U.S. patent number 3,784,209 [Application Number 05/150,722] was granted by the patent office on 1974-01-08 for golf ball.
Invention is credited to Katharine D. Berman, administratrix, Aaron Robert Berman, deceased.
United States Patent |
3,784,209 |
Berman, deceased , et
al. |
January 8, 1974 |
GOLF BALL
Abstract
One-piece, nonhomogeneous, molded golf ball is obtained by
forming a center of an uncured elastomeric material, surrounding
the center with a compatible but different uncured elastomeric
material, and curing both elastomeric materials, such that when
said materials are cured they become integral with each other to
form an one-piece molded golf ball which is harder at its center
than at its outer surface.
Inventors: |
Berman, deceased; Aaron Robert
(late of Hatfield, PA), Berman, administratrix; Katharine D.
(King of Prussia, PA) |
Family
ID: |
22535736 |
Appl.
No.: |
05/150,722 |
Filed: |
June 7, 1971 |
Current U.S.
Class: |
473/377;
473/372 |
Current CPC
Class: |
A63B
37/0003 (20130101); A63B 37/0033 (20130101); A63B
37/0043 (20130101); A63B 37/0031 (20130101); A63B
37/0074 (20130101) |
Current International
Class: |
A63B
37/00 (20060101); A63b 037/00 (); A63b
037/12 () |
Field of
Search: |
;273/218,235,214,215,216,217,219,62 ;264/250 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Marlo; George J.
Attorney, Agent or Firm: Thomas M. Ferrill, Jr. et al.
Claims
What is claimed is:
1. A golf ball consisting of a solid center of an elastomeric
material, an elastomeric cover material compatible with said
elastomeric center material and encapsulating said center, said
elastomeric cover and center materials being in direct contacting
relationship and integrally bonded together, the structural
characteristics of the bond between said cover and center materials
corresponding to those achieved by simultaneously curing said cover
and center materials while held under pressure in direct contacting
engagement with each other, the hardness of said center being
between about 65 and about 95, the hardness of the cover material
being above about 30 and below about 65, as measured by the Shore
Hardness Test on the "D" scale, and the thickness of said softer
elastomeric cover material being between about one-sixteenth and
about three-eighths inch.
Description
BACKGROUND OF THE INVENTION
The present invention relates to a novel solid golf ball and more
particularly, to an one-piece, nonhomogeneous, molded golf ball
formed by curing two elastomeric materials such that the cured
elastomeric materials become integral and the resulting golf ball
is harder at its center than its outside surface.
The United States Golf Association (USGA) has established certain
requirements and characteristics for golf balls used in tournament
play. For example, golf balls must have a diameter greater than
1.680 inches; must weigh less than 1.620 ounces; and cannot have an
initial velocity of more than 255 feet per second, as measured on a
standard USGA golf ball testing machine. In addition to these
required characteristics, golf balls must be round and retain their
roundness even after use; must be well balanced for travel in the
air and on the ground; and must be able to withstand the rigors of
play without adverse physical effect.
For many years the wound golf ball was the standard used by all
golfers. The wound golf ball, developed by Haskell prior to 1900,
involves the laborious winding of elastic thread tightly around a
suitable core (either solid or liquid) and then enclosing the
winding within a protective cover, such as a cover of a
gutta-percha compound. The characteristics of the wound golf ball
can be controlled by suitable selection of the core, the winding
tension and the cover. Wound golf balls, however, have two major
drawbacks. They are expensive to fabricate, typically involving an
eight step process which includes: core-forming, core-filling,
thread-making, thread-winding, coverstock mixing, cap-making,
cover-pressing, and vulcanizing. The other major drawback of wound
golf balls is their tendency to be rendered unsatisfactory for
further use due to cutting and damage of the outer cover --
particularly when hit with the edge of a golf club.
In order to eliminate many of the disadvantages of the wound golf
ball, a unitary golf ball composed of a homogeneous solid was
developed. The homogeneous molded golf balls simplified the
procedure for making golf balls -- requiring only mixing,
extruding, slug forming and heat molding. Although less expensive
to manufacture, homogeneous golf balls have had the serious
disadvantage of being substantially inflexible resulting in the
golf ball fracturing when contact by a golf club is made with the
golf ball. It has been estimated that a golf club head may be
moving at a speed approximately 166 feet per second when striking a
golf ball and that the club exerts an impact as much as 1000 pounds
when the golf ball is struck.
In order to improve the playing characteristics of unitary golf
balls and eliminate the "shock" or "jolt" transmitted to the player
when contact by a golf club is made with a solid golf ball, an
attempt was made to provide a molded and cured golf ball center
with a separate cover. It was hoped that this would result in a
golf ball having a desirable combination of characteristics which
would be acceptable for tournament use. Nevertheless, in spite of
constant and continual efforts to produce a completely satisfactory
molded golf ball, none have been successfully produced. The
separately molded cover tends to fracture or separate from the golf
ball center in actual use.
SUMMARY OF THE INVENTION
It is an object of this invention to produce a novel one piece,
non-homogeneous, molded golf ball possessing improved properties
and characteristics which is cheaper to manufacture than a
conventional wound golf ball.
Another object of this invention is to provide an one-piece,
non-homogeneous, molded golf ball having characteristics
satisfactory to players while meeting the requirements necessary
for tournament use.
Still another object of this invention is to produce a
nonhomogeneous, molded solid golf ball having a center which is
harder than its cover, as determined by durometer measurements.
In accordance with the invention, I have discovered that an
one-piece, nonhomogeneous molded golf ball can be produced by (a)
forming a center of uncured elastomeric material (center material),
(b) providing a cover for the center material of a compatible
uncured elastomeric material (cover material), (c) enclosing the
two elastomeric materials (center and cover materials) in a mold,
and (d) curing both elastomeric materials in a single operation
whereby the elastomeric materials become integral with each other
to form an one-piece, molded golf ball which has a center which is
harder than the cover, as determined by durometer measurements.
While the compositions of each of the two elastomeric materials can
be different, normally the compositions are composed of varying
amounts of the same elastomer, copolymerizable monomer,
polymerization initiator and filler. Heat, with pressure, is used
to cure the elastomeric compositions into the form of a golf
ball.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The elastomers which may be used for the center and cover of the
golf ball can be the same (provided the other ingredients are
different) or different (provided the elastomers are compatible).
Suitable elastomers include any elastomer which is capable of being
cross-linked and preferably such elastomers constitute a
homopolymer, copolymer or terpolymer of butadiene, isoprene or
chloroprene. Most preferably, the elastomer is a cisbutadiene
rubber containing at least 40 percent cis. Examples of other
elastomers which can be used, provided they have sufficient
molecular weight for the intended purpose, include chlorinated
polyethylene; olefins, such as ethylene and propylene, in the form
of homopolymers, copolymers and terpolymers; silicone rubbers;
propylene oxide polymers; butyl rubber, polysulfides; urethane
elastomers; styrene copolymerized with either acrylic or
methacrylic esters of alcohols containing at least 4 carbon atoms;
and the like.
The monomers which can be used in connection with the
aforementioned elastomers are those capable of cross-linking the
aforementioned elastomers and undergoing further polymerization.
Examples of such monomers include: vinyl, allyl, methallyl,
furfuryl, crotyl and cinnamyl esters of the following acids:
oxalic, malonic, succinic, glutaric, adipic, pimelic, suberic,
azelaic, sebacic, maleic, itaconic, citraconic, mesaconic,
furmaric, aconitic, phthalic, isophthalic, terephthalic,
naphthalic, dicarboxylic, mellitic, pyromellitic, trimesic,
acrylic, methacrylic, cinnamic and crotonic. Also suitable are
polyamine amides and imides of the following acids: maleic,
itaconic, acrylic, methacrylic, crotonic, citaconic, aconitic and
cinnamic; polyol esters and anhydrides of acrylic, methacrylic,
crotonic and cinnamic acids. Other suitable materials include di-
and triallyl cyanurate; di- and triallylmelamine, divinyl benzene;
diallyl benzene; diallyl amine; allyl ether; allyl gycolates; di-,
tri and tetravinyl and allyl silanes. Still further suitable
materials are low molecular weight reactive monomers of butadiene,
isoprene, chloroprene and epoxidized derivatives of these
materials. The diacrylates and dimethacrylates, as for example
butylene glycol dimethacrylate, are preferable though divinyl
compounds, such as divinyl benzene, are also highly suitable.
The amount of the monomer must be at least 20 percent by weight of
the elastomer in order to obtain the necessary degree of
cross-linking to form the required three dimensional molecular
network and to give the ball its characteristics. Amounts of the
cross-linking monomer used in the elastomeric composition in the
center of the golf ball, as high as 90 percent by weight of the
elastomer, may be used, but amounts between about 30 and 60 percent
by weight of the elastomer are preferred. The amount of monomer
used in the elastomeric composition at the outer surface of the
golf ball may be as high as 80 percent by weight of the elastomer,
but amounts between about 35 and 70 percent by weight of the
elastomer are preferred.
Any known or conventional filler may be used to reinforce the
elastomeric compositions. The filler should be in finely divided
form, as for example in a form between about +20 and -325 and
preferably +60 and -325 mesh U. S. Standard screen size. Most
preferably the filler material is in the form of a silica or
silicate as fillers. In addition to silica and silicate fillers,
such as finely divided porous SiO.sub.2, alkali metal silicates,
such as calcium silicate; and the like, and other fillers in
addition or in place of the silica, or silicates, such as carbon
black, cork, titania, cotton flock, cellulose flock, leather fiber,
plastic fiber, plastic flour, leather flour; fibrous fillers, such
as asbestos, glass, and synthetic fibers, metal oxides, carbonates,
and talc can be used.
The amount of the filler material is dictated by its type and the
type of the other constituents and may vary between about 20 and 90
percent by weight of the elastomer, and preferably 30 and 70
percent of the elastomer. A lesser amount of filler can be used for
the elastomeric composition of the outer portion of the golf
ball.
The polymerization initiator may be any known or conventional
initiator capable of causing the monomer to polymerize and
cross-link. Generally, these initiators are of the free radical
type, such as a peroxide, persulfate, azo compounds hydrozines,
amine oxides, and the like. Peroxides, such as dicumyl peroxide and
other commercially available peroxides conventionally used as
polymerization catalysts may be most conveniently used.
The polymerization initiator need only be present in the catalytic
amount required for this function and may be in general used in the
amounts that the particular agent is generally used as a
polymerization catalyst. In connection with peroxides, the same,
for example, may be used in amounts of about 0.2 - 10 percent by
weight of the elastomer.
When using the preferred components, the best results are obtained
with compositions having 100 parts by weight of the cis-butadiene
rubber and approximately 20 - 80 parts by weight of methacrylate
ester and 30 - 60 parts by weight of filler.
Once the ingredients for each of the elastomeric materials have
been selected, the ingredients for each elastomeric material are
separately and intimately mixed together using conventional means,
such as a Banbury mixer, until reasonably uniform compositions are
obtained. The temperature of mixing is not critical, provided it is
maintained below the curing temperature of the elastomeric
materials. Normally, the uncured compatible elastomeric material,
which is to provide the outer surface of the golf ball, is placed
around the inner uncured elastomeric material and the elastomeric
materials are then placed in the mold.
Molding is effectd in mating precision hemisphere molds or dies
whose molding surfaces are covered with multiple regular
projections to give the molded golf balls conventional dimpled or
waffled surface appearance for desired aerodynamic characteristics.
By preportioning the material placed in the mold, the mold is fully
filled when the mating halves of the mold are closed. The mold
halves are then held together with a pressure above 100 pounds per
square inch and preferably in the range of 300 to 1,000 psi. The
molding temperature may vary, depending on the various compositions
used, but is normally between about 200.degree. and about
400.degree. F. The molding temperature is selected to be sufficient
to cure both the uncured elastomeric material in the center of the
golf ball and the uncured compatible elastomeric material which
surrounds the center. The nature of the elastomeric materials in
the mold and the molding temperatures are so selected that both
uncured elastomeric materials cure almost simultaneously, thereby
forming an one-piece, molded, solid golf ball having a center which
is harder than its outside surface as determined using a durometer.
Optimum results are obtained in the neighborhood of 320.degree. F.,
with a molding time of between ten and twenty minutes. While there
is no real upper limitation on the length of the curing time, the
molding should be effected until both elastomeric compositions are
substantially completely cured. In general, curing times may range
between about 2 and 60 minutes and preferably between about 4 and
30 minutes. Higher temperatures, i.e., temperatures above about
400.degree. F. may be used, but are generally unnecessary and
undesirable.
After the molding operation is complete, the golf ball is removed
from the mold. Any mold mark, where the molds mate, may be removed
by suitable means such as buffing and the golf ball is then painted
and marked. Painting may be effected in the conventional manner
using paint such as enamel, polyurethane, epoxy, acrylic or vinyl
paints.
The finished golf ball is characterized by a diameter between 1.680
and 1.685 inches in diameter; a weight controlled between 1.600 and
1.620 ounces; a roundness within at least 0.01 inch; and a density
within the range of 1.11 and 1.13. The hardness of the golf ball at
its center is between about 65 and about 95 and above about 30 and
below about 65 at the surface of the golf ball, as measured by the
Shore durometer on the "D" scale which runs from 0 for full
extension to 100 for zero extension of the calibrated spring
measuring instrument. Suitable Shore durometers are illustrated in
the 1968 Vanderbilt Handbook at pages 307 and 308. The compression,
as measured on a standard golf ball compression test machine, is
between 40 and 150 points and the golf balls bounce between about
60 and 75 percent of the height from which they are dropped in
accordance with the Standard Bounce Test.
The invention will be further illustrated by the following specific
examples, it being understood that there is no intention to be
necessarily limited by any details thereof since variations can be
made within the scope of the invention.
EXAMPLE 1
A suitable composition for the uncured elastomeric material used in
the center of the golf ball constitutes 100 parts by weight of
cisbutadiene, 62.5 parts by weight of butylene glycol
dimethacrylate, 62.5 parts by weight of fine silica filler and 3.13
parts by weight of dicumyl peroxide. The ingredients are mixed
thoroughly at room temperature until the resulting material is
completely homogeneous. The material (composition 1) is then formed
into spherical shape of suitable size.
The compatible uncured elastomeric material is also formed from a
composition containing 100 parts by weight of cisbutadiene polymer,
40 parts by weight of divinyl benzene, 65 parts by weight of fine
silica filler and 3.13 parts by weight of dicumyl peroxide. These
ingredients are mixed at room temperature until completely
homogeneous. The resulting material (composition 2) is then placed
around the spherical shaped uncured elastomeric material of
composition 1 as a substantially uniform layer and both
compositions are placed into a precision hemisphere mold.
Molding is effected at pressure of 150 psi and a mold temperature
of 300.degree. F. for a molding time of ten minutes. This curing
operation simultaneously cures both uncured elastomeric
compositions to obtain an one-piece, nonhomogeneous, molded golf
ball having a hardness at the center of about 70 and a hardness on
the outer surface of about 45, as determined by Shore Hardness Test
on the "D" scale.
After the golf ball is removed from the mold and the thin fin or
flash from the mold is buffed off, the golf ball is painted and
marked.
EXAMPLE II
Composition 3
A suitable composition for the uncured elastomeric material used as
the center of the golf ball constitutes 100 parts by weight of
cisbutadiene, 62.5 parts by weight of divinyl benzene, 37.5 parts
by weight of fine silica, 6.2 parts by weight of cork, having a
particle size below 60 mesh and 3.13 parts by weight of dicumyl
peroxide. These ingredients are mixed until the resulting
composition (composition 3) is homogeneous.
Composition 4
The compatible uncured elastomeric material comprises 100 parts by
weight of cispolybutadiene, 50 parts by weight of diallyl benzene,
43 parts by weight of calcium silicate, and 2.95 parts by weight of
dicumyl peroxide. These ingredients are thoroughly mixed until the
resulting mixture (composition 4) is homogeneous.
Composition 4 is coated inside the surface of a mating precision
hemisphere mold while composition 3 is placed in the center of the
hemisphere mold. The mold is then closed and curing is effected at
a pressure of 130 psi at a mold temperature of 300.degree. F. which
is maintained for 12 minutes. The resulting golf ball is removed
from the mold and after buffing off the thin fin, the golf ball is
painted.
As an alternative to painting the golf balls, pigments (e.g.,
white, yellow, etc.) may be incorporated into the compatible
uncured elastomeric material (composition 4) prior to molding.
Thus, the resulting golf ball can be made perfectly white and thus
does not have to be painted. This whiteness is permanent and the
appearance is entirely adequate for use on practice ranges and
other non-tournament play. Titanium dioxide is the preferred white
pigment although other white pigments, such as barium sulphate,
zinc sulfide, barium carbonate, etc., may be used. The amount of
the white pigment should be different to give the molded ball its
desired white appearance and in general amounts varying between 2
and 30 percent by weight of the total golf ball can be used.
Obviously, other ingredients which are compatible with the
elastomeric materials employed to make the golf balls can be
included to the extent that the overall characteristics of the golf
ball are not adversely affected. Such other ingredients can
include, for example, limited amounts of a plasticizer.
The thickness of the outer surface, having a hardness which is less
than the center of the golf ball, normally will be greater than
about one-sixteenth inch and less than about three-eighths
inch.
The elastomeric materials can be placed in the curing mold either
separately or together, provided both are cured together.
From the foregoing, it will be seen that this invention is well
adapted to obtain all of the ends and objects hereinabove set
forth, together with other advantages which are obvious and which
are inherent therein. The golf balls produced in accordance with
the present invention are manufactured more easily and more cheaply
than conventional wound golf balls. Moreover, golf balls
manufactured in accordance with the present invention may be marked
by simply stamping with a flat die. The golf balls are abrasive
resistant and have an almost infinite shelf life. Due to their
one-piece construction, they will not waterlog and they have a
superior texture and appearance. If the paint on the golf ball
becomes worn or damaged, the golf ball may simply be reclaimed by
removing the old paint and repainting the golf ball.
Like the best conventionally wound golf balls, the golf balls made
in accordance with the present invention have all of the desirable
play characteristics, including a good "click" and excellent feel
when the golf balls are hit with a golf club. In contrast to the
homogeneous, unitary golf ball, the shock obtained when the
nonhomogeneous golf ball is struck is virtually eliminated. Unlike
covered wound golf balls, the golf balls of the present invention
are so highly resistant to cutting that they may, for all practical
purposes, be considered cut proof and indestructible in play. Like
the homogeneous unitary golf ball, the golf balls in the present
invention have a perfect center of gravity, excellent aerodynamic
properties and superior roll characteristics. Thus, the golf balls
of the present invention combine the advantageous characteristics
of both the conventionally wound balls and the homogeneous unitary
golf balls without the objectionable drawbacks of either type of
golf ball.
Obviously, many other modifications and variations of the invention
as hereinbefore set forth may be made without departing from the
spirit and scope thereof.
* * * * *