U.S. patent number 3,771,967 [Application Number 05/207,794] was granted by the patent office on 1973-11-13 for catalytic reactor with monolithic element.
This patent grant is currently assigned to Tenneco Inc.. Invention is credited to Hubert H. Nowak.
United States Patent |
3,771,967 |
Nowak |
November 13, 1973 |
CATALYTIC REACTOR WITH MONOLITHIC ELEMENT
Abstract
A catalytic converter adapter for use in the exhaust systems of
internal combustion engines comprises a tubular shell having a
differentially hardened fibrous lining to resiliently support,
insulate, and secure a monolithic type catalyst element.
Inventors: |
Nowak; Hubert H. (Jackson,
MI) |
Assignee: |
Tenneco Inc. (Racine,
WI)
|
Family
ID: |
22772026 |
Appl.
No.: |
05/207,794 |
Filed: |
December 14, 1971 |
Current U.S.
Class: |
422/179; 60/299;
422/180 |
Current CPC
Class: |
F01N
3/2853 (20130101) |
Current International
Class: |
F01N
3/28 (20060101); F01n 003/14 (); B01j 009/04 () |
Field of
Search: |
;23/288F ;60/299
;423/213,214 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Richman; Barry S.
Claims
I claim:
1. A catalytic reactor for use in exhaust systems of internal
combustion engines comprising a porous refractory catalyst element,
a tubular metal shell containing said element, and an annular
nonmetallic resilient fibrous layer located between the element and
shell, said layer being impregnated with a dried out colloidal
adhesive, fiber binding and rigidizing solution wherein the
colloidal material has been preferentially deposited out adjacent
the outermost faces of the layer.
2. A reactor as set forth in claim 1 wherein said dried out
solution serves to seal the outer surface of the porous element and
to bond the element and shell to the layer.
3. A reactor as set forth in claim 2 wherein the layer is in a
state of radial compression between said element and shell.
4. A catalytic exhaust reactor comprising a tubular metal shell, a
cylindrical fluid pervious frangible catalyst element inside said
shell, said shell having an inner surface and said element having
an outer surface spaced from said inner surface to provide an
annular space between said surfaces, an annular resilient
nonmetallic fibrous insulating member in said annular space and in
contact with each of said surfaces and serving to mount said
element in said shell, and an adhesive binder and rigidizer
material dispersed through said fibrous member in heavy
concentrations at the outside surfaces thereof to fluid seal the
exposed surfaces of the member and to bond the member to the shell
and element surfaces, the center portion of said member being
resilient and relatively free of said material to maintain
resilient support of the element in the shell.
5. A device as set forth in claim 4 wherein said material is
colloidal silica.
6. A catalytic reactor comprising a tubular metal shell, a gas
pervious refractory catalyst element inside said shell and arranged
so that flow through the element is substantially axial with
respect to the axis of the shell, means resiliently mounting said
element inside said shell so that the outer surface of the element
is spaced from the inner surface of the shell, said means
comprising a nonmetallic resilient fibrous insulating layer in the
space between said surfaces, said fibrous layer containing a
differentially dispersed solid material deposited on the fibers in
heavy concentrations adjacent the exposed surfaces of the layer and
adjacent the outer layer surfaces in juxtaposition to said element
and shell surfaces and in materially less concentration in the
center portion of the layer whereby said center portion is
resilient, said deposited material serving to harden and seal said
exposed and outer layer surfaces and to bond the outer layer
surfaces to said element and shell.
7. A reactor as set forth in claim 6 wherein said fibrous layer is
in contact with and bonded to said shell surface and said element
surface and in compression between them and serves to seal the
outside of said element.
8. A reactor as set forth in claim 6 wherein said layer comprises a
fibrous sleeve fitted over the element.
9. A reactor as set forth in claim 6 wherein said layer comprises
an overlapped fibrous blanket around the element.
10. A reactor as set forth in claim 6 wherein said layer comprises
spirally wrapped fibrous paper around the element.
11. A reactor as set forth in claim 6 wherein said layer, element,
and shell are positioned and arranged so that said element is at
all times out of contact with relatively moving metal parts of said
reactor.
12. A reactor as set forth in claim 11 wherein said fibrous layer
is in contact with and bonded to said shell surface and to said
element surface and in compression between them and serves to seal
the outer surface of the element.
13. A reactor as set forth in claim 6 wherein said material
comprises a dried out colloidal adhesive fiber binding and
rigidizing solution wherein the colloidal material has been
preferentially deposited out adjacent the outermost faces of the
layer.
14. A reactor as set forth in claim 13 wherein said material is
colloidal silica.
15. A catalytic reactor comprising a metal shell, a gas pervious
refractory catalyst element having an outer surface, and means
mounting said element in said shell so that said outer surface is
spaced from the shell, said means comprising a resilient layer of
high temperature resistant nonmetallic insulating fibers having one
side in contact with said outer surface and the other side in
contact with said shell, said layer containing dried adhesive
material dispersed therein and serving as a fiber binder and
rigidizer and to bond the layer to the outer surface and to the
shell, said adhesive material being of variable concentration in
said layer and being of lower concentration at the inner core of
the layer and of higher concentration adjacent the outer surfaces
of the layer.
Description
BRIEF SUMMARY OF THE INVENTION
It is the basic purpose of this invention to provide an improved
type mounting for a monolithic type or honeycomb catalyst element
which is suitable for mass manufacture and for use in exhaust
systems of automotive internal combustion engines.
The invention accomplishes this purpose by use of a nonmetallic
fibrous sleeve to mount the monolithic catalyst element on a metal
tube or shell which forms a part of the converter reactor
structure. The fibrous sleeve is impregnated with a suitable
binder, rigidizer, and adhesive which is differentially deposited
on drying to bind, bond, and seal the sleeve without destroying its
resiliency and thermal and shock insulating properties.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a diagrammatic side elevation partially broken away and
partly in section of an internal combustion engine exhaust system
incorporating the invention;
FIG. 2 is an enlarged section of the honeycomb catalyst element of
FIG. 1;
FIG. 3 is an enlarged cross section along the line 3--3 of FIG.
1;
FIG. 4 is a perspective view of another form of the fibrous wrap,
and;
FIG. 5 is a perspective view of a third form of fibrous wrap.
DESCRIPTION OF THE INVENTION
An internal combustion engine 1 has an exhaust manifold 3 that
discharges exhaust gases into an exhaust system 5 that includes an
enlarged exhaust pipe section 7 that carries gases to a sound
attenuating exhaust gas muffler 9 of a suitable construction which
in turn discharges gases into a tailpipe 11 that has an outlet
opening 13 through which gases flow to the atmosphere. In
accordance with this invention, and as a specific embodiment of the
broad concept of the invention, honeycomb catalyst means are
mounted within the metal exhaust pipe 7 which, therefore, serves as
a housing or outer shell for the catalyst means. Honeycomb
monolithic catalyst elements for use in elminating undesired
constituents in the exhaust gas stream of an internal combustion
engine are known in the art, and one type is described in detail in
U. S. Pat. No. 3,441,381. Generally speaking, the refractory
supports 15 are manufactured so as to have channels or passages 17
that enable gas to pass from the inlet face 19 to the outlet face
21. The desired catalytic material is deposited by a suitable
process on the walls of the cells of passages 17 so that the
exhaust gas is in contact with the catalyst as it passes through
the body 15. The refractory support 15 is relatively brittle and
has a different coefficient of expansion than the metallic housing
7, thereby creating a serious danger of damage during the
manufacture, assembly, and use of the catalytic unit. The present
invention provides a shock resistant means for mounting the
frangible refractory element 15 in a metal housing which serves
also to protect it during handling prior to operation of the
vehicle.
The refractory support member 15 is a part of a mounting and
support arrangement 23 wherein a nonmetallic resilient fibrous ring
29 encircles the outer circumference of the support body 15 and
serves as the means for resiliently mounting the body 15 inside of
a metal shell, such as that illustrated by the exhaust pipe 7. In
the unit of FIGS. 1, 2, and 3 the ring 29 is continuous or
integral, whereas the ring 29a of FIG. 4 is shown as an overlapped
blanket or wrap of fibrous material 5, and the element 29b is
indicated as a spirally wound member of layers which can be paper
thin and sufficient in number to build up the desired thickness of
the ring. Preferably, the fibrous ring is press fitted over the
honeycomb body 15 and into the shell 7 so that the natural
resiliency of the fibrous material 29 exerts radial pressure on the
outside of the body 15 and the inside of the shell 7. In a typical
assembly the element 15 might be 4 - 5 inches in diameter and the
thickness of ring 29 about 1/4 inch before compression and about
3/16 inch after radial compression in assembly with the element 15
and housing 7. Ordinarily, the outer surface of the body 15 is
uneven and irregular and the radially compressed fibrous layer 29
conforms itself to these irregularities and prevents bypassing
along the length of the outside face of the body 15.
The fibrous body is formed from materials that will withstand the
relatively high temperatures to which the catalytic elements are
subjected in use, thus, asbestos and ceramic fibers may be used.
These can be vacuum ring formed as an integral part 29, wet formed
from a blanket as the ring 29a, or wrapped from thin paper layers
as the element 29b. The materials known under the trademarks
"Fiberfrax", "Kaowool", "Cerafiber", and "Amosite" are typical of
materials that contain fibers of the type desired. "Cera Paper",
"Fiberfrax" ceramic paper, and asbestos paper can be used to form
the spiral wound element 29b.
In addition to the frictional connection provided by the ring 29
which serves to hold the unit 23 in place, it is preferred that the
fiber layer 29 be impregnated with a suitable adhesive, binder, and
rigidizer which, upon hardening, will adhere the fibrous material
to the metal shell 7 as well as to the refractory honeycomb 15. The
adhesive can be applied in various ways as by brushing, dipping,
rolling, spraying, etc. and the amount and composition of the
adhesive are controlled so that it is insufficient to cause
deposition on the walls of cells 17 and the desired differential
binder concentration or density and hardness is achieved. The
liquid adhesive also serves as a means to seal the fibrous layer
and the interfaces and to prevent bypassing of gas.
The adhesive is preferably a refractory cement that resists the
high temperature of operation (up to 2,300.degree. F). The
preferred fibers are ceramic and for these applications an adhesive
and rigidizer such as a colloidal solution of silica is preferably
used to provide surface hardening, bonding, and resistance to gas
flow erosion. By varying the amount of solutions applied to the
fibrous layer 29, 29a, or 29b, the surface hardness can be
controlled without sacrificing the resiliency needed in the center
of the fibrous layer during handling of the element and operation
of the vehicle. When the adhesive is dried out (as by application
of suitable heat) the colloidal material (such as silica) tends to
preferentially migrate, concentrate, and settle, due to
vaporization of the liquid vehicle, at the exposed ends and faces
where, upon hardening, it serves to provide a gas impervious
barrier to prevent bypassing or gas flow through the fiber layer
along the interfaces, or out of broken cell walls in the outer
surface of honeycomb element 15.
In use, exhaust gas leaving manifold 3 and entering pipe 7 flows
through the honeycomb element 23 where it is treated to remove
undesired constituents such as nitrogen oxides, carbon monoxide,
and unburned hydrocarbons. It then passes through the muffler means
9 where it is acoustically treated to remove undesired sound, after
which it passes to atmosphere through outlet 13. Gas is prevented
from bypassing the element 15 by the hardened binder in the layer
29.
The features described have many advantages. The sleeves 29, 29a,
and 29b provide a resilient interface between the element 15 and
the shell 7 that gives a high degree of mechanical shock resistance
and eliminate the need for stringent dimensional tolerances. The
high temperature withstanding fibers (such as alumina silica
refractory fibers) of the sleeves are stable up to the usual
maximum operating temperatures of about 2,300.degree. F so that the
reactors are safely positioned and insulated at all normally
encountered temperatures. The thermal insulating properties of the
layers 29 minimize the temperature of shell 7 to protect the
surrounding environment, provide for faster warm-up and better heat
retention in the catalyst, minimum cross sectional thermal
gradients due to conductive heat loss into the shell, and enable a
better selection of metals for use in the shell 7 because of metal
isolation from very high temperatures, for example, low grade, low
expansion stainless steel might be used. Substantially stress-free
relative movement between the elements 15 and shell 7 is provided
by layers 29 to accomodate different rates of thermal expansion and
contraction. The simple construction of the unit 23 enables the
thickness of layers 29 to be readily varied in accordance with the
degree of thermal and shock insulation desired. Effective positive
sealing against leakage around the outside of elements 15 is
obtained, in spite of the usual rough and broken exteriors thereon,
and there is no need for a special coating on the outsides of the
elements. The differentially hardened nature of the sleeves due to
migration of the colloidal material (e. g., silica) to the surfaces
where vehicle vaporization occurs provides a positive gas
impervious barrier that prevents gas entry into or flow out of the
fibrous layer as well as sealing and bonding along the interfaces
with shell 7 and element 15 while retaining resiliency in the
center of the sleeve. In unit 23 there is no possible abrasion of
element 15 by contact with metal.
Modifications in the specific details described may be made without
departing from the spirit and scope of the invention.
* * * * *