U.S. patent number 3,773,477 [Application Number 05/280,119] was granted by the patent office on 1973-11-20 for clad aluminum base alloy.
This patent grant is currently assigned to Aluminum Company of America. Invention is credited to Michael K. McGinnis, Paul F. Wallace.
United States Patent |
3,773,477 |
McGinnis , et al. |
November 20, 1973 |
**Please see images for:
( Certificate of Correction ) ** |
CLAD ALUMINUM BASE ALLOY
Abstract
A composite clad sheet product made up of an aluminum base alloy
containing about 2.5 to 6% zinc, about 0.4 to 3% magnesium, about
0.2 to 1% manganese, and balance essentially aluminum, clad with a
magnesium-free aluminum base alloy containing about 0.5 to 1.8%
manganese. The product may have an outside porcelain enamel finish
and an inside cured organic resin finish and be in the form of a
cooking utensil.
Inventors: |
McGinnis; Michael K. (Lower
Burrell, PA), Wallace; Paul F. (New Kensington, PA) |
Assignee: |
Aluminum Company of America
(Pittsburgh, PA)
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Family
ID: |
27386580 |
Appl.
No.: |
05/280,119 |
Filed: |
August 14, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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147624 |
May 27, 1971 |
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787523 |
Dec 27, 1968 |
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Current U.S.
Class: |
428/654;
428/622 |
Current CPC
Class: |
B32B
15/016 (20130101); C22C 21/10 (20130101); C23D
5/00 (20130101); Y10T 428/12542 (20150115); Y10T
428/12764 (20150115) |
Current International
Class: |
C23D
5/00 (20060101); B32b 015/20 () |
Field of
Search: |
;29/197.5,194 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rutledge; L. Dewayne
Assistant Examiner: Weise; E. L.
Parent Case Text
This is a continuation of application Ser. No. 147,624, filed May
27, 1971 now abandoned, which was in turn a continuation of Ser.
No. 787,523, filed Dec. 27, 1968 now abandoned.
Claims
Having thus described our invention and certain embodiments
thereof, we claim:
1. A composite clad sheet product adapted for shaping into a
cooking utensil comprising an aluminum base alloy core having as
essential alloying components from about 2.5 to about 6% by weight
zinc, from about 0.75 to about 2% by weight magnesium, from not
less than about 0.3 to about 1% by weight manganese, not exceeding
about 0.25% by weight copper, and balance essentially aluminum, the
total amount of other elements other than aluminum, zinc,
magnesium, and manganese in said alloy core not exceeding about 2%
by weight, and, on at least one side of said core, a magnesium-free
aluminum base alloy cladding having as the essential alloying
component from about 1 to about 1.8% by weight manganese, not
exceeding about 0.15% by weight copper, and balance essentially
aluminum, the total amount of silicon and iron and other elements
except magnesium, manganese and copper in said alloy cladding not
exceeding about 1% by weight.
2. The composite clad sheet product of claim 1 wherein the core is
clad on both sides by the magnesium-free aluminum base alloy
cladding.
3. A composite clad sheet product comprising an aluminum base alloy
core having as essential alloying components from about 2.5 to
about 6% by weight zinc, from about 0.4 to about 3% by weight
magnesium, from about 0.2 to about 1% by weight manganese, and
balance essentially aluminum, and on at least one side of said core
a magnesium-free aluminum base alloy cladding having as the
essential alloying component from about 0.5 to about 1.8% by weight
manganese and balance essentially aluminum.
4. A clad aluminum base alloy article consisting essentially of an
aluminum base alloy having as essential alloying components from
about 2.5 to about 6% by weight zinc, from about 0.4 to about 3% by
weight magnesium, from about 0.2 to about 1% by weight manganese,
and balance essentially aluminum clad on at least one side thereof
with a magnesium-free aluminum base alloy cladding having as the
essential alloying component from about 0.5 to about 1.8% by
weight-manganese and balance essentially aluminum.
5. The clad aluminum base alloy article of claim 4 wherein said
clad aluminum base alloy has as essential alloying components
thereof from about 2.5 to about 6% by weight zinc, from about 0.75
to about 2% by weight magnesium, from not less than about 0.3 to
about 1% by weight manganese, not exceeding about 0.25% by weight
copper, and balance essentially aluminum, the total amount of
elements other than aluminum, zinc, magnesium and manganese in said
alloy not exceeding about 1.8% by weight, and said magnesium-free
aluminum base alloy cladding has as the essential alloying
component from about 1 to about 2% by weight manganese, not
exceeding about 0.15% by weight copper, and balance essentially
aluminum, the total amount of silicon and iron and other elements
except magnesium, manganese and copper in said cladding not
exceeding about 1% by weight.
Description
BACKGROUND OF THE INVENTION
This invention relates to a composite clad sheet product made up of
an aluminum base alloy core clad with another aluminum base alloy.
More particularly, it involves a clad aluminum base alloy composite
sheet which will form a highly satisfactory host for a vitreous
enamel coating on one side and a high temperature curable organic
resin coating on the other side.
A continuing problem in the aluminum industry has been the finding
of an aluminum base alloy product that will retain high mechanical
strength when subjected to the elevated temperatures required to
apply finishes such as vitreous enamels and heat-curing resinous
finishes. Such a product may not only retain its strength after
finishing heating cycles but must also be a satisfactory host for
finishes. To be commercially useful, the finishes must not only
adhere when applied but must continue to adhere during constant
use. Furthermore, such products must be capable of being fabricated
without having forming defects such as those commonly known as
earing, roping and the like.
It is known that one way of improving the strength of aluminum
sheet is by means of solution heat treatment. Such heat treatment
may be effected at the temperatures normally required to apply
vitreous enamel and heat-curing resinous coatings. However,
aluminum base alloys that are responsive to heat treatment at these
temperatures are not the best hosts for vitreous finishes. Cladding
alloys are known which will provide satisfactory host surfaces on a
heat-treatable, strong alloy core. However, until now a
firmly-bonded core-cladding combination has not been found which
will provide the desired high strength and dent resistance when
subjected to the heating cycles required for finishing while at the
same time furnishing a satisfactory host for the finishes, and
which will additionally be substantially free from forming defects
such as earing, roping and the like.
Clad products such as those of U. S. Pat. No. 3,377,145 are
satisfactory for providing moderate strength when coated with
vitreous enamel. However, such products are not satisfactory for
cooking utensil use. The reason is that when coated on one side
with vitreous enamel requiring heating at about 900.degree. to
1,050.degree.F. and on the other with a resinous coating curable at
about 675.degree. to 850.degree.F., they tend to lose their
strength and dent resistance. Furthermore, they cannot withstand
drawing or the like without exhibiting the above-mentioned defects
such as earing, roping and the like, nor will they have the
required integrity of bond between cladding and core. While for
known clad alloys the enamelling temperature improves strength by
amounting to solution heat treatment, the lower finish-curing
temperature generally acts as an anneal, thereby limiting the
strength of the finished product.
SUMMARY OF THE INVENTION
It is accordingly an object of this invention to provide an
improved clad aluminum base alloy composite sheet product. A
further object is to provide an aluminum clad sheet composite
product which profits by, rather than being detrimentally affected
by, thermal exposure such as that encountered during enamelling and
resin coating to form a houseware product. Still another object is
to provide a clad product which is of high strength after surface
finishing on one side with porcelain enamel fired at 950.degree. to
1,050.degree.F. and on the other side with an organic resin coating
which requires curing at a temperature of about 675.degree. to
850.degree.F., for example, polymers of halogenated ethylene or of
halogenated propylene, silicones, polyimides and the like. A
further object is to provide a clad product which can be formed
into useful articles devoid of forming defects such as earing,
roping and the like. Still another object is to provide a clad
product having cladding bonded securely to core and an integrity of
bond between cladding and core unaffected by heating used to apply
vitreous enamels thereto and to cure resinous coatings thereon and
by subsequent conditions of use. These and other objects will be
apparent from the description and claims which follow.
Our invention is predicated upon the discovery that an improved
aluminum base alloy clad product can be obtained by using a core
made up of about 2.5 to 6% by weight zinc, about 0.4 to 3% by
weight magnesium, and about 0.2 to 1% by weight manganese as
essential alloying components and balance essentially aluminum, and
a magnesium-free aluminum base alloy cladding on at least one side
of the core made up of about 0.5 to 1.8% by weight manganese as the
essential alloying component and balance essentially aluminum.
Magnesium may be present in the cladding as an impurity, but the
amount should not exceed about 0.005%. According to one embodiment
of our invention, the clad core may have a vitreous enamel applied
on at least one side over the surface of the cladding and may be in
the form of a cooking utensil with the cladding on both the outside
and the inside, a vitreous enamel coating applied to the external
or outer surface of the outside cladding and a coating of a
heat-curable organic resin on the internal surface of the inside
cladding. The heat-curable organic resin may be, for example, a
polyimide, a polymer of a halogenated ethylene or a halogenated
propylene such as polytetrafluoroethylene or a silicone. We have
found surprisingly that the thermal exposure to which the clad core
composite sheet of our invention is subjected during fusion or
curing of the finishes, normally deleterious when used on other
alloys or alloy combinations, somehow actually serves as a
beneficial heat treatment, for example, in improving the strength
and dent resistance or the like of the finished product.
The core alloy may contain small amounts of the usual silicon and
iron and the like impurities, for example, in percent by weight up
to about 0.5% of each. There may also be present up to about 0.5%
chromium, up to about 0.1% titanium or boron, and up to about 0.25%
copper, or the like. To achieve the results set out hereinabove,
however, the total amount of elements other than aluminum, zinc,
magnesium, and manganese in the core alloy should not exceed about
2%. The magnesium-free aluminum base cladding alloy may also
contain small amounts of silicon and iron and other elements except
magnesium not exceeding about 1%, that is, up to about 0.1% of
each. As mentioned above, the amount of magnesium must not be
greater than 0.005%. Preferably, the cladding alloy should contain
in percent by weight not more than about 0.15% copper and not more
than about 0.25% zinc.
Using a clad aluminum base alloy composite of the kind described
hereinabove, the heating incident to the resin curing operation,
which may be by fusion or cross-linking and is commonly referred to
as baking, is actually beneficial to the strength and
dent-resistance of the clad sheet composite product formed.
The aluminum clad sheet composite of our invention may be fashioned
by known rolling techniques or procedures. For example, the
cladding may be applied to the core alloy by hot rolling. The clad
sheet may then be formed into useful articles by known forming
methods.
BRIEF DESCRIPTION OF THE DRAWING
For a better understanding of our invention, reference will now be
made to the attached drawing, which is illustrative of one
embodiment of our invention.
In the drawing, broken away in part to illustrate layers, clad
cooking utensil product 10 consists of an
aluminum-zinc-magnesium-manganese alloy core 12 clad on both sides
with an aluminum-manganese alloy cladding 14 and coated on the
outside with a vitreous enamel finish 16 and on the inside with a
polytetrafluoroethylene or like heat-curable organic resin 18. The
utensil 10 may be provided with a handle 20, which may be of wood,
metal, plastic, or the like.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The following examples are illustrative of our invention.
EXAMPLE 1
A clad product was prepared having as the core an aluminum base
alloy nominally composed of aluminum, 4.5% zinc, 1.5% magnesium,
0.35% silicon, 0.35% iron, 0.10% copper, 0.3% manganese and 0.02%
titanium. A cladding of a magnesium-free aluminum 1.2% manganese
alloy was roll bonded to the core in accordance with commercial
practice. The clad product was rolled to sheet having a thickness
of 0.025 inch, the cladding being 0.0025 inch in thickness on each
side. Samples were taken from the sheet and degreased. A commercial
pigmented vitreous enamel slip was applied to the clad surface. The
samples were heated in an oven to 1000.degree.F., held at that
temperature for 10 minutes, withdrawn from the oven and cooled to
room temperature in air. To accentuate the effects of diffusing
elements into the cladding, the samples were reheated in the same
manner and cooled and the cycle repeated a third time. The samples
were then examined for spalling, shearing off, or breaking away of
the porcelain enamel according to the standard test described in
ASTM C 486. Substantially no spalling was detected.
EXAMPLE 2
The procedure of Example 1 was followed except that the cladding
was only about 0.0015 inch in thickness. Again, no spalling or
chipping away of the vitreous enamel was detected.
EXAMPLE 3
The clad product of Example 2 before enamelling was drawn into the
form of a deep pan cooking utensil. Vitreous enamel was then
applied to the outer surface and the utensil heated to
1,000.degree.F. for 10 minutes and cooled under ambient conditions.
The finish was substantially uniform in appearance and bright in
color. Afterwards, the inner surface was finished with a smooth
non-sticking polytetrafluoroethylene coating which was baked on at
750.degree.F. prior to natural cooling under ambient conditions.
The finished product was substantially dent resistant and had high
mechanical strength. Additional samples given the above-mentioned
double heating cycle had high strength and dent resistance and
retained substantially all of the high strength and dent resistance
when subsequently heated to temperatures such as ordinarily
encountered during cooking of foods in such a utensil.
While the invention has been described in terms of preferred
embodiments, the claims appended hereto are intended to encompass
all embodiments which fall within the spirit of the invention.
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