U.S. patent number 3,777,816 [Application Number 05/134,463] was granted by the patent office on 1973-12-11 for method for the ignition of in-situ combustion for the recovery of petroleum.
This patent grant is currently assigned to Deutsche Texaco Aktiengesellschaft. Invention is credited to Albert Meier.
United States Patent |
3,777,816 |
Meier |
December 11, 1973 |
METHOD FOR THE IGNITION OF IN-SITU COMBUSTION FOR THE RECOVERY OF
PETROLEUM
Abstract
A method of initiating in situ combustion in a subterranean
hydrocarbon-bearing formation wherein a substance capable of
reacting with hydrogen peroxide is introduced into the formation
via a well bore and thereafter a mixture of hydrogen peroxide
containing from 10 to 20 percent by weight of water is injected to
effect an exothermic reaction thereby to increase the temperature
of the formation adjacent the well bore to the ignition temperature
of the hydrocarbons contained therein and resulting in ignition of
those hydrocarbons and the initiation of an in situ combustion.
Inventors: |
Meier; Albert (Reinbek,
DT) |
Assignee: |
Deutsche Texaco
Aktiengesellschaft (Hamburg, Mittelweg, DT)
|
Family
ID: |
5768285 |
Appl.
No.: |
05/134,463 |
Filed: |
April 15, 1971 |
Foreign Application Priority Data
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|
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Apr 17, 1970 [DT] |
|
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P 20 18 372.6 |
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Current U.S.
Class: |
166/260; 44/902;
44/251; 166/302 |
Current CPC
Class: |
E21B
43/17 (20130101); C09K 8/592 (20130101); E21B
43/243 (20130101); Y10S 44/902 (20130101) |
Current International
Class: |
C09K
8/58 (20060101); E21B 43/243 (20060101); E21B
43/16 (20060101); E21B 43/17 (20060101); C09K
8/592 (20060101); E21b 043/24 () |
Field of
Search: |
;166/260,261,302
;117/97,135 ;44/3R,3B |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
L F. Audrieth, The Chemistry of Hydrazine, 1951, Pages
129-133..
|
Primary Examiner: Champion; Marvin A.
Assistant Examiner: Ebel; Jack E.
Claims
I claim:
1. In the production of hydrocarbons from a hydrocarbon-bearing
formation by means of an in situ combustion process, said formation
being penetrated by a well bore, the method of initiating in situ
combustion comprising the steps of:
a. introducing into said well bore a reducing substance capable of
reacting with hydrogen peroxide whereby the temperature of said
formation adjacent said well bore will be raised to at least the
ignition temperature of said hydrocarbons in said formation by
reaction with said hydrogen peroxide,
b. introducing into said well bore a solution of hydrogen peroxide
and water whereafter said hydrogen peroxide reacts with said
reducing substance to raise the temperature of said formation
adjacent said well bore to at least the ignition temperature of
said hydrocarbons,
c. thereafter introducing a solution of hydrogen peroxide and
water, said hydrogen peroxide thereby being thermally decomposed at
said temperature and forming oxygen and effecting in situ
combustion of said hydrocarbons adjacent said well bore by reaction
with said oxygen.
2. The method of claim 1 wherein said solution of hydrogen peroxide
and water contains from 10 to 20 weight percent water.
3. The method of claim 1 wherein said reducing substance capable of
reacting with said hydrogen peroxide is hydrazine, hydroxylamine,
and derivatives thereof.
4. The method of claim 1 wherein said reducing substance capable of
reacting with said hydrogen peroxide is introduced into said well
bore via a first tubing means and said solution of hydrogen
peroxide and water is introduced via a second tubing means.
5. The method of claim 4 wherein said tubing is coated internally
with a decomposition inhibiting substance.
6. The method of claim 5 wherein said decomposition inhibiting
substance is paraffin, polyethylene or bitumen.
7. The method of claim 1 wherein said reducing substance is
introduced into said well bore via a tubing means and said solution
of hydrogen peroxide and water is introduced via the annulus formed
between said tubing means and the face of said well bore.
8. The method of claim 7 wherein said tubing is coated internally
with a decomposition inhibiting substance.
9. The method of claim 8 wherein said decomposition inhibiting
substance is paraffin, polyethylene or bitumen.
10. In the production of hydrocarbons from a hydrocarbon bearing
formation by means of an in situ combustion process, said formation
being penetrated by a wellbore having a plurality of tubing means
therein, thereby forming an annulus between said tubing means and
said wellbore, the method of initiating in situ combustion
comprising the steps of:
a. introducing into said wellbore a substance capable of reacting
with hydrogen peroxide whereby the temperature of said formation
adjacent said wellbore will be raised to at least the ignition
temperature of said hydrocarbons in said formation by reaction with
said hydrogen peroxide;
b. introducing into said wellbore a solution of hydrogen peroxide
and water whereafter the said hydrogen peroxide reacts with said
substance to raise the temperature of said formation adjacent said
wellbore to at least ignition temperature of said hydrocarbons;
c. thereafter introducing a solution of hydrogen peroxide and
water, said hydrogen peroxide thereby being thermally decomposed at
said temperature and forming oxygen and effecting in situ
combustion of said hydrocarbons adjacent said wellbore by reaction
with said oxygen.
11. The method of claim 10 wherein said substance capable of
reacting with hydrogen peroxide is introduced via one of said
tubing means and thereafter said solution of hydrogen peroxide and
water is introduced via another of said tubing means.
12. The method of claim 11 wherein said tubing is coated internally
with a decomposition inhibiting substance.
13. The method of claim 12 wherein said decomposition inhibiting
substance is paraffin, polyethylene or bitumen.
14. The method of claim 10 wherein said substance capable of
reacting with hydrogen peroxide is introduced by one of said tubing
means and said solution of hydrogen peroxide and water is
introduced into said annulus defined between said tubing means and
said wellbore.
15. The method of claim 10 wherein said solution of hydrogen
peroxide and water contains from 10 to 20 weight percent of
water.
16. The method of claim 10 wherein said substance capable of
reacting with said hydrogen peroxide is an oxidizing substance.
17. The method of claim 16 wherein said oxidizing substance is a
permanganate.
18. The method of claim 10 wherein said substance capable of
reacting with said hydrogen peroxide is a reducing substance.
19. The method of claim 18 wherein said reducing substance is
hydrazine, hydroxylamine and derivatives thereof.
20. The method of claim 10 wherein said substance capable of
reacting with hydrogen peroxide is a component of said hydrocarbons
contained in said hydrocarbon-bearing formation.
21. The method of claim 10 wherein said substance capable of
reacting with said hydrogen peroxide is a catalytically active
substance.
22. The method of claim 10 wherein said catalytically active
substance are substances with large surfaces, manganese dioxide,
ferrous salts, catalases and platinum metals, finely divided of an
inert supporting material.
Description
BACKGROUND OF THE INVENTION
This invention relates generally to a method of igniting and
initiating an in situ combustion in a subterranean
hydrocarbon-bearing formation.
In modern day production of hydrocarbons from subterranean
formations, it is common practice to apply secondary recovery
techniques to recover additional quantities of hydrocarbons. One of
the more common secondary recovery techniques currently employed is
that of in situ combustion. In this method of producing
hydrocarbons, in situ combustion is initiated in the
hydrocarbon-bearing formation near a well bore penetrating the
formation and a combustion front is established. Once the formation
has been successfully ignited, a combustion-supporting gas, e.g.,
an oxygen-containing gas such as compressed air, is injected into
the well bore to support and drive the combustion front through the
formation, thereby displacing the hydrocarbons in the formation
toward a production well from which they are produced.
Successful ignition is generally dependent upon generating a
temperature sufficient to support and propagate the combustion
front. Among the techniques used for initiating the in situ
combustion included in the prior art are various types of ignitors
such as downhole heaters, electrical heating devices and
combustibles introduced into the well bore. Results from the
utilization of many of these techniques have been less than
satisfactory, primarily due to the fact that sufficiently high
temperatures were not generated to ignite successfully the
formation and establish a combustion front.
SUMMARY OF THE INVENTION
The invention herein disclosed provides an improved method of
generating sufficiently high temperatures in a well bore adjacent a
hydrocarbon-bearing formation to initiate an in situ combustion
therein. A high temperature is attained by the reaction of a
solution of hydrogen peroxide containing water in amounts of from
10 to 20 percent by weight, which solution is contacted in the well
bore with a substance that reacts with the hydrogen peroxide to
produce an exothermic reaction. As a result of the high temperature
generated thereby within the formation adjacent the well bore, the
ignition temperature of the hydrocarbons therein is attained and in
situ combustion is initiated.
DESCRIPTION OF THE PREFERRED EMBODIMENT
A broad aspect of the invention comprises introducing into a well
bore penetrating a hydrocarbon-bearing formation a substance
capable of reacting with hydrogen peroxide whereby the temperature
of the formation will be raised at least to the ignition
temperature of the hydrocarbons contained therein, and thereafter
introducing a solution of hydrogen peroxide and water containing
from 10 to 20 percent by weight of water. By the heat set free as a
result of the reaction of the hydrogen peroxide with the
aforementioned substance, the temperature increases until reaching
at least the ignition temperature of the hydrocarbons and oxygen
which is formed as a result of the thermal decomposition of
hydrogen peroxide burns the ignited hydrocarbons.
The ignition process and the combustion rate are controlled by
varying the water content of the hydrogen peroxide. The initiation
and the combustion rate are established in a known manner by
measuring the pressure and temperature. The ignition process may be
halted or the combustion interrupted any time by a sufficient
increase of the water content. The preferred water content for
ignition is from 10 to 20 weight percent.
The substances capable of reacting with an decomposing the hydrogen
peroxide include catalytically active substances and hydrogen
peroxide oxidizing or reducing substances. Examples of
catalytically active substances are substances with large surfaces,
manganese dioxide, ferrous salts, catalases and platinum metals
finely divided on an inert supporting material. These substances do
not undergo substantial changes in the reaction with hydrogen
peroxide or its decomposition process. Examples of hydrogen
peroxide oxidizing substances are the permanganates. Examples of
hydrogen peroxide reducing substances are hydrazine, hydroxylamine
and derivatives thereof. By the reaction of these latter substances
with hydrogen peroxide, heat of reaction is set free contributing
advantageously to an additional increase of the temperature.
In a preferred embodiment the hydrogen peroxide and the reacting
substance are contacted within the formation well bore adjacent the
hydrocarbon-bearing formation, for example, by lowering the
reacting substance via tubing in the well bore and pumping hydrogen
peroxide containing water into the formation through the tubing. If
the reacting substance is in solid form, it is first broken into
pieces and may be introduced in a perforated container. If the
reacting substance is in liquid form, the container is designed as
a closed vessel provided with outlet closing means. The container
may be lowered either hanging on a rope or by permitting it to fall
down. If the substance contains a liquid decomposing agent, it may
be provided with a striker by which the closing or bursting disk or
the striker itself is crushed causing the decomposing agent to flow
out the underground end of the tubing. Prior to pumping the
hydrogen peroxide containing water down the tubing, the tubing may
be flushed by an agent such as paraffin oil to inhibit the
decomposition of the hydrogen peroxide prematurely.
In a particular embodiment of the method of the invention an
internal pipe is run through the tubing to the underground of said
tubing. The hydrogen peroxide containing water is pumped down
either through the annulus or through the internal pipe, while a
liquid decomposing agent, e.g., hydrazine, is pumped down through
the annulus or through a second tubing. Because of the lesser pipe
diameter it is economically justified to treat the internal wall of
the internal pipe with decomposition inhibiting substances, e.g.,
paraffin, polyethylene or bitumen.
By pumping water down the combustion rate may be reduced or the
combustion process stopped.
Use is made under particular circumstances which have to be
established by pilot tests of the petroliferous layer to serve as
the hydrogen peroxide decomposing agent, thereby saving the need
for charging the decomposing agent from outside.
The steam developing during the decomposition of the hydrogen
peroxide has the advantageous effect of acting as an additional
driving agent for the petroleum.
Once the formation has been successfully ignited, a combustion
supporting gas, e.g., air, is utilized to drive the combustion
front forward toward an adjacent production well from which
recovery of hydrocarbons is realized. Alternatively, it may be
found advantageous to discontinue injection of the combustion
supporting gas and use a water flood to drive the combustion front
toward the production well.
* * * * *