U.S. patent number 3,764,951 [Application Number 05/327,175] was granted by the patent office on 1973-10-09 for non-linear resistors.
This patent grant is currently assigned to Mitsubishi Mining & Cement Company, Ltd.. Invention is credited to Michihiro Nishioka, Mikiya Ono, Kan-ichi Tachibana.
United States Patent |
3,764,951 |
Tachibana , et al. |
October 9, 1973 |
NON-LINEAR RESISTORS
Abstract
New non-linear resistors having a remarkably stable volt-ampere
characteristic are provided. Such resistors comprise several
sintered wafers superposed, said sintered wafer consisting of iron
oxide as the main component and the respective prescribed
quantities of calcium oxide, rare earth oxide and the like, and
electrodes applied to opposite surfaces of said several sintered
wafers superposed and are based on utilization of the property of
the contact surfaces between said several sintered wafers
superposed.
Inventors: |
Tachibana; Kan-ichi (Yahata-ku,
Kitakyushu-shi, Fufukaoka-ken, JA), Nishioka;
Michihiro (Yahata-ku, Kitakyushu-shi, Fufukaoka-ken,
JA), Ono; Mikiya (Yahata-ku, Kitakyushu-shi,
Fufukaoka-ken, JA) |
Assignee: |
Mitsubishi Mining & Cement
Company, Ltd. (Tokyo, JA)
|
Family
ID: |
11912759 |
Appl.
No.: |
05/327,175 |
Filed: |
January 26, 1973 |
Foreign Application Priority Data
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|
|
|
Feb 16, 1972 [JA] |
|
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47/16303 |
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Current U.S.
Class: |
338/20; 338/21;
29/610.1 |
Current CPC
Class: |
H01C
7/108 (20130101); Y10T 29/49082 (20150115) |
Current International
Class: |
H01C
7/105 (20060101); H01C 7/108 (20060101); H01c
007/10 () |
Field of
Search: |
;338/13,20,21 ;29/610
;317/234V |
References Cited
[Referenced By]
U.S. Patent Documents
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|
|
3496512 |
February 1970 |
Matsuoka et al. |
3632528 |
January 1972 |
Matsuoka et al. |
3682841 |
August 1972 |
Matsuoka et al. |
|
Primary Examiner: Albritton; C. L.
Claims
What is claimed is:
1. A non-linear resistor comprising several sintered wafers
superposed, said sintered wafer consisting of iron oxide as the
main component, 0.1.about.34 weight percent of calcium oxide (CaO)
and 0.1.about.34 weight percent of rare earth oxide, and electrodes
applied to opposite surfaces of said several sintered wafers
superposed respectively,
2. A non-linear resistor as described in claim 1, wherein said
sintered wafer comprises iron oxide as the main component,
0.1.about.34 weight percent of calcium oxide (CaO), 0.1.about.34
weight percent of rare earth oxide and 0.1.about.10 weight percent
of at least one oxide selected from the group consisting of
aluminum oxide (Al.sub.2 O.sub.3), zirconium oxide (ZrO.sub.2) and
cobalt oxide (CoO).
Description
BACKGROUND OF THE INVENTION
This invention relates to economical non-linear resistors having a
remarkably stable volt-ampere charecteristic manufactured by
superposing several sintered wafers, each sintered wafer
comprising, as the main component, iron oxide which contains
calcium oxide, rare earth oxide, etc. and has resistance of about
or not more than 1K.OMEGA. and also small thermal negative
resistance, and applying electrodes to opposite surfaces of the
several sintered wafers superposed.
Conventional non-linear resistors (the term "non-linear resistor"
is referred to as "varistor" hereinafter) comprise silicon carbide
varistors, silicon varistors, barium titanate varistors and the
like.
The volt-ampere characteristic of such a varistor is generally
given by the following Equation (1):
I = I.sub.o (V/V.sub.o).sup..alpha. (1)
where I is the current flowing through the varistor, V is the
voltage accross the varistor, V.sub.o is the voltage applied to the
opposite surfaces of the varistor at I=I.sub.o mA, that is, the
threshhold voltage, and exponent .alpha., an index representing
non-linearity is a numerical value greater than 1, usually
3.about.5.
Silicon varistors and barium titanate varistors are limited in used
because their V.sub.o values are both only 0.5.about.1.2V, while
silicon carbide varistors have large .alpha. above 30V, but small
.alpha. under 30V. Moreover, in such varistors based on utilization
of the mutual contact between internal particles of sintered bodies
as silicon carbide varistors, it is difficult to completely control
the state of said mutual contact between the internal particles
even under the same manufacturing conditions, consequently the
products are inevitably variable in the characteristics.
This invention has been devised to overcome the defects of the
conventional varistors as described hereinabove.
SUMMARY OF THE INVENTION
A primary object of this invention is to provide a varistor which
has a remarkably stable volt-ampere characteristic.
Another object of this invention is to provide a varistor which is
inexpensive in cost.
According to this invention, there is provided a non-linear
resistor comprising several sintered wafers superposed, said
sintered wafer consisting of iron oxide as the main component, 0.1
.about.34 weight percent of calcium oxide and 0.1.about.34 weight
percent of rare earth oxide, and electrodes applied to opposite
surfaces of said several sintered wafers superposed.
The sintered wafer may also comprise iron oxide as the main
component, 0.1.about.34 weight percent of calcium oxide (CaO),
0.1.about.34 weight percent of rare earth oxide and 0.1.about.10
weight percent of at least one oxide selected from the group
comprising aluminum oxide (Al.sub.2 O.sub.3), zirconium oxide
(ZrO.sub.2) and cobalt oxide (CoO).
The invention is now explained in detail with reference to the
attached drawings.
BRIEF DESCRIPTION OF THE ATTACHED DRAWINGS
FIG. 1 is a sectional view of an embodiment of this invention, a
non-linear resistor manufactured by superposing two sintered
wafers, each sintered wafer comprising iron oxide as the main
component.
FIG. 2 shows the volt-ampere characteristic of the non-linear
resistor of FIG. 1.
In FIG. 2, voltage E is plotted as abscissa and current I as
ordinate.
DETAILED DESCRIPTION OF THE INVENTION
This invention provides for, example, a non-linear resistor
manufactured, as shown in FIG. 1, by superposing two sintered
wafers 1, 1, each sintered wafer obtained by sintering a molded
material comprising iron oxide as the main component and the
respective prescribed quantities of calcium oxide (CaO) and rare
earth oxide, or a molded material comprising iron oxide as the main
component and the respective prescribed quantities of calcium oxide
(CaO), rare earth oxide and at least one oxide selected from the
group consisting of aluminum oxide (Al.sub.2 O.sub.3), zirconium
oxide (ZrO.sub.2) and cobalt oxide (CaO), applying electrodes for
example silver electrodes 2, 2 to the opposite surfaces of the two
sintered wafers superposed respectively, attaching lead wires 5, 5
to the silver electrodes 2, 2 by using solder 4 and fixing the
whole with suitable insulating coating material 6.
The wafer 1 is a sintered plate having any one of various shapes
such as circular, square, rechtangular, etc.
In that case, because of usual ohmic junction at the surface of the
sintered wafer 1 which the electrode 2 is applied to, there exists
no surface barrier there. But a surface barrier exists at the other
surface 3 of the sintered wafer 1 which no electrode is applied to.
Therefore, when such sintered wafer 1 is superposed upon the other,
there generates a high resistance R.
Furthermore, as the non-linear resistor of this invention shows
both very stable V.sub.o and .alpha., especially V.sub.o of a
little less than 20V, it proves to have an aptitude for a varistor.
Such stable V.sub.o and .alpha. also makes the yield rate of the
product to be improved greatly. In addition, as the non-linear
resistor of this invention utilizes iron oxide as the main raw
material, it is also advantageous in cost.
This invention also provides non-linear resistors manufactured by
superposing more than three plates of said sintered wafer and
applying electrodes to opposite surfaces of said sintered wafers
superposed respectively. The thus manufactured resistors also have
remarkably stable volt-ampere characteristics, proving to be
suitable for a varistor.
This invention, as described hereinabove, provides varistors having
remarkably more stable characteristics at much higher yield rate
and at quite lower cost, as compared with the conventional
varistors, consequently it is industrially of great value.
The invention will be understood more readily with reference to the
following examples. However, the examples are intended to
illustrate the invention and are not to be construed to limit the
scope of the invention.
EXAMPLE 1
The sintered body is prepared by a conventional technique. The
starting material in the composition defined in Table 1 is
respectively mixed in a pot mill so as to produce a homogeneous
mixture. The mixture is dried in a dryer, pressed in a mold at a
pressure of about 1,000kg/cm.sup.2 into a disc of 15mm in diameter
and 2mm in thickness. The molded disc is sintered in air at above
1,200.degree. C, thus the sintered disc 1 is obtained.
A non-linear resistor is manufactured, as shown in FIG. 1, by
superposing two sintered discs 1, 1, applying silver electrodes 2,
2 to opposite surfaces of the superposed sintered discs 1, 1,
attaching lead wires 5, 5 to silver electrodes 2, 2 by using solder
4 and fixing the whole with epoxy resin 6. Because of the ohmic
junction at the surface of sintered disc 1 which silver electrode 2
is applied to, there exists no surface barrier there. But a surface
barrier exists at the other surface 3 of sintered disc 1 which no
silver electrode is applied to. Therefore, when sintered discs 1, 1
are superposed, there generates a high resistance R. The measured
value of R, together with these of V.sub.o and .alpha. which are
constants of Equation (1) at I.sub.o =1mA, are shown in Table 1.
##SPC1##
As Table 1 shows, there are obtained varistors having especially
stable V.sub.o and in the range of 5.about.15wt percent of La.sub.2
O.sub.3 and 0.1.about.10wt percent of CaO. This means much higher
yield rate of the product, as compared with the conventional
silicon carbide varistors.
Moreover, superposing more than three plates of said sintered body
1 enables to increase V.sub.o value by about integral multiples of
a little less than 20V. For example, the measured values of R,
.alpha., V.sub.o of the varistors manufactured by superposing
two.about.four plates of the sintered body consisting of 5 weight
percent of La.sub.2 O.sub.3 and 10 weight percent of CaO as shown
in Table 1 are shown in Table 2.
TABLE 2
Number of plates: 2 3 4
__________________________________________________________________________
R (K.OMEGA.) 40 80 119 .alpha. (-) 5 5 5 V.sub.o (V) 19.5 39.0
78.5
EXAMPLE 2
Example 1 shows that 5.about.15wt percent of La.sub.2 O.sub.3 is
required to make .alpha. up to 5. In order to decrease the quantity
of La.sub.2 O.sub.3 which is expensive, Example 2 is carried out.
The starting materials in Example 2 are Fe.sub.2 O.sub.3 containing
15wt percent of CaO and 0.1wt percent of La.sub.2 O.sub.3 added
with 0.1.about.10wt percent of at least one oxide selected from the
group consisting of Al.sub.2 O.sub.3, ZrO.sub.2 and CoO as shown in
Table 2.
The starting material is respectively processed and sintered in the
same manner as Example 1, thus the sintered disc is obtained
respectively. A non-linear resistor is manufactured by using said
sintered disc in the same manner as Example 1. The measured values
of R, .alpha., V.sub.o of the thus manufactured varistors are shown
in Table 3. ##SPC2##
As table 3 shows, each of the sintered bodies gives a non-linear
resistor of which .alpha. and V.sub.o are both remarkably stable
because .alpha. is 5 and V.sub.o is 19.5V and which is more
inexpensive in cost because of the decreased quantity of La.sub.2
O.sub.3.
Moreover, the measured values of R, .alpha., V.sub.o of the
varistors manufactured by superposing two.about.four plates of the
sintered body consisting of 10 weight percent of Al.sub.2 O.sub.3,
0.1 weight percent of ZrO.sub.2 and 0.5 weight percent of CoO as
shown in Table 3 are shown in Table 4.
TABLE 4
Number of plates 2 3 4
__________________________________________________________________________
R (K.OMEGA.) 20 40 60 .alpha. (-) 5 5 5 V.sub.o (V) 19.5 39.0
18.5
Table 4 shows that varistors of good quality having different
V.sub.o values can be manufactured by superposing more than three
plates of such sintered bodies as shown in Table 3.
* * * * *