U.S. patent number 3,773,677 [Application Number 05/311,511] was granted by the patent office on 1973-11-20 for press wash.
This patent grant is currently assigned to Consolidated Foods Corporation. Invention is credited to Henry Barringer Boyles.
United States Patent |
3,773,677 |
Boyles |
November 20, 1973 |
PRESS WASH
Abstract
A solvent composition for cleaning ink and other soil material
from printing presses is formulated by blending together in a
critical ratio higher boiling non-flammable chlorinated or
brominated hydrocarbon liquid, low boiling chlorinated or
brominated hydrocarbon liquid, petroleum solvent such as mineral
spirits, and a compatible surfactant, such as nonylphenoxy
polyethoxy ethanol. When blended together in proper ratio the blend
is non-flammable, possesses desirable characteristics so as not to
dry so quickly that the printer or pressman does not have
sufficient time to wipe the equipment clean but completely
evaporates within a few minutes after application, and is highly
efficacious as a solvent for the soil materials.
Inventors: |
Boyles; Henry Barringer
(Atlanta, GA) |
Assignee: |
Consolidated Foods Corporation
(Atlanta, GA)
|
Family
ID: |
23207230 |
Appl.
No.: |
05/311,511 |
Filed: |
December 4, 1972 |
Current U.S.
Class: |
510/170; 101/424;
252/364; 134/40; 510/412; 510/413; 510/461 |
Current CPC
Class: |
C09D
9/005 (20130101); C23G 5/02806 (20130101); B41N
3/06 (20130101); C11D 3/43 (20130101) |
Current International
Class: |
C23G
5/028 (20060101); C09D 9/00 (20060101); C23G
5/00 (20060101); C11D 3/43 (20060101); B41N
3/06 (20060101); B41N 3/00 (20060101); C11d
007/52 () |
Field of
Search: |
;252/172,170,171,364
;106/301 ;101/424 ;134/40 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Schulz; William E.
Claims
What I claim is:
1. A solvent composition consisting essentially of the following
constituents and volume percents: non-flammable halogenated
hydrocarbon boiling within the range of about 60.degree. to
170.degree. C and selected from the group consisting of chlorinated
hydrocarbons, brominated hydrocarbons and hydrocarbons which are
chlorinated and brominated in the amount of 40- 50 percent, a low
boiling petroleum solvent in the amount of 30-40 percent,
non-flammable halogenated hydrocarbon liquid boiling no higher than
about 40.degree. C and selected from the group of chlorinated and
brominated hydrocarbons in the amount of 10-25 percent, and 0.5 to
1.5 percent of a compatible detergent.
2. The solvent in accordance with claim 1 in which the halogenated
hydrocarbon boiling within the range of 60.degree. to 170.degree. C
is 1,1,1 trichlorethane, the solvent is mineral spirits, and the
halogenated hydrocarbon boiling no higher than about 40.degree.C is
methylene chloride.
3. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of about 45-50 percent, the
mineral spirits present in the amount of about 35-40 percent, the
methylene chloride is present in the amount of about 10-25 percent
and the detergent is nonylphenoxy polyethoxy ethanol present in the
amount of about 0.5 to 1 percent.
4. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of 55 percent, the mineral
spirits is present in the amount of 34 percent, the methylene
chloride is present in the amount of 10 percent and the detergent
is nonylphenoxy polyethoxy ethanol present in the amount of 1
percent.
5. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of 40 percent, the mineral
spirits is present in the amount of 40 percent, the methylene
chloride is present in the amount of 19 percent, the detergent is
nonylphenoxy polyethoxy ethanol present in the amount of 1
percent.
6. The solvent in accordance with claim 2 in which the 1,1,1,
trichlorethane is present in the amount of 44 percent, the mineral
spirits is present in the amount of 40 percent, the methylene
chloride is present in the amount of 15 percent and the detergent
is nonylphenoxy polyethoxy ethanol present in the amount of 1
percent.
7. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of 46 percent the mineral
spirits is present in the amount of 30 percent, the methylene
chloride is present in the amount of 23 percent and the detergent
in nonylphenoxy polyethoxy ethanol present in the amount of 1
percent.
8. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of 52 percent, the mineral
spirits is present in the amount of 35 percent, the methylene
chloride is present in the amount of 12 percent and the detergent
is nonylphenoxy polyethoxy ethanol present in the amount of 1
percent.
9. The solvent in accordance with claim 2 in which the 1,1,1
trichlorethane is present in the amount of 45.5 percent, the
mineral spirits is present in the amount of 38 percent, the
methylene chloride is present in the amount of 15 percent and the
detergent is nonylphenoxy polyethoxy ethanol present in the amount
of 1.5 percent.
10. The solvent in accordance with claim 1 in which the halogenated
hydrocarbon boiling within the range of about
60.degree.-175.degree.C is a mixture of 1,1,1, trichlorethane and
perchlorethylene.
11. The solvent in accordance with claim 10 in which the
halogenated hydrocarbon boiling no higher than about 40.degree.C is
methylene chloride.
12. The solvent in accordance with claim 10 in which the 1,1,1
trichlorethane is present in the amount of 22 percent, the
perchlorethylene is present in the amount of 24 percent, the
mineral spirits is present in the amount of 38 percent, the
methylene chloride is present in the amount of 15 percent and the
surfactant is nonylphenoxy polyethoxy ethanol present in the amount
of 1 percent.
13. The solvent in accordance with claim 1 in which the halogenated
hydrocarbon boiling within the range of about 60.degree. to
175.degree. C is methylene bromide and the halogenated hydrocarbon
boiling no higher than about 40.degree.C is ethyl bromide.
14. The solvent in accordance with claim 13 in which the methylene
bromide is present in the amount of 47 percent, mineral spirits is
present in the amount of 37 percent, ethyl bromide is present in
the amount of 15 percent and nonylphenoxy polyethoxy ethanol is
present as the surfactant in the amount of 1 percent.
15. A solvent in accordance with claim 1 in which the halogenated
hydrocarbon boiling in the range of about 60.degree. to 175.degree.
C is from the group consisting of 1,1,1 trichlorethane, chloroform,
trichorethylene, perchlorethylene, trichlorpropane, bromoform,
ethylene dibromide, methylene bromide and bromochloromethane.
16. A solvent in accordance with claim 1 in which the halogenated
hydrocarbon having a boiling point no higher than 40.degree.C is
from the group consisting of methylene chloride and ethyl
bromide.
17. A solvent in accordance with claim 15 in which the halogenated
hydrocarbon having a boiling point no higher than 40.degree.C is
from the group consistng of methylene chloride and ethyl
bromide.
18. The method of removing ink, oil, grease and other soiling
substances from printing equipment comprising applying thereto the
solvent of claim 1 and wiping the equipment with a clean cloth
before the solvent evaporates.
19. The method of removing ink, oil, grease and other soiling
substances from printing equipment comprising applying thereto the
solvent of claim 3 and wiping the equipment with a clean cloth
before the solvent evaporates.
Description
BRIEF SUMMARY OF THE INVENTION
Printing presses must be cleaned completely free of ink between
changes of ink color and prior to any lengthy shutdown of the
press. The cleaning job is commonly done by a highly paid printer
or pressman and is to the advantage of the owner or operator to
expedite the cleaning operation.
It is common practice when cleaning presses to accomplish the
cleaning in two steps. In the first step the press is cleaned of
ink and ink residue while in the second step the press is rinsed to
remove soil material from the rollers and cylinders. During the
first step all traces of ink whether wet or dry must be carefully
removed without attacking the rollers or cylinders. In the second
step a rapid drying solvent is used. The drying time of the solvent
will depend on the size of the press, more rapid drying solvents
being used on the smaller presses than on the larger ones. The
solvents that are commonly used are highly flammable fast drying
types such as naphtha, isopropanol, methyl ethyl ketone, hexane,
gasoline, mineral spirits and kerosene. They constitute a safety
and health hazard to the workers in the printing establishment.
It is an object of this invention to provide solvents for cleaning
printing presses in a one step operation.
It is a further object of the invention to provide non-flammable
solvents for cleaning printing presses.
It is still another object of the invention to provide
non-flammable solvents which dry rapidly so as to avoid long down
times between printing operations.
It is still another object of the invention to provide a cleaning
solvent for printing equipment which remains wet for a long enough
period of time to enable a workman to effectively clean the
printing equipment, but which dries within a reasonably short
time.
Other objects and advantages of the invention will become apparent
from the following detailed description.
DETAILED DESCRIPTION OF THE INVENTION
In accordance with my invention there is blended together
non-flammable higher boiling brominated and/or chlorinated
hydrocarbons boiling within the range of about
60.degree.-175.degree.C, non-flammable lower boiling chlorinated or
brominated hydrocarbons, liquids boiling no higher than about
40.degree.C, a hydrocarbon solvent of petroleum origins such as
mineral spirits and a compatible detergent such as nonylphenoxy
polyethoxy ethanol or other nonionic polyglycol ether
group-containing detergent such as described in U.S. Pat. No.
2,931,777. The solvent blend is non-flammable while at the same
time possessing the necessary drying characteristics and soil
removing efficacy. The constituents of the solvent blend must be
mixed in a critical ratio so that the higher boiling halogenated
hydrocarbon is present in an amount of 40 to 55 percent, the
mineral spirits or equivalent hydrocarbon solvent is present in the
amount of 30 to 40 percent, the lower boiling halogenated
hydrocarbon is present in amount of 10 to 25 percent and the
surfactant is present in an amount of 0.5 to 1.5 percent. When
blended within the ranges specified the resulting solvent will have
a drying time of approximately 3 to 15 minutes depending on the
quantities of each constituent present within the limits specified.
Where faster drying times are desired the higher boiling
halogenated hydrocarbon is used in amounts approaching the lower
limit and the lower boiling halogenated hydrocarbon is used in
amounts approaching the upper limit. As the quantity of mineral
spirits approaches the upper limit and the higher halogenated
hydrocarbon approaches the lower limit, the drying time of the
solvent is shortened. Although surfactants of the nonionic, alkyl
polyethoxy ethanol type are preferred, anonic surfactants may be
used if they are compatible.
As previously set forth one of the important characteristics of the
solvent blend is its non-flammability, as determined by ASTM Test
Method D-92-57.
Within the scope of the invention are compositions effective for
removing printing inks in the dry, tacky, or wet state. These inks
are generally composed of petroleum based ink oils of a drying oil
type, resins, solvents and pigments to impart color. They dry
either by internal curing or by solvent evaporation. It is
important that the solvent be capable of removing all traces of the
printing ink while not attacking working parts such as ink rollers
or cylinders.
A typical solvent cleaning composition in accordance with the
invention is: 1, 1, 1 Trichlorethane 40 to 55 percent, mineral
spirits 30 to 40 percent, Methylene Chloride 10 to 25 percent and
Nonylphenoxy polyethoxy ethanol 0.5 to 1.5 percent. In a preferred
composition the 1, 1, 1 Trichlorethane is present in the amount of
45 to 50 percent, mineral spirits 35 to 40 percent, methylene
chloride 10 to 25 percent and nonylphenoxy polyethoxy ethanol 0.5
to 1 percent.
As examples of other higher boiling chlorinated and/or brominated
hydrocarbons which may be used in place of 1, 1, 1 trichlorethane
or mixed together therewith may be mentioned chloroform,
trichlorethylene, perchlorethylene, bromochloromethane,
trichlorpropane bromoform, ethylene dibromide and methylene
bromide. Among the lower boiling halogenated hydrocarbons that may
be used may be mentioned methylene chloride and ethyl bromide.
While I prefer to use mineral spirits as the hydrocarbon portion of
the solvent other petroleum fractions boiling within the range of
approximately 40.degree.C to 200.degree.C may be used. Mineral
spirits is a well known commercial product and is composed
principally of saturated aliphatic hydrocarbons boiling within the
range of apporoximatley 38.degree.C to 210.degree.C. For further
information as to the nature of mineral spirits attention is
directed to "Petroleum Products Handbook" by Guthrie, published by
McGraw-Hill 1960, pps. 11-14 to 11-15.
Although the mineral spirits used in formulating the blends
disclosed herein had a flash point of 38.degree.C as determined by
the Cleveland Cup method in general mineral spirits which fall
under the ASTM designation D235 may be used. In general, saturated
aliphatic petroleum solvents having a flash point not less than
100.degree.F may be used.
As previously pointed out other chlorinated and/or brominated
hydrocarbons may be used instead of the 1, 1, 1 trichlorethane and
methylene chloride in the preferred blend. However, care should be
used in selecting other halogenated hydrocarbons so as to avoid
health and ecological problems. For example, while chloroform is
effective as a component of the solvent, it presents health
hazards. Trichlorethylene is also effective but presents an
ecological problem.
Following are a number of examples of blends which have been
prepared and found to be highly effective. Percentages are by
weight.
EXAMPLE I
1, 1, 1 Trichlorethane 55% Mineral Spirits 34% Methylene Chloride
10% Nonylphenoxy polyethoxy ethanol 1%
This composition is not flammable when tested according to ASTM
Test Method D-92-57. It will dry completely and removes either wet
or dried ink. As measured by ASTM Test Method D-1901-67, the drying
time of this composition is about six minutes. This is an
acceptable rate for use on medium sized presses.
EXAMPLE II
1, 1, 1 Trichlorethane 40% Mineral Spirits 40% Methylene Chloride
19% Nonylphenoxy polyethoxy ethanol 1%
This blend was found not to be flammable when tested according to
ASTM Test Method D-92-57. When tested according to ASTM D-1901-67,
the drying time was about 10 to 11 minutes.
EXAMPLE III
1, 1, 1 Trichlorethane 44% Mineral Spirits 40% Methylene Chloride
15% Nonylphenoxy polyethoxy ethanol 1%
When tested according to the test methods of Examples I and II, the
drying characteristics were acceptable and the composition was
non-flammable.
EXAMPLE IV
1, 1, 1 Trichlorethane 46% Mineral Spirits 30% Methylene Chloride
23% Nonylphenoxy polyethoxy ethanol 1%
When tested according to the ASTM Methods applied in Examples I and
II, the blend was non-flammable and it dried in less than six
minutes. This blend is useful in cleaning smaller type presses.
EXAMPLE V
1, 1, 1 Trichlorethane 52% Mineral Spirits 35% Methylene Chloride
12% Nonylphenoxy polyethoxy ethanol 1%
When tested according to the ASTM Methods applied in Examples I and
II the blend was non-flammable and had an acceptable drying
time.
EXAMPLE VI
1, 1, 1 Trichlorethane 45.5% Mineral Spirits 38.0% Methylene
Chloride 15.0% Nonylphenoxy polyethoxy ethanol 1.5%
This composition when tested according to the aforesaid ASTM Test
Methods was non-flammable and had acceptable drying characteristics
for use in a press wash. It cleans without leaving a residue on the
press rollers or cylinders.
EXAMPLE VII
1, 1, 1 Trichlorethane 22% Perchlorethylene 24% Mineral Spirits 38%
Methylene Chloride 15% Nonylphenoxy polyethoxy ethanol 1%
When tested according to ASTM Test Method D-92-57 the composition
was non-flammable. It had an acceptable drying time when tested
according to ASTM Test Method D-1901-67 and is useful as a one-step
wash for presses.
EXAMPLE VIII
Methylene Bromide 47% Mineral Spirits 37% Ethyl Bromide 15%
Nonylphenoxy polyethoxy ethanol 1%
This blend had the desired non-flammable and drying
characteristics.
It will be seen therefore that I have succeeded in formulating a
cleaning solvent for printing presses and other printing equipment
which is capable of removing ink and other soil materials in a
one-step operation. The solvent formulation has the additional
advantages in that it is non-flammable and dries within a
relatively short period of approximately 3 to 13 minutes. By
judicious selection of the components of the blend and blending
within the ratios above set forth, a blend can be formulated which
dries slower or faster so that if the equipment to be cleaned is
small a faster drying blend can be formulated whereas if the
equipment is large it may be desirable to blend together
constituents which dry in a little longer period of time.
When used in the specification and claims, the term non-flammable
means non-flammable when tested according to ASTM Test Method
D-92-57. Drying time means drying time is determined by ASTM Test
Method D-1901-67.
* * * * *