U.S. patent number 3,764,575 [Application Number 05/052,716] was granted by the patent office on 1973-10-09 for salt core containing synthetic resin and water-glass as binders.
This patent grant is currently assigned to Karl Schmidt GmbH. Invention is credited to Kurt Anderko, Adolf Diez, Manfred Stark.
United States Patent |
3,764,575 |
Anderko , et al. |
October 9, 1973 |
SALT CORE CONTAINING SYNTHETIC RESIN AND WATER-GLASS AS BINDERS
Abstract
In the manufacture of a casting having a cavity, wherein a
water-soluble salt core is suspended in a mold, molten material is
poured into said mold about said core, the molten material is
allowed to harden to the desired casting, and the core is washed
away with water to leave a hollow casting, the improvement which
comprises employing as said core one comprising a water-soluble
salt, about 5 to 20 percent by weight of water-glass and about 2 to
15 percent by weight of a synthetic resin as binder. The invention
also extends to the core and the process by which it is
produced.
Inventors: |
Anderko; Kurt (Heilbronn,
DT), Stark; Manfred (Neckarsulm, DT), Diez;
Adolf (Heilbronn, DT) |
Assignee: |
Karl Schmidt GmbH (Neckarsulm,
DT)
|
Family
ID: |
5739305 |
Appl.
No.: |
05/052,716 |
Filed: |
July 6, 1970 |
Foreign Application Priority Data
|
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|
|
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Jul 9, 1969 [DT] |
|
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P 19 34 787.6 |
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Current U.S.
Class: |
523/143; 164/132;
523/144; 164/36; 524/442; 249/61 |
Current CPC
Class: |
B22C
9/105 (20130101) |
Current International
Class: |
B22C
9/10 (20060101); C08g 051/04 () |
Field of
Search: |
;260/37R,38,DIG. 40/
;164/36,41,43 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Liebman; Morris
Assistant Examiner: Person; S. M.
Claims
We claim:
1. A core for use in making foundry castings having cavities,
comprising a water-soluble salt, about 5 to 20 percent by weight of
water-glass and about 2 to 15 percent by weight of a synthetic
resin as binder.
2. A core according to claim 1 wherein said water-soluble salt is
present in about 76 to 87 percent by weight and comprises one or
more alkali or alkaline earth metal chlorides, sulfates or
borates.
3. A core according to claim 2 wherein said water-glass is present
in about 8 to 12 percent by weight and said synthetic resin is
present in about 5 to 12 percent by weight.
4. A core according to claim 1 wherein said synthetic resin
comprises a condensation product based on furane or phenol.
5. A process for manufacturing a core for use in making foundry
castings having cavities, comprising forming a mixture of a
water-soluble salt, about 5 to 20 percent by weight of water-glass
and about 2 to 15 percent by weight of a synthetic resin as binder,
forming said mixture into a pre-determined shape, and hardening
said shaped composition.
6. A process according to claim 5, wherein hardening is effected by
heating at about 100.degree. to 150.degree.C.
7. A process according to claim 6, including the further step of
thereafter heating said core at about 450.degree. to 650.degree. C
whereby any gases contained therein are evolved.
8. A process according to claim 6, including the further step of
thereafter heating said core at about 500.degree. to 600.degree.C
for about 5 to 30 minutes whereby any gases contained therein are
evolved.
Description
This invention relates to a water-soluble salt core for use in
foundries.
Cavities in castings are generally formed with the aid of sand
cores. With cores which are difficultly accessible, the application
of that method is limited because the complete removal of residues
of the sand core after the casting operation is not always ensured.
In view of these difficulties it is better to embed hollow cores of
steel or copper in the casting and subsequently to remove the same
by etching with nitric acid. That process too has serious
disadvantages, which oppose its commercial application in
foundries.
For this reason it has been proposed in the Swiss Pat.
specification No. 246,046 to use cast cores of potassium carbonate
in the manufacture of aluminum castings. Such cores have not been
successful in foundries because they are hygroscopic.
These disadvantages have been eliminated to a large extent by the
use of cast cores of sodium silicate (French Pat. specification No.
813,689). The latter cores have the disadvantage, however, that the
silicates have relatively high melting points and a relatively low
solubility so that the castings must be rinsed with water for a
long time to remove the core. The cores are too brittle to be used
in ingot molds because the contact with the hot melt results in a
premature formation of incipient cracks in the core. Molten
material can enter these incipient cracks so that the casting has
an irregular surface.
To eliminate this disadvantage, it is taught in the U.S. Pat.
specification No. 3,356,156 to use cores of water-soluble salts,
such as sodium chloride or potassium chloride, which are pressed
and subsequently sintered at temperatures between 500.degree. and
750.degree.C. When the casting has been cooled, the salt cores
embedded therein are completely removed from the casting with
water. That process has been fully satisfactory with castings
having simple contours. With complicated contours, e.g., with
abrupt changes in cross-section, the changes in temperature and the
mechanical stresses result in higher stresses in such salt cores
which may cause a destruction of the salt cores at the critical
points.
For this reason it has been proposed in the Published German
application No. 1,483,641 to improve the thermal and mechanical
properties of pressed and sintered salt cores by adding up to 10
percent of borax, magnesia or talcum, individually or in admixture,
to the salt in order to promote the sintering process so that the
compressive and bending strengths are much improved.
It is an object of the invention to provide an inexpensive core
which can be produced without compression and sintering which
nonetheless is of adequate compressive and bending strength.
This and other objects and advantages are realized in accordance
with the present invention wherein there is provided a salt core
composition comprising a water-soluble salt, about 5 to 20 percent
by weight of water-glass and about 2 to 15 percent by weight of a
synthetic resin as binder.
The water-soluble salt, which may range from about 65 to 93 percent
and preferably from about 76 to 87 percent by weight of the
composition, preferably comprises an alkali or alkaline earth metal
chloride, sulfate or borate. The water-glass is preferably present
in about 8 to 12 percent by weight. The synthetic resin binder
advantageously comprises a condensation product based on furane or
phenol and preferably is present in about 5 to 12% by weight.
To make the salt core, it is sufficient to ram the salt core
composition according to the invention into a suitable core die
and, in accordance with another feature of the invention, to cure
the composition at a temperature of about 100.degree. to
150.degree.C. Cores so made may be subjected to the machining
operations required for the mounting of such cores, such as thread
cutting, milling or turning, without destruction of or damage to
the cores.
To avoid evolution of gases when the salt cores made from the core
composition according to the invention are embedded in molten
material, the salt core may be heated to a temperature of about
450.degree. to 650.degree. C and preferably about 500.degree. to
600.degree.C for a short time, e.g., for about 5 to 30 minutes and
preferably for about 10 to 20 minutes, before it is thus embedded.
By these high temperatures carbonization of the synthetic resin
binder occurs without undue reduction in the compressive and
bending strengths of the salt cores. When the casting has
solidified, the salt core can be removed from the cavity by rinsing
without difficulty and without need for special measures.
In a preferred embodiment of the invention the salt core is coated
with a layer of water-glass in a thickness of up to 0.1 millimeter
to ensure the formation of a smooth surface on the casting and to
increase the compressive and bending strengths of the salt core.
This is done before heating to 450.degree. to 650.degree. C.
The invention will now be explained more fully with reference to
the following illustrative embodiment:
EXAMPLE
A core composition consisting, by weight, of
80 percent NaCl
11 percent water-glass and
9 percent synthetic resin
is rammed into an annular core mold of wood and then cured in a
drying oven at a temperature of 120.degree.C for 2 hours. The
annular salt cores are then provided with tapped bores and milled
planar surfaces. The salt core is heated at 550.degree.C for 15
minutes in an electrically heated air-circulating furnace embedded
in an eutectic aluminum-silicon alloy melt. When the casting has
been cooled, the salt core is dissolved out of the cavity, without
leaving any residue, by passing cold water therethrough for 2
minutes.
It will be appreciated that the instant specification and examples
are set forth by way of illustration and not limitation, and that
various modifications and changes may be made without departing
from the spirit and scope of the present invention.
* * * * *