U.S. patent number 3,772,124 [Application Number 05/235,413] was granted by the patent office on 1973-11-13 for method of forming tissue laminate.
This patent grant is currently assigned to Johnson & Johnson. Invention is credited to Warren C. Mayer.
United States Patent |
3,772,124 |
Mayer |
November 13, 1973 |
**Please see images for:
( Certificate of Correction ) ** |
METHOD OF FORMING TISSUE LAMINATE
Abstract
An impregnated paper product having strength, toughness, tear
resistance, softness, hand and breathability sufficient to permit
such papers to be used as substitutes for woven or non-woven
fabrics in making disposable fabric products. By applying
conventionally known strength imparting resins, polymers, and
copolymers to multi-ply, dry creped tissue papers of low basis
weight, which multi-ply laminate has the crepe removed therefrom as
a result of passing through an aqueous suspension or emulsion of
such resins, polymers or co-polymers, the stiffness, noisiness and
loss of breathability that result from such impregnation of single
ply creped or uncreped papers does not occur.
Inventors: |
Mayer; Warren C. (Somerville,
NJ) |
Assignee: |
Johnson & Johnson (New
Brunswick, NJ)
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Family
ID: |
27506438 |
Appl.
No.: |
05/235,413 |
Filed: |
March 16, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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22942 |
Mar 26, 1970 |
3720573 |
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671963 |
Oct 2, 1967 |
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Current U.S.
Class: |
156/324;
156/543 |
Current CPC
Class: |
B32B
29/005 (20130101); D21H 27/30 (20130101); B32B
29/00 (20130101); B32B 38/08 (20130101); D21H
25/06 (20130101); D21H 27/40 (20130101); D21H
23/42 (20130101); B32B 2601/00 (20130101); D21H
17/06 (20130101); B32B 2260/046 (20130101); B32B
2437/04 (20130101); Y10T 428/31906 (20150401); B32B
2260/028 (20130101); Y10T 156/1712 (20150115); Y10T
428/31909 (20150401); B32B 2250/26 (20130101); D21H
21/18 (20130101); D21H 23/56 (20130101); B32B
2432/00 (20130101) |
Current International
Class: |
B32B
38/08 (20060101); B32B 29/00 (20060101); D21H
27/40 (20060101); D21H 25/00 (20060101); D21H
25/06 (20060101); D21H 27/30 (20060101); D21H
17/06 (20060101); D21H 21/18 (20060101); D21H
21/14 (20060101); D21H 23/00 (20060101); D21H
23/42 (20060101); D21H 23/56 (20060101); D21H
17/00 (20060101); C09j 005/00 () |
Field of
Search: |
;156/324,547,183,543
;162/112 ;117/155 ;161/129,268 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Powell; William A.
Parent Case Text
RELATED APPLICATIONS FOR PATENT
This is a division of application, Ser. No. 22,942, filed Mar. 26,
1970 now U.S. Pat. No. 3,692,715.
Which is a continuation-in-part of application Ser. No. 671,963
filed Oct. 2, 1967 now abandoned.
Claims
I claim:
1. The method of making a laminated paper product suitable as a
substitute for woven and dry-laid non-woven fabrics comprising the
steps of:
a. superimposing at least two plies of a plies dry creped
tissue;
b. removing the crepe from each of said plis while impregnating
therein strength imparting polymeric resins by passing said
superimposed plies through an aqueous suspension or emulsion of
said resins;
c. removing the water from the suspension or emulsion impregnated
in said superimposed plies; and
d. curing said resins impregnated in said superimposed webs in
their water insoluble state.
2. The method according to claim 1 wherein said aqueous suspension
or emulsion contains from about 5 percent to about 50 percent
polymeric resin solids.
3. The method according to claim 1 wherein said superimposed plies
are passed through said suspension or emulsion at a rate of speed
sufficient to obtain a wet pick-up of the suspension or emulsion
ranging from about 75 percent to about 250 percent based upon the
combined weight of the superimposed plies.
4. The method according to claim 1 wherein each of said
superimposed plies of dry creped tissue has a basis weight ranging
from about 5 pounds up to 30 pounds, a crepe-based stretch level in
the machine direction ranging from about 5 percent to about 50
percent and an inter-fiber stretch level in the cross direction
ranging from about 2.3 percent to about 6 percent prior to
impregnation with said polymeric resin and removal of the crepe
therefrom.
5. The method according to claim 2 wherein said aqueous suspension
or emulsion contains about 15 percent polymeric resin solids.
6. The method according to claim 3 wherein said superimposed plies
are passed through said suspension or emulsion at a rate of speed
sufficient to obtain a wet pick-up of the suspension or emulsion of
about 150 percent based upon the combined weight of the
superimposed plies.
7. The method according to claim 4 wherein each of said
superimposed plies of dry creped tissue has a basis weight of about
10 pounds, a crepe-based stretch level in the machine direction of
about 15 percent and an inter-fiber stretch level in the cross
direction of about 4.5 percent prior to impregnation with said
polymeric resin and removal of the crepe therefrom.
Description
BACKGROUND OF THE INVENTION
This invention relates to paper, and more particularly, is directed
to improved paper products useful as a substitute for woven and
non-woven fabrics.
There has been and there continues to be a growing tendency for
single use disposable fabric products. This is particularly true in
the medical field and especially in modern hospitals where
disposable surgical drapes, caps, masks, gowns, bedding, and the
like have acquired wide acceptance. Similarly, disposable aprons,
towels, frocks, etc., are in ever increasing demand by food
processing and handling establishments. Even the clothing industry
today is looking to inexpensive disposable dresses as a fashionable
and practical item.
To satisfy the need for disposable products, it is readily apparent
that they must be made of inexpensive materials to warrant but a
single use. The first approach to making disposable fibrous
products was to substitute dry-laid non-woven fabrics for the woven
fabrics from which reusable products had been made in the past.
However, while this was a step in the right direction, such
non-woven fabrics are still relatively expensive and in many
instances have not reached full acceptance for disposable products
because of the expense involved.
Substituting paper and paper-like products for woven and non-woven
fabrics would be ideal for the making of disposable products, but
paper, in general, has had several serious drawbacks from the
standpoint of physical characteristics. While paper can be made
from very inexpensive wood pulp fibers at a very high rate of
speed, such papers that might be suitable as a substitute for
fabrics such as creped or uncreped tissues or waddings suffer from
an inherent lack of strength and toughness, particularly in the
cross direction.
Tear resistance and tensile strength of papers have been increased
considerably by saturating or impregnating them with polymeric
resins. Particularly suitable have been self-crosslinking acrylic
resins such as ethyl acrylates, ethyl hexyl acrylates, ethyl
acrylate-methylmethacrylate copolymers, ethyl hexyl acrylate-methyl
methacrylate copolymers, ethyl acrylate-polyvinyl acetate
copolymers, and ethyl hexyl acrylate-polyvinyl acetate
copolymers.
It is also well known that tear resistance and tensile strength can
be imparted to papers by the addition of other materials such as
styrene-butadiene polymers, methyl-methacrylates, urea formaldehyde
and melamine resins, etc. However, when papers are impregnated or
saturated with acrylic resins and such other polymeric materials,
the strength and tear resistance may be increased to acceptable
levels, but the papers do not have the desirable characteristics of
hand, drape, softness and breathability inherent in woven fabrics.
Some degree of softness can be imparted to resin impregnated papers
by the addition of glycerin or polyethylene glycol softeners to the
paper. But, even in such instances, the hand, drape and
breathability have been so inferior as to prevent the use of resin
or polymer strengthened papers as a substitute for woven or
non-woven fabrics.
SUMMARY OF THE INVENTION
I have found, quite unexpectedly, and for some unknown reason, that
if two or more plies of light weight, dry creped tissue or wadding
are superimposed and are then saturated or impregnated with an
emulsion of wellknown strength imparting resins of the types set
forth above, the resin bonded laminated, uncreped paper produced
does not loose to any appreciable degree its preimpregnated
characteristics of hand, drape, softness, and most importantly,
breathability. Further, by starting with dry creped tissues having
a relatively high level of stretch in the machine direction due to
the crepe, and then removing the crepe from the superimposed plies
by passing them through the aqueous suspension or emulsion of
resins, an overall resin bonded, uncreped laminate results in which
the stretch level due to internal fiberpolymer association in both
the machine and cross directions are increased and substantially
equalized. By contrast, if a single ply of light weight, dry creped
tissue wadding of the same basis weight as the combined basis
weight of the two or more plies of dry creped tissue wadding are
saturated with the same amount of the same strength imparting
resins, the tensile strength and tear resistance of the paper is
about the same, but it is hard, noisy and of greatly reduced
breathability.
Thus it is seen, that by using at least two superimposed sheets of
dry creped tissue prior to impregnation or saturation with the
strength imparting resin additives, not only is an uncreped paper
product produced that has increased wet strength and tear
resistance as would be expected, but also a paper product is
produced having excellent hand, drape, softness and breathability
making it eminently suitable as a substitute for woven or non-woven
fabrics in the making of disposable products of the type mentioned
above.
DESCRIPTION OF DRAWING
The present invention will be even more readily understood by
reference to the following detailed description when read in
conjunction with the attached drawings wherein:
FIG. 1 is a schematic flow diagram showing one method of making the
paper products of the present invention; and
FIG. 2 is a schematic flow diagram showing another method of making
the paper products of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
Treatment of papers with strength imparting resins is
conventionally accomplished by two well-known methods. These are
known as the "tubbing" or "impregnation" method and the "internal
addition" method. In the former, an aqueous solution of pulp from
which the paper is to be made is processed as a slurry and is
placed upon a screen where the actual formation of the paper sheet
takes place. Once the paper sheet is formed it is dried to extract
the water. The preformed paper sheet is then impregnated with an
emulsion of the particular resin desired. In the latter method, the
emulsion of the resin is added to the pulp slurry prior to the
paper sheet being formed on the screen. In both methods the paper
sheet, subsequent to being treated with the emulsion of the resin,
is heated to remove any water which may remain and to cure the
resin in its water insoluble state.
In practicing the present invention, the first mentioned tubbing or
impregnation method is required since at least two preformed dry
creped tissue sheets must be first superimposed before being
subjected to treatment with resin emulsion. After the preformed
sheets have been superimposed they are then passed through the
emulsion of the particular strength imparting resin employed. The
resin concentration of the emulsion and the speed with which the
paper is passed through the emulsion is controlled within limits to
give the desired tensile strength and tear resistance
characteristics as set forth more fully hereafter.
Referring now particularly to FIG. 1, the unique paper products of
the present invention are shown being made by first superimposing
two webs, 10, and 12, of dry creped tissue or wadding being
delivered from supply rolls 14 and 16, respectively. The
superimposed webs 10 and 12 then pass over a driven vacuum roll 18
which is provided in the usual manner to control tension in the
web. An idler roll 19 is provided to change direction of the web
prior to its passing over a spreader roll 20. The spreader roll 20
is a conventional "Mount Hope" type and is used to maintain the
combined web 10 and 12 at its maximum width and wrinkle free.
From the spreader roll 20, the combined web 10 and 12 is passed
into a nip 22 existent between a pair of superimposed, rotating
squeeze rolls 24 and 26, the latter of which is positioned with a
portion of its lower half in vat 28 containing an aqueous emulsion
or suspension 30 of the resins or polymeric substances to be
impregnated into the web. During its rotation, squeeze roll 26
picks up on its surface the resin or polymer suspension 30 and
carries it into the nip 22 where the webs 10 and 12 become
saturated with the suspension by impregnation. Rolls 24 and 26 are
normally biased together to exert a squeezing pressure on the webs
10 and 12 at the nip 22 to squeeze out and remove any excess of the
resin or polymer suspension from the web.
Because the webs 10 and 12 are a dry creped tissue or wadding
(i.e., the crepe has been imparted thereto while the paper is in a
dry state whereby the fiber to fiber bonds have been formed therein
while in the uncreped wet state prior to creping), passing through
the aqueous suspension 30 readily causes the crepe to be removed
therefrom, thus forming an uncreped, overall resin bonded laminate.
To further aid in removal of the crepe, however, vacuum roll 18
mentioned earlier, is driven at an angular velocity slightly under
the angular velocity of the squeeze rolls 24 and 26 thereby
imparting sufficient tension in the webs 10 and 12 to add a
mechanical force for the removal of the crepe.
From the squeeze rolls 24 and 26 the combined, saturated webs 10
and 12 pass through a conventional hot-air heating tunnel 32 to
drive off excess water and to start curing of the resin or
polymeric materials impregnated therein. Curing of the resin or
polymeric materials is completed in a series of conventional heated
can driers 34 following which the resin bonded, uncreped laminate
36 is rewound into rolls 38 ready to be made into disposable
products having true woven and non-woven fabric-like
properties.
In FIG. 2 of the drawings, the resin emulsion or suspension is
impregnated into the superimposed dry creped webs by passing them
directly into the vat containing the aqueous suspension or
emulsion. As shown, the webs 50 and 52 of dry creped tissue or
wadding are delivered separately from supply rolls 54 and 56
respectively into superimposed relationship over and under
respectively a pair of idler rolls 58 and 59. The superimposed webs
50 and 52 are then passed under the lower roll 66 of a pair of
superimposed squeeze rolls 64 and 66, which lower roll 66 is
positioned in a vat 68 with a portion of its lower half immersed in
the aqueous resin or polymeric suspension or emulsion 70 contained
therein. The combined webs 50 and 52 then follow around the lower
roll 66 passing through the nip 60 defined between rolls 64 and 66
where the excess emulsion or suspension picked up by the web is
squeezed out. From the following over the upper roll 64, the
impregnated and saturated web passes through the conventional
hot-air tunnel 32 and the series of heated can driers 34 to remove
excess water and to cure the resin or polymeric materials in
precisely the same manner as shown and described with respect to
the method depicted in FIG. 1. The resin bonded, uncreped laminate
36 is also then rewound into rolls 38 ready for use in fabric-like
products.
As with the method of FIG. 1, the crepe present in the dry creped
webs 50 and 52 is readily removed when the combined webs pass into
the aqueous emulsion or suspension 70 in the vat 68, thus assuring
overall resin bonding between the webs in the uncreped laminate
ultimately produced.
The papers used as the starting materials for making the products
of the present invention are of the class known as dry creped
wadding or tissues which are of a porous character having a
thickness ranging from about 2 mils to about 20 mils. Their basis
weight (each single ply) can be from about 5 pounds up to about 30
pounds which means the weight in pounds of a standard ream (3,000
square feet) of paper. Most preferred is a basis weight of about 10
pounds. As a dry creped paper, the wadding used As have a crepe
based stretch level in the machine direction ranging from about 5
to about 50 percent and most preferred is a stretch level of about
15 percent, and an inter-fiber stretch level in the cross direction
ranging from about 2.3 percent to about 6 percent and most
preferred is a stretch level of about 4.5 percent.
When two or more continuous webs of dry creped tissue or wadding
having the above characteristics, are superimposed prior to removal
of the crepe and impregnation with aqueous suspension of the
particular resins or polymers, the combined web will have a total
basis weight ranging from about 10 ponds to about 60 pounds and
most preferably about 30 pounds. Its machine direction stretch
level due to creping will remain substantially unchanged from the
individual plies as will the cross-direction stretch level due to
inter-fiber bonding.
The saturation bath in general will be made up of an aqueous
suspension or emulsion containing from about 5 to about 50 percent
resin or polymer solids and preferably about 15 percent solids. As
mentioned earlier, the particular resins or polymers used or
mixtures thereof, can be any or all of those well known in the
paper making art as strength imparting additives, whether they are
added to impart increased dry strength or wet strength or to
increase abrasion or tear resistance or any combination of such
properties to papers of all types. It is only essential in making
the uncreped, resin bonded paper laminate of the present invention
that a lightweight dry creped tissue or wadding be used as a
starting material and that at least two plies of such tissue or
wadding be superimposed prior to saturation or impregnation of the
superimposed webs with the strength imparting resins or
polymers.
The superimposed dry creped webs are delivered together to the
aqueous emulsion or suspension of resins or polymetic materials at
a controlled rate of speed to provide a dwell time in the
suspension sufficient to obtain a wet pick-up of the suspension or
emulsion ranging from about 75 percent to about 250 percent based
upon the weight of the combined superimposed webs. Most preferred
is a wet pick-up of about 150 percent of the suspension or
emulsion. The wet pick-up is further controlled by adjusting the
biasing force between the squeeze rolls where any excess pick-up of
the emulsion or suspension is pressed out of the webs.
Following such saturation, the saturated webs are dried at
240.degree.F-350.degree.F for about 2 minutes to remove the water
from the webs and to cure the resins or polymers in their water
insoluble state. Such treatment results in a lightweight, resin
bonded, uncreped paper laminate containing from about 10 percent to
about 30 percent resin and most preferred, about 20 percent of
resin or polymer solids based upon the weight of the dry resin
bonded laminate.
The resin bonded uncreped paper laminate thus formed exhibits
substantially equal stretch levels in both the machine and cross
directions, and since the crepe has been removed, the stretch
exhibited by the laminate is due solely to the internal resin-fiber
bonding relationship. The resin bonded, uncreped laminate produced
exhibits an internal resin or polymer-fiber stretch level in both
the machine and cross directions ranging from about 8 to about 20
percent and most preferred is a stretch level of about 13
percent.
It is also found that removal of the crepe in the aqueous solution
of the dry creped webs assures overall lamination of the webs and
reduces the bulk of the resulting resin bonded laminate, thus also
assuring low flexural resistance which, among other factors,
contributes to the paper laminate's fabric-like quality.
The paper product of the present invention, even though containing
hardening water-insoluble resins, has excellent softness, hand,
drape and breathability, Softeners such as glycerin or polyethylene
glycols are not required when practicing the present invention to
produce a suitable paper substitute for woven and non-woven
fabrics, but they may be included where it is desired to produce a
paper product having a very high degree of softness. When such
conventional softeners are used, they are added to the saturation
emulsion or suspension along with the resin or polymer solids. If
used at all, the bath will contain no more than 25 percent of the
glycerin or polyethylene glycols. But it is emphasized, softeners
are not required in most instances to make the unique resin bonded,
uncreped paper laminate of the present invention.
While I have described my invention with some degree of
particularity in the resins or polymers employed, it is to be
understood that such resins and many other equivalents are well
known in the paper making art, and that many substitutions can be
made while still remaining within the spirit and scope of the
invention as defined in the appended claims.
* * * * *