U.S. patent number 3,763,604 [Application Number 05/233,572] was granted by the patent office on 1973-10-09 for coated abrasive belt joint.
This patent grant is currently assigned to Norton Company. Invention is credited to John F. Malloy.
United States Patent |
3,763,604 |
Malloy |
October 9, 1973 |
COATED ABRASIVE BELT JOINT
Abstract
A butt joint is provided in coated abrasive material in which
the abutting ends are joined together by means of an adhesive layer
reinforced with a patch woven from man-made fibers of high tensil
strength, the preferred butt joint being not only of higher tensile
strength initially than the coated abrasive material but retaining
this high tensile strength in usage to a high degree.
Inventors: |
Malloy; John F. (Waterford,
NY) |
Assignee: |
Norton Company (Troy,
NY)
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Family
ID: |
22877792 |
Appl.
No.: |
05/233,572 |
Filed: |
March 10, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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822934 |
May 8, 1969 |
|
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103148 |
Dec 31, 1970 |
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Current U.S.
Class: |
451/531;
51/293 |
Current CPC
Class: |
B24D
11/06 (20130101) |
Current International
Class: |
B24D
11/06 (20060101); B24D 11/00 (20060101); B24d
011/06 () |
Field of
Search: |
;51/293,399 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Simpson; Othell M.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of application Ser. No.
822,934 filed May 8, 1969, now abandoned, and application Ser. No.
103,148 filed Dec. 31, 1970 now abandoned.
Claims
What I claim is:
1. Article of manufacture comprising coated abrasive material in
which abrasive grains are adhesively bonded to the front side of a
flexible backing member, said abrasive material having two free
ends thereof joined together in abutting relationship to each
other, a woven reinforcing patch having warp and fill yarns forming
interstices therein bridging together said abutted ends, and a
layer of adhesive intermediate the back side of the backing member
and said patch and extending only for a short distance adjacent
each said end, said patch embedded in the adhesive layer to the
extent that the adhesive at least partially fills the interstices
in the woven patch, said joined coated abrasive material having a
joint tensile strength at least greater than the tensile strength
of the coated abrasive material and having relatively good
resistance to flexural fatigue.
2. Article of manufacture in accordance with claim 1 in which said
joint tensile strength is at least 150 lbs./in. of width and after
being subjected to controlled flexing for 10,000 cycles is at least
50 percent of that initially determined.
3. Article of manufacture in accordance with claim 2 in which the
warp and fill yarns of said woven reinforcing patch comprise high
tensile strength polyamide fibrous yarns.
4. Article of manufacture in accordance with claim 3 in which the
polyamide is an aromatic polyamide.
5. Article of manufacture in accordance with claim 4 in which said
aromatic polyamide is the reaction product of a member of the class
consisting of a phthalic acid or the acid halide with a member of
the class consisting of phenylene diamine.
6. Article of manufacture in accordance with claim 5 in which said
aromatic polyamide is poly-m-phenylene isophthalamide.
7. Article of manufacture in accordance with claim 3 in which said
yarns are filamentary yarns.
8. Article of manufacture in accordance with claim 1 wherein the
adhesive layer comprises polyurethane.
9. Article of manufacture in accordance with claim 1 wherein, in
addition to said adhesive layer, the woven reinforcing patch
includes a previously applied, dried, cured impregnant.
10. Article of manufacture in accordance with claim 1 wherein the
woven reinforcing patch is so positioned in the joint that one of
said yarns is approximately parallel to the edges of the coated
abrasive material.
11. Article of manufacture in accordance with claim 1 in which the
coated abrasive material joined forms an endless belt.
12. Article of manufacture comprising coated abrasive material in
which abrasive grains are adhesively bonded to the front side of a
flexible backing member, said abrasive material having two free
ends thereof joined together in abutting relationship to each
other, a reinforcing patch bridging together said abutted ends, and
a layer of adhesive intermediate the back side of the backing
member and said patch and extending only for a short distance
adjacent each said end, said joined coated abrasive material having
a joint tensile strength of at least about 160 lbs./in. of width of
abrasive material and retaining at least 50 percent of this initial
tensile strength after being subjected to controlled flexing for
10,000 cycles.
13. Article of manufacture in accordance with claim 12 in which the
reinforcing patch is a woven patch material, said patch being
embedded in the adhesive layer at least to the extent that the
adhesive partially fills the interstices in the patch.
14. Article of manufacture in accordance with claim 13 in which
said reinforcing patch comprises fibrous yarns of poly-m-phenylene
isophthalamide.
15. An endless coated abrasive belt comprising a flexible,
abrasive-coated backing member having two ends positioned in
substantially abutting relationship to each other; a layer of
adhesive extending for a short distance on the back surface of said
backing member adjacent each end thereof; and a woven reinforcing
patch positioned on said back surface and embedded in said adhesive
layer to the extent that said adhesive at least partially fills the
interstices of said woven patch, said patch being composed of yarns
made from fibers which are the reaction product of an aromatic
diamine with a member of the group consisting of a phthalic acid
and phthalic acid halides.
16. A belt as in claim 15 wherein the aromatic diamine is selected
from the group consisting of m-phenylene diamine and p-phenylene
diamine.
17. A belt as in claim 15 wherein said fibers comprise
poly-m-phenylene isophthalamide.
18. A belt as in claim 15 wherein said fibers comprise
poly-p-phenylene terephthalamide.
19. A belt as in claim 15 in which said yarns are filamentary
yarns.
20. A belt as in claim 15 wherein the woven reinforcing patch is so
positioned that some of the yarns extend approximately parallel to
the edges of the coated abrasive belt.
21. A belt as in claim 15 wherein, in addition to the adhesive
layer, the woven reinforcing patch includes a previously applied,
dried, cured impregnant.
22. A belt as in claim 21 wherein said adhesive layer comprises
polyurethane.
23. A belt as in claim 22 wherein the impregnant comprises, in
combination, a nylon polyamide and a thermosetting phenolic
resin.
24. A belt as in claim 22 in which the impregnant comprises
polyurethane.
25. A belt as in claim 22 in which the impregnant comprises, in
combination, a nylon polyamide and an epoxy resin.
26. A belt as in claim 25 in which the epoxy resin is the
condensation product of epichlorohydrin with bisphenol-A, said
condensation product having an epoxide equivalent of from about 185
to 192, and said nylon polyamide is a copolymer of hexamethylene
diammonium adipate, hexamethylene diammonium sebacate, and
caprolactam.
27. A belt as in claim 15 in which said adhesive layer extends
laterally some distance on each side of said reinforcing patch.
28. Process for joining coated abrasive material which comprises
the following procedural steps:
a. providing a strip of flexible coated abrasive material having
two free ends and having a front side with abrasive grains bonded
thereto and a back side free of abrasive grain;
b. applying to the back side of said coated abrasive material
adjacent said ends an adhesive composition;
c. abutting the two adhesively coated ends together;
d. superimposing on the layer of adhesive so as to extend there
across a woven reinforcing patch having warp and fill yarns of high
tensile strength man-made fibrous yarns, thereby forming a joint
assembly;
e. applying pressure to said joint assembly thereby to embed the
patch at least partially within said adhesive layer and to cause
the adhesive to form a bond between the reinforcing patch and the
back side of said coated abrasive material, the resulting butt
joint having a tensile strength of at least 160 lbs./in. of width
of abrasive material and relatively good resistance to flexural
fatigue.
29. Process according to claim 28 in which, in addition to applying
adhesive to the ends of the coated abrasive material, adhesive is
applied to said reinforcing patch.
30. Process according to claim 28 wherein the reinforcing patch
prior to assembly is impregnated with an adhesive composition and
it is cured to an essentially non-tacky state before it is
superimposed on the adhesive layer.
31. Process according to claim 30 wherein the chemical formulation
of the adhesive composition used to pre-impregnate the patch is
different from that of the adhesive layer.
32. Process according to claim 29 wherein the adhesive composition
applied to the reinforcing patch is applied to it in the form of a
preformed film.
33. Process according to claim 29 in which the layer of adhesive
applied to the ends of the backing member is wider than the
reinforcing patch.
34. Process according to claim 32 in which said preformed film
extends laterally beyond said reinforcing patch on each side.
35. Process according to claim 28 in which the patch is so
positioned that one of said yarns extends approximately parallel to
the edges of the coated abrasive material.
36. Process according to claim 28 in which heat is applied
simultaneously with the application of pressure.
37. Process according to claim 28 in which the adhesive composition
comprise polyurethane.
38. Process according to claim 29 in which the adhesive applied to
the reinforcing patch comprise polyurethane.
39. Process according to claim 30 wherein said pre-impregnant
adhesive composition comprises a blend of nylon polyamide and an
epoxy resin.
40. Process for joining coated abrasive material which comprises
the following procedural steps:
a. providing a strip of flexible coated abrasive material having
two free ends and having a front side with abrasive grains bonded
thereto and a back side free of abrasive grain;
b. abutting said two ends together thereby forming a joint
line;
c. applying to said abutted ends and equally on each side of said
joint line a woven reinforcing patch on the front side of which is
a laterally non-coextensive preformed adhesive film, said adhesive
film being positioned directly against the back side of said
abrasive material, thereby forming a joint assembly;
d. pressing said joint assembly while simultaneously applying heat
thereto whereby to form a joint in the abrasive material of high
tensile strength and resistance to flexural fatigue.
Description
BACKGROUND OF THE INVENTION
1. Field of Invention
The present invention relates to the art of joining and, in
particular, to the joining together of two free ends of flexible
coated abrasive material. Even more particularly, it relates to
endless coated abrasive belts and their manner of manufacture.
2. Description of the Prior Art
Although coated abrasive belts having butt joints therein have been
used for some time in the coated abrasive industry and these belts
have been used relatively extensively in certain applications,
particularly where fine finishes are required, abrasive belts
having such a joint have found substantially minor usage compared
with coated abrasive belts formed with a lap joint.
In a lap joint, contrasted to a butt joint, the ends of a segment
of coated abrasive material forming the belt overlie, or lap, one
another. These overlying ends, or at least one of them, is usually
tapered so as to provide a joint approximating the thickness of the
coated abrasive material. Moreover, in most cases the abrasive ends
are backrubbed thereby to provide for better adhesion.
Traditionally, a lap joint in a coated abrasive belt has been
considered stronger than a butt joint and, as indicated, has been
much more widely used in belt formation despite the tendency of
such a belt during use to bump and cause marking of the work piece
due to the somewhat necessarily thicker area of the joint relative
to the rest of the coated abrasive material.
Butt joints, on the other hand, are formed by butting together two
free ends or the like of coated abrasive material and thereafter
securing these ends together in some fashion, usually by means of
an adhesive. Over the years, various attempts have been made to
improve on these joints and, for the most part, these attempts have
involved basically some sort of reinforcing material in combination
with an adhesive. Exemplary of the prior art involving butt joints
are U.S. Pat. Nos. 1,588,255; 1,728,673; 2,391,731; 2,733,181;
2,794,726; 3,154,897; 3,427,765; and 3,402,514. Although some of
the coated abrasive belt joints disclosed in the prior art may be
found satisfactory in certain applications, none of them, to my
knowledge, has been found totally satisfactory. In particular, they
have not, it is believed, resulted in coated abrasive belts having
the desirable physical characteristics, for example, resistance to
flex fatigue and joint tensile strength, found in the butt joint of
my invention.
SUMMARY OF THE INVENTION
In its basic aspects, the present invention involves a butt joint
in coated abrasive material, e.g., an endless belt, wherein, in the
preferred joint, the joint tensile strength initially exceeds that
of the coated abrasive material joined, and during use, it retains
this tensile strength to a high degree. That such a joint is
obtained with my invention may be shown by subjecting joints
manufactured in accordance with the invention to conditions of
controlled flexing. The joint tensile strength will be found to
still be a high percentage of that tensile strength determined
initially.
A joint in accordance with the invention is made possible by
incorporating therein, in combination with a suitable adhesive, a
reinforcing material having unique physical properties. This
reinforcing material is of man-made fibers and, in the most
preferred embodiment of my invention, is woven from man-made
fibrous yarns of certain polyamides.
Quite unexpectedly, it is believed, the butt joints of my invention
not only possess desirable resistance to flexural fatigue and high
joint tensile strength but coated abrasive belts in which such a
joint is provided far out-perform any "lap-jointed" coated abrasive
belt tested under actual operating conditions.
BRIEF DESCRIPTION OF THE DRAWING
In the sole FIGURE of the drawing there is shown, in exaggerated
scale, a perspective view of a strip or segment of coated abrasive
material butt-jointed in accordance with the present invention.
DETAILED DESCRIPTION OF THE DRAWING AND THE PREFERRED
EMBODIMENTS
Turning now to the drawing, there is disclosed therein a strip of
coated abrasive material 10 in which two free ends 11 and 12
thereof are abutted together and against one another to form a butt
joint. Joint line 13, resulting from the abutted ends 11, 12 is
seen to extend laterally across the strip of coated abrasive
material making a 90.degree. angle with respect to the longitudinal
direction thereof. However, it will be appreciated by those skilled
in the coated abrasive art that such a joint line is
conventionally, and may extend, if desired, in fact will
preferably, at some angle less than 90.degree. with respect to the
longitudinal direction of the coated abrasive material. In general,
one will find that the lower the joint line angle, the stronger the
joint in tensile.
Coated abrasive material 10 is made up of a flexible backing member
(usually cloth) 14 to the front side of which is adhered an
adhesive layer 15 termed the maker coat. Embedded in maker coat 15
are a plurality of abrasive grains 16. A layer 17 of the same or a
different adhesive termed the size coat, may be provided or not, as
desired, and as is conventional in the coated abrasive art. These
two adhesive layers constitute the bond for the abrasive grain.
The joint assembly, in accordance with my invention, comprises ends
11 and 12 of the abrasive material 10 butted together, a layer 18
of adhesive which extends for a distance (A) on each side of joint
line 13, and an overlying woven reinforcing patch 19. The
reinforcing patch, described in greater detail below, is positioned
on the back side 20 of the backing member 14 of abrasive material
10 and is embedded, at least partially, in the adhesive layer
18.
Reinforcing patch 19, it will be appreciated hereinafter, is the
most critical component in the joint assembly. In its most
preferred aspects, the patch will provide a joint in which the
tensile strength initially, i.e., prior to any usage of the coated
abrasive article incorporating the joint, exceeds that of the
coated abrasive material and, moreover, during usage the tensile
strength is retained to a substantial degree. Such a joint will
have a joint tensile strength of at least 150 lbs./in. width and
after the joint is subjected to a controlled flexural fatigue test,
as hereinafter described, of 10,000 cycles, of at least 50% of that
determined initially.
These requirements are met, it has been discovered, in utilizing
reinforcing patches woven from high tensile strength man-made
fibrous yarns and, in particular, those of certain polyamides. A
highly suitable woven reinforcing patch comprises aromatic
polyamide yarns which are available from E. I. du Pont de Nemours
& Co. under the trade designation NOMEX. These polyamide yarns
are described in their Technical Bulletin N-201 of October
1966.
The manner of manufacture of NOMEX aromatic polyamide, which is
believed to be the reaction product of a phthalic acid (iso-or
tere-) or the acid halide thereof with m- or p-phenylene diamine,
is believed disclosed in U.S. Pat. Nos. 3,063,966 and 3,287,324. In
general, and as disclosed in these patents, the manufacture of such
a polyamide involves a relatively simple, straight forward manner
of solution polymerization of two monomers, e.g., m-
phenylene-diamine and isophthaloyl chloride. On the other hand, by
properly selecting the reactants one may produce, instead,
poly-p-phenyleneterephthalamide. In the last mentioned patent, the
manner of manufacture of fibers of poly-meta-phenylene
isopthalamide is specifically disclosed. A process for the dry
spinning of these aromatic polyamides into fibers is also disclosed
in U.S. Pat. No. 3,360,598 which issued on Dec. 26, 1967.
Although in the preferred embodiment of my invention, both the warp
and fill yarns of woven reinforcing patch 19 are of NOMEX aromatic
polyamide, the patch may comprise, if desired, either warp or fill
yarns of an aromatic polyamide and the yarns in the other direction
of weave some other suitable yarn material, for example, fibers of
a high tenacity nylon polyamide. In this way, as will hereinafter
become more obvious, one can still obtain the results desired from
this invention, and at a somewhat lower manufacturing cost.
However, the manner of positioning the reinforcing patch, described
more fully below, becomes more critical to obtain the desired joint
properties.
Reinforcing patch 19, as shown in the drawing, is usually
coextensive with adhesive layer 18 and, preferably, will extend at
least 1/16 inch, and even more desirably at least 1/8 inch from
joint line 13 on each side thereof and will run across the entire
width (B) of the belt joint. However, in some instances, as
hereinafter more fully explained, adhesive layer 18 may be, in fact
will desirably be, noncoextensive with the reinforcing patch.
As pointed out in my earlier above-mentioned application, it is
preferred that reinforcing patch 19 be applied over joint line 13
with the warp yarns of the patch extending approximately parallel
to the edges of the coated abrasive material. However, where the
fill yarns are the more desirable yarns, e.g., NOMEX aromatic
polyamide, and the warp yarns are of some different material, it
may be more desirable, as hereinafter made more clear, to have the
fill yarns in this parallel position. Thus, as is believed obvious,
where the joint line extends other than perpendicularly with
respect to the longitudinal direction of the coated abrasive
material, the reinforcing patch furnished must be cut on the bias,
e.g., where the warp yarns are desired parallel, cut from the
source material at the same angle with respect to its longitudinal
direction as the angle of joint line 13. The reinforcing patch, in
case it is bias cut will be, of course, necessarily of some greater
length than the width of the web of coated abrasive material.
In general, where it is desired to use a bias cut patch, a patch of
suitable width and length is cut from a longitudinal web of
reinforcing material at the desired bias angle. Reinforcing
patches, however, can be provided continually for, e.g., a belt
making operation, by cutting a plurality of strips of some desired
width and bias angle, selvage to selvage, from the source material
and adhesively splicing these strips of reinforcing material
together into a more or less continuous strip. The continuous strip
of reinforcing patch material is then wound into rolls of suitable
length for use in the belt making operation after which, if
desired, it may be slit into rolls of more suitable width, e.g.,
rolls 3/4 inch wide. In the formation of, e.g., an endless belt, a
suitable length of reinforcing patch material is withdrawn from the
roll and cut after which it is applied to the coated abrasive
material as hereinafter further described. Splices in the
continuous strip must, of course, be removed as it is undesirable
to use such a strip of reinforcing material in the formation of a
joint.
Alternatively, a continuous strip of bias cut reinforcing material,
and without undesirable splices therein, can be provided from a
tubular woven fabric. Such a strip is provided, in general, by
spirally slitting a tubular fabric into a strip or web of material
of some desired width and bias angle. Subsequently, the bias cut
web is wound into rolls of some desired length of material and may,
if desired, be further slit into rolls of lesser width. This can be
accomplished, for example, on a bias slitter commercially available
from Lever Manufacturing Corporation of Paterson, New Jersey.
With a bias cut patch, as above-described, the warp or fill fibrous
yarns, whichever desired, can always be aligned in the running
direction of the abrasive material. Thus, where the adhesive used
in the joint is elastomeric in nature, this will result in reduced
elongation in the patch on application of force during usage of the
abrasive material. The reinforcing patch, being so positioned,
allows the joint to stretch along with the normal stretch of the
coated abrasive backing member. Therefore, the elongation
characteristics of the patch will more nearly approximate that of
the coated abrasive material. In addition to this, a patch so
positioned will always provide the greatest joint strength in that
the desired high strength fibers will extend approximately parallel
to the edges of the coated abrasive material and in the running
direction thereof. A still further advantage results in that
greater dimensional stability is obtained in having, for example,
the warp yarns of the reinforcing patch parallel to the coated
abrasive material edges.
A straight cut patch, i.e., one in which the patch is cut at
90.degree. or 180.degree. with respect to the longitudinal edge of
the source of the patch material, is relatively easily distorted
when used in a joint construction where the joint line angle is
less than 90.degree. and such a joint is subjected to tensile
forces. Of course, as will be obvious, the closer the joint line
angle approaches 90.degree., the more suitable a straight cut patch
will become. In so-called "wide" belts, e.g., those 15 inches and
over in width, the joint line angle is generally likely to be
closer to 90.degree. than in the case of narrower belts. A joint in
accordance with the invention in such a belt will be found
satisfactory, in particular in the wider belts, provided the warp
yarns, i.e., the high strength yarns, of the reinforcing patch are
no more than about 20.degree. off the running direction of the
coated abrasive material. However, as will be evident, whether the
reinforcing patch is straight cut or cut on the bias will be of
lesser concern when a high modulus, or less elastomeric, adhesive
is used in the joint.
Any adhesive composition which possesses the properties of
providing adequate adhesion for the specific patch material of this
invention and which, in addition, provides a tough, heat-resistant
bond with the coated abrasive backing member material can be used
in the practice of this invention. Typical of these types of
adhesives are the phenolic resin adhesives, urea-formaldehyde resin
adhesive, polyurethane resin and elastomeric adhesives, and epoxy
resin adhesives. All of these adhesives are known to those in the
coated abrasive art.
The adhesive composition may be applied to either the reinforcing
patch or the back side of the coated abrasive material or both, if
desired, in either liquid form or in the form of a dry, preformed,
adhesive film. In the latter instance, the adhesive film may be,
prior to assembly in the joint construction, laminated to the
reinforcing patch.
Preferably, the reinforcing patch used in the joint of the present
invention is pre-impregnated with a suitable adhesive composition
and this adhesive composition is then dried or cured to an
essentially tack-free condition prior to joint assembly. The
adhesive composition used for pre-impregnation can be of the same
or of a different composition than that used to make the actual
joint, if desired. However, the pre-impregnating adhesive obviously
needs to be of a compatible, heat-hardenable character. Merely by
way of example, the pre-impregnant adhesive composition can be of
the same composition as the joint bonding adhesive except in a more
dilute form.
Impregnating the reinforcing patch will provide greater stability
thereto thus enabling the patch material to be more readily handled
without distortion. Additionally, and of great advantage,
impregnation results in a more abrasion resistant patch and at the
same time one that is stiffer, i.e., less flexible. This latter
feature aids in reducing the hinging effect which in turn promotes
joint failure through peeling.
After application of the adhesive composition, the coated abrasive
ends are abutted together, and a reinforcing patch is positioned so
as to bridge the abutted ends as shown in the drawing. Heat and
pressure, depending on the abrasive material being joined, is
usually then applied to the joint assembly -- preferably in steps,
e.g., a 20 second press at a low pressure, e.g., 90-300 psi, at
175.degree. F.-335.degree. F., preferably 240.degree.-335.degree.
F. (bottom bar only) followed by at least one, sometimes two
additional pressings, e.g., for from 10-20 secs., using a heated
bar top and bottom. In the second pressing stage, the top bar and
bottom bar are both heated to 240.degree. F.-335.degree. F. The
pressure setting in these two final presses may be as high as 1.5
tons per inch of belt width. Even higher pressures, e.g., 2.0 tons
or more, may be used, in some instances, if a thinner joint is
desired. Although heat is generally used in the joining operation,
a joint can be made satisfactorily without heat (high pressure)
provided the adhesive layer has had a relatively low dwell time. As
a result of the application of heat and pressure, the adhesive sets
up to a tough state and intimately bonds the special reinforcing
patch to both ends of the coated abrasive material. Thus, the
reinforcing patch and adhesive, in combination, provides a joint
which offers advantageous resistance to failure because of forces
and temperatures on the coated abrasive material in the grinding
operation.
The reinforcing patch must be sufficiently porous and so positioned
in the completed joint that the adhesive will penetrate the weave
(warp and fill yarns form interstices) of the patch to develop
satisfactory adhesion. Although the patch can be applied directly
on the surface of the backing member of the coated abrasive
material so as to avoid undue weakening of the threads of the
coated abrasive backing member, it may be desirable in some
instances to roughen the back side or surface of the backing member
to break up or remove backing treatment materials which may have
been applied previously to the backing member. Where this is done,
it may be found desirable, at least in some instances, to provide
an adhesive layer which is non-coextensive with respect to, i.e.,
is wider than, the reinforcing patch. Thus, in use, the backing
member of the coated abrasive material will be protected against
grinding fluids in the joint area and more likely to resist
flexural and other forces in use which have heretofore sometimes
lead to premature failure.
The following examples will, it is believed, better illustrate my
invention.
EXAMPLE 1
A number of reinforcing patches (3/4 inch wide) were cut
(45.degree. bias) from a commercially available woven fabric of
NOMEX aromatic polyamide continuous filament yarns. This fabric,
available from Stern & Stern Textiles, Inc., of Hornell, New
York under the trade designation HT-48, is a 2 .times. 2 chain
weave fabric having a yarn count of 100 .times. 86.5. The NOMEX
polyamide yarns are 200 denier. Physical properties of this
reinforcing patch material are as follows:
Porosity 13.8 cu. ft./min./sq. ft. Tear Strength 28 lbs. in warp
direction 21 lbs. in cross direction Tensile Strength 247 lbs./in.
in warp direction 211 lbs./in. in cross direction % Elongation 41%
in warp direction 35% in cross direction TABER Abrasion 75
cycles
The reinforcing patch has an average thickness of 0.0104 percent
and weighs 5.05 ozs. per sq. yd.
Several of the patches were saturated, in a conventional dip and
squeeze fashion, with a nylon-phenolic adhesive having the
following composition:
COMPONENT % By Weight Elvamide 8061 10.7 Thermosetting Phenolic
Resin 6 Methanol 66.6 Water 16.7
(The nylon-phenolic adhesive composition is similar to that
disclosed in U.S. Pat. No. 3,296,022. Elvamide 8061 is an ethyl
alcohol/water mixture soluble nylon polyamide formed from the
reaction of hexamethylene-diammonium adipate and
hexamethylene-diammonium sebacate with caprolactam.)
After saturation, the wet impregnated reinforcing patches were
dried and cured by heating them for 1/2 hour each at 160.degree.
F., 200.degree. F., and 250.degree. F., and for 1/4 hour at
275.degree. F. The dried, cured impregnant constituted about 10
percent by weight (dry) of the weight of the patch.
On testing, saturating is found to decrease the tensile strength of
the reinforcing patch slightly, i.e., from 247 lbs./in. to 229
lbs./in. in the warp direction and from 211 lbs./in. to 208
lbs./in. in the cross direction. However, the elongation is
improved to a slight degree, decreasing from 41 to 36 percent in
the warp direction. Elongation in the cross or fill direction also
shows a slight improvement dropping from 35 to 28 percent. Abrasion
resistance, as measured by the TABER Abrasion Tester, shows a
marked improvement, moving up from 75 cycles to 700 cycles.
EXAMPLE 2
A strip of conventional 60X RESINALL METALITE OPENKOTE coated
abrasive material was provided of suitable length and the free ends
thereof were cut to complement one another at an angle of
45.degree. with respect to the lengthwise direction. The backside
of the coated abrasive material was then back rubbed according to
usual techniques. Afterwards, a layer of adhesive of the following
composition was applied, by means of brushing, to the backside of
the coated abrasive material and to a reinforcing patch of Example
I which had not been impregnated:
COMPONENT % By Weight Bostik 7076 90.9 Mondur CB75 7.9 Dimethyl
cocoamine catalyst 1.1
(Bostik 7076 is a hydroxyl-terminated polyurethane-polyester in
acetone-toluene solvent (United Shoe Machinery Co.); and Mondur
CB75 is a reaction product of toluene di-isocyanate and
tri-methylol propane (Mobay Chemical Co.).)
The adhesive coated materials were then assembled, after a 45
minute dwell or open time, and subjected to curing conditions.
Sufficient adhesive was applied to result in a dry adhesive film of
about 1 mil thickness on both the patch and the coated abrasive
material. Curing was accomplished in two cycles. In the first or
pre-cure cycle, the assembly was heated under 300 psi pressure for
20 seconds at 240.degree. F. (bottom bar only). Afterwards, the
assembly was subjected to 2,10 sec. presses (2800 psi) at
240.degree. F. (both bars heated).
The coated abrasive belt joint thus formed was then subjected to
testing in an Instron Tensile Strength Tester to determine the
joint tensile strength. Testing was conducted under a load of 500
lbs., a jaw speed of 1 inch/min., a chart speed of 5 inch/min., and
a guage (distance between jaws) of 3 inch. Failure occurred in the
coated abrasive material rather than in the joint per se
indicating, however, a joint tensile strength of more than 187
lbs./in.
A belt joint similarily produced, as above-described, was subjected
to testing to determine its resistance to flexural fatigue. In this
test, the specimen (1/2 .times. 16 inches coated abrasive strip) is
held under tension (27 lbs. gage) and moved back and forth at 200
cycles per minute in a 90.degree. change in direction over a 1/4
inch diameter roll. Actual tension was 16 lbs. Resistance to
flexural fatigue was discovered to be extremely high, 50,000 cycles
being achieved without joint failure.
A belt joint manufactured as above was subjected to 10,000 cycles
in the flexural fatigue testing apparatus after which it was
Instron tested as before. Quite unexpectedly, it is believed, the
joint tensile strength was found to be 86 percent of that
determined previously. Moreover, failure occurred in the coated
abrasive material, not the joint.
By way of comparison, the butt joints in two commercially available
competitive coated abrasive belts were evaluated for their
resistance to flexural fatigue. The belts were also subjected to
tensile strength testing. In one of these abrasive belts -- using a
patch of Dacron polyester fabric -- failure occurred in flexural
fatigue after only 9600 cycles. On tensile strength testing,
failure occurred in the belt joint per se at 154 lbs./in. The other
belt joint, utilizing glass fibers, while failing at higher tensile
strength (184 lbs./in.) showed considerably less resistance (1600
cycles) to flexural fatigue than did the joint using a patch of
polyester fabric. However, failure in tension occurred in the
coated abrasive material in this latter belt rather than in the
joint per se.
EXAMPLE 3
A belt joint was produced as in Example 2; however, rather than a
NOMEX aromatic polyamide reinforcing patch, a patch of S7016 Nylon
(nylon 6,6), a conventional aliphatic polyamide used heretofore in
joints, was used. The resulting butt joint failed in flex fatigue
after only 2800 cycles. The tensile strength of such a joint was
determined to be only 123 lbs./in. making it highly unsuitable as a
reinforcing patch in a butt joint construction.
EXAMPLE 4
A reinforcing patch was cut from a high strength woven cotton
fabric referred to in the trade as Airplane Cloth and which is
available from Westpoint-Pepperell under the trade designation No.
1701. This fabric has a yarn count of 80 .times. 92 and weighs 4.3
ozs./yd..sup.2
The butt joint resulting from using a reinforcing patch of this
material was found to have exceptionally good resistance to
flexural fatigue (41,400 cycles to failure). On tensile strength
testing, the joint retained, after 10,000 cycles, 89 percent of its
initial tensile strength (150 lbs./in.); however, failure occurred
undesirably in the joint per se.
EXAMPLE 5
On a commercial J.M. Lancaster Drawer Sanding Machine, using a
reinforcing patch of Nylon S7016, the coated abrasive product
failed in the butt joint after only 12.0 hours operation. With a
NOMEX polyamide patch, the coated abrasive belt held up for over 35
hours. Similarly, using these types of patches in the same butt
joint construction and operating the belt so manufactured in a
specialized belt testing machine using a small diameter roll (1/4
inch) to place maximum stresses in the joint, the coated abrasive
belt having the Nylon S7016 patch failed at 38.7 minutes. On the
other hand, the belt using a patch of the present invention ran for
223.0 minutes.
EXAMPLE 6
A belt joint was produced with coated abrasive material as in
Example 2 except that a nylon-phenolic impregnated patch from
Example 1 was used.
On testing for resistance to flexural fatigue, this joint, while
showing less resistance (34,320 cycles to failure) than that using
a reinforcing patch which had not been impregnated, provides
considerably greater resistance than any competitive product of
which I am aware. Moreover, the joint tensile strength seems little
effected by patch impregnation. Tensile strength after 10,000
cycles controlled flexing, as before described, was found to be 84
percent of that (187 lbs./in.) in a similar joint not so subjected.
Failure occurred in both instances in the coated abrasive material
rather than in the joint per se.
EXAMPLE 7
Reinforcing patches, as before mentioned, were cut from a fabric
commercially available from Stern & Stern Textiles, Inc., under
the trade designation A5392. This fabric is a 2 .times. 2 chain
weave fabric having a yarn count of 95 .times. 86 and is woven from
yarns of 210 denier high tenacity nylon polyamide. The properties
of the fabric, weighing 5.4 ozs. per sq. yd., and having a
thickness of 11.5 mils are as follows:
Porosity 16.0 cu. ft./min./sq. ft. Tensile Strength 243 lbs./in. in
warp direction 223 lbs./in. in fill direction % Elongation 52 in
warp direction 45 in fill direction
Several of these patches were impregnated as were the NOMEX
aromatic polyamide reinforcing patches before mentioned.
Coated abrasive material (6oX RESINALL METALITE OPENKOTE) was butt
spliced as disclosed in Example 2, and the joints resulting were
tested for resistance to flexural fatigue and tensile strength.
These results are indicated below:
Flex Tensile Tensile Strength Fatigue Strength after 10,000 cycles
Strength Patch (No. of (lbs./in.) (lbs./in.) Retained cycles)
Impreg- 32,320 183 154 84% nated Not impreg- 50,000+ 189 166 88%
nated
One can readily see from this data that the results from using a
reinforcing patch material of high tenacity nylon polyamide is
somewhat comparable to a NOMEX aromatic polyamide reinforcing
patch. Failure occurred in the coated abrasive material rather than
in the joint, both before and after controlled flexing.
EXAMPLE 8
A reinforcing patch, as in Example 1, was saturated with the
following composition:
COMPONENT % By Weight Elvamide 8061 12.2 Epon 828 4.1 Methanol 68.6
Trichloroethane 14.6 Triethylene Tetramine 0.5
(Epon 828 is an epoxy resin resulting from the condensation of
epichlorohydrin with bisphenol-A having an epoxide equivalent of
185-192 and is available commercially from Shell Chemical Co.)
The patch, after saturating, was heated for 4 hours at 250.degree.
F. to cure the impregnant (10 percent dry pickup) to a dry,
tack-free condition. Afterwards, the patch was used to prepare a
coated abrasive material belt joint as before described. On
evaluation, as before, for resistance to flex fatigue, the joint
failed only after 39,200 cycles.
EXAMPLE 9
A strip of coated abrasive material, as in Example 8, was
butt-spliced except that the reinforcing patch was impregnated (10
percent by weight dry pick up) with the following composition:
COMPONENT % By Weight Bostik 7076 73.6 Mondur CB75 6.5 Dimethyl
cocoamine catalyst 1.4 Ethyl Acetate 18.5
The wet coated patch was allowed to cure, prior to assembly, at
room temperature (70.degree. F.) for 24 hours.
On evaluation for fatigue resistance, the abrasive material was
removed, joint intact, after 12,000 cycles.
EXAMPLE 10
Reinforcing patches of NOMEX aromatic polyamide yarnwere saturated
with the nylon-epoxy adhesive composition disclosed in Example 8.
Afterwards, a preformed adhesive film (3 mil) was laminated to the
dried impregnated patch by subjecting the superposed assembly to a
pressure of 300 psi while being heated (bottom bar only) for 3
seconds at 240.degree. F.
The preformed film was provided by coating the following
polyurethane adhesive composition on a conventional release
liner:
COMPONENT % By Weight Bostik 7076 91.0 Mondur CB75 4.6 Thylon
D-406* 4.4 *A one part blocked urethane system available from
Thiokol Chemical Co.
After application to the release liner, the adhesive composition
was dried and cured for 4 minutes at room temperature, 13 minutes
at 100.degree. F., and 32 minutes at 250.degree. F.
The adhesive film -- reinforcing patch assembly was then assembled
with a strip of 50X RESINALL METALITE OPENKOTE coated abrasive
material to form a butt joint as before disclosed. On testing for
resistance to flex fatigue, the joined coated abrasive material was
removed, joint intact, after 12,000 cycles.
Similar results were obtained when the polyurethane adhesive film
was formed by coating the adhesive composition directly on the
nylon-epoxy impregnated patch. Neither of these joints, it should
be pointed out, involved application of adhesive to the back side
of the coated abrasive backing member thus eliminating this
application step.
EXAMPLE 11
A coated abrasive belt was manufactured in accordance with Example
6, except that 50X coated abrasive material was used, for
evaluation in a drawer sanding application. The belt was removed
after 4 days with the joint intact and the belt still usable. In
contrast, belts used prior to this invention in this application
using glass fiber reinforcement in the joint construction failed in
anywhere from 1 to 3 days.
EXAMPLE 12
A coated abrasive belt was manufactured as disclosed in Example 2
except that the impregnant adhesive composition was the nylon-epoxy
composition disclosed in Example 8. On testing, as before
described, resistance to flexural fatigue was determined to be
outstanding -- 39,000 cycles being achieved before failure. Initial
joint tensile strength was in excess of 190 lbs./in.; however,
after 10,000 cycles in the fatigue testing apparatus joint tensile
strength in a similar belt had dropped to 126 lbs./in. (66 percent
retained).
EXAMPLE 13
A NOMEX aromatic polyamide fabric (plain weave, 200 denier yarns,
yarn count 69 .times. 64), avilable from Stern & Stern
Textiles, Inc., under the trade designation HT3, having the
following physical properties:
Porosity 32.3 cu.ft./min./sq.ft. Tensile Strength 155 lbs./in. in
warp direction 144 lbs./in. in fill direction % Elongation 35 in
warp direction 30 in fill direction
and weighing 3.62 ozs./sq. yd. (6.5 mils thick), was saturated with
the nylon-epoxy adhesive composition in Example 8.
Afterwards, the saturated fabric was air dried for 15 minutes and
then cured for 4 hours at 250.degree. F. A dry deposit of 9
percent, by weight of the fabric, was obtained.
The saturated or pre-impregnated fabric was then cut to provide a
55.degree. bias patch, 3/4 inch in width. A 3.5 mil dry, preformed,
polyurethane adhesive film, provided as in Example 10, was then
laminated (13/16 inch width film) to the bias cut reinforcing patch
by means of an air operated press at 194 lbs./in..sup.2 while being
heated at 240.degree. F. for 3 seconds.
The ends of a strip of coated abrasive material (180 X RESINALL
METALITE cloth), which were cut at a 55.degree. angle with respect
to their running direction, were sandblasted backrubbed after which
they were then coated with the polyurethane composition of Example
2. The adhesively coated ends were then allowed to air dry at room
temperature, e.g., about 70.degree. F., for 45 minutes.
The preformed adhesive film -- reinforcing patch assembly was then
assembled with the adhesive coated ends of the coated abrasive
material in such a fashion that the warp yarns of the reinforcing
patch extended approximately parallel to the edges of the coated
abrasive material. This assembly was then subjected, in a
conventional platen press, to a 15 second press (bottom platen only
heated - 240.degree. F.) at 194 lbs./in..sup.2 followed by a 20
second press at 4300 lbs./in..sup.2 using a 30 TON press (American
Steel Foundry, Elmes Engineering Division, Cincinnati, Ohio) with
both platens heated at 240.degree. F.
After the usual conditioning before testing, e.g., 24 hours at 50
percent R.H. - 70.degree. F., the following physical properties
were obtained on abrasive belts similarily manufactured:
Value Physical Property (lbs./in. of width) Tensile Strength a.
coated abrasive material 222.4 b. joint tensile 177.0 c. joint
tensile after 10,000 cycles 140.0 d. % tensile strength retained
after 10,000 cycles 79.0
Thus, from this data, and even though failure occurred in the
joint, one can readily see that with a much thinner patch material
and a somewhat greater joint line angle than in Example 2, a joint
can be produced that will still be found, in many instances, quite
satisfactory. Of significance, however, is the fact that even after
being subjected to 10,000 cycles, the joint tensile strength is
still 79 percent of that determined initially.
As will be appreciated from what has been previously disclosed, a
somewhat stronger joint can be produced in providing a joint line
of lesser angle, e.g., 45.degree. or less.
EXAMPLE 14
A fabric available from Stern & Stern Textiles, Inc., under the
trade designation HT-131, was impregnated by a conventional dip and
squeeze method, with the nylon-epoxy saturant disclosed in Example
8.
This fabric, yarn count 99 .times. 64, is a 2 .times. 2 twill
weave, 200 denier NOMEX aromatic polyamide continuous filament
yarns in the warp direction and 333 denier NOMEX staple yarns in
the fill direction, fabric having a thickness of 14.4 mils and a
weight of 5.64 ozs. per sq. yd. Its porosity is 54.9 cu.
ft./min./ft..sup.2 and the fabric has a tensile strength of 250
.times. 158 lbs./in. width, a tear strength (lbs.) of 18 .times.
18, and an elongation (percent) of 40 .times. 26.
After a 15 minute air dry, the saturated fabric was heated for 10
minutes at 325.degree. F. to cure the resinous adhesive material.
The per cent by weight (dry) pick up was 14.3.
A strip of 60X RESINALL METALITE abrasive cloth was cut at a
55.degree. angle and the cut ends were subjected to a sandblasted
backrub. To the abrasive material ends was then applied the
polyurethane adhesive composition described in Example 2.
Sufficient composition was applied to result in a 1.0 mil thick dry
film.
The saturated fabric was cut into 3/4 inch wide 55.degree. (off the
fill yarns) bias reinforcing patch material so that a 55.degree.
joint angle would have the spun or staple yarns in the running
direction of the belt produced.
A 3.5 mil (13/16 inch wide) dry, preformed polyurethane adhesive
film, coated onto a Weyerhauser Co. No. 662 release paper, was
laminated to the reinforcing patch using a pressure of 194
lbs./in..sup.2 and a temperature of 240.degree. F. for 3
seconds.
The adhesive coated ends of the abrasive material, after a 60
minute dwell, were abutted together in a platen press, as before
described, on the adhesive film-patch (release liner removed) so
that the adhesive film was directly against the coated abrasive
backing member. This assembly was then subjected to a 15 second
press at 194 lbs./in..sup.2 at 240.degree. F. (bottom bar only
heated) followed by a 20 second press (4300 lbs./in..sup.2) in a 30
TON press, both platens heated to 240.degree. F.
The joint tensile strength was determined before and after
controlled flexing, as before described, the results being
indicated below:
Tensile Strength % Patch Initial Tensile after 10,000 Strength
Material Strength cycles (lbs./in.) Retained HT-131 216 173 80
HT-48 216 187 86.5 (control)
In the case of the control, where the reinforcing patch is HT-48,
failure occurred in the abrasive material rather than in the joint
in both tests. However; failure, in the case of the staple fiber
yarns, occurred in the coated abrasive material, rather than in the
joint, before controlled flexing and in the joint per se after
controlled flexing. Nevertheless, the results indicate, it is
believed, that while a reinforcing patch of continuous filament
aromatic polyamide yarns is preferred, a joint incorporating a
patch of staple fiber aromatic polyamide yarns will be satisfactory
for less severe applications.
The non-coextensive adhesive film, on examination of the abrasive
belt, was seen to have substantially covered over any exposed areas
of the backing member due to the backrubbing operation. Thus, in
use involving wet conditions, the backing member material is not
left exposed to water or other wet grinding aids used. Moreover,
such an adhesive film -- reinforcing patch assembly results in
imparting smoother operation to the abrasive material as the
abruptness of the leading and trailing edge of the reinforcing
patch is somewhat lessened.
EXAMPLE 15
A 9.7 mil thick blended fabric, i.e., one having high tenacity, 210
denier nylon polyamide yarns in the warp direction and 200 denier
NOMEX aromatic polyamide yarns in the fill direction, available
from Stern & Stern Textiles, Inc., Style A5424, having a 2
.times. 2 chain weave (86 .times. 100), weighing 5.4 ozs. per sq.
yd., and having the following physical properties:
Porosity 3.8 cu. ft./min./sq. ft. Tensile Strength 284 lbs/in. in
warp direction 227 lbs./in. in fill direction % Elongation 42 in
warp direction 38 in fill direction
was saturated (dry pick up 7.8 percent by weight of fabric) with
the nylon-epoxy adhesive composition before disclosed. The wet
saturated fabric was then, after air drying for 30 minutes, heated
for 10 minutes at 325.degree. F. to cure the pre-impregnant to a
dry, tack-free condition.
A reinforcing patch was bias cut (35.degree. off warp direction)
from the source fabric and was used in the manufacture of a belt
joint as in Example 14 except that, the coated abrasive material
was 60X RESINALL METALITE cloth, and, instead of a single 20 second
press, two ten second pressings were used. In the assembly,
however, and this is deemed critical to obtain the preferred joint
of the invention, the reinforcing patch was inverted so that the
initially top surface of the patch faced away from the back side of
the coated abrasive backing member. Thus, the NOMEX aromatic
polyamide yarns extended parallel to the edges of the coated
abrasive material.
On evaluation as before, the joint tensile strength was determined
to be in excess of 212 lbs./in. width. By comparison, the joint
tensile in a control belt in which the reinforcing patch was HT-48
NOMEX aromatic polyamide was determined to be in excess of 208
lbs./in.
Abrasive belts as above manufactured when subjected to an
accelerated flex fatigue test (35 lbs. gage tension instead of 27,
actual 22 lbs.) failed in 8440 flexes (blend) and 9660 flexes
(HT-48), respectively.
The data from both tests indicate that comparable results may be
obtained even though the woven reinforcing patch material is not
wholly of the aromatic polyamide yarns.
EXAMPLE 16
Abrasive belts (12 .times. 181 inches) manufactured as in Example
15, except that the abrasive material was 50X RESINALL METALITE
cloth, were used in a drawer sanding application. In subsequently
tensile testing such a belt, after being used for at least about 3
hours, failure occurred in the coated abrasive material per se
leaving the joint in tact.
Although the preferred embodiments of my invention have been
limited primarily to reinforcing patches incorporating NOMEX
aromatic polyamide fibrous yarns, it will be appreciated that it is
not so limited. The NOMEX aromatic polyamide fibrous material is
preferred because it, among other things, appears to retain to a
high degree, in a coated abrasive joint and at the temperatures
attained during grinding, a desirable combination of physical
properties, e.g., high initial tensile strength and high initial
modulus. However, other fibrous materials may be found useful in
the practice of this invention, in particular those of aromatic
polyamides such as the ordered aromatic copolyamides obtained by
the polymerization of N,N -m- phenylene - bis (m-amino- benzamide)
and isophthaloyl chloride with terephthaloyl chloride, and imides,
e.g., the reaction product of anhydrous bis (4 - aminophenyl) ether
and anhydrous pyromellitic dianhydride.
Obviously, the reinforcing patch may be any of a wide variety of
yarn sizes and weaves. However, in certain instances, it need not
even be a woven structure. The patch, in the case of a preformed
film, for example, may merely be a plurality of yarns assembled
with the adhesive film in the direction of travel of the coated
abrasive material being joined. Nevertheless, whether an endless
belt is being formed or a reinforcing patch is being used in
forming some other joint in the abrasive material, e.g., in
splicing the ends of two rolls in a continuous operation, or the
formation of spiral belts or the like, the patch material used
hence the joint ordinarily will be as thin as is consistent with
the strength required in any particular application. The
reinforcing patch must be sufficiently porous for any
pre-impregnant adhesive and joint bonding adhesive to penetrate, at
least partially. Thus, abrasion resistance can be somewhat
improved. The yarns used for the reinforcing patch material, while
necessarily of high tensile strength fibrous material may be
mono-or multi-filamentary, or even staple fiber yarns, and of any
denier provided they meet the requirements set forth herein.
* * * * *