U.S. patent number 3,768,271 [Application Number 05/218,738] was granted by the patent office on 1973-10-30 for method and plant for storing and transporting a liquefied combustible gas.
Invention is credited to Louis Henri Daniel Denis.
United States Patent |
3,768,271 |
Denis |
October 30, 1973 |
METHOD AND PLANT FOR STORING AND TRANSPORTING A LIQUEFIED
COMBUSTIBLE GAS
Abstract
For the purpose of storing and transporting a liquefied
combustible gas, in a methane tanker for example, together with a
virtually inert gas such as nitrogen in contact with said
combustible gas, use is made of additional energy either, as the
case may be, in order to liquefy the inert gas -- utilizing the
evaporation of the combustible gas to that end -- or in order to
reliquefy the evaporated combustible gas -- utilizing the
evaporation of the liquid inert gas to that end.
Inventors: |
Denis; Louis Henri Daniel
(Paris, FR) |
Family
ID: |
9070515 |
Appl.
No.: |
05/218,738 |
Filed: |
January 18, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Jan 19, 1971 [FR] |
|
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7101682 |
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Current U.S.
Class: |
62/50.3;
220/88.3; 422/40 |
Current CPC
Class: |
F25J
1/0052 (20130101); F25J 1/0221 (20130101); F25J
1/025 (20130101); F17C 9/04 (20130101); F25J
1/0251 (20130101); F25J 1/005 (20130101); F25J
1/0037 (20130101); F25J 1/023 (20130101); F25J
1/0072 (20130101); F25J 1/0288 (20130101); F25J
1/0204 (20130101); F25J 1/0015 (20130101); F25J
1/0025 (20130101); F25J 1/0277 (20130101); F25J
2210/42 (20130101); F17C 2221/033 (20130101); F17C
2223/0161 (20130101); F17C 2221/014 (20130101); F25J
2290/62 (20130101); F17C 2270/0105 (20130101); F25J
2210/62 (20130101); F25J 2210/60 (20130101) |
Current International
Class: |
F17C
9/00 (20060101); F17C 9/04 (20060101); F25J
1/00 (20060101); F25J 1/02 (20060101); F17c
007/02 () |
Field of
Search: |
;62/45,55 ;114/74A
;220/88B ;23/281 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Perlin; Meyer
Assistant Examiner: Capossela; Ronald C.
Claims
I claim:
1. In a system for handling a liquefiable combustible gas for
storage and transportion, including a container for liquefiable
inert gas in liquid form, a container for a liquefiable combustible
gas in liquid form, a source of said inert gas in gaseous form, and
a source of said combustible gas in gaseous form, an improved
arrangement for optionally liquefying a selected one of said gases
in gaseous form for delivery to the corresponding container
comprising:
a. means for circulating said inert gas through a refrigeration
cycle including an expansion stage, a compression stage, and power
means for supplying to said compression stage at least a portion of
the energy required thereby;
b. heat exchange means through which said circulating inert gas
passes while in expanded cooled condition;
c. means for expanding one of said gases from its liquefied form in
the corresponding container and passing the expanded cooled gas
through said heat exchanger;
d. means for applying the cooling effect of said two expanded gases
to the selected gas from its source to liquefy said gas; and
e. means for delivering the thus liquefied gas to the container
therefor.
2. The system according to claim 1 including
f. means for passing surplus expanded combustion gas from said
liquefied combustion gas container in heat exchange relation with
said cooled inert gas to re-liquefy the same for return to said
container, liquefied inert gas from the container thereof being
expanded to cool the same and passed in cooled condition through
said heat exchange means (b).
3. The system according to claim 2 wherein compressed inert gas
from said compression stage is cooled by passage through said heat
exchange means (b) and then passed in heat exchange relation with
said expanded combustible gas in means (f).
4. The system according to claim 1 wherein said inert gas after
compression in said compression stage is cooled to liquefy the same
and a fraction of said liquefied inert gas is delivered to said
inert gas container, and make-up fresh inert gas from said source
thereof is added to said circulating means.
5. The system according to claim 4 wherein said compressed inert
gas is cooled by passage through said heat exchange (b).
6. The system according to claim 4 including means for combusting
said combustible gas and wherein said inert gas is extracted from
the flue gases of said combusting means.
7. The system according to claim 6 wherein said combusting means is
a boiler and including further means for treating the resulting
smoke, which further means include means for eliminating the carbon
dioxide from the smoke whereby to extract nitrogen inert gas
therefrom, and a booster connected to said circulating means for
compressing this nitrogen and injecting it into said circulating
means whereby to liquefy it.
8. The system according to claim 6 wherein liquefied combustible
gas from said container thereof is expanded and passed through said
heat exchange means before being combusted in said combusting
means.
9. In a method of handling a liquefiable combustible gas for
storage and transportion, including a container for liquefiable
inert gas in liquid form, a container for a liquefiable combustible
gas in liquid form, a source of said inert gas in gaseous form, and
a source of said combustible gas in gaseous form, an improved
arrangement for optionally liquefying a selected one of said gases
in gaseous form for delivery to the corresponding container
comprising:
a. circulating said inert gas through a refrigeration cycle
including an expansion stage, a compression stage, while supplying
to said compression stage at least a portion of the power required
thereby;
b. passing said circulating inert gas while in expanded cooled
condition through a heat exchanging zone;
c. expanding one of said gases from its liquefied form in the
corresponding container and passing the expanded cooled gas through
said heat exchanging zone;
d. applying the cooling effect of said two expanded gases to the
selected gas from its source to liquefy said gas; and
e. delivering the thus liquefied gas to the container therefor.
Description
This invention covers a method and a plant for storing and
transporting a liquefied combustible gas, such as the plant aboard
a methane tanker, in which use is made of a virtually inert gas
such as nitrogen which may be in contact with the combustible gas
and exist likewise in liquid form in the plant.
In certain cryogenic plants it is occasionally required to
alternately liquefy one of two gases, depending on the phases of
operation of the plant.
A case in point arises with ships used to transport liquid
hydrocarbon gases, usually methane tankers. In such vessels several
possible operating modes or phases exist, with variants in each
case.
In one mode of operation, when the tanker is travelling empty
towards its loading port, an inert gas, usually nitrogen, is
required in order to place and maintain the liquefied natural gas
tanks in a neutral atmosphere until the port is reached. For this
reason such vessels are equipped with liquid nitrogen tanks or with
inert-gas generators.
In a second mode, corresponding to the tanker loading phase, a
similar requirement for liquid nitrogen exists during these
operations in order to maintain the atmosphere neutral before the
methane gas fills all the spaces not occupied by the fuel.
In a third mode, when the loaded tanker leaves the port on its way
to the terminal port, the ship consumes in its propulsion machinery
the natural gas that evaporates from the tanks, or approximately
0.1 to 0.3 percent of the transported quantity daily. More often
than not a good state of equilibrium exists between evaporation on
the one hand and consumption by the ship's boilers or engines on
the other, but if the engines must be slowed or stopped there is a
surplus of evaporated gas and the problems of eliminating it then
arise and have heretofore been unsatisfactorily resolved.
The fourth mode corresponds to the phase of approach to the
terminal port and the time during which the ship is laid up with
its engines stopped. In this case it is impossible to burn the gas
in the engines since ship propulsion requirements are minimal or
nil, so that elimination of the evaporated gas poses problems
heretofore unresolved.
A fifth mode corresponds to the unloading phase. In this case it is
usually possible to discharge the evaporated gas to land through
pipes provided for the purpose.
A sixth mode corresponds to the degassing phase, namely the
discharging into the atmosphere of the gas contained in the empty
tanks, in conjunction with the process of filling with nitrogen and
the subsequent entry of atmospheric air. This operation requires a
certain amount of nitrogen which is produced by an inert-gas
generator or a store of liquid nitrogen, and in order to accomplish
all the above-mentioned operations a very large stock of liquid
nitrogen may be carried on board, namely approximately one ton of
liquid nitrogen for every thousand cubic metres of natural gas
tankage.
Thus the operation of methane tankers involves two requirements
which it has heretofore been the custom to meet separately. One is
the production and/or storage of liquid nitrogen, the other is the
elimination of evaporated natural gas when consumption of the
latter is slowed or arrested -- by design or not -- when the
vessel's propulsion system is slowed or stopped on reaching
port.
As stated precedingly, this second requirement has been met
unsatisfactorily or not at all heretofore.
The present invention rests on the discovery that it is possible to
meet both these requirements together under satisfactory
conditions.
To that end and in accordance with the subject method of this
invention, which may be used for storing and transporting a
liquefied combustible gas with a virtually inert gas in contact
therewith, the inert gas is liquefied by making use of additional
energy derived from the evaporation of the combustible gas, or else
the evaporated combustible gas is reliquefied by making use of the
evaporation of the liquid inert gas, as the case may be.
The associated plant or equipment, most notably for a methane
tanker, includes a machine capable of receiving surplus energy for
assuring the two herein-specified operating modes in alternation,
some at least of the component parts of said machine being used for
both operating modes.
The description which follows of a possible embodiment of the
invention, given with reference to the accompanying non-limitative
exemplary drawings, will provide a clear understanding of how the
invention can be carried into practice.
In the drawings :
FIG. 1 is a schematic diagram of the overall arrangement of a plant
according to this invention, as used aboard a methane tanker ;
FIG. 2 shows the same plant adapted for producing liquid nitrogen ;
and
FIG. 3 shows the same plant adapted for reliquefying natural
gas.
In FIGS. 2 and 3, the piping circuits which are in service are
shown in bold lines, while the others, which are inoperative
through closure of appropriate cocks and valves, are shown in fine
lines.
In the embodiment shown in the drawings, the plant includes a
turbo-compressor set consisting of an alternating or rotary
compressor 1 coupled either directly or through gearing to a
reciprocating or rotary expansion engine 2 and to an extra-power
motor 3, which motor may be an electric motor or a heat or steam
engine, or be formed of a plurality of motors. Preferably, it is
powered with natural gas taken from the natural gas transported in
the ship.
The plant includes a plurality of heat-exchangers, the drawings
most clearly showing the cooling exchanger 4 which utilizes water
supplied by the ship's cooling network 5, and the cooling exchanger
6 which in this case involves four separate fluid flow-paths 6a,
6b, 6c, 6d.
The plant further comprises :
a liquid nitrogen separator 7 and a natural gas liquefier 8 ;
liquid methane tanks as represented by the tank 9, and liquid
nitrogen tanks as represented by the tank 10 ;
a natural-gas-fired boiler 11, the combustion smokes from which are
discharged through the stack 12 ;
and associated pipes, valves (see below) and other gear.
When it is required to produce nitrogen, the gaseous nitrogen
generator 13 is activated and extracts the carbon dioxide from the
stack gases (CO.sub.2 + N.sub.2) and retains the nitrogen.
The cycle generated by the turbine engine 1-2 can be designed to
work at atmospheric pressure during suction of compressor 1.
Alternatively, a two-pressure cycle could be used, in which the
lower pressure would be higher than atmospheric pressure. In this
latter event, as well as in certain operating modes, the gaseous
nitrogen produced by generator 13 is compressed by a booster 14
driven by an appropriate motor 15.
Manually-operated or automatic isolating valves allow of
establishing different circuits for performance of the plant's
different functions, these valves being designated from left to
right by reference numerals 16, 17 . . . . 33, 34 (only the valves
relevant to the present description being shown on the
drawing).
When valve 26 is open it allows boiler 11 to be fed directly with
evaporated gas without passing through the heat exchanger 6 when
the production of nitrogen is stopped.
When valve 27 is open, the ship's ancillary systems and services
are supplied with nitrogen in the gaseous state.
As indicated precedingly, the plant is capable of operating in at
least two different ways :
in a first operating mode liquid nitrogen is produced, and for
exemplary purposes the case will be taken of a refrigerating system
the lower pressure of which is higher than atmospheric
pressure.
As shown in FIG. 2, this is accomplished by opening the valves 19,
20, 22, 24, 25, 28, 29, 31, 32, 33 and closing the valves 16, 17,
18, 21, 23, 26, 30, 34.
The shaft lines 1, 2, 3 and 14, 15 are set in rotation, and the
evaporated gas is caused to pass through open valve 24 and heat
exchanger circuit 6d, where the evaporated gas at around -
161.4.degree. C relinquishes its `frigories` and issues at around
40.degree. C in order to feed the boiler 11 through open valve
25.
The operating conditions of a nitrogen-cycle refrigerating machine
are accordingly established this way, the nitrogen being delivered
under pressure and cooled in separator 7, whence the liquid
nitrogen is discharged into tank 10, while the cold gaseous
nitrogen under pressure is directed to the inlet side of expansion
turbine 2.
The plant achieves steady-state operating conditions when it
liquefies a quantity of nitrogen equal to the nitrogen produced by
the generator. Production of liquid nitrogen is facilitated by the
extra cold which is produced by the methane evaporated in tanks 9
and which is given up in heat exchanger 6.
Alternatively, the plant may be designed to produce liquid nitrogen
without extra cold from methane evaporation in the tanks 9 (e.g.,
when the latter are waiting to be filled with, or else no longer
contain any, liquefied methane), in which case the extra power
supplied by motors 3 and 15 will attain its highest level, these
motors being accordingly designed to be capable of continuous
operation under these conditions without being overloaded.
In a second operating mode, the plant is devised in such manner as
to reliquefy the evaporated natural gas from the tanks 9.
As shown in FIG. 3, this is accimplished by opening the valves 16,
17, 18, 21, 23, 34 and closing the valves 19, 20, 22, 24, 25, 26,
28, 30, 32, 33.
Boiler 11 and generator 13 are shut off and the shaft lines 1, 2, 3
and 14, 15 are set rotating. Liquid nitrogen is conveyed from tank
10 (assumed to already contain liquid nitrogen from a previous
operation or an external source) to cooling heat-exchanger 6b and
issues therefrom under gravity, pressure or pumping. This
additional cooling effect enables the nitrogen refrigeration cycle
to be initiated in a closed circuit.
The plant will achieve steady operating conditions when the extra
`frigories` provided by the liquid nitrogen and the extra energy
provided by the motor 3 allow all the evaporated gas from the tanks
to be liquefied in the condenser 8, the liquid procuded in this way
returning to tank 9 through open valve 17.
The liquid nitrogen is evaporated and heats up in the circuit 6b of
heat-exchanger 6 and is discharged to the stack at a temperature of
approvimately 20.degree. C to 30.degree. C.
Thus a plant devised according to this invention allows of
accomplishing two entirely different functions, to wit, producing
liquid nitrogen and reliquefying the natural gas evaporating from
the methane tanker's tanks, These functions are moreover performed
by utilizing the same basic elements, namely the liquefaction line
formed by compressor 1, turbine 2, motor 3, heat-exchanger 4 and
heat-exchanger 6, an important feature of the invention being this
dual function of the elements 1, 2, 3, 4 6.
The efficiency and economics of the plant are thus considerably
increased, making the plant economically viable aboard a methane
tanker. This contrasts with liquid nitrogen producing plants or
methane reliquefying plants devised in conventional fashion or as
individual systems, which are of debatable profitability.
It goes without saying that the invention has been described in
schematic form only, but with sufficient clarity for the specialist
in the art to be able to carry it into practice without difficulty.
Obviously, alternatives could be introduced in the exemplary
schematic form described herein, and for instance the
heat-exchanger 6 could be devised as a plurality of separate
elements grouped in series or in parallel. It will therefore be
manifest that many changes and substitutions of parts could be made
without departing from the scope of the invention as defined by the
claims .
* * * * *