use of a
combustible liquid opens up the possibility of using, as additives
in accordance with the present invention, other compounds of the
metals hitherto used, provided the selected additive (s) will
dissolve, in the concentration(s) needed, in the combustible
liquid; consequently, the present invention is in no way limited to
the use of conventional flame-colouring additives the properties of
which are necessarily dictated by the need for compatibility with
the solid candle material. The chemical(s) used in a particular
case will depend on the flame colour required, and the relative
cost and ease of handling when a choice is available. Examples
include boric acid and salts of many metals, for example, lithium,
sodium, potassium, strontium, and barium. The salts may be, for
example, acetates (which are often particularly suitable),
chlorides, nitrates, citrates, tartrates and carbonates. The
ability to dissolve the additive(s) in the liquid in the cold or
with only slight heating is advantageous. Mixtures of
flame-colouring chemicals may be used in order to produce desired
colours or novel, "two tone" affects. The concentration of the
flame-colouring chemical(s) required will depend on the particular
chemical(s) used, but can be determined readily by trial. In
general, the range of concentration is quite wide, Although from
the point of view of achieving clean burning, it is preferable to
use the smallest amount consistent with obtaining a good
colouration. Guidance in regard to the quantities of additives
which can be used will be obtained from the formulations
exemplified hereinafter. However, the following additives in the
concentration ranges quoted have been found to be particularly
effective with ethane diol for producing flame colours which are
particularly popular with users of the liquid candles of the
present invention:
Green : 1.3 to 1.7% wt. of boric acid
Red : 0.2 to 0.4% wt. of lithium acetate, preferably together with
an equal amount of potassium chloride
Lilac : 0.2 to 0.5% wt. of potassium chloride
Combustible liquids containing one or more flame-colouring
additives and optionally also one or more dyes may be supplied to
users in capped containers from which the liquid can be poured into
any suitable open-topped container of the user's choice to form,
with a floating wick holder, a liquid candle in accordance with the
invention. For asthetic appeal the capped container may be shaped,
and perhaps also textured, to look like a conventional solid
candle. A wick holder, together with a wick which is conveniently
already fitted thereto, can be supplied to the user together with
the capped container of combustible liquid, together, if desired,
with a glass open-top container. The wick holder can be of a
plastics material, for example, a urea formaldehyde resin or it can
be of metal, for example, aluminium. Whilst the size, shape and
dimensions of the holder should be such that it will float safely
on the combustible liquid, a degree of decoration is advantageous
from the appearance aspect. For example, the base of the wick
holder can be cone-shaped to some extent. Preferably, the wick
holder is made from a non-inflammable material, and aluminium is
preferred; in such case the aluminium holder can be anodised in a
variety of colours to enhance its appearance. Alternatively, the
wick holder can be made of glass. Although the wick holder can be
designed so that it can also form a cap for the container of
combustible liquid, it is considered preferable to supply separate
wick holders.
One example of a suitable form of wick holder is illustrated in the
drawing accompanying the provisional specification, in which FIG. 1
shows a perspective side view and FIG. 2 a plan view. The wick
holder comprises a float in the form of a cap 3 having an
upstanding tubular portion 4 for holding the wick 5. The base 6 of
the cap 3 to which the portion 4 is secured, or of which is forms
an integral part, as, for example, when the cap is moulded in a
plastics material, is apertured to enable the wick 5 to pass
through it. In use a short length of the wick 5 protrudes from the
tubular portion 4 to form a burning end. If the wick holder is used
as a screw cap for a container of liquid, the cap 3 is provided
with an internal screw thread, and when in use as screw cap a plug
or like seal is inserted in the cap 3 to seal off the tubular
portion 4, thereby preventing spillage of the liquid and access of
atmosphereic air (in particular moisture therefrom) to the
liquid.
A preferred form of wick holder is illustrated in FIG. 3 of the
accompanying drawing. The wick holder comprises a float in the form
of a tray 3 having a dished base portion 3A of cone shape to
enhance the appearance of the float. An upstanding tubular portion
4 is provided for holding the wick 5, and the upper end of the
tubular portion 4 is located below the level of the rim 3B of the
tray 3. Advantageously the wick holder is of anodised aluminium and
the following dimensions of a typical wick holder can be given by
way of illustration as follows: tray diameter: 11/2inches; tray
height: three-fourths inch, plus up to one-fourth inch for the
dished base portion; height of tubular portion: one-half inch; and
diameter of tubular portion: one-fourth inch (outside) and
one-eighth inch (inside).
The wick holder can be of other forms or shapes depending on
requirements. It is envisaged that one or more wick holders can be
marketed in combination with a container of combustible liquid and
an open-top glass as a presentation pack for customers.
Certain flame colouring chemicals, for example, lithium nitrate,
lithium acetate, potassium chloride and sodium chloride can produce
an accumulation of incombustible ash on the wick during burning and
the shape of the floating wick holder is advantageously such that
any material falling from the wick is caught and prevented from
coming into contact with the combustible liquid where it might act
as a secondary wick. It is also possible by simply pulling more
wick through the tubular portion of the wick holder to restore
normal burning characteristics if, after a period of burning,
accumulations on the wick, affect the performance of the liquid
candle; normally, the burning time before any retrimming is needed
will be at least one hour depending on the flame-colouring
additive(s) used, and with some additives and/or concentrations of
additives it is not really necessary at all. The optimum
combinations and concentrations of the various additives which give
the desired flame colourations with the minimum of ash formation on
the wick can be ascertained by experiment.
The wick itself can consist of conventional cotton candlewick or
taper which has not been treated with any of the wick conditioning
chemicals normally used in candle manufacture which might otherwise
introduce contaminants affecting the flame colour. (In any case
such wick conditioning would be an unnecessary in carrying out the
present invention). A loose plait or twisted taper cotton is
preferred.
Liquid candles in accordance with the present invention can be
expected to have many hours of life. For example, a 100 ml. of
combustible liquid can burn for up to about 8 hours depending on
the flame size, which can be controlled by adjusting the length of
wick showing above the tubular portion of the wick holder. In the
latter respect about one-fourth inch gives a good result. In order
to avoid a falling off in performance after a period of use due to
absorption by the combustible liquid of moisture from the air, it
is advisable to keep the glass or other open-topped container of
the candle covered when not in use.
The present invention is illustrated by the seven typical
formulations of the following examples. These are all based on
commercial ethylene glycol (ethane diol), and the specified
additives were dissolved therein in the cold or, if necessary, by
heating:
EXAMPLE 1.
ETHANE DIOL 90-99% wt. BORIC ACID 1-10% wt.
plus a green dye.
This formulation gives a bright green flame. Large amounts of boric
acid should be avoided since these tend to produce a white film on
the side of the glass after prolonged burning which looks rather
unsightly. The extent of this film depends largely on the shape of
the glass used, but a concentration of boric acid of 2 percent wt.
or less, and advantageously about 1.5 percent wt., is to be
preferred.
EXAMPLE 2
ETHANE DIOL 95-99.9% wt. LITHIUM ACETATE 0.1-5% wt.
plus a red dye.
A vivid red flame is produced. From the ash formation point of
view, it is advantageous to keep the concentration of lithium
acetate low, for example, at about 0.25 percent wt, and even better
results are obtained by using it in combination with about an equal
amount of potassium chloride. Lithium nitrate can also be used, but
in such case the concentration is also best kept low to reduce the
tendency for ash to accumulate on the wick; for example 1.0 percent
wt. has been found satisfactory.
EXAMPLE 3
ETHANE DIOL 99% wt. POTASSIUM CHLORIDE 0.5 to 1% wt., preferably
0.5% wt.
plus a lilac dye.
This formulation gives a lilac colour, which becomes increasingly
vivid after about 10 minutes burning. Ash can build up on the wick,
and the reduction in potassium chloride concentration to 0.5
percent wt. reduces this tendency while still maintaining a
satisfactory colouration.
EXAMPLE 4
ETHANE DIOL 99.9% wt. SODIUM CHLORIDE 0.1% wt.
plus an orange dye.
This formulation gives a bright golden flame. Larger amounts of
sodium chloride e.g., 0.2 percent wt. lead to more ash formation
and are best avoided.
EXAMPLE 5
ETHANE DIOL 99.2% wt. BORIC ACID 0.5% wt. LITHIUM ACETATE 0.3%
wt.
This formulation gives a flame with an orange/red interior and a
green edging.
EXAMPLE 6.
ETHANE DIOL 98.8% wt. SODIUM CHLORIDE 0.2 % wt. BORIC ACID 1.0%
wt.
This formulation gives a golden flame with a green edge.
EXAMPLE 7
ETHANE DIOL 99.5% wt. POTASSIUM CARBONATE 0.5% wt.
This formulation gives a lilac flame.
EXAMPLE 8
Similar results to those quoted above in regard to Examples 1 to 7
may be obtained by substituting for the ethane diol other alcohols
such as glycerol.
The amounts of flame-colouring additives used with such other
alcohols are essentially similar to those quoted for ethane diol,
optimum amounts within the ranges quoted being readily determined
by simple experiment on the basis of the colour and intensity of
colour required in relation to cost considerations and ease of
forming the required alcohol solutions thereof.
* * * * *