U.S. patent number 3,765,189 [Application Number 05/227,637] was granted by the patent office on 1973-10-16 for method and apparatus for deep-freezing.
This patent grant is currently assigned to L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des. Invention is credited to Raymond Le Diouron.
United States Patent |
3,765,189 |
Le Diouron |
October 16, 1973 |
METHOD AND APPARATUS FOR DEEP-FREEZING
Abstract
An improved method and apparatus for the transformation of a
liquid product into flakes by freezing, said method utilizing a
cylinder rotating about its own axis and having its outer face
passing in succession in front of a station at which a thin layer
of said liquid is deposited on said outer face, and a station
adapted to scrape-off said thin layer in the frozen state, the
cooling being effected inside said cylinder by a refrigerant fluid
injected into the interior of said cylinder and adapted to
circulate in heat-exchange relation with said cylinder, in which
method substantially all the internal volume of said cylinder is
caused to participate in the heat-exchange process by injecting a
cryogenic liquid as the refrigerant fluid in circulation in a
plurality of conduits in heat-exchange with a thermal filling
medium occupying substantially all the interstitial space between
said conduits and the outer face of said freezing cylinder, the
vaporization of said cryogenic liquid and the heating of the
vapours being effected in said conduits. The cryogenic liquid may
be for example liquid nitrogen.
Inventors: |
Le Diouron; Raymond (Grenoble,
FR) |
Assignee: |
L'Air Liquide, Societe Anonyme Pour
L'Etude Et L'Exploitation Des (Paris, FR)
|
Family
ID: |
22853880 |
Appl.
No.: |
05/227,637 |
Filed: |
February 17, 1972 |
Current U.S.
Class: |
62/71; 165/91;
62/346 |
Current CPC
Class: |
F28F
5/02 (20130101); F25C 1/142 (20130101); A23G
9/18 (20130101) |
Current International
Class: |
A23G
9/04 (20060101); A23G 9/18 (20060101); F25C
1/12 (20060101); F28F 5/02 (20060101); F28F
5/00 (20060101); F25C 1/14 (20060101); F25c
005/12 () |
Field of
Search: |
;62/71,346
;165/91,89 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wayner; William E.
Assistant Examiner: Tapolcai, Jr.; William E.
Claims
What we claim is:
1. In a method of freezing a product which is initially in liquid
phase, by rotating a cylinder about a horizontal axis with a
portion of the periphery of the cylinder immersed in the product
and removing frozen liquid from another portion of the periphery of
the cylinder while passing a refrigerant fluid through the
cylinder; the improvement in which the refrigerant fluid is a
cryogenic liquid and passes in a plurality of conduits in heat
exchange with a thermal filling medium which is a solid metallic
heat transfer mass and that occupies substantially all of the
interstitial space between the conduits and the outer face of the
cylinder, the refrigerant fluid being introduced into the cylinder
adjacent the axis of the cylinder and moving from adjacent the axis
of the cylinder to adjacent the periphery of the cylinder through a
progressively increasing number of said conduits thereby to
accommodate the expanding volume of the refrigerant fluid as it
warms.
2. In a method of freezing a product which is initially in liquid
phase, by rotating a cylinder about a horizontal axis with a
portion of the periphery of the cylinder immersed in the product
and removing frozen liquid from another portion of the periphery of
the cylinder while passing a refrigerant fluid through the
cylinder; the improvement in which the refrigerant fluid is a
cryogenic liquid and passes in a plurality of conduits in heat
exchange with a thermal filling medium which is a solid metallic
heat transfer mass and that occupies substantially all of the
interstitial space between the conduits and the outer face of the
cylinder, the refrigerant fluid flowing in a zig-zag path including
a plurality of said conduits that extend parallel to said axis with
the fluid moving in opposite directions through adjacent conduits
that are spaced progressively farther from said axis.
3. In a method of freezing a product which is initially in liquid
phase, by rotating a cylinder about a horizontal axis with a
portion of the periphery of the cylinder immersed in the product
and removing frozen liquid from another portion of the periphery of
the cylinder while passing a refrigerant fluid through the
cylinder; the improvement in which the refrigerant fluid is a
cryogenic liquid and passes in a plurality of conduits in heat
exchange with a thermal filling medium which is a solid metallic
heat transfer mass and that occupies substantially all of the
interstitial space between the conduits and the outer face of the
cylinder, the refrigerant fluid being introduced along the axis of
the cylinder and vaporizing by the time it reaches the periphery of
the cylinder.
4. In apparatus for freezing an initially liquid product,
comprising a cylinder, means mounting the cylinder for rotation
about a horizontal axis whereby the cylinder dips into the liquid
product and the liquid product freezes on the surface of the
cylinder and the frozen liquid product is removed from the surface
of the cylinder, and means for introducing a refrigerant fluid into
the cylinder to cool the cylinder; the improvement in which the
cylinder is a metallic body having passageways therethrough
parallel to the axis of the cylinder, the space between the
passageways and the periphery of the cylinder being occupied by
solid metal, said passageways being relatively small in number
adjacent the axis of the cylinder and relatively great in number
adjacent the periphery of the cylinder, means for introducing a
refrigerant fluid comprising a cryogenic liquid into the cylinder
adjacent the axis of the cylinder, and means for removing vaporized
cryogenic liquid from adjacent the periphery of the cylinder.
5. Apparatus as claimed in claim 4, and means for directing said
refrigerant fluid through said passageways in series in a
progressively radially outward direction.
6. Apparatus as claimed in claim 5, and means for directing said
fluid through said passageways in zig-zag relationship with the
fluid passing in opposite directions parallel to the axis of the
cylinder through radially adjacent passageways.
7. Apparatus as claimed in claim 6, said directing means comprising
end plates on said cylinder, said end plates cooperating with the
ends of said passageways whereby some of said passageways
communicate only with radially inward passageways at one end and
only with radially outward passageways at the other end.
Description
The present invention relates to a method of deep-freezing of a
product initially in the liquid form, and more particularly to the
preparation of flakes of frozen products, utilizing a cylinder
rotating about its own axis and having its outer face presented
successively in front of a station at which a thin layer of the
said liquid is deposited on the said face, and in front of a
station for scraping-off the said thin layer in the frozen
state.
In this kind of operation, it has been proposed to effect the
cooling of the freezing cylinder in numerous ways. In operation, a
cooling fluid is continuously injected into the cylinder in which
it circulates in conduits in heat exchange with a cylindrical wall,
the outer face of which forms the freezing face. Up to the present
time, efforts have been made to cause the frigorific energy to be
evolved in the immediate vicinity of the freezing wall, and to this
end, conduits have been prepared for the flow of the cooling fluid
which are practically underlying the freezing wall. As it is
necessary to have simultaneously a relatively high speed of flow
and a relatively long period of contact of the cooling fluid with
the contact wall, a great variety of combinations of flow circuits
has been proposed by putting in series and/or in parallel conduit
elements which are all placed in an underlying layer of the
freezing wall.
Arrangements of this kind permit the use of moderately cold cooling
fluids, at most at a few degrees or a few multiples of 10.degree.
below zero, but already at these temperatures they frequently have
the drawback of failing to ensure a satisfactory distribution of
the temperature over the freezing surface, while in addition they
necessitate expensive auxiliary cooling devices for the cooling
fluid, for example by means of thermostatically controlled chambers
supplied with cooling fluid at a very much lower temperature, for
example that of liquid nitrogen. Furthermore, it is necessary to
provide circulation means for the cooling fluid between the cooling
station and the freezing cylinder.
A device for freezing a liquid product such as water has also been
proposed, utilizing a rotating cylinder in which the internal space
participates in the heat exchange of a refrigerant fluid injected
with a sealed heat-transfer liquid filling medium which extracts
the heat from the product to be frozen, for example a brine.
However, this heat-transfer filling medium is essentially comprised
in a very small annular space between the outer active face of the
cylinder and an internal casing, with the addition of a few
conduits and means permitting the operation of a circulation in
closed circuit of the heat-transfer liquid, by periodically
plunging the said conduits in a renewed bath of refrigerant which
occupies the lower space of the cylinder.
For this reason, this heat-transfer medium occupies a small
fraction of the internal volume of the cylinder, so that the result
is a low heat efficiency of the frigories inside the cylinder,
causing an increase in the heat evacuation time, since only a part
of the conduits is immersed in the refrigerant during the rotation
of the cylinder.
It is clear that it would be more economical to feed the freezing
cylinder directly with a very cold liquid, but in that case the
drawbacks referred to above concerning lack of uniformity of
temperature at the point of freezing, already considerable with a
moderately cold fluid, become so great that it is not possible to
operate in this manner with the methods and apparatus as at present
employed.
An object of the present invention concerns a method of freezing
permitting direct injection of a very cold liquid, for example
liquid nitrogen, into a freezing cylinder. Another object of the
invention is furthermore to ensure practically complete uniformity
of temperature at the place of cooling. Still a further object of
the invention is to achieve all these objects with a good thermal
efficiency. Still a further object of the invention is a thermal
device which can be used as a freezing device and in this case
utilizing the above method, or as an evaporator.
In the method according to the invention, substantially the whole
of the internal volume of the said cylinder is caused to
participate in the heat exchange by injecting a cryogenic liquid as
the refrigerant fluid in circulation in a plurality of heat
exchange conduits with a thermal filling medium occupying
substantially all the interstitial space between the said conduits
and the outer face of the freezing cylinder, while the vaporization
of the said cryogenic liquid and the heating of the vapours is
effected in the said conduits. There is thus obtained an efficient
heat exchange by conduction in a good heat conducting medium.
Another characteristic feature of the invention is that the vapours
of the cryogenic liquid are gradually heated up to a temperature at
the outlet of the vapours, which is only slightly less than the
temperature of the heat-transfer medium in the vicinity of the
periphery of the cylinder.
In fact, the whole volume of the cylinder is utilized to the
maximum extent for the heat exchange and it is thus possible to
form freezing devices which develop a high freezing power per unit
volume.
The invention has also for its object a thermal device which can be
employed for freezing, of the kind comprising a cylinder rotating
about an axial shaft, when so desired a station for depositing a
liquid in a thin layer, angularly downstream of the said freezing
station, a station for scraping-off the product in the frozen
state, means for cooling inside the said cylinder, said cooling
means incorporating conduits for the circulation of a cryogenic
fluid injected into the interior of the cylinder, characterized in
that substantially all the internal volume comprised between the
outer surface of the said cylinder and the said conduits for the
circulation of the heat-exchange fluid is constituted by a
heat-transfer filling medium.
The characteristic features and advantages of the invention will
further be brought out in the description which follows below by
way of example, reference being made to the accompanying drawings,
in which:
FIG. 1 is a view in axial cross-section of a freezing cylinder
according to the invention;
FIG. 2 is a view in cross-section, taken along the line II--II of
FIG. 1.
Referring to FIGS. 1 and 2, a freezing cylinder is essentially
composed of a metal core 1, of aluminum, copper or iron for
example, chromium plated on its lateral face, pierced with a large
number of longitudinal passages 2, for example forming five rings
2a, 2b, 2c, 2d, 2e, these passages being uniformly distributed in
the metallic mass 1. This metallic mass 1 has on the one hand an
axial perforation 3 to permit the introduction of a shaft 4 formed
by a portion 4a with an axial clearance forming a supply conduit
for a cryogenic liquid, while a second portion 4b constitutes the
evacuation conduit for the vapours of this cryogenic liquid. The
supply conduit 4a is essentially composed of a bore 5 formed in the
shaft 4, with a plurality of radial conduits such as 6 and 7, each
opening into one of the conduits 2a of the first ring of conduits
2a which is the closest to the axis. In order to permit the
introduction of the cryogenic liquid into the body of the cylinder,
a conduit 8, insulated at 9, is engaged in the bore 5 up to the
level of the radial passages 6 and 7.
On the other hand, the metallic mass 1 of the freezing cylinder is
provided, opposite each front face, with recesses 11 and 12 serving
as housings for the end shields 13 and 14 and with masks 15, 15'
permitting the passage of the cryogenic fluid from a conduit 2a to
a conduit 2b of the next outer ring of conduits and from thence to
a conduit 2c of the ring 2c, etc, the whole being preferably
arranged so that all the conduits 2a, 2b are fed radially in series
in the central zone, while some are fed in series and some in
parallel in the peripheral zone, where the transverse passages are
more numerous. In order to permit these changes from one conduit to
the other, it is observed that clearances such as 16 are provided
on the front faces of the cylinder 1 in such manner that the
adjacent conduits such as 2b, 2c, 2d, are connected in series.
The annular end-plate 14 with its mask 15 forms an annular radial
passage 19 which is fed at the periphery by the peripheral conduits
2e, and which communicates by radial perforations 20 with the
interior through the evacuation conduit 4b.
This freezing device ensures the introduction into the conduit 4a
of the cryogenic liquid, for example liquid nitrogen, which flows
through passages 6 and 7 and from thence into each of the
longitudinal conduits 2a, then into the conduits 2b, and so on into
the conduits 2c, 2d, 2e. In the first conduits, the cryogenic
liquid is vaporized while giving up to the metallic mass of the
cylinder 1 the frigorific energy due to the heat of vaporization,
while in the peripheral conduits 2d and 2e, the vapours of
cryogenic liquid are gradually heated, so that the outlet
temperature of the cryogenic liquid vapours is only slightly less
than the temperature of the metallic mass of the cylinder 1 in the
vicinity of its periphery.
In the usual manner, this cylinder 1 is arranged to dip at its
lower portion into a mass of liquid 20 to be frozen, placed in a
tank 21, while in a downstream portion with respect to the
direction of rotation is arranged a scraper device which detaches
and breaks-up the frozen products into flakes in a manner known per
se. It is preferable that the flow of the vapours of the cryogenic
liquid in the peripheral channels is of the turbulent type. To this
end, the section of passage of the said channels is reduced, for
example by cores 23 engaged in these latter.
The means for driving in rotation (not shown in the drawings) are
of course arranged on the shaft 4 of the freezing cylinder. These
means have not been described since they are well known per se.
This method of freezing is especially applicable to a first phase
of lyophilization of products.
* * * * *