U.S. patent number 3,766,718 [Application Number 04/440,069] was granted by the patent office on 1973-10-23 for chemical liquid oxide spray separator.
This patent grant is currently assigned to General Dynamics Corporation. Invention is credited to Sterling A. Campbell.
United States Patent |
3,766,718 |
Campbell |
October 23, 1973 |
CHEMICAL LIQUID OXIDE SPRAY SEPARATOR
Abstract
Apparatus for collecting oxygen from air which employs a
substance having two oxidation states that absorbs oxygen when
introduced into the air. The oxygen laden substance is then removed
from the air by a centrifugal separator and reduced to produce
oxygen.
Inventors: |
Campbell; Sterling A. (San
Diego, CA) |
Assignee: |
General Dynamics Corporation
(San Diego, CA)
|
Family
ID: |
23747294 |
Appl.
No.: |
04/440,069 |
Filed: |
March 11, 1965 |
Current U.S.
Class: |
96/242; 62/640;
422/120; 422/198; 96/265; 96/360 |
Current CPC
Class: |
C01B
13/0233 (20130101); C01B 2210/0046 (20130101); C01B
2210/0098 (20130101) |
Current International
Class: |
C01B
13/02 (20060101); B01d 047/00 () |
Field of
Search: |
;23/184,221,281,282,260,252,284,264 ;60/270,218,206,214
;55/226,227,228,229,253,259,442,445,446 |
References Cited
[Referenced By]
U.S. Patent Documents
|
|
|
2958189 |
November 1960 |
Britton et al. |
|
Primary Examiner: Quarforth; Carl D.
Assistant Examiner: Tate: R. L.
Claims
What I claim is:
1. A gas collection system comprising
air duct means capable of passing a stream of air therethrough,
a chamber,
means connecting said air duct and said chamber,
heat generator means for generating heat within said chamber to
establish and maintain therein a predetermined temperature,
liquid spray generator means for spraying a liquid under pressure
from said chamber into said air duct means,
liquid spray separator means located downstream from said spray
generator means for separating liquid spray from a stream of air in
said air duct means and means connecting said liquid spray
separator means and said chamber for introducing said liquid spray
into said chamber,
and gas recovery means connected to said chamber for recovering gas
evolved within said chamber.
2. A gas collection system comprising
air duct means capable of passing a stream of air therethrough,
said air duct means comprising a substantially straight portion and
a curved portion with an opening therethrough,
said opening being located on the side of said curved portion
having the greater radius,
a chamber connected to said duct curved portion through said
opening,
heat generator means for generating heat within said chamber to
establish and maintain therein a predetermined temperature,
liquid spray generator means for spraying a liquid under pressure
from said chamber into said air duct means at said substantially
straight portion,
louvers positioned within the curved portion of said duct
downstream from said spray generator means and across said opening
to divert liquid spray from a stream of air in said air duct means
to said chamber,
and gas recovery means connected to said chamber for recovering gas
evolved within said chamber.
3. A gas collection system comprising
air duct means capable of passing a stream of air therethrough,
a chamber,
heat generator means for generating heat within said chamber to
establish and maintain therein a predetermined temperature,
a spray nozzle positioned in said air duct means,
pump means connected to said chamber and said spray nozzle for
forcing liquid under spray pressure from said chamber into said
duct means,
liquid spray separator means located downstream from said spray
nozzle for separating liquid spray from a stream of air in said air
duct means and means connecting said liquid spray separator means
and said chamber for introducing said liquid spray into said
chamber,
and gas recovery means connected to said chamber for recovering gas
evolved within said chamber.
4. A gas collection system comprising
air duct means capable of passing a stream of air therethrough,
a chamber,
heat generator means for generating heat within said chamber to
establish and maintain therein a predetermined temperature,
liquid spray generator means for spraying a liquid under pressure
from said chamber into said air duct means,
liquid spray separator means located downstream from said spray
generator means for separating liquid spray from a stream of air in
said air duct means and means connecting said liquid spray
separator means and said chamber for introducing said liquid spray
into said chamber,
gas liquefaction means connected to said chamber for liquefying gas
evolved in said chamber,
and pump means for pumping said liquefied gas to a tank for storage
therein.
5. A gas collection system comprising
air duct means capable of passing a stream of air therethrough,
said air duct means comprising a substantially straight portion and
a curved portion with an opening therethrough,
a chamber connected to said duct curved portion through said
opening,
heat generator means for generating heat within said chamber to
establish and maintain therein a predetermined temperature,
a spray nozzle positioned in said duct straight portion,
pump means connected to said chamber and said spray nozzle for
forcing liquid under spray pressure from said chamber into said
duct means,
louvers positioned within the curved portion of said duct
downstream from said spray nozzle and across said opening to divert
liquid spray from a stream of air in said duct means to said
chamber,
said louvers being located on the side of said curved portion
having the greater radius,
gas liquefaction means connected to said chamber for liquefying gas
evolved in said chamber,
and pump means for pumping said liquefied gas to a tank for storage
therein.
Description
Briefly, in accordance with this invention a substance capable of
entering into a reversible chemical reaction with oxygen is caused
to oxidize in a stream of air. The oxide thus formed is separated
from the oxygen depleted air and reduced to evolve the substance
and oxygen gas. The oxygen gas is then liquefied and stored, and
the substance is introduced into the stream of air to begin again
the oxidation-reduction cycle.
The present invention has utility in space vehicles to increase
pay-load potential. For example, the oxidizable substance can be
introduced into the air intake duct of a ram jet engine of a space
vehicle during the ram jet propulsion stage of the vehicle. The
oxygen recovered during the ram jet propulsion stage can be stored
in the tanks of the space vehicle for use later as an oxidizer
during the rocket propulsion stages of the vehicle. The oxygen
depleted air can be utilized in the ram jet engine for burning with
hydrogen to provide the necessary propulsive force during the ram
jet propulsion stage.
Accordingly, an object of the present invention is to provide a
method and apparatus capable of collecting oxygen from air.
Another object of this invention is the provision of a method and
apparatus capable of cyclically oxidizing and reducing a substance
in air to collect oxygen.
Still another object of the invention is the provision of a method
and apparatus capable of continuously collecting oxygen from air by
oxidizing a substance in the air, separating the oxidized substance
from the oxygen depleted air, reducing the oxidized substance,
storing the evolved oxygen, and repeating the above cycle of
events.
Other objects of the present invention will be readily apparent to
those skilled in the art from the following description and
drawings.
In the drawings:
FIG. 1 is a schematic showing of the apparatus of the present
invention; and
FIG. 2 is a graph showing a reversible chemical reaction
equilibrium curve, and an exemplary oxygen collection cycle
utilized in the practice of the present invention superimposed on
the equilibrium curve.
Referring now to FIG. 1, the numeral 10 designates a ram jet engine
on a space vehicle (not shown) which has an air intake duct with a
relatively straight portion 12 and a curved portion 14.
The curved portion 14 of the intake duct has an opening 16 leading
into a container or expansion chamber 18 of a regenerator attached
to the curved portion. A plurality of vanes or louvers 19 are
mounted across the opening 16 within the curved duct portion 14 and
serve, along with the duct portion 14 and opening 16, as an
inertial turn separator arrangement which is capable of separating
liquid spray from the stream of air traveling through the inlet
duct to the engine 10, as will hereinafter be more clearly
apparent.
The chamber 18 of the regenerator has a burner 20 positioned
therethrough and is adapted to contain a quantity of oxidizable
substance 22, as will hereinafter be more fully described.
A line 24 connects the bottom of chamber 18 through a pump 26 to a
spray nozzle 28 which is mounted in the wall of the duct portion 12
for producing a spray of liquid substance 22 in the stream of air
passing through the air intake duct.
A line 32 having a pump 33 therein conveys hot gaseous oxygen from
the chamber 18 to a liquefaction system 34 and then to a tank 35
which serves to store the liquefied oxygen for use later. The
liquefaction system 34 can be any conventional heat exchanger unit
as long as it is capable of utilizing liquid hydrogen as a cooling
agent.
The liquid hydrogen is pumped by means of a pump 36 and line 38
from a tank 39 to the liquefaction system 34 and then to the
combustion chamber portion of the jet engine 10 for combination
with oxygen in the stream of air to produce propulsive thrust to
the space vehicle (not shown).
A line 40 is connected to the line 38 for supplying hydrogen to the
burner 20. The hydrogen combines with oxygen which is conveyed to
the burner 20 by means of a line 42 connected through a pump 44 to
the oxygen line 32.
A suitable material 22 for use in the collection system of the
present invention can be a lower oxide of potassium such as
potassium peroxide. Potassium peroxide melts at approximately
1,375.degree. R, has a vapor pressure of one atmosphere at
approximately 1,870.degree. R, and combines with oxygen in a
reversible adsorption-desorption reaction with a low heat of
reaction to produce a higher oxide state of potassium such as
potassium dioxide. It is to be understood that other substances,
materials, compositions, alloys, or mixtures having similar
properties could be used in the practice of the present invention,
as will hereinafter be more fully apparent to those skilled in the
art.
Referring now to FIG. 2 there is shown a plotted curve 47 setting
forth the oxygen partial pressures in atmospheres and the
corresponding absolute temperatures at which potassium peroxide,
oxygen, and potassium dioxide maintain chemical equilibrium with
each other in accordance with the indicated reversible chemical
equation involving these substances. Superimposed on the
equilibrium curve is a typical collection cycle 49 employed in the
practice of the present invention. The points A, B and C of the
collection cycle 49 refer to the oxidation states of the material
22 and correspond to the same points on FIG. 1, as will hereinafter
be more fully described in the description of operation of the
invention.
Preliminary to oxygen collection, in accordance with this
invention, a quantity of powdered potassium peroxide 22 is obtained
and deposited within chamber 18 wherein it is liquefied and raised
to a predetermined temperature at which the peroxide is in chemical
equilibrium and has a vapor pressure of one atmosphere. This is
accomplished by combustion of hydrogen within the burner 20.
Hydrogen for this purpose is obtained from the hydrogen tank 39 by
means of pump 36 and line 40. The oxidizer is obtained from oxygen
tank 35 through the valve 45, pump 44, and line 42. Sufficient heat
is thus generated in chamber 18 by the burner 20 to liquefy the
potassium peroxide 22 and raise it to a predetermined temperature.
After collection of oxygen is actually commenced the valve 45 may
be closed and the oxygen necessary to support the combustion of
hydrogen in the burner 20 can be obtained directly from chamber 18
through lines 32 and 42.
Referring to FIG. 2, and the equilibrium curve 47 shown therein, it
is readily apparent that liquefaction of the potassium peroxide
occurs at approximately 1,375.degree. R and a partial pressure of
0.085 atmospheres. At approximately 1,870.degree. R the potassium
peroxide 22 is in chemical equilibrium and has a partial vapor
pressure of approximately one atmosphere. It is at this point,
commonly designated A on both the equilibrium curve 47 and the
collection cycle 49, that oxygen collection is preferably
commenced. Between points A and B a portion of the potassium
peroxide 22 is pressurized by the pump 26 and forced through the
spray nozzle 28 as a spray into the stream of air flowing through
the air duct. Referring to FIG. 2 and the collection cycle 49 it
can be seen that spraying occurs at approximately the equilibrium
temperature of 1,870.degree. R and at a pressure greater than the
equilibrium pressure of the potassium peroxide at this temperature.
The pressure utilized is indicated as being approximately three and
one-half atmospheres.
Between points B and C on the collection cycle 49, the chemical
equilibrium being upset by the sudden increase in pressure, the
potassium peroxide spray readily combines with oxygen in the stream
of air to produce potassium dioxide. Since this oxidation reaction
is exothermic, the temperature between points B and C will rise to
about 2,060.degree. R and the pressure drops to approximately two
atmospheres.
Between points C and A the potassium dioxide is separated from the
stream of air by the action of centrifugal force on the potassium
dioxide particles, and introduced into the chamber 18 wherein it
undergoes decomposition to potassium peroxide and oxygen gas. The
heat lost during the oxidation reaction between points B and C is
supplied by the heater 20 during the reduction reaction. Thus, the
temperature falls from approximately 2,060.degree. R to
1,870.degree. R, and the pressure falls from approximately two
atmospheres to one atmosphere.
The oxygen gas evolved in the chamber 18 by reduction of the
potassium dioxide is continuously pumped by means of pump 33
through line 32 and the liquefaction system 34 to the oxygen tank
35 for storage and use later as desired.
While the invention has been described in connection with a
specific embodiment it will be recognized by those skilled in the
art that numerous modifications and applications are possible and
that the invention is not in any way limited to the specific
embodiment disclosed herein.
* * * * *