U.S. patent number 3,778,654 [Application Number 05/303,015] was granted by the patent office on 1973-12-11 for molybdenum alloy target for mammographic usage in x-ray tubes.
This patent grant is currently assigned to General Electric Company. Invention is credited to Frank Bernstein, Robert E. Hueschen.
United States Patent |
3,778,654 |
Hueschen , et al. |
December 11, 1973 |
MOLYBDENUM ALLOY TARGET FOR MAMMOGRAPHIC USAGE IN X-RAY TUBES
Abstract
Low temperature ductility and high temperature strength of a
molybdenum target for X-ray tubes employed in mammographic
applications is achieved by alloying molybdenum with tungsten. The
alloy target provides the necessary characteristic radiation of
molybdenum while maintaining exceptional resistance to surface
fracture and radiation output degradation under the required
exposure condition for mammography.
Inventors: |
Hueschen; Robert E. (Hales
Corners, WI), Bernstein; Frank (Milwaukee, WI) |
Assignee: |
General Electric Company
(Milwaukee, WI)
|
Family
ID: |
23170203 |
Appl.
No.: |
05/303,015 |
Filed: |
November 2, 1972 |
Current U.S.
Class: |
378/125; 378/144;
378/37 |
Current CPC
Class: |
H01J
35/10 (20130101); C22C 27/04 (20130101) |
Current International
Class: |
C22C
27/04 (20060101); H01J 35/10 (20060101); H01J
35/00 (20060101); C22C 27/00 (20060101); H01j
035/10 () |
Field of
Search: |
;313/60,330 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lake; Roy
Assistant Examiner: Hostetter; Darwin R.
Claims
We claim:
1. An X-ray tube anode wherein at least the target of said anode
comprises an alloy of molybdenum and from about 5 to about 35
percent of tungsten.
2. An X-ray tube anode as in claim 1 wherein the alloy comprises
about 70 percent molybdenum and about 30 percent tungsten.
3. An X-ray tube anode as in claim 1 wherein said anode is a
rotating anode.
4. An X-ray tube anode as in claim 3 wherein said rotating anode
consists essentially of an alloy of molybdenum with from about 5 to
about 35 percent of tungsten.
5. An X-ray tube anode of claim 4 wherein said anode consists
essentially of about 70 percent molybdenum and 30 percent
tungsten.
6. In an X-ray tube adopted for mammographic applications having a
rotary metallic anode body with an exposed target area and electron
beam means for producing an electron beam impinging on said target
area thereby producing X-ray emission, the improvement comprising
said anode body having at least the target area comprising an alloy
of molybdenum and from about 5 to about 35 percent tungsten.
7. In an X-ray tube as in claim 6 wherein the alloy comprises about
70 percent molybdenum and about 30 percent tungsten.
8. In an X-ray tube as in claim 6 wherein the anode consists
essentially of an alloy of molybdenum with from about 5 to about 35
percent of tungsten.
9. In an X-ray tube as in claim 8 wherein said alloy consists
essentially of about 70 percent molybdenum and 30 percent tungsten.
Description
BACKGROUND OF THE INVENTION
This invention relates to mammography. More specifically, this
invention relates to the X-ray tube and the anode therein employed
in mammography.
The amount of tissue through which X-rays pass is generally much
smaller with respect to the female breast compared to other parts
of the body. Since there is no bone in the breast, it is not
required, nor is it desirable to employ as high an energy beam to
penetrate the breast as compared with the energy requirements for
bone tissue. Therefore, in the area of diagnostic mammography, it
is generally desirable to employ lower kilovoltages as compared to
ordinary diagnostic X-ray techniques. The use of lower energy
provides for greater contrast between fat and soft tissue and it is
such contrast that is needed in order to obtain an optimum
mammogram.
Most medical diagnostic X-ray techniques utilize large amounts of
"hard" radiation, i.e., X-radiation having greater penetrating
power than "soft" X-rays. For these applications, tungsten is an
ideal anode target primarily because of its high atomic number and
melting point. However, to obtain this hard radiation and excite
the characteristic K.alpha. and K.beta. lines for tungsten requires
a minimum of 70 kilovolts.
Mammography, however, as a special medical diagnostic technique,
requires special techniques in exposure, exposure time and
exceptional X-ray film quality and detail. The employment of lower
kilovoltages is one means of achieving the fine film quality and
details required in mammography. By employing hard X-radiation the
diagnostic quality of exposed film is seriously reduced because of
a costly reduction in contrast.
The continuous and characteristic X-ray spectra for most metals and
materials is well known. The characteristic lines of a target
material are excited at some minimum kilovoltage. The kilovoltage
required to produce the characteristic spectra changes regularly
with the atomic number of the metal. As compared with the
characteristic tungsten K.alpha. line, the characteristic
molybdenum K.alpha. line is excited at a minimum of 20
kilovolts.
It can readily be realized therefore that there is a decided
advantage in using molybdenum instead of tungsten with reference to
mammography, since at lower kilovoltages one obtains the intense
characteristic molybdenum radiation which is not obtainable with
tungsten.
In accordance with mammographic techniques, it is generally
required to employ a relatively high number of milliampere-seconds
(mas) per exposure. Depending on the breast size, the mas employed
can vary from about several hundred mas to over 1,000 mas. In
consideration of the high milliampere-second values, it is
generally most desirable to operate the X-ray tube at maximum
current in order to maintain the exposure times to the patient as
low as possible.
Because of the high mas which is employed in mammography, severe
mechanical stresses are imposed on the electron track surface of a
molybdenum target. These mechanical stresses result in surface
fractures in the focal track of the target area. Distortion of the
target surface caused by the fracturing results in a marked
decrease of X-radiation output intensity because the probability of
an X-ray photon escaping from the target is markedly less for a
rough target surface than for a smooth surface. The susceptibility
of a molybdenum target to surface fracturing in the focal track
area is greater than that of tungsten.
Metallurgists have been trying to solve the surface fracturing
problem for X-ray targets and the like by various means. In U.S.
Pat. No. 3,650,846 of Holland and Hueschen, a process is described
for reconstituting the grain structure of refractory metals whereby
the ductile-to-brittle transition temperature is reduced thereby
reducing the tendency of the surface fracture under mechanical
stresses as caused by the use of high mas and the like.
Because of the benefits obtained through the employment of a
molybdenum target with respect to mammography, the art would be
greatly advanced if additional techniques are discovered for
expanding the useful lifetime of molybdenum targets.
SUMMARY OF THE INVENTION
A primary object of the present invention is to provide an X-ray
target substantially comprising molybdenum, this target having
superior properties with respect to withstanding mechanical stress
from high energy impinging electrons. More specifically, it is an
object to provide an X-ray anode which is an alloy of molybdenum
and tungsten. Upon being subjected to low voltage techniques, the
alloy will yield the continuous and characteristic X-ray spectra
for molybdenum. The alloy unexpectedly and advantageously has
improved properties with respect to low temperature ductility,
resistance to thermal fatigue and increased high temperature
strength as compared to a pure molybdenum target.
It is a further object to provide an X-ray anode comprising an
alloy of molybdenum and tungsten. The alloy is a solid solution
having superior strength compared to molybdenum at room
temperatures and at elevated temperatures. The grain size is
smaller as compared to pure molybdenum and the atoms of the alloy
are in clusters in the solid solution rather than in short range
atom order.
Solid solution strengthening is important, particularly at elevated
temperatures since the exposures required for mammography are
relatively long. This strengthening causes the anode to be more
resistant to high thermal fatigue while being subjected to the
impinging of high energy electrons.
The reduction of grain size results in reduced ductile-to-brittle
transition temperature thereby providing greater ductility at and
above room temperature when the electron beam first strikes the
cold anode target. For an explanation of ductile-to-brittle
transition temperature, see U.S. Pat. No. 3,650,846 issued Mar. 21,
1972. The reduction in ductile-to-brittle transition temperature
results in a significant decrease in surface fracturing of the
anode and more particularly of the target area. The inhibition of
brittle fracture is highly desirable since such fractures cause a
marked decrease in X-radiation output intensity.
Clustering of atoms is more desirable than short range order since
the alloy will evidence increased strength at high temperatures by
solute strengthening and by providing improved dislocation
mobility, and hence increased ductility at lower temperatures since
solute clustering causes removal of interstitial elements from the
matrix. That is, the increased ductility is a direct result of
decreased interstitial elements within the grains (notably carbon
and oxygen) which are known to drastically increase the
ductile-to-brittle transition temperature.
A further object of this invention is to provide an X-ray tube
adapted for mammographic application having a rotary metallic anode
body with an exposed target area and electron beam means for
producing electrons for impingement on the target area of the anode
thereby producing X-ray emission, the anode comprising the alloy
described herein.
It is a further object to provide the above improvements in an
inexpensive and economical manner.
FIG. 1 is a plot of X-ray tube output in terms of relative units
versus thousands of exposures.
FIG. 2 is also a plot of X-ray tube output in terms of relative
units versus thousands of exposures.
EXAMPLES
1. A pure molybdenum target is continuously exposed to an electron
beam so as to provide X-radiation for mammographic applications
under the following conditions: 40 peak kilovolts, 300
milliamperes, 2.5 second exposures. Two exposures are made per
minute thereby providing 60,000 heat units per minute inputs. Heat
units per minute (H) is defined as the product of the peak
kilovoltage applied across the anode and cathode (kvp), the
milliamperes (ma), the exposure time (s), and the number of
exposures per minute (n) during a life test; H = (kvp) (ma) (s)
(n).
A molybdenum-tungsten alloy target consisting essentially of 70
percent molybdenum and 30 percent tungsten is exposed under the
same conditions.
The results of the radiation data are plotted in FIG. 1. The X-ray
output data is plotted as percent to which it decreased from the
initial roentgen per minute value against the number of exposures
taken by the tube during a life test. In all instances, the data is
obtained using a 0.5 mm aluminum equivalent filter since the filter
is generally employed in all mammographic applications.
2. A pure molybdenum target is continuously exposed to an electron
beam so as to provide X-radiation for mammographic applications
under the following conditions: 40 peak kilovolts, 300
milliamperes, 2.5 second exposures. One exposure is made per minute
thereby providing 30,000 heat units per minute inputs.
A molybdenum-tungsten alloy target consisting essentially of 70
percent molybdenum and 30 percent tungsten is exposed under the
same conditions.
The results of the radiation data are plotted in FIG. 2 in the same
manner as for Example 1.
As in Example 1, a 0.5 mm aluminum equivalent filter is
employed.
Discussion of the Examples
The molybdenum target output deteriorated rapidly as shown in FIGS.
1 and 2. At the energy input of 60,000 heat units per minute (FIG.
1), the pure molybdenum target output degraded to 45 percent (line
B) of the original radiation output level after 3,500 exposures
whereas the target prepared from the molybdenum-tungsten alloy
(line A) evidenced an initial decrease to the 45 percent level
after 9,500 exposures. Upon reaching the 45 percent level, the
crack propagation or fracturing of the target material ceased and
the alloy target continued to produce useful radiation to 20,000
exposures. The molybdenum target, on the other hand, continued to
degrade until after 20,000 exposures it retained only 20 percent of
the initial radiation output level.
With respect to the targets exposed to energy inputs of 30,000 heat
units per minute (FIG. 2), the pure molybdenum target output
initially did not deteriorate as rapidly as the molybdenum target
exposed to 60,000 heat units. After 3,600 exposures (line B), the
target degraded to 60 percent of the original radiation output
level however thereafter it continued to rapidly deteriorate. The
alloy target (line A) however showed an initial decrease to the
same 60 percent level only after 12,200 exposures and thereafter
the target continued to produce useful radiation.
Upon close examination of the molybdenum targets, it was
immediately apparent that the targets were subjected to severe and
deep surface fractures in the target areas which are continuously
developed by the thermal stress of the electron beam. The decrease
in X-ray emanation is the result of those X-rays produced in the
fractured crevices and absorbed in the crevice itself thereby not
reaching the patient and film.
It is unexpectedly apparent as illustrated by FIGS. 1 and 2 that
the alloying of tungsten to molybdenum enhances low temperature
ductility while increasing the high temperature strength thereby
enhancing its mammographic applications. This is shown upon
comparison of FIGS. 1 and 2. The molybdenum target subjected to
30,000 heat units per minute deteriorated at a more constant rate
as compared to the same target subjected to 60,000 heat units per
minute. The more constant rate of deterioration of the former is
apparently the results of being subjected to greater stresses
because of the longer cooling time between exposures. The alloy
target subjected to 30,000 heat units per minute initially
deteriorated more rapidly than the alloy exposed to 60,000 heat
units per minute, however, the rate of deterioration of the former
leveled out at a higher percentage output level.
The foregoing description and the accompanying drawings pertain to
the presently preferred embodiment of the invention heretofore
disclosed. It is not intended that the invention be limited to
either that which has been shown in the accompanying drawings or
described in the specification since it will be obvious to those
skilled in the art that various changes and modifications may be
made after benefit of this disclosure. It is therefore intended
that the appended claims cover all changes and modifications
embraced within the true spirit and scope of the invention.
* * * * *