U.S. patent number 3,780,305 [Application Number 05/305,073] was granted by the patent office on 1973-12-18 for apparatus for treating wood chips with electrons.
This patent grant is currently assigned to Radiation Development Co., Ltd.. Invention is credited to David Free.
United States Patent |
3,780,305 |
Free |
December 18, 1973 |
APPARATUS FOR TREATING WOOD CHIPS WITH ELECTRONS
Abstract
Apparatus for irradiating wood chips with electrons includes
electron generator with means to inject electrons into conduit
through which chips are pneumatically conveyed.
Inventors: |
Free; David (West Vancouver,
CA) |
Assignee: |
Radiation Development Co., Ltd.
(Vancouver, British Columbia, CA)
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Family
ID: |
23179209 |
Appl.
No.: |
05/305,073 |
Filed: |
November 9, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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93060 |
Nov 27, 1970 |
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Current U.S.
Class: |
250/400; 250/435;
250/492.1; 250/492.3; 976/DIG.442; 250/398 |
Current CPC
Class: |
H01J
33/00 (20130101); G21K 5/04 (20130101) |
Current International
Class: |
G21K
5/04 (20060101); H01J 33/00 (20060101); H01j
037/30 () |
Field of
Search: |
;250/396,398,400,435,492 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Lindquist; William F.
Parent Case Text
RELATED APPLICATIONS
This application is a continuation-in-part of application Ser. No.
93,060, filed Nov. 27, 1970, now abandoned.
Claims
I claim:
1. Apparatus for treating wood chips with electrons comprising
a pneumatic conveying system for conveying said wood chips
including a conduit of substantially uniform cross-section and
means for propelling air and wood chips therethrough, at a velocity
such as to cause chips to tumble and change elevation in said
conduit as they are carried therethrough,
and means for injecting high energy electrons into a straight
section of said conduit free of obstruction over a substantially
length sufficient to enable chips to tumble and migrate
substantially throughout the cross-section of said conduit section
whereby all surfaces of said chips will be exposed to irradiation
by said electrons and accumulate the required dosage from the
various energy levels of the injected electrons in said conduit
substantially uniformly over all the chips and over each chip.
2. Apparatus for treating wood chips with electrons comprising:
means for creating a beam of high energy electrons,
cycling means for causing said beam to reciprocate in a linear
path,
a pneumatic conveying system for conveying said wood chips
including a conduit section free of obstruction having its axis
coincident to said linear path and an electron transparent window
in said path and means for propelling air and wood chips through
said conduit section at a velocity such as to cause chips to tumble
and migrate throughout the cross-section of said conduit section so
that all surfaces of said chips will be substantially uniformly
exposed to said electron beam.
3. Apparatus as set forth in claim 2 wherein said conduit section
has side walls substantially coincident with the effective side
edges of said beam.
4. Apparatus as set forth in claim 2 wherein said conduit section
is trapezoidal in cross-section.
5. Apparatus as set forth in claim 4 wherein said conduit section
is of uniform cross-sectional area throughout its length, and said
pneumatic system comprises a conduit means of cross-sectional area
substantially equal to the area of said conduit section connected
to the inlet end of said section whereby the chips maintain a
substantial uniform velocity through said section.
6. The apparatus of claim 2 wherein said conduit section is of a
length of about 12 feet and said cycling means is adapted to cause
said beam to sweep through substantially the entire length of said
conduit section.
7. In apparatus for treating wood chips with electrons the
combination comprising:
means defining an evacuated chamber,
means for creating a beam of high energy electrons at one end of
said chamber and directing said beam toward the opposite end,
means to cause said beam to reciprocate in a linear path at said
opposite end,
electron permeable window means in said opposite end of said
chamber to permit emergence of electrons therefrom,
a conduit section adjacent said chamber opposite end having its
axis coincident with the axis of said path,
said conduit section being trapezoidal in cross-section with the
side walls of said section substantially coincident with the
effective side edges of said electron beam,
the top wall of said conduit section comprising electron permeable
window means so as to permit entry of said beam into said conduit
section,
and means for pneumatically conveying wood chips through said
conduit section at a high velocity whereby the wood chips will
tumble and migrate throughout the cross-section of said conduit
section exposing all surfaces of said chips to bombardment by said
electrons and to electrons of various energy levels whereby said
chips will receive substantially uniform dosage.
Description
BACKGROUND OF THE INVENTION
In the making of pulp from wood a conventional procedure involves
the cutting of the wood into oblong chips about three-quarters of
an inch square and one-eighth of an inch thick. A pulp mill may
chip wood on its own premises but frequently purchases chips that
are manufactured at other sites such as at sawmills from scrap
pieces, and other residue material accumulating at the mill. It is
not generally possible to place the chips into processing
immediately as they are produced or received, and at most pulp
mills large storage piles of chips are maintained. During storage,
chips usually undergo deterioration in one form or another. In some
instances chips develop fungi growth that causes discoloration of
the chips and the resulting pulp and pulp product, and other
cellular breakdowns occur that decrease the ultimate yield of pulp
and thus paper or other products from the chips. Depending upon the
length of storage this can result in from 5 to 20 per cent loss by
weight.
Efforts have been made to devise methods of sterilizing chips so as
to kill bacteria and fungi which cause chip deterioration, but
economically feasible and practically acceptable systems of chip
treatment have not heretofore been developed.
SUMMARY OF THE INVENTION
In accordance with the subject invention, wood chips are
pneumatically conveyed through a specially shaped conduit through
which electrons are passed transversely so as to impinge upon the
chips as they move through the conduit. The chips are conveyed
through the conduit under conditions assuring that essentially all
surfaces of the chips are exposed to the electrons to effect
irradiation and thus sterilization of all surface and some
subsurface portions. By sterilizing the chips in such manner the
sterilization can be carried out as chips are conventionally
pneumatically conveyed from the chip producing mechanism or from
their point of receipt to the chip storage pile, but assuring
complete exposure of all surface portions to the electrons in an
economically feasible manner.
In addition to enhancing the storage life of the chips and
minimizing breakdown of the chips from bacteria, fungi, and like
micro-organisma, it has been further discovered that the electron
bombardment of the chips, if carried out at certain levels, enables
the processing, that is, cooking time, of the chips to be
substantially reduced and increase the amount of pulp producible
from a given quantity of chips with betterment of its physical
properties.
DRAWINGS
FIG. 1 is a side elevation of an apparatus for carrying out the
invention;
FIG. 2 is a cross-sectional view taken along line 2--2 of FIG. 1;
and,
FIG. 3 is a cross-sectional view taken along line 3--3 of FIG.
1.
Referring to the drawings, indicated at 10 is a pipeline or conduit
forming a portion of a pneumatic system through which wood chips
are being conveyed. Conventionally, such pipelines are circular in
cross-section being on average 6 to 24 inches in diameter, and wood
chips are conventionally carried in an air stream having a velocity
of about 6,000 feet per minute. In such conveying systems the wood
chips are evenly dispersed in the conveying air stream as opposed
to being layered as in belt conveyors and the like. In accordance
with the illustrated embodiment of the present invention, the
conveying system is provided with a conduit section 12 that is
essentially of trapezoidal cross-section but which has a
cross-sectional area substantially equal to that of the pipeline
10. A suitable transition 14 is provided at either end of the
section 12 so as to permit its connection within the line 10. For
purposes to be made apparent, section 12 preferably has a length of
6 to 12 feet.
Means are provided to effect exposure of the wood chips in the
section 12 to high energy electrons. The illustrated means
comprises a suitable source of high energy electrons 18 capable of
producing a narrow beam of high speed electrons, the energy of
which should be in the order of several hundred thousand volts. The
generator may be of the VAN de GRAFF type or any other suitable
type.
The electron beam generated by the source 18 in the scanner system
illustrated is projected downwardly into a scanner 20 which is
provided with means to cause the beam to reciprocate in a linear
path having its axis coincident to the axis of the conduit section
12. The cycling frequency of the electron beam is preferably
several hundreds to thousands of cycles per second. The deflection
of the beam may be obtained by any conventional means such as by
magnetic means or by electrostatically operating deflecting means,
all of which are well known to the art. The scanner 20 comprises an
evacuated chamber defined by vertical parallel sidewalls 24, 26 and
inclined end walls 28, 30. The bottom wall 32 of the scanner is
preferably formed of titanium or other material providing low
resistance to the passage of electrons therethrough but resistant
to temperature effects caused by the electron bombardment.
Likewise, the top wall 34 of the pipe section 12 is formed of
titanium or other easily electron penetrable material. The space
between walls 32, 34 is washed with air in order to provide cooling
of wall 32. The double effect of walls 32, 34 and the intervening
space provide additional protection to the evacuated area of the
scanner 20. An alarm or shut-down device (not shown) may be
provided to indicate any rupture in the wall 34, which will be
indicated by increase in pressure in the chamber 36, and to prevent
damage to wall 32 and contamination of the scanner chamber.
Preferably a suitable screen is provided beneath the wall 34 to
protect such wall from chip impingement and air may be injected
into the space between such screen and wall 34 by nozzles
positioned along conduit section 12 to wash the screen of chips and
provide additional cooling to wall 34.
In place of a scanner type beam source any other suitable electron
source may be utilized which will provide a flux of electrons
transversely of the conduit section 12 so as to enable complete
exposure of chip surfaces at sufficiently high dosages. For
example, a source which will provide a steady or pulsed curtain of
electrons extending the length of the conduit section 12 may be
utilized.
After entrance into the conduit the electron beam of whichever type
used will spread latterly by reason of the repulsive force between
electrons and the scattering resulting from impact with air
molecules to form a diverging beam. The trapezoidal configuration
of the pipe section 12 is selected so that the side walls 38, 40
are substantially coincident with the effective side edges of the
electron beam so as to obtain substantially uniform coverage across
the entire width of the conduit section 12. As the wood chips pass
along the conduit section 12, due to the "magnus" effect on the
flat chip surfaces they will continually tumble and change
elevation across the pipe section. In a six-foot length of travel
the wood chip will ordinarily rotate and change elevation about six
times when conveyed in an air stream having a velocity of about
6,000 ft. per minute. As will be apparent at the high oscillation
frequency of a scanned electron beam a chip will be exposed to the
beam a multitude of times during the course of travel through the
section 12 to assure that all surfaces of the chip will be exposed
to electron bombardment. The radiation intensity is controlled such
that with the velocity and attitude variations of the chips, the
chips accumulate sufficient irradiation over all surfaces to attain
the desired sterilization or other effect, which in most instances
is thought to be between 0.1 and 0.5 megarads.
The energy level of irradiation required for treatment of wood
chips in accordance with the invention necessitates that the
irradiation be applied over a relatively large area. One
requirement is imposed by limitations of the window through which
the irradiation must pass. The energy must be spread out over a
large area of the window to prevent overheating. More importantly
the irradiation must be applied over an elongated area in order to
permit the wood chip which is being irradiated to sufficiently
change in attitude and position so as to expose all surfaces of the
chip to the desired amount of irradiation as it travels through the
conduit section. Thus, as a practical matter the irradiation must
be supplied to the conduit in an area of application that is
rectangular in configuration when viewed in a direction normal to
the axis of the conduit. The length of application should be a
minimum of about six feet to permit complete exposure of all
surfaces of the chip where complete exposure of chips is desired on
all surfaces. Experience has indicated that a length of travel of
12 feet is adequate where the air velocity is 100 feet per second
in a conduit section having a cross-sectional area slightly greater
than 1 square foot. If another type of source is utilized, the
source intensity and conveying conditions are adjusted so as to
attain the desired uniform exposure level over the entire chip.
In order to obtain the required dosage on all surfaces of a chip
without disrupting the pneumatic conveying characteristics of a
system or reducing the conveying air velocity, it is necessary to
convey the chips through an irradiating conduit section which does
not depart too much in configuration from that of the conveying
pipe.
The pipe section 12 is preferably surrounded by a housing 44
defining a chamber 46 through which water or other coolant fluid
may be circulated to prevent overheating of the section 12 as a
result of the electron bombardment.
Because of the fact that essentially all surfaces of the chips are
exposed to radiation by their dispersion and tumbling in their
passage through the section 12, the source of electrons 18 can be
of much lesser intensity than if attempts were made to treat the
chips by bombardment only from one side, such as by treating them
on a belt conveyor or the like. In the latter case the intensity of
the source would have to be such as to permit penetration of the
layered chips by the electrons.
It has been found that treatment of chips by electron bombardment
substantially increases the storage life of the chips or, putting
it conversely, the deterioration of chips over a given length of
time is materially reduced.
Perhaps more importantly, it has been discovered that irradiation
of wood chips improves the pulp obtained from the chips in quality
and yield. It has been found, for example, that the pulp freeness
is substantially increased but that the strength of the pulp is
maintained or increased. It has also been found that the lignin
content of the pulp may be higher. This can reduce the necessary
pulping time and, of course, reduces the amount of lignin that has
to be disposed of, while at the same time increasing the strength
properties and the yield of pulp obtained from a given amount of
wood chips.
EXAMPLE
The effectiveness of a system such as has been described herein for
substantially achieving uniform irradiation of wood chips is shown
in the following example.
A pneumatic conveying system having a fourteen inch diameter pipe
supplied with air at a rate to cause air to pass through the system
at 100 feet per second and convey wood chips therethrough at a
velocity of about eighty feet per second was utilized. Mill run
Douglas fir chips were conveyed through such a system and through a
pipe section having a trapezoidal cross-section similar to that
shown in FIG. 3 of the application and of 12 feet in length. An
electron source was provided for irradiating wood chips passing
through such section, the source having a potential of 500
kilovolts and a beam current of 200 milliamps which was swept along
the length of the pipe section at 100 cycles per second. To measure
the dosimetry amberperspex dosimeters were inserted in the pipeline
at a point forward of the irradiation section so as to pass
therethrough together with the wood chips which were being conveyed
in the line. These dosimeters were 3/4 .times. 1/4 .times. 1/8 inch
or approximately the size of wood chips although they were of
slightly greater density. After passing through the equipment, the
dosimeters were collected and the dosage received by each dosimeter
analyzed and recorded. The dosage distribution is shown in the
table below.
TABLE
Dosage Number (Megarads) Dosimeters 0 1 .05 0 .10 3 .11 0 .12 8 .13
7 .14 23 .15 24 .16 13 .17 4 .18 1 .19 2 .20 0 .21 3 .22 0 .23 1
.24 2 .31 1 .34 1
If chips were to be conveyed through a line with relatively uniform
distribution across the cross-section, but without the tumbling and
migration that is a part of the process of the present invention,
the distribution of dosage would not be substantially uniform
around the medium level in the manner obtained herein but a
majority of the particles would receive little (i.e. less than 0.1
Megarads dosage) or no irradiation, while only a small number would
acquire irradiation at medium and high levels because of the
isodose profile that occurs within the pipeline relative to its
cross section. A relatively high energy level of irradiation is
present at the entrance of the beam to the pipeline, but the energy
level rapidly falls off as the beam spreads out within the
pipeline.
Having illustrated and described a preferred embodiment of the
invention it should be apparent to those skilled in the art that it
permits of modification in arrangement and detail.
* * * * *