U.S. patent number 3,768,955 [Application Number 05/266,089] was granted by the patent office on 1973-10-30 for reactant ratio control process.
This patent grant is currently assigned to Universal Oil Products Company. Invention is credited to James H. McLaughlin.
United States Patent |
3,768,955 |
McLaughlin |
October 30, 1973 |
REACTANT RATIO CONTROL PROCESS
Abstract
The ratio of the reactants fed to a continuous exothermic or
endothermic reaction is controlled by measuring the thermodynamic
effect caused in a second reaction zone by the addition of a small
additional amount of any one reactant to the reaction products. The
amount of any reaction, and subsequent temperature changes, in this
second reaction zone corresponds to the deficiency of the added
reactant in the initial reaction zone. The difference between the
temperature of the material in this reaction zone before and after
the reactant addition is converted to an electrical signal supplied
to a controller which regulates the rate of flow of the added
reactant to the main reaction zone.
Inventors: |
McLaughlin; James H. (Des
Plaines, IL) |
Assignee: |
Universal Oil Products Company
(Des Plaines, IL)
|
Family
ID: |
23013136 |
Appl.
No.: |
05/266,089 |
Filed: |
June 26, 1972 |
Current U.S.
Class: |
431/12 |
Current CPC
Class: |
F23N
5/003 (20130101) |
Current International
Class: |
F23N
5/00 (20060101); F23n 005/10 (); F23n 001/02 ();
F23n 003/04 () |
Field of
Search: |
;431/12,8,2
;137/6,90 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: O'Dea; William F.
Assistant Examiner: Anderson; William C.
Claims
I claim as my invention:
1. A process for controlling at a preset value the ratio of the
reactants in a continuous reaction possessing a net heat of
reaction, which comprises the steps of:
a. passing at least a portion of the reaction products from an
initial reaction zone into a separate second reaction zone which
second zone is maintained at conditions suitable for initiation of
the reaction being monitored;
b. measuring the temperature of said portion of said first reaction
zone products;
c. adding to said portion of said first reaction zone products a
stream of one of the reactants;
d. measuring the temperature of the resultant mixture formed by
said portion of said first reaction zone products and the added
reactant stream; and,
e. regulating the flow of at least one of the reactants fed to the
initial reaction zone to maintain the two measured temperatures at
a predetermined temperature relationship corresponding to said
preset value of the reactant ratio.
2. The process of claim 1 wherein the reactants comprise an oxygen
containing gas and a fuel selected from the group consisting of CO,
H.sub.2, CH.sub.4, C.sub.2 H.sub.6, C.sub.2 H.sub.4, C.sub.3
H.sub.8, C.sub.3 H.sub.6, C.sub.4 H.sub.10 and C.sub.5
H.sub.12.
3. The process of claim 1 wherein the initial reaction zone and
said second reaction zone contain catalyst.
4. The process of claim 3 wherein at least the initial reaction
zone is located in a reaction vessel used in the conversion of
hydrocarbon material.
5. A process for adjusting the ratio of an oxygen containing gas to
fuel being fed to a primary combustion zone as reactants, which
process comprises the steps of:
a. passing at least a portion of the flue gas from the primary
combustion zone to a second combustion zone maintained at
conditions suitable for the initiation of combustion;
b. measuring the temperature of the flue gas entering said second
combustion zone;
c. adding to the flue gas in said second combustion zone a quantity
of one of the reactants that is equal in temperature to the flue
gas at the point of addition;
d. measuring the temperature of the gas mixture formed by the
additions made in step (c) as said gas mixture leaves said second
combustion zone;
e. comparing the temperature determined in step (d) to the
temperature determined in step (b); and,
f. regulating the ratio of fuel and air fed to the primary reaction
zone to maintain the relationship between the compared temperatures
of step (e) at a value corresponding to the desired ratio of air to
fuel fed to the primary combustion zone.
6. The process of claim 5 wherein the added reactant is the
fuel.
7. The process of claim 5 wherein the added reactant is air.
8. The process of claim 5 wherein the added reactants are
alternately switched so to control the total reactant ratio.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The field of the art to which the claimed invention pertains is the
control of the ratio of reactants in a continuous reaction. More
specifically, the invention provides a means for the continuous
control of the ratio of a fuel to an oxygen containing gas in a
combustion process. In a specific application the ratio of a fuel
gas to air in a premixture to a burner is controlled to maximize
the flame temperature and the efficiency of the combustion
process.
2. Description of the Prior Art
The prior art in the determination of premixture compositions has
called for both primary flame temperature measurement and optical
observation of a secondary flame produced by the addition of air to
the reaction products.
The primary flame temperature is used in the art as a guide to the
efficiency of the combustion. This flame temperature is dependent
on the composition of fuel being burned and on whether or not the
ratio of air to fuel is at an optimum. If air is in an excess, this
excess must be heated resulting in the waste of available energy
and the lowering of the flame temperature. If the fuel is in
excess, incomplete combustion occurs resulting in an inefficient
operation, lower flame temperature, a reduction in the available
heat, and wasted fuel. Combustion products normally proceed
directly to an exhaust system and incomplete combustion would
therefore produce an air pollution problem unless the gases are
properly treated.
The prior art, as exemplified by U. S. Pat. No. 2,603,085, teaches
the monitoring of the primary flame temperature as a guide to the
efficiency of the combustion. If a deviation from the normal
temperature is noticed the gas to air ratio is adjusted. To
determine which reactant is in excess, the hot flue gases are
allowed to contact air at a second combustion zone and the presence
or absence of a flame at this second zone is taken as an indication
of the corresponding presence or absence of excess fuel. The second
combustion zone is observed visually during this manual adjustment
process until the combustion ratio is again optimized and the flame
is not present.
My invention resides in the use of the temperature change caused by
the addition of a small amount of one reactant to a reaction zone
product stream as an indication of the initial reactant ratio. If
the addition of hot air to equally hot flue gas promotes
combustion, the heat generated will raise the temperature of the
flue gas at this point above that present before the point of air
addition. There is no necessity to view the second zone manually.
This process allows the continuous optimization of the reactant
ratio independently of changes in fuel gas composition or pressure
and also makes it possible to locate the control system in places
where visual observation is difficult due to high temperatures or
incon-venience. This process provides for continuous prevention or
reg-ulation of excesses of either fuel gas or air whereas the prior
art shows only a point in time optimization.
SUMMARY OF THE INVENTION
The method by which the process of the present invention controls
the ratio of reactants fed to a first reaction zone, con-taining
either a continuous exothermic or endothermic reaction, is by
converting into an electrical signal any temperature change caused
by a chemical reaction in a second reaction zone, wherein the
reaction products while at reaction supporting conditions are
contacted with a small amount of one reactant. This electrical
signal is fed to a con-troller which compares the signal to a
predetermined optimum value and which in turn adjusts the flow rate
of the added reactant to the first reaction zone. The presence of a
reaction in the second reaction zone displaces the normal energy
balance that is in effect when the desired reactant ratio is
present in said first reaction zone.
DESCRIPTION OF THE DRAWING
In the simpler application of the invention shown in FIG. 1 of the
drawing, fuel entering by line 1 is mixed with air from line 2 to
form a premixture in line 3 which is burned at burner section 4
contained in furnace 5. Combustion products flow upward through
flue 6 with a small portion of them passing through flow isolation
means 7, over heat transfer means 8, past thermocouple 10, mixing
with a small amount of air at nozzle 9 on air line 17 and past
thermocouple 11 before leaving the flow isolation means 7. Voltages
produced in thermocouples 10 and 11 are carried by means 12 and 13
to controller 14 which sends a signal by means 15 to a control
valve 16 on the air line 2. A small line 17 carries an air flow
preset by valve 18 and monitored at rate measuring device 19 to the
nozzle 9. This embodiment of the invention regulates the amount of
air added to the premixture to maintain complete combustion.
A more sophisticated application of the invention shown in FIG. 2
provides a process for regulation of the extent of the combustion
by the addition of either air or fuel to the temperature measuring
zone. Air flow through line 20 to a combustion zone not shown is
controlled by main valve 21 driven in response to a signal carried
by means 33 from controller 32. The flue gases from the combustion
zone pass through chimney 22 and a small portion enters flow
isolation zone 23. This portion is controlled by valve 24,
monitored by rate indicator 25, mixed with any reactant added
through line 36, temperature equilibrated with a second entering
reactant stream by heat transfer means 26, passed over thermocouple
27, mixed with said second reactant stream at nozzle 28 on line 38,
passed over thermocouple 29 and discharged from the flow isolation
zone 23. Signals from thermocouples 27 and 29 are passed to
controller 32 by means 30 and 31 for use in adjusting the main air
flow. This flow is common to all variations of this application of
the invention.
There are 3 basic variations to this embodiment which consist of;
(1) adding air at nozzle 28, (2) adding fuel at nozzle 28, and (3)
adding air through line 36 simultaneously with air addition at
nozzle 28, within each variation the rate of addition being
monitored by the controller. The first variation has a small air
flow from line 34 pass into line 35 and through valve 39 to travel
by line 38 through rate indicator 40 to nozzle 28. Signals from
rate indicator 40 and to valve 39 respectively are carried by means
41 and 42. The purpose of this arrangement, like that of the
previous simple embodiment, is to insure that sufficient air is
being fed to the combustion zone. The controller 32 adjusts main
valve 21 by means 33 according to the temperature change
detected.
The second variation allows the detection of an insufficient fuel
flow to the combustion zone to perform the optimization using fuel
as the added reactant. Fuel flows by line 43 through valve 37,
which is controlled through means 44, line 38 and flow indicator 40
to nozzle 28 for mixture with the flue gases. As in the first
variation, the controller 32 then adjusts the combustion mixture
according to signals from thermocouples 27 and 29.
The third variation permits a controlled amount of air from line 34
to flow through line 36, valve 45 controlled by means 46, flow rate
indicator 47 and heat exchange means 48 to contact and complete the
combustion of the flue gases in isolation zone 23 prior to the
first temperature measurement. Simultaneously, the effect of air
addition at nozzle 28 by the method of the first variation is
determined by thermocouples 27 and 29. The ratio of flue gas to air
added by line 36 is monitored by the controller 32 through means 49
and 50 and adjusted with control valves 24 and 45 controlled
through means 51 and 46. The air addition ratio is combined with
readings from thermocouples 27 and 29 to enable the controller 32
to adjust main control valve 21 for any desired air deficiency
ratio.
The drawing of preferred embodiments of the invention and the
description are not intended to place any limitation on the
invention and are meant as examples only. Modifications and
additions as are obvious to those skilled in the art may be
beneficial to the utilization of this invention are included within
the scope of this description. Pneumatic, electrical or fluidic
control means are applicable for use with this invention, as is any
suitable type of valve or other means to control the various gas
flows. The controller may be either analog or digital and may
receive its signals from thermocouples as suggested or from
thermistors, expansion tubes or pyrometers.
DETAILED DESCRIPTION OF THE INVENTION
This method of controlling a reactant ratio is applicable to any
reaction that is either exothermic or endothermic and that is
suitable for a continuous operation. The reactant ratio will
normally be at a preset value established to ensure some desired
reactant concentration in the reaction products, which may be zero.
The examples given so far have been concerned with the combustion
of a fuel gas which could be a natural gas, hydrogen, carbon
monoxide or a vaporized liquid fuel. Hydrogenation of a diene or
halogenation of an alkane are two other common reactions having a
net heat of reaction and which are therefore suitable for
application of this method. The regulation of the amount of air fed
into a catalytic muffler or CO.sub.2 --CO--O.sub.2 ratios in a
fluidized catalytic cracking process are other possible uses. The
process of this invention is not restricted to combustion or to a
chemical reaction. It is adaptable to any situation in which
contacting two fluid streams creates a positive or negative heat
generation such as the mixing of a strong acid and water where a
standard solution would be used as the added reactant. The place at
which the controlled reactant flow is consumed is referred to as
the initial, or first, reaction or combustion zone.
The most direct application of this invention is the maintenance of
the exact reactant ratio necessary for complete reaction of all
material fed to the reaction one. The extent of a reaction can also
be controlled by this process by the proper selection of the
desired temperature change that occurs in a second reaction zone.
The second reaction or combustion zone comprises a zone separated
from the primary reaction zone and containing a temperature
measuring means located upstream and downstream of the point at
which the controlled reactant is added to the primary reaction zone
products. If it is desired to maintain a 1:1 CO to CO.sub.2 ratio
in a furnace flue gas, a specific positive temperature rise in the
second reaction zone would be desired when adding air to the flue
gas in this second zone whereas for complete combustion to CO.sub.2
no temperature rise would be desired. Incomplete reactions may be
desirable for economic reasons in chemical conversions where there
is a decrease in selectivity with increased conversion.
There are two methods in which this process can be operated to
provide a less than complete chemical reaction. The first method is
to calibrate the amount of temperature change in the second
reaction zone caused by the addition of a known amount of
additional reactant versus the degree of reaction, and then to set
the control device to maintain the temperature relationship
corresponding to the desired degree of reaction and preset reactant
ratio value. The second method is to add to the reaction products a
proportioned amount of the missing reactant before the first
temperature measurement and to set the control device to maintain
no temperature change in the second reaction zone. In this second
method, this first amount of the reactant added must be regulated
to be that which will bring the reaction products to be totally
reacted before they enter the two temperature measurement zones.
This amount may be determined most easily by the control process
itself by having the flow of this first added reactant stream
regulated by a flow control valve which is operated by the
controller in response to the signals it receives from the two
temperature measuring points. This may be described as an internal
control loop contained within the control loop for the main
reaction zone. The amount of the first controlled flow of reactant
required to produce no temperature change in the temperature
measurement zone, where an additional amount of the same reactant
is added, is a direct measurement of the deficiency of the reactant
in the main reaction zone and can therefore be used to regulate
this deficiency. Both the first and the second method require that
the rate of flow of reaction products into the control zone is
known.
In those cases where complete reaction of all reactants is desired,
it is best to have a separate temperature measurement zone and
reactant addition point for each reactant. The process can then
easily adjust the flow rates to avoid either an excess or
deficiency in any reactant. For example, optimum combustion
efficiency occurs when there is no excess of either air or fuel,
and at separate points a small amount of fuel and air should be
contacted with the flue gas. The complete usage of both available
fuel and air in the main burner would be shown by no combustion
being present at either point of reactant addition.
This method of control is independent of any changes in fuel gas
composition or rate of flow to the main burners. The process is
versatile, continuous and automatic. These features are all
improvements over the prior art.
As previously mentioned, the optimum control of a reaction in which
it is desired that there be no excess of any reactant necessitates
a separate temperature indication for each reactant. In the
advanced control system of the drawing, only one temperature
measurement zone is required if the controller is preset to switch
between reactants entering the zone and is properly programmed to
interpret the results. The different reactants may be fed to the
single zone through a header system with automatic flow control
valves.
The amount of reactant added to the secondary reaction zone should
be kept small enough to avoid attenuating the thermodynamic effect
caused by its addition by increasing the total reactant stream to
more than required. The amount of this addition can be either
preset manually or determined by the controller. An advantage of
the second method is that the controller may be programmed to
occasionally shut off the flow of the added reactant and to compare
the two temperature readings. In this way the system can rezero
itself and check for a malfunction automatically. The additional
reactant should be heat exchanged wtih the incoming reaction
products prior to the first temperature measurement. This is done
to prevent any extraneous thermodynamic effect in the secondary
reaction zone caused by an added reactant stream's temperature. The
added reactant may be cooler than the flue gas, but the controller
would require programming for this arrangement. Complete reaction
would be indicated by a temperature drop, but a deficiency of the
added reactant in the feed to the main reaction zone would cause a
change from this normal temperature difference.
The drawing shows the secondary reaction zones located in the flue
of a furnace. It is assumed that at this location the temperature
of the flue gas would be sufficient to cause spontaneous ignition
of any combustible mixture that occurs with the addition of either
more air or fuel. The invention as it relates to this application
is not limited to this location. A portion of the flue gas may be
diverted into an insulated or heated secondary reaction zone
located at quite a distance from the flue. There is no compelling
reason to maintain the reaction products at an elevated temperature
if this is inconvenient. Rather, a source of ignition such as an
electrically heated wire would be sufficient to make the invention
operable. The placement of the secondary reaction zones in contact
with the hot reactant flow, in this example a flue gas, does have
the advantage of maintaining an even temperature distribution. The
flue gas flow acts as a temperature bath which prevents uneven
temperature gradients. The inclusion of an ignition source
introduces a secondary heat source and must be accounted for in the
operation of the temperature monitoring apparatus.
The use of catalytically promoted reactions is universal among the
chemical process industries. The method of this invention is
applicable to those reaction vessels which contain catalyst, but it
is required that the reaction zones contain identical catalyst
which has had equal usage. This is necessary to assure that effects
caused by a difference in catalytic activity are not confused with
effects caused by the addition of more reactant.
PREFERRED EMBODIMENT
The preferred embodiment of this invention is the regulation of the
amount of air or fuel being fed to a combustion zone, to maintain a
desired ratio between the fuel and air, by a process which
comprises the steps of: (a) passing reaction products from an
initial combustion zone to a second separate combustion zone; (b)
measuring the temperature of the reaction products as they enter
the second zone; (c) adding to the reaction products in the second
zone, a small stream of one of the reactants; (d) measuring the
temperature of the stream formed by the reaction products and the
additional reactant as it leaves the second combustion zone; (e)
converting the two temperatures into electrical signals fed to a
control device; and, (f) adjusting the ratio of the added reactant
to the other reactant to maintain the relationship between the two
measured temperatures at a preset value corresponding to a desired
degree of combustion in the initial combustion zone.
* * * * *