U.S. patent number 3,778,126 [Application Number 05/214,174] was granted by the patent office on 1973-12-11 for gas display panel without exhaust tube structure.
This patent grant is currently assigned to International Business Machines Corporation. Invention is credited to Donald Miller Wilson.
United States Patent |
3,778,126 |
Wilson |
December 11, 1973 |
GAS DISPLAY PANEL WITHOUT EXHAUST TUBE STRUCTURE
Abstract
Projecting exhaust tube constructions of earlier gas panels are
eliminated by the disclosed process. In the present method an
unfused low-softening-point glass sealant, arranged in a picture
frame pattern, is sandwiched loosely between aligned flat glass
plates, and the disjoint assembly is placed in a vacuum oven
enclosure. The enclosure is successively evacuated, filled with the
requisite gas mixture at predetermined pressure and heated above
the softening point of the sealant to establish a sealed gas-filled
envelope within the assembly. Previously the plates have been
joined initially by heat fused sealant to form an envelope which is
thereafter evacuated and filled with gas by connection to a thin
glass tubular orifice projecting from one of the plates.
Manipulation of this tube for evacuation and gas back-filling of
the envelope, which is a difficult operation requiring considerable
time, technique and skill, is eliminated by the present method.
Inventors: |
Wilson; Donald Miller
(Kingston, NY) |
Assignee: |
International Business Machines
Corporation (Armonk, NY)
|
Family
ID: |
22798061 |
Appl.
No.: |
05/214,174 |
Filed: |
December 30, 1971 |
Current U.S.
Class: |
445/25; 65/43;
65/58; 313/584 |
Current CPC
Class: |
H01J
9/261 (20130101) |
Current International
Class: |
H01J
9/26 (20060101); H01j 009/38 () |
Field of
Search: |
;316/19,20 ;315/169R
;313/109.5,182,220 ;29/63B |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lanham; Charles W.
Assistant Examiner: Davie; J. W.
Parent Case Text
CROSS-REFERENCE TO RELATED APPLICATIONS
U. S. Pat. application Ser. No. 214,298 for "Sealing Technique For
Gas Panel," by Perry R. Langston, Jr. et al., filed Dec. 30,
1971.
U. S. Pat. application Ser. No. 214,348 for "Gas Panel
Fabrication," by P. H. Haberland et al., filed Dec. 30, 1971.
U. S. Pat. application Ser. No. 198,953 for "Protection of Terminal
Metallurgy During Working and Reworking of Gas Discharge Display
Devices" filed No. 15, 1971 by N. M. Poley et al.
U. S. Pat. application Ser. No. 176,625 for "Dielectric Insulator
For Gaseous Discharge Device" filed Aug. 31, 1971 by P. H.
Haberland et al.
U. S. Pat. application, Ser. No. 829,692, for "Pilot Light Gas
Cells For Gas Panels" filed June 2, 1969 by P. Soltan, now U.S.
Pat. No. 3,609,658 issued Sept. 28, 1971.
Claims
What is claimed is:
1. A process for constructing a gas discharge display device devoid
of gas-filling ducts or tubulations, comprising:
assembling discrete parts -- including a pair of transparent
dielectric support plates bearing dielectric coated conductive
circuits in a spaced apart unfused configuration with uniform
spacing between the unfused plates established by a heat fusible
sealing material of generally uniform thickness arranged in an
enclosure shape of predetermined form in an unfused condition, said
sealing material having a pedetermined softening temperature
substantially lower than the softening temperatures of said plates
-- to form an enclosed space which is relatively permeable to gas
flow at a boundary between said sealing material and said
plates;
providing spacer elements within said enclosed space having
thickness dimensions establishing a predetermined limiting
dimension within said space less than the thickness of said unfused
sealing material; said elements having softening temperature
substantially higher than that of the sealing material;
filling said enclosed space, with an ionizable gas suited for
display usage, by exposing said assembled parts to an atmosphere of
said gas at predetermined pressure; and
heating said assembled parts with said enclosed space filled with
and retaining said gas, over a temperature range exceeding the
softening point of the sealing material but below the softening
points of said support plates and spacer elements, to cause
selective softening of said sealing material with resulting fusion
of said sealing material, dielectric circuit coatings and plates
into a sealed unit impermeably confining a predetermined volume of
said gas between said circuits in an envelope space of
predetermined uniform height dimension established by said spacer
elements.
2. A process according to claim 1 wherein said step of filling said
space is accomplished by successively evacuating a volume of space
containing said unfused assembled parts and filling said containing
volume of space with said gas at said predetermined pressure while
maintaining said volume at a temperature below the softening
temperature of said sealing material.
3. A process for constructing ductless gas discharge display
devices comprising in succession:
arranging transparent flat glass plates, bearing orthogonally
oriented printed circuit conductors encapsulated in transparent
dielectric films, in substantially parallel spaced apart
orientation with initial spacing determined by an enclosed strip of
heat fusible envelope sealing material in unfused condition and
ultimate spacing determined by glass spacer elements thinner than
said sealing material; said material and dielectric films having
softening temperatures lower than softening temperatures of said
plates and spacer elements;
locating said arranged parts in the interior of a vacuum oven
equipped for selective evacuation, gas filling and heating;
evacuating said oven interior while maintaining a temperature
therein below the softening temperatures of said sealing material
and dielectric films;
filling said oven interior with a gas subject to ionization display
usage at predetermined pressure while maintaining temperature in
said interior below said sealing material and dielectric film
softening temperatures; and
varying the temperature in said oven interior over a range
encompassing the said sealing material and film softening
temperatures but substantially below the softening temperature of
the glass plates and spacer elements to effect selective softening
of said sealing material and films and fusion of said sealing
material to said plates forming an integral unit impermeably
confining an ionization space of predetermined uniform height
dimensions determined by said spacer elements, said ionization
space filled exclusively with a predetermined volume of said gas at
a predetermined pressure.
4. Process of claim 3 wherein said sealing material is arranged
initially in a uniformly thick picture frame strip pattern with
initial thickness exceeding the desired height dimensions of said
ionization space.
5. A process for constructing gas discharge display devices devoid
of specialized gas-filling structural projections or tubulations
comprising:
arranging components -- including transparent flat dielectric
support members having predetermined softening temperature and
bearing integral printed circuit metallization patterns
encapsulated in transparent dielectric film coatings of
predetermined thickness, said coatings having predetermined
softening temperature, and transparent dielectric spacer rods
having predetermined softening temperature assembled in a spaced
configuration established by a closed strip of heat fusible sealing
material forming a permeable enclosure of a space between said
members; said strip having predetermined generally uniform
thickness greater than the diameter of the spacer rods and having
predetermined softening temperature less than the softening
temperatures of said members, film coatings and spacer rods --
within a vacuum oven enclosure; said spacer rods being located and
dimensioned to establish a predetermined limiting spacing between
the encapsulated metallization patterns on said plates upon
subsequent softening of said sealing material;
evacuating said oven enclosure with said arranged components
located therein and with the temperature thereof maintained below
the softening temperature of said sealing material;
filling said oven enclosure with a predetermined gas suited for
display usage; with said gas at predetermined pressure specifically
related to the pressure required for display operation and with
said enclosure maintained at temperature below the softening point
of said sealing material;
uniformly heating said gas-filled oven enclosure, with said gas
confined therein, to a selected temperature above the softening
points of said sealing material and film coatings but below the
softening points of said members, film coatings and spacer rods
thus effecting selective softening of said sealing material and
fusion of said sealing material to said flat members forming an
impermeable gas-filled envelope between said members of
predetermined uniform height dimension determined by the thickness
of said spacing rods, said envelope sealably confining a
predetermined fractional volume of the gas in said oven enclosure
at a predetermined elevated pressure; and
restoring said oven enclosure to ambient temperature and atmosphere
and pressure conditions.
6. Process according to claim 5 wherein said oven enclosure is
maintained at the temperature of the ambient environment
surrounding the enclosure during said evacuating and gas filling
step.
7. Process according to claim 5 wherein said oven enclosure is
pre-heated to a temperature above the temperature of the
surrounding ambient and below the softening points of said material
prior to said gas filling step, whereby said gas may be introduced
at a reduced pressure.
8. A process according to claim 5 wherein a plurality of panels are
aggregately assembled in stacked formation to form a
three-dimensional display.
9. A process according to claim 6 wherein the evacuating step
comprises reducing pressure within said oven enclosure from
atmospheric ambient to approximately 10 Torr in approximately 5
minutes and from 10 Torr to between 10.sup.-.sup.3 and
10.sup.-.sup.6 Torr in approximately 60 minutes; and wherein the
heating step comprises raising the oven temperature at a rate of
between 1.degree. and 3.degree. C per minute to a point sufficient
to establish selective softening and complete fusion of the sealing
material and the restoring step comprises first cooling the oven
enclosure at said rate of 1.degree.-3.degree. C per minute and then
restoring ambient atmosphere and pressure to the oven
enclosure.
10. A process according to claim 7 wherein the evacuating step
comprises reducing the pressure in said oven enclosure from
atmospheric ambient to approximately 10 Torr in approximately 5
minutes and from 10 Torr to between 10.sup.-.sup.3 and
10.sup.-.sup.6 Torr in approximately 60 minutes; and said
pre-heating step is executed between said evacuating and filling
steps by adding heat to produce a temperature rise of between
1.degree.-3.degree. C per minute; and wherein said heating step
comprises adding more heat sufficient to increase the temperature
at 1.degree.-3.degree. C per minute to a value above the selective
softening point of the sealing material before initiating ambient
cooling and re-pressurization.
Description
BACKGROUND OF THE INVENTION
Earlier gas panels have included a special tube structure
communicating with and used for evacuating and gas-filling a
confined envelope formed in an early stage of assembly processing.
This tube has been considered a weak link in the assembly process
and the resulting panel structure since it is a relatively thin and
fragile glass part projecting from an exterior surface of the panel
structure. Its coupling to and disconnection from sources of vacuum
and gas has required special skills and sealing tenchiques. The
coupling operation therefore is quite time consuming and
expensive.
Accordingly an object of the present invention is to provide a
simpler gas panel assembly process and product structure
characterized by elimination of formation and handling of special
exhaust connections to the envelope contained in the structure.
An associated object is to provide improved gas panel display
stuctures of uniformly flat construction which can be stacked
adjacently in layers to form three-dimensional displays.
A further object is to provide a gas panel display structure having
uniformly flush surfaces without projections; whereby one surface
of the structure may be conveniently arranged for viewing as a
display while the opposite surface may be positioned in contact
with photocopying equipment for contact printing of hard copy of
displayed images.
Another object is to reduce significantly the time and cost of
fabricating a gas panel display structure.
Another object is to reduce the possibility of gas panel failure by
eliminating tubular exhaust/gas filling couplings and associated
seals which inherently tend to be thermally and mechanically
mismatched in relation to other elements of a panel assembly.
The foregoing and other related objectives are achieved by
arranging high softening point glass spacing rods and low softening
point glass sealing material in picture frame pattern between
disjoint high softening point glass plates within a vacuum oven
enclosure. The oven is adapted for selective coupling of vacuum,
gas and heat into its enclosure. The disjoint assembly is thereby
successively scrubbed by vacuum, immersed in the gas which forms
the light emitting medium of the display panel, and heat-fused
while immersed in the gas. In the heat fusion stage the blass
sealing material fuses with the plates to form a containing
envelope around the gas surrounded by these elements. As the
sealing material softens the upper plate collapses gradually
towards and settles upon the spacing rods (diameter less than
initial thickness of the unfused sealant); establishing the desired
predetermined spacing of the envelope. The sealing material is
selected to have viscosity sufficiently low to flow during heat
fusion cycling and yet high enough so that it will not run off and
leave voids during such cycling.
Since the foregoing evacuating, gas-filling and heating functions
are all performed within the oven enclosure there is never a
differential in the pressure exerted upon the glass parts of the
panel assembly. In the earlier exhaust tube processing vacuum and
gas were coupled to the envelope while the exterior of the glass
plates received atmospheric pressure. Consequently the thickness
(and weight) of present glass substrata may be considerably reduced
(e.g. from one-fourth inch to one-eighth inch) for more economical
usage, more efficient light transmission and generally easier bulk
shipment and handling.
Accordingly, additional objects of the present invention are to
provide for improved display panel fabrication processing under
conditions of reduced pressure stress whereby glass parts forming
the bulk of the panel structure may be made with reduced thickness;
such being desirable for both economy, and general effectiveness of
light transmission and handling.
It is worth noting also that with equalized pressures throughout
the in situ filling/sealing stages of the present process the glass
plates do not need central support. Previously an additional
spacing rod was used to provide central support for large area
glass parts during evacuation of the enclosure since the parts by
themselves could not sustain the external atmospheric pressure
without bending. With the present arrangement the center spacer is
unnecessary and it is therefore eliminated.
Therefore another object of the invention is to reduce or eliminate
central support elements of gas panel structures which although
useful only during assembly processing are incorporated in the
assembly and may interfere with panel operation or viewing.
The foregoing and other objects and features of the present
invention may be more fully appreciated and understood by referring
to the following detailed description of a specific embodiment
thereof and claims.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1 and 4 provide contrasting partially schematic perspective
views of gas panel assemblies formed respectively by earlier and
present methods (FIG. 4 serves to indicate the elimination of the
exhaust tube and the relatively reduced thickness of the glass
plates forming the gas enclosure);
FIGS. 2 and 3 provide sectional views of the assembly of either
FIG. 1 or FIG. 4 respectively before and after the heat fusion
stage of assembly processing;
FIG. 5 is a schematic view of vacuum furnace apparatus utilized in
the practice of the present invention to provide equalized pressure
handling of the assembly throughout the in situ evacuation,
gas-filling and heat sealing stages of the present process;
FIGS. 6 and 7 indicate additional uses which can be made of the
flush rear surfaces of gas panels formed by the present method.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
FIGS. 1 and 4 show earlier and present gas panel assemblies. The
respective fabrication/assembly processes are compared as
follows:
Prior Method Present Method . Prepare components (Note 1) . Prepare
(Note 1a) . Assemble in unjoined state (Note 2) place in oven used
only for temperature cycling; . Assemble in unjoined state; place
in air-tight vacuum-oven enclosure (Note 2a) . Join (heat fuse)
into integral assembly (Note 3) . Evacuate, gas fill, heat fuse,
restore ambient; all in situ in oven chamber, no handling of
assembly required (Note 3a) . Evacuate space confined by joined
assembly through tube (Note 3) . Bake-out confined space (Note 3) .
Tip-off tube (Note 3) . Leak test (Note 3) . Couple tube to gas
source (Note 3) . Fill confined space of assembly with gas (Note 3)
. Tip-off tube (Note 3) . Complete terminal connection processing
(Note 4) . Complete terminal connection processing per prior
method
Notes:
1. Prepare plates, plate sealant, spacers, tube, tube sealant.
Plate preparation:
cut to size and clean soda-lime-silica window glass (e.g. 1/4 inch
thick) into front and rear substrates; make hole in rear (top)
plate for tube coupling; metallize "interior" surfaces of plates
(deposit layer of metal, etch, passivate by heat treatment in
forming gas, test); insulate (spary lead-borosilicate powdered
glass frit over passivated metallization and fuse by heating);
inspect.
1a. Same as 1 but omit preparation of tube, tube sealant and tube
coupling hole in rear plate; also use thinner plates (e.g.
one-eighth inch instead of one-fourth inch).
2. Lay down unfused plate sealant "picture frame strips" on
"interior" surface of front plate (pre-shaped lead-borosilicate
glass rod or powdered glass frit in viscous binder; preparation
available in strip form on plastic release tape); spacer rods on
surface of same plate near and within sealant border; place other
(rear) plate, with "interior" face down, on top of border sealant
orthogonally aligning metallization on the two plates; place tube
sealant and tube over rear plate opening.
2a. Assembly same as 2 but omit placement of tube sealant and tube.
Oven equipped for selective coupling of vacuum, gas plasma and heat
to enclosure.
3. Heat in oven at atmospheric pressure to above softening point of
sealants (plate and tube) and dielectric covering of plate
metallization (softening point of latter approx. 400.degree. C).
Heating cycle: room temperature (approx. 25.degree. C) to approx.
500.degree. C at rate of 1.degree.-3.degree. C per minute --
establishes fusion of tube sealant to tube and outer surface of
rear plate and fusion of envelope sealant between plates to
dielectric coatings of plates -- and back to room temperature at
1.degree.-3.degree. C per minute. Softening point of glass
composition of plates, spacers and tube is well in excess of
500.degree. C. This and other steps of process are performed with
exterior of assembly at atmospheric pressure.
3a. Vacuum oven enclosure successively exhausted at room
temperature, filled with Ne-A gas mixture at specific pressure (700
torr), heated (at temperature cycle of note 3 above) to establish
envelope sealant fusion and, upon cooling to room temperature,
restored to ambient pressure. Exhaust cycle: pressure reduced from
atmospheric pressure (approx. 750 torr) to about 10 torr in about 5
minutes, and from 10 torr to between 10.sup.-.sup.3 and
10.sup.-.sup.6 torr in about another hour. Alternate process
sequence: a) evacuate enclosure; b) heat enclosure to temperature
T(.degree.C) below softening point (400.degree. C) of envelope
sealant and dielectric plate coatings; c) supply gas plasma to oven
enclosure at elevated pressure T/25 .times. 700 torr; d) continue
oven temperature cycle, per note 3, from T to 500.degree. C and
back to room temperature; e) restore oven enclosure to atmospheric
pressure.
4. Remove dielectric and passivation coatings from plate
metallization at appropriate (edge) termination sites; test; make
connections; test; etc.
Referring to FIGS. 1-3 in the prior method the
metallized-passivated-dielectric coated front and rear glass plates
1, 2 and exhaust tube 3 are formed into an integral structure by
heat union of envelope sealant 4 with dielectric plate coatings 5,
6 and heat union of tube sealant 7 with tube 3 and plate 2. For
large area panels edge spacer rods such as 8 may be supplemented by
a not shown central spacer rod providing central support for the
glass plates during subsequent evacuation and gas filling of
envelope space 9 (FIG. 3) through tube 3 and hole 10 in plate 2
(FIG. 3) with the parts subject externally to atmospheric pressure.
The fused dielectric layers 5, 6, formed from sprayed and heated
glass frit cover the patterned metallization (indicated
schematically at 11 in FIG. 1) intersecting at illuminatable cross
points of the panel. Layers 5, 6 have specific dielectric
properties requisite to support of gas plasma discharge in envelope
space 9. All glasses (substrate, dielectric layers, tube, tube
sealant, border sealant) must have compatible thermal coefficients
of expansion, albeit differing optical, physical, dielectric, and
heat softening properties. The expense and effort involved in the
exhaust and back filling operation are considerable. The projecting
exhaust tube structure 3 is also a relatively weak element in
comparison to the main body of the panel formed by glass parts 1,
2.
Tube 3 also restricts contact between the exterior surface of plate
2 and other media; for instance other panels as suggested in FIG. 6
or hard copy photocopying equipment as suggested in FIG. 7.
Glass plates 1, 2 must have substantial thickness (e.g. one-fourth
inch) and may require potentially obstructive central support rods
in order to be able to withstand the differential pressures
existing when envelope space 9 is evacuated while atmospheric
pressure exists externally.
Gas panels processed in accordance with the present invention have
the form exemplified in FIGS. 4, 2 and 3. In this process
metallized-passivated-insulated glass plates 1a, 2a entirely free
of projecting exhaust tubes or other obstructions, are assembled as
in the previous method about low softening point envelope sealant
4a (e.g. powdered lead borosilicate glass in viscous binder peeled
from plastic release tape or lead borosilicate glass rod pre-formed
into "picture frame" outline). Peripheral spacer rods such as 8a
having higher softening temperature than the envelope sealant
establish ultimate separation spacing of the fused glass parts.
The unjoined assembly is positioned in the desired orientation
(FIG. 2) within vacuum oven enclosure 16 (FIG. 5), associated with
gas supply apparatus 18, 19, vacuum coupling apparatus 20 and
heating unit 22. Such ovens, without the gas supply fittings, are
sold under commercial designation High Temperature Vacuum Oven,
Model 1408, by T-M Vacuum Products Co.
The unfused envelope sealant 4a permits unimpeded evacuation of the
extended envelope space 26 bounded by the unjoined plates when
enclosure 16 is evacuated and unimpeded permeation of gas into the
same space when oven enclosure 16 is filled with gas. When
enclosure 16 is thereafter heated in accordance with note 3a above
envelope sealant 4a softens, flows and fuses with the dielectric
metallization coating layers 5a, 6a of the plates as suggested at
30 (FIG. 3), while the upper plate sinks down against spacers 8a
establishing the desired final dimensions of the gas-filled/sealed
envelope 9a contained between the plates. Thickness and viscosity
of the unfused envelope sealant are selected so that upon softening
and flowing the sealant forms a uniform void-free lining around the
rectangular parellepiped gas enclosure space 9a.
When enclosure 16 (FIG. 5) is restored to room temperature the
fused border sealant hardens into a firm totally impervious seal.
At this time the plasma gas within the enclosure 16 and therefore
within confined space 9a is under pressure just slightly less than
atmospheric (about 700 torr).
Further details of component preparation, assembly handling and
terminal connection processing ancillary to but not directly
relevant to the present process are found in the references listed
above under Cross-Reference to Related Applications.
Typical parameters of the present process are:
Glass plate (1a, 2a) dimensions:
4 .times. 2 1/8 .times. 1/8inches (compared to 4 .times. 2 1/8
.times. 1/4inches previously) Envelope sealant 4a:
glass frit (Corning 7570) or Glass Rod (PbO-62 percent, ZnO-15
percent, B.sub.2 O.sub.3 -20 percent, Bi.sub.2 O.sub.3 -3 percent)
the frit in viscous binder (amyl acetate nitrocellulose) applied to
glass plate in thickness 10 mil where final envelope height is 4.5
mil
Dielectric/metallization layers 5a, 6a:
1 mil thick lead borosilicate glass sprayed and fired 600.degree. C
Composition:
a. metallization: Cr 1,000A, Cu 10,000A, Cr 1,000A
b. passivation: 525.degree. C in forming gas 5.degree.-8.degree. C
per minute up and down
c. insulation: PbO-73.5 percent, Si.sup.O -13.6 percent, B.sub.2
O.sub.3 -12.7 percent,
Al.sub.2 O.sub.3 -0.2 percent
We have shown and described above the fundamental novel features of
our invention as applied to a preferred embodiment. It will be
understood that various omissions, substitutions and changes in
form and detail of the invention as described herein may be made by
those skilled in the art without departing from the true spirit and
scope of the invention. It is the intention therefore to be limited
only by the scope of the following claims.
* * * * *