U.S. patent number 3,763,686 [Application Number 05/223,753] was granted by the patent office on 1973-10-09 for process for obtaining aluminum alloy conductor.
This patent grant is currently assigned to Olin Corporation. Invention is credited to Fred A. Besel, William C. Setzer.
United States Patent |
3,763,686 |
Besel , et al. |
October 9, 1973 |
**Please see images for:
( Certificate of Correction ) ** |
PROCESS FOR OBTAINING ALUMINUM ALLOY CONDUCTOR
Abstract
An improved aluminum alloy conductor. The conductor is
characterized by a combination of good mechanical and electrical
properties and contains from 0.04 to 1.0 percent iron, 0.02 to 0.2
percent silicon, 0.1 to 1.0 percent copper, 0.001 to 0.2 percent
boron, balance essentially aluminum.
Inventors: |
Besel; Fred A. (Southbury,
CT), Setzer; William C. (Hamden, CT) |
Assignee: |
Olin Corporation (New Haven,
CT)
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Family
ID: |
26785488 |
Appl.
No.: |
05/223,753 |
Filed: |
February 4, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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92289 |
Nov 23, 1970 |
3711339 |
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66067 |
Aug 21, 1970 |
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885315 |
Dec 15, 1969 |
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715552 |
Mar 25, 1968 |
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Current U.S.
Class: |
72/364; 29/527.7;
148/689; 72/700; 148/692 |
Current CPC
Class: |
H01B
1/023 (20130101); C22C 21/00 (20130101); Y10T
29/49991 (20150115); Y10S 72/70 (20130101) |
Current International
Class: |
H01B
1/02 (20060101); C22C 21/00 (20060101); B21c
009/02 () |
Field of
Search: |
;72/364,700 ;148/11.5A
;75/143 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Larson; Lowell A.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a division of application Ser. No. 92,289, by
Fred A. Besel and William C. Setzer for "Aluminum Alloy Conductor"
filed Nov. 23, 1970, now U.S. Pat. No. 3,711,339, which in turn is
a continuation-in-part of application Ser. No. 66,067, by Fred A.
Besel and William C. Setzer for "Aluminum Alloy Conductor," filed
Aug. 21, 1970, now abandoned, which in turn is a
continuation-in-part of application Ser. No. 885,315, by Fred A.
Besel for "High Conductivity Aluminum Alloys," filed Dec. 15, 1969,
now abandoned, which in turn is a continuation-in-part of Ser. No.
715,552, by Fred A. Besel for "Super-Strength, High Conductivity
Aluminum Alloys," filed Mar. 25, 1968, now abandoned.
Claims
What is claimed is:
1. A process for obtaining an improved aluminum base alloy
conductor having high strength and conductivity which
comprises:
A. providing an aluminum base alloy consisting essentially of from
0.04 to 1.0 percent iron, from 0.02 to 0.2 percent silicon, from
0.1 to 1.0 percent copper, 0.001 to 0.2 percent boron, balance
aluminum;
B. deforming said material to redraw rod at a temperature between
400.degree. and 950.degree.F; and
C. cold deforming said material to a diameter of between 0.002 to
0.375 inch at a reduction of at least 75 inch,
wherein the resultant conductor has copper substantially present in
solid solution and iron, silicon and boron substantially present as
a dispersion of extremely fine precipitate.
2. A process according to claim 1 wherein said cold deformation (C)
is at a reduction of at least 90 percent.
3. A process according to claim 1 wherein said deformation (B) is
at a temperature between 600.degree. and 950.degree.F.
4. A process according to claim 9 including an annealing step.
5. A process according to claim 4 wherein said material is drawn to
gage following said annealing step.
6. A process according to claim 5 wherein the resultant conductor
has a final diameter of between 0.002 inch and 0.125 inch.
Description
BACKGROUND OF THE INVENTION
The present invention relates to the art of electrical
conductors.
It is highly desirable to obtain high strength and high
conductivity aluminum alloy conductors with excellent formability,
that is, with the capability of taking many reverse plastic bends
and manipulations, etc., without cracking. One may readily
appreciate that it is highly desirable commerically to obtain wire
having the foregoing characteristics and to obtain it at a
reasonable cost.
The foregoing is particularly important in communication wire. In
this application, high conductivity is important; however,
electrical grade (EC grade) aluminum having high conductivity often
has low strength or is susceptible to elevated temperature strength
degradation and room temperature creep and relaxation. This
naturally has an adverse effect on mechanical electrical
contacts.
The higher strength alloys which overcome the foregoing strength
deficiencies are generally deficient with respect to electrical
conductivity.
High purity aluminum can only be moderately strengthened by cold
working; likewise, cold working causes a loss in formability.
However, there are many applications where the excellent
formability is not critical, as, for example, in overhead electric
transmission lines. In these applications, it is important to
achieve a combination of high strength and high conductivity in
order to reduce the number of supporting line poles or line towers.
Thus, in these applications, it is important to achieve a
combination of high strength and high conductivity.
Accordingly, it is a principal object of the present invention to
provide improved aluminum base alloy conductors.
It is a further object of the present invention to provide improved
aluminum alloy conductors which are characterized by a combination
of high strength and high conductivity.
It is a still further object of the present invention to provide
improved conductors as aforesaid which have excellent formability
or ductility.
An additional object of the present invention is to provide an
improved conductor which satisfies the foregoing objectives and
which is obtainable at a reasonable commercial cost.
SUMMARY OF THE INVENTION
In accordance with the present invention it has now been found that
the foregoing objects and advantages may be readily obtained. The
present invention provides improved conductors comprising an
aluminum base alloy conductor having a diameter between 0.002 and
0.375 inch containing from 0.04 to 1.0 percent iron, from 0.02 to
0.2 percent silicon, from 0.1 to 1.0 percent copper, from 0.001 to
0.2 percent boron, balance essentially aluminum.
The iron, silicon and boron alloying additions are substantially
contained in the matrix in a dispersion of extremely fine
precipitate.
The copper addition is substantially present in solid solution.
Thus, the conductor of the present invention has impurity and the
alloying elements, except for copper, precipitated throughout the
matrix. The copper addition is present as a solid solution addition
to provide some solid solution strengthening of the matrix rather
than as a dispersion or precipitation hardening agent as is
normally the case for this addition.
One conductor of the present invention achieves high strength and
high conductivity in combination with excellent formability. In
this case, the diameter would generally be between 0.002 and 0.125
inch and the copper content should be maintained between 0.1 and
0.4 percent and the boron content should be maintained between
0.001 and 0.1 percent.
It has been found that the foregoing conductor readily achieves the
objectives of the present invention and attains high strength and
high conductivity in combination with excellent formability.
Formability may be characterized as a combination of ductility and
bendability at a sufficiently high strength level such that the
material may be distorted from its original shape or formed into a
new shape without fracture. Thus, in its most flexible form, i.e.,
the fully annealed condition, the conductor of the present
invention has a minimum IACS conductivity of 60 percent and readily
obtains a minimum tensile strength of 16,000 psi and an elongation
in excess of 10 percent. Further, the tensile strength of the wire
in the annealed condition can be increased to 18,000 psi, the yield
strength to 16,000 psi, by an additional wire reduction with almost
no measurable loss in conductivity or formability, and with an
elongation in excess of 2 percent. This reduction is limited to
about 25 percent. Greater reductions cause a decrease in
formability in the cold worked wire.
The tensile properties of heavily cold worked material are
significantly higher than those of the annealed material; however,
cold worked material has significantly less mechanical formability.
Hence, with very large cold reductions one may achieve mechanical
strengths of at least about 42,000 psi tensile strength in
combination with at least 57 percent IACS electrical conductivity,
but with an elongation of about 2 percent and limited
formability.
Alternatively, when excellent formability is not a prerequisite,
another conductor of the present invention has an excellent work
hardening rate which may be used to achieve a combination of higher
strength and high conductivity. In this case one obtains an
improved combination of strength and conductivity. Thus, one may
obtain increased conductivity at strength levels comparable to
conventional materials or conversely increased strength levels at
conductivities comparable to conventional materials or variations
therebetween. For example, the conductivity is at least 57 percent
IACS and the tensile strength may be, for example, at least 48,000
psi at 0.081 inch gage. The material having these properties is
capable of passing the conventional wrap test (ASTM-B-398-67). The
material having said excellent combination of strength and
conductivity should be processed in the following manner:
A. provide an aluminum base alloy bar containing from 0.04 to 1.0
percent iron, 0.02 to 0.2 percent silicon, 0.1 to 1.0 copper, 0.001
to 0.2 percent boron, balance essentially aluminum;
B. deform said material at least 10 percent at a temperature of
400.degree.F up to 950.degree.F; and
C. cold deform said material to final gage with a reduction of at
least 75 percent and preferably at least 90 percent.
DETAILED DESCRIPTION
As stated hereinabove, the conductors of the present invention may
be obtained having a good combination of strength and conductivity
with excellent formability or alternatively some formability may be
sacrificed in order to obtain an excellent combination of strength
and conductivity.
The first portion of the specification will discuss that
modification which obtains high strength and high conducitivity
with excellent formability.
CONDUCTOR HAVING HIGH STRENGTH, HIGH CONDUCTIVITY AND EXCELLENT
FORMABILITY
As stated hereinabove, this conductor of the present invention
contains iron in an amount from 0.04 to 1.0 percent and preferably
from 0.1 to 0.3 percent. The silicon content ranges from 0.02 to
0.2 percent. Too high a silicon content causes loss in
conductivity. The preferred silicon range is from 0.02 to 0.1
percent. The copper content may range from 0.1 to 0.4 percent and
is preferably present in an amount from 0.25 to 0.35 percent. The
boron is present in an amount from 0.001 to 0.1 percent. The
balance of the alloy is essentially aluminum.
Small amounts of magnesium, zirconium, manganese and chromium or
other elements may be added for particular reasons, such as added
strength or thermal stability; however, these materials adversely
affect electrical conductivity and additions should be limited on
this basis. Titanium may be added as a grain refiner in amounts
less than the stoichiometric quantity necessary to form TiB.sub.2
and in an amount such that electrical conductivity is not
materially affected. Similarly, conventional impurities may be
tolerated in amounts such that electrical conductivity is not
materially affected.
In addition to the solid solution hardening provided by the copper,
it is significant that the conductor of the present invention
contains a dispersion of extremely fine precipitate of the iron,
silicon and boron alloying additions. The precipitate acts as a
hardening dispersion, at the same time depleting the matrix of
solute to critical levels in order to retain high conductivity.
This conductor of the present invention is provided in wire form
having a diameter of from 0.002 inch to 0.125 inch. This conductor
may be readily employed in industrial conductor sizes in the range
of B and S gages including transmission, communication and building
wire. The conductor may be readily employed advantageously as a
single strand conductor, as a multi-stranded conductor or a
stranded conductor in combination with alloys or EC grade aluminum
or a steel wire core.
This conductor of the present invention may be processed in
accordance with conventional techniques. Thus, the alloy may be
cast in a conventional manner. The as-cast billet may then be
deformed to rod in a conventional manner, such as by rod rolling.
The rod may then be drawn to gage or drawn, annealed and drawn to
gage.
Thus, this conductor of the present invention can be processed in
accordance with conventional or specialized techniques for
processing communications wire, transmission wire, building wire,
etc. The advantages of this conductor of the present invention
resides in its critical chemistry which yields the desired
combination of conductivity, strength and formability.
As indicated hereinabove, this conductor of the present invention
is characterized by several advantages, especially a combination of
good strength, conductivity and formability.
Formability may be measured or determined by a free loop bend test
wherein a two inch length of, for example, 0.020 inch wire is
pushed together and pulled apart repeatedly. If this can be done 10
times without failing as by cracking, the wire has satisfactory
formability. The wire of the present invention has formability such
that generally above 15 free loop bends can be performed even when
the elongation is low. Normally a substantially higher number can
be performed.
It is a particular advantage of the present invention that the
highly desirable characteristics of the instant conductor are
obtained with ease of manufacture.
Thus, this conductor of the present invention is useful in a wide
variety of applications and is especially useful for building wire
or communications wire where its high formability allows a high
level of bendability. Furthermore, the presence of fine precipitate
to stabilize the mechanical properties will provide a significant
improvement in room temperature relaxation or creep which has been
found to be troublesome in terminal connections involving spring or
set screw clamping devices.
The precipitated particles present before annealing assist the
nucleation of recrystallization during the anneal, hinder grain
growth, and prevent exaggerated grain growth which would be
particularly deleterious to formability. The alloy content
(primarily that in solid solution) and fine grain size both serve
to cause an initially higher strength level in the annealed wire,
and both, together with the precipitated particles, an increased
work hardening rate. Further the small grain size causes any local
deformation to be redistributed over many small grains and thus
over a greater volume of material. All of these factors interact
synergistically to cause a significant increase in formability.
CONDUCTOR HAVING EXCELLENT COMBINATION OF STRENGTH AND
CONDUCTIVITY
As stated hereinabove, one of the conductors of the present
invention may be obtained which achieves an excellent combination
of strength and conductivity. This conductor contains iron in an
amount from 0.04 to 1.0 percent and preferably from 0.5 to 1.0
percent. The silicon content ranges from 0.02 to 0.2 percent and
preferably 0.02 to 0.1 percent. The copper content may range from
0.1 to 1.0 percent and preferably 0.35 to 0.5 percent. The boron is
present in an amount from 0.001 to 0.2 percent. The balance of the
alloy is essentially aluminum. Small amounts of zirconium,
magnesium, manganese, and chromium or other elements may be added
for particular improvements, such as added strength or thermal
stability; however, these materials adversely affect electrical
conductivity and additions should be limited on this basis.
Titanium is a preferred addition as a grain refiner in an amount
less than the stoichiometric quantity necessary to form TiB.sub.2
and in an amount such that the electrical conductivity is not
materially affected, in amounts generally less than 0.5 percent.
Zirconium and magnesium are preferred additions for thermal
stability. Magnesium also increases the work hardening rate.
Zirconium is generally present in amounts less than 0.1 percent and
magnesium less than 0.2 percent. Similarly, conventional impurities
may be tolerated in amounts such that the electrical conductivity
is not materially affected.
In this modification, as in the previous modification, the
conductor contains a dispersion of extremely fine precipitate of
iron, silicon and boron alloying additions, with the copper
addition being substantially present in solid solution.
For this modification, the conductor is provided in wire form
having a diameter from 0.002 to 0.375 inch, that is, improvement is
obtained up to large diameters including redraw rod. Most often,
the wire diameter is from 0.060 to 0.200 inch.
As stated hereinabove, the particular advantage of this
modification is that due to the high work hardening rate an
excellent combination of strength and conductivity is obtained.
Thus, by cold working, one may readily achieve improved strength at
conductivity levels comparable to conventional materials or
improved conductivity at strength levels comparable to conventional
materials. In both cases, the material is capable of passing the
standard wrap test referred to hereinabove which involves wrapping
the wire around itself without fracture. In fact, the conductor of
the present invention readily passes this test at high strength
levels and is readily capable of being wrapped around itself a
plurality of times.
The basis for the excellent characteristics of the conductor of the
present invention is that the chemistry of the material provides an
increased work hardening rate. Therefore, less work is required to
achieve a given strength level. In addition, as will be apparent,
the conductor of the present invention is subjected to a large
amount of cold work.
Thus, in accordance with this modification, the alloy may be cast
in a conventional manner. The as-cast billet or bar may or may not
be homogenized, if desired, for example, at 930.degree.F
.+-.40.degree.F for eight hours or more.
The material is deformed at an elevated temperature above
400.degree.F, preferably above 600.degree.F and at a temperature up
to 950.degree.F. This hot or warm deformation step has been found
to be important in obtaining the desired properties.
The material is then cold deformed directly to gage. The material
is cold deformed to a reduction of at least 75 percent and
preferably at a reduction of at least 90 percent in order to obtain
high mechanical properties. Naturally, the amount of cold reduction
required to achieve a given strength level is dependent upon the
particular chemistry and the hot rolling profile.
The present invention will be more readily apparent from a
consideration of the following illustrative examples.
EXAMPLE I
A 2 .times. 2 .times. 7 inches billet was prepared in a
conventional manner having the following compositions: iron 0.18
percent, silicon 0.06 percent, boron 0.015 percent, copper 0.25
percent, balance essentially aluminum. The billet was hot rolled
from 750.degree.F without reheating to 3/8inch redraw rod. The
material was drawn to 0.29 inch and annealed for 24 hours at
550.degree.F. The material was then drawn to wire having a diameter
of 0.021 inch and given an anneal of short duration which fully
recrystallized the material. Properties were determined on the
fully recrystallized material which are given in the table below.
The material was then given an additional small amount of cold work
-- between about 4 and 12 percent and the properties determined on
this material. These properties are also given in the table
below.
Both the fully recrystallized material and the fully recrystallized
and cold worked material were characterized by having a fine grain
size, high strength, high conductivity and excellent formability.
The iron, silicon and boron were substantially present as a
dispersion of extremely fine precipitate and the copper was
substantially present in solid solution.
The properties are shown in the table below.
TABLE
Fully Recrystallized
UTS Y.S. Elong. Free Loop Cond. Grain (ksi) (ksi) (%) Bends % IACS
Size (mm) 17.5 7.2 19 10- 24 62.1 0.008- 0.016 Fully Recrystallized
and Cold Worked UTS Y.S. Elong. Free Loop Cond. Grain (ksi) (ksi)
(%) Bends % IACS Size (mm) 18.5 17.8 7 10- 25 61.7 0.008- 0.016
EXAMPLE II
Several 2 .times. 2 .times. 7 inches billets were prepared in the
conventional manner having the following nominal compositions: iron
0.6 percent, silicon 0.04 percent, boron 0.01 percent, copper 0.4
percent, balance essentially aluminum. All the materials were
homogenized at a temperature of 930.degree.F for 8 hours. All
billets were then hot rolled to 3/8 inch redraw rod with an entry
temperature of 850.degree.F and an exit temerature of
375.degree.F.
One billet was then given a cold deformation reduction of 75
percent from 0.365 inch to 0.182 inch. The material had an ultimate
tensile strength of 36,000 psi and a conductivity of over 59
percent. The second material was given a cold deformation of 90
percent from 0.365 inch to 0.114 inch and had an ultimate tensile
strength of 39,000 psi and a conductivity of over 59 percent. A
third bar was given a cold deformation of 95 percent from 0.365
inch to 0.081 inch and had an ultimate tensile strength of 48,000
psi and a conductivity of over 59 percent IACS.
All materials successfully passes the wrap test. In all cases the
iron, silicon and boron were substantially present as a dispersion
of extremely fine precipitate and the copper was substantially
present in solid solution.
EXAMPLE III
Two additional billets were prepared and processed in the same
manner as Example II except that they were hot rolled to 0.660 inch
gage instead of being hot rolled to 3/8 inch redraw rod.
One sample billet was cold deformed from 0.660 to 0.182 inch and
had resultant properties of 42,000 psi ultimate tensile strength
and electrical conductivity over 59 percent.
A second billet was cold deformed from 0.660 gage to 0.135 inch
gage and had an ultimate tensile strength of 46,000 psi with an
electrical conductivity of over 59 percent IACS.
Both materials successfully passed the wrap test. The iron, silicon
and boron were substantially present as a dispersion of extremely
fine precipitate and the copper was substantially present in solid
solution.
This invention may be embodied in other forms or carried out in
other ways without departing from the spirit or essential
characteristics thereof. The present embodiment is therefore to be
considered as in all respects illustrative and not restrictive, the
scope of the invention being indicated by the appended claims, and
all changes which come within the meaning and range of equivalency
are intended to be embraced therein.
* * * * *