U.S. patent number 3,772,881 [Application Number 05/228,677] was granted by the patent office on 1973-11-20 for apparatus for controllable in-situ combustion.
This patent grant is currently assigned to Deutsche Texaco Aktiengesellschaft. Invention is credited to Hans Lange.
United States Patent |
3,772,881 |
Lange |
November 20, 1973 |
APPARATUS FOR CONTROLLABLE IN-SITU COMBUSTION
Abstract
A system of apparatus for controllable in-situ combustion in
subterranean hydrocarbon bearing formations containing bitumens
with simultaneous production and recovery of energy sources
supplying the mechanical and thermal energy required for the
in-situ combustion and operation of the facilities involved.
Inventors: |
Lange; Hans (Wietze,
DT) |
Assignee: |
Deutsche Texaco
Aktiengesellschaft (Hamburg, DT)
|
Family
ID: |
26720541 |
Appl.
No.: |
05/228,677 |
Filed: |
February 23, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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43547 |
Jun 4, 1970 |
3700035 |
|
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Current U.S.
Class: |
60/39.182;
60/39.55; 166/261 |
Current CPC
Class: |
E21B
43/243 (20130101); E21B 36/00 (20130101); E21B
36/001 (20130101) |
Current International
Class: |
E21B
36/00 (20060101); E21B 43/243 (20060101); E21B
43/16 (20060101); F02c 007/02 () |
Field of
Search: |
;60/39.55,39.18B
;166/272,261 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Croyle; Carlton R.
Assistant Examiner: Olsen; Warren
Parent Case Text
This is a division, of application Ser. No. 43,547, filed June 4,
1970, now U.S. Pat. No. 3,700,035.
Claims
We claim:
1. A system including apparatus for recovering oil from a
subterranean hydrocarbon-bearing formation by controllable insitu
combustion whereby means are provided for regulating the injection
of oxygen enriched gas, steam, and an exhaust gas containing carbon
dioxide into said injection well comprising:
a. a combustion chamber for producing a gas-steam mixture having
means for supplying thereto a fuel and an oxygen-containing gas,
burner means for combustion of said fuel, a closed means for
providing said combustion chamber with a first flow of water
thereby generating steam in said closed means, a means for
providing said combustion chamber with a second flow of water said
means having nozzles directed into said combustion chamber, means
for preheating said oxygen-containing gas, and means for exhausting
said gas-steam mixture from said combustion chamber into a
combustion turbine and thence into said injection well;
b. a first means for providing air to said system comprising a
first source of compressed air in communication with an oxygen
producing plant for producing a highly concentrated oxygen stream,
a compressor and a means for providing injection of said oxygen
concentrated stream into said injection well;
c. a second means for providing air to said system comprising an
air compressor in communication with said combustion chamber, said
air compressor being integral with a combustion turbine said
combustion turbine being driven by said exhaust gases from said
combustion chamber thereby generating power for said system of
apparatus, and said first air means and said second air means being
in communication with each other thereby to control the relative
volumes of compressed air provided to said oxygen producing plant
and said combustion chamber;
d. a means for providing water to said steam system comprising a
water treatment plant a first heat exchanger in communication with
said combustion turbine for passage of said exhaust gases from said
combustion turbine, a portion of said water from said treatment
plant being supplied to said combustion chamber whereby steam
generation occurs in said combustion chamber and a second portion
being supplied to said nozzles to supply steam in said combustion
chamber said steam being generated in said combustion chamber being
thereafter supplied into a steam turbine to provide power
generation and thence means for providing said steam to said
injection well;
e. means for providing said exhaust gas from said combustion
chamber into said combustion turbine and to said first heat
exchanger and thereafter providing means for injection of said
exhaust gas into said injection well.
2. A combustion chamber according to claim 1 having an external
wall, an interior wall and a tube supporting wall said tube
supporting wall tightly fitting to the bottom of said combustion
chamber thereby providing for the oxygen-containing air to be
supplied to the burner of said combustion chamber separately from
the circulation system of the steam and combustion gases.
3. A combustion chamber according to claim 1 wherein the tube
supporting wall is provided with openings fitted with injectors to
increase suction of water vapors and combustion gases from the
combustion chamber.
4. A combustion chamber according to claim 1 wherein said
combustion chamber is fitted with first and second tube systems,
separately controlled, said first tube system being open and
provided with injection nozzles directed into said combustion
chamber and said second tube system being closed and separate from
said combustion chamber for the production of high pressure steam,
said first and second tube systems being provided with means for
injecting water to control temperature.
5. A combustion chamber according to claim 1 wherein said
combustion chamber has a burner with horizontally superimposed
burner elements and a central jet directed downward.
6. A combustion chamber according to claim 1 wherein said
combustion chamber is fitted with exchangeable filter bodies for
absorbing solid or dust-like particles.
Description
FIELD OF THE INVENTION
This invention relates to a system of apparatus for effecting
in-situ combustion in subterranean hydrocarbon bearing formations
especially formations containing bitumens whereby the in-situ
combustion is controlled by using highly concentrated oxygen with
residual nitrogen and a partial and/or temporary supply of
superheated high-pressure steam, with simultaneous production of
energy suitable for operating the necessary above ground facilities
and auxiliary equipment.
DESCRIPTION OF THE PRIOR ART
In-situ combustion in subterranean hydrocarbon bearing formations
use low hydrogen petroleum residues as fuel for the combustion
front, and the heat developed from their combustion produces
additional combustional gases such as carbon monoxide and hydrogen
which together with the dissolved hydrocarbon gases and the
combustion product, such as carbon dioxide, escape from the
production wells in gaseous form. The heat from the combustion and
the heat contained in the steam formed in the burn-out matrix
behind the combustion front flows before the combustion front
heating the hydrocarbon bearing reservoir and reducing the
viscosity of the hydrocarbon therein and displacing the hydrocarbon
toward the production wells.
The combustible gas mixtures and the carbon dioxide escaped enter
into pressure-resistant fireboxes or pressure-resistant furnaces of
a special steam boiler, are burnt with evolution of heat by means
of highly concentrated oxygen with residual nitrogen or of air used
in heavy excess, and produce forms of energy, such as steam or hot
combustion gases under pressure, that may supply energies to the
facilities installed above ground and may also partly be introduced
into the deposit through injection boreholes.
The generation of combustion heat in the underground deposit and
the additional production above ground of different forms of energy
that are partly and temporarily supplied to the deposit from above
ground create a more comprehensive effect upon the content of the
deposit. The addition of high-pressure steam in quickly variable
amounts leads to an even spreading of the combustion front,
facilitates the start of the process in each injection borehole,
and increases the yield from the deposit. The use of carbon dioxide
recovered in minor quantities from the condensation plant improves
safety in the injection boreholes and also has a favorable
influence upon the yield. It is advantageous, therefore, to combine
all conditioning agents above ground so that they can be produced,
applied, and controlled with the operation of the surface plants.
The activated combustion gas can easily be varied in its
composition and adjusted to operating conditions at any given time.
In the starting phase, it may temporarily consist almost
exclusively of steam with little oxygen; in the actual burning
phase, it may contain plenty of oxygen with small quantities of
residual nitrogen and carbon dioxide. The formation of steam may be
either reduced by throttling down the supply of fuel gas, or it may
be increased to provide mechanical energy for covering other energy
requirements in the production field.
It is, therefore, an object of the invention to use various process
elements in the deposit and in the surface installations for making
available all necessary operating agents at short notice and in a
controllable manner. There are several possibilities of variation,
thus allowing of several application techniques. Moreover, the
plant and equipment involved can be readily transported owing to
their light weight and small dimensions, thus facilitating
adjustment to the conditions in oilfields being opened out.
SUMMARY
This invention relates to system of apparatus for controlling
in-situ combustion using highly concentrated oxygen with residual
nitrogen and a partial and/or temporary supply of superheated steam
together with simultaneous production of energy for the operation
of the necessary above ground facilities.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a diagramatic cross-section of the firebox.
FIG. 2 is a diagramatic cross-section of high-pressure steam
boiler.
FIG. 3 is a general illustration of the overall layout.
FIG. 4 is a diagramatic cross-section showing a double-walled steam
boiler.
DESCRIPTION OF THE PREFERRED EMBODIMENT
When using high pressures of injection into the borehole, such as
for steam coming from a closed system of tubes, it is envisaged
that the pressure of the feed water flowing in the annular space of
the double-walled firebox or steam boiler should be smaller or
slightly higher that that prevailing in the combustion chamber, and
only after leaving the annular space should the feed water be
pumped up to the pressure required for injection into the
borehole.
The invention achieves these objects mainly by producing hot
high-pressure steam in the combustion chamber, injecting water into
a pressure flame from an open system of tubes, and by additionally
producing high-pressure steam in a closed system of tubes. The two
types of steam may be used both for injection into the deposit and
for supplying surface installations. Moreover, a mixture of
separated dry carbon dioxide and residual nitrogen may be
introduced at combustion chamber pressure, or at increased pressure
after passing through a compressor, into the deposit via special
pipes in the injection boreholes.
Technically, these requirements are met by using means known per
se, such as a firebox or a steam boiler provided with a
high-pressure combustion chamber. Particularly suitable is a
firebox or steam boiler surrounded by a double wall forming an
annular space through which a cooling medium, such as the feed
water for the firebox or steam boiler, is passed, the surface area
of the interior wall being enlarged at the side of the flowing feed
water so that the interior and exterior walls will always have the
same temperature and thus the same expansion, enabling them to take
up high pressure from within the combustion chamber.
According to the invention, when using highly concentrated oxygen
at very high pressures up to and above 200 atmospheres, only a
small volume of combustion gases will be present in the combustion
chamber. Alternatively, at medium pressures ranging from 3 to 15
atmospheres, air will be used in heavy excess over the amount of
air required to provide combustion of the fuel, and part of the air
from the compressor for the combustion turbine before the steam
boiler will be branched off for the oxygen plant. In both cases,
however, flue gas is taken from the combustion chamber and steam is
taken from the high-pressure steam section for two different
purposes, the flue gas and the steam each simultaneously doing two
different jobs above ground and in the deposit. The temperature of
a flame is known to increase as the pressure of the gases in the
combustion chamber and the oxygen content of the combustion air
increase. The shorter the period of time during which a given
quantity of oxygen is converted to combustion gas, and the smaller
the combustion chamber volume in which this conversion takes place,
the higher the flame temperature will be. The pressure flame used
in the method of the invention meets all conditions that will
increase the flame temperature at a high rate of combustion. Thus,
it is a flame maintained in a small-volume combustion chamber. Its
characteristic feature is an extremely high flame temperature with
an extraordinarily strong radiation of heat, which cannot be cooled
down sufficiently by a system of water and steam tubes even with
normal circulation of the combustion gases. Almost invariably, film
evaporation will occur in the water tubes, which will further
deteriorate the cooling of the flame and will allow the
temperatures to rise to an undesirable degree. To that case, the
flow of feed water through the annular space between the two walls
will scarcely lower the temperatures in these walls sufficiently to
maintain adequate mechanical resistance values for the material of
the walls.
To eliminate these disadvantages, water is injected into the flames
so that a radiation-absorbing envelope of steam is formed around
the flames which will effect an inertialess reduction of the flame
temperature by evaporation of the water and will considerably
diminish the effect of heat radiation on the walls of the
combustion chamber. Heat distribution is further improved by
providing in the combustion chamber and near the double wall of
said combustion chamber a tube-mounted wall having circular
openings to permit circulation of the cooled-down steam.
In such steam boilers or fireboxes having pressure-resistant
features, it is also possible to withdraw from the combustion
chamber, from a condensation plant, or from a closed system of
tubes such combustion products as carbon dioxide with residual
nitrogen and steam in the desired temperature range, or cold dry
carbon dioxide with residual nitrogen, as diagrammatically shown in
the attached drawings.
The simplest case is illustrated in FIG. 1, when the oxygen with a
small amount of residual nitrogen is available at such a high
pressure that it can be forced into the deposit at 20 against the
pressure of the deposit, using an additional pressure of 50 to 75
atmospheres, a very small part stream of oxygen stream is
introduced at its full pressure into a double-walled
pressure-resistant firebox to be burnt with hydrocarbons to form
carbon dioxide with residual nitrogen and steam. Since the
combustion of hydrocarbons with highly concentrated oxygen leads to
very high temperatures endangering the steel construction material
of the firebox, water is injected at 15 and 16 through injection
tubes 6 and 11 directly into the flame in combustion chamber 18.
The injection water evaporates immediately thus reducing the
temperature in the combustion chamber. To be able to resist the
high pressures encountered, the firebox is surrounded with a double
wall 1 and 2, enclosing an annular space 3. For cooling the two
walls, the slightly preheated injection water is introduced into
annular space 3 at 13. At 14, the water can be separated into two
part streams and passed to the injection tubes via the inlet
openings 15 and 16. Inlet 15 provides an upper injection water
supply with injection openings 6 and inlet 16 provides a lower
injection water supply with openings 11. The upper injection
openings 6 form the steam envelope for protecting the combustion
chamber, and with the lower injection openings 11 the outlet
temperature of the combustion gases and vapors is adjusted to the
necessary temperature for entry into the injection borehole 28. The
tube-supporting wall 4 has openings fitted with steam injectors at
17 and further injectors 12 in the annular space 5 permitting
circulation via outlet 10 of part streams from combustion chamber
18 to provide balanced temperature conditions.
Oxygen 8 and hydrocarbon 9 enter into the burner (not indicated) at
7 and leave the combustion chamber as combustion products together
with steam from the injection water at 19, any entrained solids
being kept back by small refractory bodies 31, which may consist of
sintered iron or small ceramic bodies having large pores, to
prevent obstructions in the deposit. Through sluices 29 and 30 the
bodies 31 can be replaced without interrupting operations. A
completely unchanged stream from outlet 19 is introduced into the
interior corrosion-resistant tube 24 of the injection bore. After
cooling, a smaller part stream of dry carbon dioxide with residual
nitrogen passes into the annular space 27 of borehole 28 and
temporarily, alternating with the oxygen, into the annular space 25
of the ascending tube 26. Similarly, the hydrocarbon 23,
alternating with the combustion products and steam 21 and 22,
passes into the interior tube 24.
FIG. 2 shows an additionally installed closed system of tubes 32
which is used as a high-pressure steam boiler. Since the interior
wall 2 of the double wall is very closely covered with tubes, only
small amounts of radiation and conduction heat can reach this wall,
so that a special tube-supporting wall is not required. The water
for the high-pressure steam boiler entering at 13 and the injection
water pass through annular space 33 for cooling the double walls
and enter the two systems of tubes at 33 and 35 at a controlled
rate.
Combustion of the oxygen and hydrocarbons with cooling of the flame
as well as the entry of the combustion products formed into the
bore are effected in the same way as shown in FIG. 1. However, the
amount of fuel and oxygen must be increased to such an extent, that
the steam leaving at 39 can be used for operating steam turbine 36
and power generator 37, the waste steam being condensed in
condenser 38. Opening 34 is used for introducing water for
temperature regulation.
In FIG. 3 compressed air in the pressure range of 3 to 15
atmospheres is used as oxidation agent for combustion chamber 18,
while highly concentrated oxygen with residual nitrogen is produced
in an oxygen plant 57 on the oilfield and brought to the required
pressure by means of high-pressure compressor 59 so that it can be
introduced into the deposit in sufficient quantity through
injection borehole 28.
The overall layout shown in FIG. 3 provides for a complete
coordination of the methods of operating the in-situ combustion in
the deposit with the supply of installations above ground. It will
be desirable, however, to supplement the equipment shown in FIG. 3
by a firebox as shown in FIG. 1, so that in the event of breakdowns
or when starting the in-situ combustion no major pause or delay can
occur during which the fire in the deposit might be
extinguished.
Two separate plants are installed for the energy production,
accordingly the steam boiler with its pressure-resistant furnace is
equipped for using compressed air, part of which serves for the
production of oxygen. The second source of energy is based on
steam; the steam has a pressure sufficient for injection into the
borehole and is also used continuously or temporarily for driving a
turbogenerator 36 whose energy output is used for operating
installations above ground.
The inter-connected plate elements, air compressor 49 and
combustion turbine 50, are combined with a steam boiler forming the
combustion chamber. 85 percent .+-. 20 percent of the air is passed
into annular space 44 between walls 2 and 43, where it is
preheated. Then the air is passed through annular space 44 to point
7 and is mixed with the hydrocarbons 9 at the outlets to the burner
(not indicated). The mixture is burnt in combustion chamber 18
using a heavy excess of air.
From line 47, a part quantity of 30 percent .+-. 15 percent of the
compressed air is branched off to oxygen plant 57, supplementing
the quantity of air from air compressor 56. Thus, there are two
separate sources of air for the oxygen plant, each of which can
provide about 50 percent of the total air required.
The combustion gases formed in combustion chamber 18, being
products of the combustion of the hydrocarbons with compressed air,
have a high temperature. These gases are exhausted from the
combustion chamber 18 and are passed through combustion turbine 50
and thereafter passed into heat exchanger I and condenser I 52
wherein they are cooled by water provided from water treatment
plant 55. The gases and condensed water are passed to condenser II,
53. The condensate from condenser II is passed through pipe 15 with
openings 6, having been cooled to such an extent that no film
evaporation can occur in pipes 32. The injection water, introduced
through inlet 40 to pipe system 41 leading to the injection
openings 42 into the combustion chamber is controlled so that the
water entering the evaporator 45 at 46 is evaporated and the steam
is drawn off through pipe 39, having the desired temperature both
for the injection borehole 28 and for steam turbine 36 which may,
for example, drive the power generator 37. The volume of steam
formed by the injection water replaces the air from air compressor
49 branched off for oxygen plant 57, thus resulting in a total gas
volume or additional steam volume for combustion turbine 50 driving
power generator 51.
The waste steam from steam turbine 36 is partially condensed in
heat exchanger II (point 38, combined with condenser III), and the
residual steam in condenser III, point 38. The condensate is passed
via pump 2 into heat exchanger I, point 52, which receives its heat
from the waste gases of the combustion turbine 50. In heat
exchanger I, point 52, combined with condenser I, the feed water
from feed water treatment plant 55 introduced via pump 3 and the
condensation water from point 38 introduced via pump 2 are heated,
the water for the closed system of tubes 32 entering pipes 32 at 34
as a part stream. The steam from the injection water from
combustion turbine 50 having an inlet temperature of about
450.degree. C. is cooled in heat exchanger I, point 52, condensed
in condenser I, and mixed via pump 4 with part of the feed water 55
in condenser II, point 53. The heat from heat exchanger II and
condenser III is further used at point 38 for heating the wet
petroleum recovered from the deposit, thus separating oil and
water. The separated water can be used in other boreholes for
flooding purposes. Parts of the condensate obtained at 38 can be
introduced without heating into annular space 3 between walls 1 and
2 at point 13 via pump 1.
The combustion gases from chamber 18 and steam generated by
injecting water into the flame will enter the heat exchanger I
(position 52) via line 48 and combustion turbine 50. The
temperature of the gaseous mixture decreases from 950.degree. to
450.degree. C. while passing combustion turbine 50. Loss water from
apparatus 55 for dehardening the feeding water also will enter the
heat exchanger 52. The inside temperature of chamber 18 will be
controlled furthermore by injecting feeding water at 34.
Inside the condenser II (position 53) especially near its upper
warm end gaseous products, like nitrogen, oxygen, and carbon
dioxide will escape from the condensate. A mixture from carbon
dioxide and remaining nitrogen will be delivered at the bottom of
condenser 53 and supplied to the injection borehole 28.
Owing to the cold water the carbon dioxide and residual nitrogen
are also obtained cold containing very little steam, it may be
considered in the borehole as dry carbon dioxide which is not
corrosive even if it must be pressurized. With the same degree of
cooling the oxygen may also become non-corrosive after
compression.
Air from air compressors 49 and 56 is used for producing oxygen in
plant 57, almost all of the nitrogen escaping at 58. In compressor
59 the oxygen is sufficiently pressurized for passing into the
deposit via the injection borehole. Also in the case of combustion
chamber 18 using compressed air as oxidation agent for the
hydrocarbons from the deposit, the injection borehole 28 is
supplied with the necessary agents as shown in FIG. 1.
The double-walled combustion chamber with its walls 1 and 2 also
receives part of the feed water for reducing the temperature direct
from condenser III, point 38, at a pressure below that of
combustion chamber 18. The feed water enters the annular space 3 at
13, leaves it at 60, is brought to the pressure of the closed
system of tubes 32 by means of pump 61, and passes into the closed
system of tubes at 62.
In combustion chamber 18, the tube-supporting wall 4 is provided
within pipe wall 43 so that in annular space 5 with injectors 12
and 17, a circulating effect can be achieved at 10 by means of the
injection water introduced at 16 to create balanced temperature
conditions.
This special double-walled steam boiler thus supplies the injection
borehole 28 and turbines 36 and 50 so that a coherent system has
been provided and a maximum of conditioning agents is available for
controlling the in-situ combustion.
FIG. 4 is a diagrammatic drawing of a double-walled steam boiler
having a multi-stage burner and pressure-resistant upper and lower
cover plates. This design is suitable for higher pressures even at
temperatures of 300.degree. C.
For transport from one oilfield to the other, the exterior wall can
be removed so that the remaining low weight of the interior wall
with its installations permits its transport as a unit. The lower
rings 66 are suitably parted and fitted to the walls 1 and 2.
Thus, the exterior wall 1 and the interior wall 2 have inner and
outer rings 66 at the top and bottom. The upper ring 82 has
openings only for bolts 63.
The upper and lower cover plates 68 are welded to the inner rings
66 and 70.
By means of screw joints 63 and 64 the upper counter-ring 82 is
pressed on the soft iron rings 65 and rings 66 to form a tight
seal.
Additional seals are provided by rings 67 and 71.
The flange openings 69 are screwed to the upper and lower cover
plate rims 68. The burner with its inner opening 74 and its outer
opening 72 is welded or screwed to the upper flange opening.
The combustible gases enter at 9 and the oxidation agent at 44. The
oxidation agent passes from 47 into the annular space 44 formed by
walls 2 and 43. It passes between walls 72 and 73 and is mixed at
ring burners 75 and 78 or, respectively, 79 and 81, at the conical
outlet 80.
The burner having several ring burners 75 and 78 is able to produce
a very long downward flame through the vertical openings 79 and 81.
The feed water is introduced into annular space 3 at 13 and leaves
it at 60.
The bottom of the boiler casing corresponds in design to the top
part. The top and bottom of the boiler casing are practically
symmetrical.
* * * * *