U.S. patent number 3,764,796 [Application Number 05/295,335] was granted by the patent office on 1973-10-09 for chemical lighting device.
This patent grant is currently assigned to The United States of America as represented by the Secretary of the Navy. Invention is credited to Clarence W. Gilliam, Thomas N. Hall.
United States Patent |
3,764,796 |
Gilliam , et al. |
October 9, 1973 |
CHEMICAL LIGHTING DEVICE
Abstract
A chemical lighting device having an outer cylindrical sleeve of
light trmitting material and first and second frangible ampoules
positioned within said outer cylindrical sleeve. Indentions are
provided in the outer cylindrical sleeve for keeping the ampoules
separated in the cylindrical sleeve. One ampoule contains a
chemiluminescent material and the other ampoule contains an
activator material. The ampoules can be broken by bending the outer
cylindrical sleeve and light is obtained when the chemiluminescent
material and activator are mixed.
Inventors: |
Gilliam; Clarence W.
(Bloomington, IN), Hall; Thomas N. (Adelphi, MD) |
Assignee: |
The United States of America as
represented by the Secretary of the Navy (Washington,
DC)
|
Family
ID: |
23137253 |
Appl.
No.: |
05/295,335 |
Filed: |
October 5, 1972 |
Current U.S.
Class: |
362/34; 116/209;
222/541.6; 116/202; 222/94 |
Current CPC
Class: |
F21K
2/06 (20130101) |
Current International
Class: |
F21K
2/00 (20060101); F21K 2/06 (20060101); F21v
009/16 () |
Field of
Search: |
;240/2.25
;222/94,541 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Braun; Fred L.
Claims
We claim:
1. A chemiluminescent light device comprising,
an outer cylindrical sleeve of light transmitting material having
flat end portions and first and second reduced diameter portions
between said flat end portions,
first and second frangible ampoules positioned in said outer
cylindrical sleeve, one of said ampoules being positioned between
one flat end portion and said first reduced diameter portion and
the other of said ampoules being positioned between the other flat
end portion and said second reduced diameter portion,
a chemiluminescent fluid in said one frangible ampoule, and
activator fluid in said other frangible ampoule.
2. A chemiluminescent light device as set forth in claim 1 wherein
said frangible ampoules are glass.
3. A chemiluminescent light device as set forth in claim 1 wherein
said frangible ampoules have a neck portion to facilitate breakage.
Description
BACKGROUND OF THE INVENTION
The present invention relates to a chemical lighting device and
more particularly to a chemical lighting device which can be held
in a hand and readily activated.
Various chemiluminescent peraminoethylene compounds have been used
for lighting and marking purposes. One such use is described in U.
S. Pat. 3,239,406, entitled, "Chemiluminescent Structures And Their
Preparation," which issued Mar. 8, 1966, to Donald D. Coffman and
Hilmer E. Winberg. This patent teaches the coating of flexible
material, such as plastic strips, with tetrakis (dimethylamino)
ethylene to provide a nocturnal marking tape. As tetrakis
(dimethylamino) ethylene becomes luminescent upon exposure to air,
the preparation of the tape is made under nitrogen and the
saturated material is protected from air by covering with
polyethylene film.
Another group of chemiluminescent compounds are made by adding a
fluorescer to an oxalate-ester compound and then activating the
mixture with an oxidizing material. U. S. Pat. 3,612,857, entitled,
"Location Marker For Producing Luminous Display," which issued Oct.
12, 1971, to Dave Beatty and James Reinhart, describes a location
marker which is a cloth streamer saturated with a mixture of
bis(2,4,5 Trichloro-6-carbobutoxyphenyl) oxalate, anthracene
cyanacryl terpolymer, and bis(2-ethylhexyl) phthalate in benzene.
The activator fluid used to activate the chemiluminescent mixture
is hydrogen peroxide in dimethyl phthalate.
SUMMARY OF THE INVENTION
The present invention relates to a chemical lighting device which
can be held in the hand and which can be readily activated. An
outer cylindrical sleeve of light transmitting material contains
first and second ampoules which are kept separated in the
cylindrical sleeve. One ampoule contains a chemiluminescent
material and the second ampoule contains a activator fluid. Each
ampoule is provided with a reduced neck portion which facilitates
breaking the ampoule. When both ampoules are broken, the
chemiluminescent material and activator fluid are mixed and light
is obtained and transmitted through the cylindrical sleeve. As
chemiluminescent material deterioates when even very small amounts
of moisture are present, the sealing of the chemiluminescent
material in a glass ampoule prevents such deterioration and permits
long shelf life.
It is therefore a general object of the present invention to
provide a chemical lighting device which can be readily
activated.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a longitudinal sectional view of a preferred embodiment
of the present invention; and
FIG. 2 is a longitudinal sectional view of another embodiment of
the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring now to the drawing, there is shown a tubular outer sleeve
11 having glass ampoules 12 and 13 positioned therein. Sleeve 11 is
made of material which will transmit light such as clear
radiation-crossed-linked polyolefinic plastic tube. The ends of
sleeve 12 have been flattened by applying heat and pressure to form
flat ends 14 and 15 that serve to retain ampoules 12 and 13 within
sleeve 11. Referring now to FIG. 1 of the drawing, it can be seen
that sleeve 11 is provided with a reduced diameter portion 16 which
prevents ampoules 12 and 13 from moving together and be susceptible
to breaking. Ampoule 12 is retained between flat end 14 and reduced
diameter portion 16 and ampoule 13 is retained between flat end 15
and reduced diameter portion 16. By way of example, sleeve 11 might
be of a heat shrinkable material and reduced diameter portion 16
can be formed by applying heat to sleeve 11. In FIG. 2 of the
drawing, two reduced diameter portions 17 and 18 are provided to
retain ampoules 12 and 13 in position. The space 21 inside reduced
diameter portion 16 and the space 22 between reduced diameter
portions 17 and 18 serves as a mixing area when ampoules 12 and 13
are broken and the fluids therein are released. Ampoules 12 and 13
are provided with necks 23 that facilitate breaking the
ampoules.
Ampoule 12 contains a chemiluminescent material which, by way of
example, might be a mixture of an oxalate ester, such as
bis(2,4,5-trichloro-6-carbopentoxyphenyl) oxalate, and a
fluorescer, such as 9,10,-bis(phenylethynl) anthracene. Ampoule 13
contains an activator, such as hydrogen peroxide.
When it is desired to activate the chemical lighting system
described herein, sleeve 11 is bent first in the region of the neck
23 of ampoule 12 to break ampoule 12 and then in the region of the
neck of ampoule 13 to break ampoule 13. Mixing of the
chemiluminescent material and the activator produces light that
passes through sleeve 11.
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