U.S. patent number 3,757,879 [Application Number 05/283,474] was granted by the patent office on 1973-09-11 for drill bits and methods of producing drill bits.
This patent grant is currently assigned to Christensen Diamond Products Company. Invention is credited to Harold C. Bridwell, Arthur G. Wilder.
United States Patent |
3,757,879 |
Wilder , et al. |
September 11, 1973 |
DRILL BITS AND METHODS OF PRODUCING DRILL BITS
Abstract
A diamond bit comprising a steel shank coated with abrasive
particles, with a ring of tungsten-coated iron particles bonded
together in a metal matrix and by metal to the end of the
shank.
Inventors: |
Wilder; Arthur G. (Salt Lake
City, UT), Bridwell; Harold C. (Salt Lake City, UT) |
Assignee: |
Christensen Diamond Products
Company (Salt Lake City, UT)
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Family
ID: |
23086233 |
Appl.
No.: |
05/283,474 |
Filed: |
August 24, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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219973 |
Jan 24, 1972 |
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220351 |
Jan 24, 1972 |
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220352 |
Jan 24, 1972 |
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Current U.S.
Class: |
175/434 |
Current CPC
Class: |
E21B
10/46 (20130101) |
Current International
Class: |
E21B
10/46 (20060101); E21b 009/36 () |
Field of
Search: |
;175/329,330,409-411 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Brown; David H.
Parent Case Text
This application is a continuation-in-part of Applications Ser. No.
219,973; 220,351; 220,352 filed Jan. 24, 1972.
Claims
We claim:
1. In a drill bit comprising a shank, a bore through said shank,
the improvement comprising a coat, said coat including abrasive
particles, metal matrix bonding said abrasive particles in said
coat and bonding said coat to the lower end of said shank, an
external ring of metal-encapsulated iron particles bonded in metal
to said coat covering the end of said coat on the exterior of said
shank and metal bonded to said coat.
2. The drill bit of claim 1 in which the metal encapsulating said
iron particles is tungsten, or tantalum, or columbium (niobium) or
molybdenum or titanium.
3. In the drill bit of claim 2, said abrasive particles in said
coating are tungsten carbide, or metal-encapsulated alumina, or
metal-encapsulated silicon carbide, or metal-encapsulated boron
nitride.
4. In the drill bit of claim 3 in which the ring is metal-bonded
tungsten-coated iron or iron-based alloy.
5. The drill bit of claim 1 in which said coat extends over the
crown end of said shank and in which diamond particles are surface
set in said end, in space configuration over the said end surface
forming the crown of said bit.
6. The drill bit of claim 5 in which the metal encapsulating
particles in said ring is tungsten, or tantalum, or columbium
(noibium) or molybdenum or titanium.
7. The drill of claim 5 in which the ring contains metal-bonded
tungsten-encapsulated iron, or iron-based alloy.
8. The drill of claim 1 in which the coat extends over the crown
end of said shank and at said crown end contains a metal-bonded
mixture of diamond particles and particles of tungsten carbide, or
metal-encapsulated alumina, or metal-encapsulated silicon carbide,
or metal-encapsulated boron nitride.
9. The drill of claim 8 in which the metal-encapsulating said ring
contains iron, or iron-based alloy encapsulated with tungsten, or
tantalum, or columbium, or molybdenum, or titanium.
10. In the drill bit of claim 8 in which the ring contains iron or
iron-based alloy encapsulated with tungsten.
11. The drill of claim 1 in which said coat extends over the crown
end and contains a mixture of diamond particles and tungsten
carbide particles and said coat above said crown is substantially
free of diamond particles and contains tungsten carbide, or
metal-encapsulated alumina, or metal-encapsulated silicon carbide,
or metal-encapsulated boron nitride.
12. The bit of claim 11 in which said encapsulating metal in the
particles of metal in said ring is tungsten, or tantalum, or
columbium (niobium), or molybdenum, or titanium.
13. The drill of claim 11 in which the ring contains iron or
iron-based alloy encapsulated with tungsten.
Description
This invention is an improvement on diamond drills in which
diamonds are incorporated in the body of or positioned on the
surface of an abrader structure in the form of a drill, for
example, as may be used for earth boring.
In the conventional earth-boring drills, a plurality of different
abrasive particles are employed. In addition to particles of high
hardness values, for example, diamonds which act on the primary
abrasive, there is positioned in the continuous phase of a metal
matrix binder a secondary abrasive of lower hardness value.
The purpose of this secondary abrasive particle is to wear away
preferentially thus exposing new abrasive faces of the primary
abrasive particle.
The abrader structures thus formed are deemed self-sharpening. That
is, the matrix including the secondary abrasive wears away
preferentially and uniformally exposing new primary abrasive
cutting surfaces. This, however, tends to reduce the area of the
interfacial surfaces between the bonding metal of the matrix and
the primary and secondary abrasive particles. Where the bond is
weak, the particles are torn out of the metal matrix, causing
excessive wear.
In such a structure, it is conventional to form the abrader body of
tungsten carbide to act as the secondary abrasive particle. The
diamonds and tungsten carbide are bonded by means of a metal matrix
which is formed by percolating molten metal to infiltrate the body
of discrete tungsten carbide in a suitable mold to bond the
tungsten carbide; if diamonds are also distributed throughout this
metal matrix, the mixture of diamonds and tungsten carbide form the
mass which is infiltrated by the molten metal. In another form, the
diamonds are positioned in space configuration on the external
grinding surface of the drill. These are termed surface set diamond
drills.
There are a number of difficulties in forming such drills arising
from the nature of the tungsten carbide as the secondary abrasive
and the diamonds as the primary abrasive.
One of the problems arising when using tungsten carbide and
diamonds in such structures is the restriction which it places on
the machinable metal which may be used for the purpose of producing
the machinable section of the bit.
The form of the drills includes a hollow steel shank coated at its
exterior surfaces and over its end forming the crown end of the
drill, with a metal bonded sheath of abrasive particles bonded to
the steel shank by the metal.
It is desirable to cover the end of the metal bonded sheath at its
end away from the crown end with a smooth bevel end. Such a
structure would have the advantage that the bit when withdrawn from
the bore hole would not hang up on a projection in the bore hole or
the end of a casing section through which it is to be removed.
However, the abrasive sheath is not conveniently machinable.
In order to solve this difficulty, we place a ring of machinable
metal such as iron or nickel or alloys of these metals over the end
of the abrasive section.
Conveniently, this may be done by providing a ring of such metal
powder so that when the sheath is formed it will be welded to the
body and may be machined to suitable form.
However, since the structure is formed under fusion conditions,
there is a danger that the molten machinable metal will invade the
body of the sheath and attack the tungsten carbide and
diamonds.
Diamonds and tungsten carbide are attacked by iron-based or
nickel-based alloys. The W.sub.2 C tungsten carbide is attacked or
dissolved in the binder, and on freezing precipitates a new phase
called Eta. This phase is an M.sub.6 C type carbide, and in the
case of nickel binders will have the composition Ni.sub.3 W.sub.3
C. Eta phase is more brittle than the original particle. The
particle is said to be "haloed." The "haloed" portion of particle
will have a hardness only of about 1,500 kilograms per square
millimeter, compared, for example, to 1,950 to 2,100 kilograms per
square millimeter (Knoop) for the core of the particle.
Tungsten carbide has been used in the past among other properties
because of its high specific gravity, hardness, and high melting
point.
The bonding metal chosen should be fluid at the temperature at
which it is desired to employ the molten metal in forming the
composite drill structure, for example, below 2,000.degree. F. and
desirably should have, when solid, ductility as measured in the
terms of microhardness of below about 400 kg/mm.sup.2. Desirably,
also, it should have a compressive strength above about 90,000
p.s.i. and an impact strength above about 5 foot pounds.
For this purpose, we may use copper-based alloys such as brass and
bronze alloys and copper-based alloys, for example, copper-based
alloys containing various amounts of nickel, cobalt, tin, zinc,
manganese, iron and silver, cast iron, iron-based alloys,
nickel-based alloys, for example, nickel-copper-aluminasilicon
alloy melting below 2,000.degree. C.
We have found that we may use alumina, silicon carbide, boron
nitride, and other abrasives as listed in Table 1 in place of
tungsten carbide. The most practical both from point of view of
economy and functional suitability are aluminum oxide, boron
nitride, and silicon carbide. However, these materials may not be
employed when a metal matrix is to be used as a bonding agent. The
particles are not sufficiently wetted by the molten metal.
We have solved this problem by forming the drill bit by either the
conventional procedures, using an abrader body for the bit formed
of secondary abrasive such as tungsten carbide employing either the
infiltrant method to produce a surface set diamond bit or an
impregnated bit and forming at the upper end of the abrader body a
ring of metal-bonded, metal-encapsulated iron or iron alloy. The
secondary abrasive as well as the tunsten-coated iron is bonded
with a molten metal forming a matrix. The iron ring after cooling
is machined to a suitable shape.
In selecting the metal for the envelope when the encapsulated
particle is to be used with metal matrix acting as a bonding agent,
it is desirable that the metal in the envelope have a suitably
higher melting point than the metal matrix.
We prefer to produce the aforesaid encapsulated iron particle by a
process of chemical vapor deposition, by subjecting the abrasive
particles to contact with a volatile metal compound at an elevated
temperature sufficient to maintain the metal compound in vapor form
and contact the vapor with a solid substrate under metal deposition
conditions.
While diamonds and the secondary abrasive may be used as the
primary abrasive and secondary abrasive in encapsulated form, our
invention permits their use in unencapsulated form in the structure
of our invention.
Cobalt-based, nickel-based, or iron-based alloys are undesirable as
metal-bonding agents since in their molten condition they attack
tungsten carbide and the diamonds. The inclusion of these metals
when used to produce the machinable portion of the drill is avoided
in our invention by the encapsulation of the particles of these
metals.
We prefer to use for encapsulation of the abrasive particles and
the aforesaid iron particles tunsten, tantalum, niobium
(columbium), and molybdenum, and, among the primary abrasive
particles, we prefer to employ diamonds, either the natural or
synthetic forms; and as secondary abrasive, we may use tungsten
carbide but we may employ encapsulated alumina, or encapsulated
silicon carbide or encapsulated boron nitride with tungsten carbide
or the encapsulated alumina most preferred because of the inherent
properties and relatively low cost of alumina, or boron nitride and
prefer to employ tungsten as the encapsulating material, deposited
under conditions to produce pure tungsten of the crystal form as
described herein.
We prefer to employ as a bonding agent a metal having a
significantly lower melting point than the metal envelope.
TABLE 1
B.P. .degree.C. at 760 m.m.* Molybdenum Pentachloride [MoCl.sub.5 ]
268 Molybdenum Hexafluoride [MoF.sub.6 ] 35 Molybdenum Carbonyl
[Mo(CO).sub.6 ] 156.4 Tungsten Pentabromide [WBr.sub.5 ] 333
Tungsten Hexabromide [WBr.sub.6 ] 17.5 Tungsten Pentachloride
[WCl.sub.5 ] 275.6 Tungsten Hexachloride [WCl.sub.6 ] 346.7
Tungsten Carbonyl [W(CO).sub.6 ] 175 at 766 m.m. Tantalum
Pentachloride [TaCL.sub.5 ] 242 Tantalum Pentafluoride [TaF.sub.5 ]
229.5 Titanium Tetraboride [TiB.sub.4 ] 230 Titanium Hexafluoride
[TiF.sub.6 ] 35.5 Titanium Tetrachloride [TiCl.sub.4 ] 136.4
Columbium Pentabromide [CbBr.sub.5 ] 361.6 Columbium Pentafluoride
[CbF.sub.5 ] 236 Columbium Pentachloride [CbCl.sub.5 ] 236 * Unless
otherwise indicated
When employing encapsulated or unencapsulated diamonds as the
primary abrasive particle, we prefer to limit the melting point of
the metal matrix to a temperature below about 2,800.degree. F.,
i.e. 1,538.degree. C., in order not to expose the diamonds to
excessive temperature which may impair the mechanical strength of
the diamonds.
We prefer to employ for the encapsulation of the abrasive particles
the reduction of a vapor of the metal compound.
In view of the above consideration, the metals whose compounds are
listed in Table 1 may be employed; however, we prefer to employ
tungsten as an encapsulating metal because of its particular
suitability in the drill of our invention. It gives under the
conditions of fabrication according to our invention a coating of
exceptionally high strength. It is readily wetted by the molten
metal matrixes described above and forms a strong metallurgical
bond with the metal matrixes employed in our invention.
The invention will be further described by reference to the
following figures:
FIG. 1 is a diagrammatic flow sheet of our preferred process of
encapsulation.
FIG. 2 is a schematic vertical section through a mold for use in
the infiltrant technique of forming a bit according to our
invention.
FIG. 3 is a partial section of one form of drill bit of our
invention.
FIG. 4 is a fragmentary view partly in section of a modified
mold.
FIG. 5 is a view partly in section of a modified drill bit of our
invention .
FIG. 1 illustrates a flow sheet of our preferred process for
producing the novel encapsulated abrasive of our invention. The
particles to be coated are placed in the reactor 1, whose cap 2 has
been removed. The reactor has a perforated bottom to support the
particles of selected mesh size. With cap 2 replaced and the valves
3, 4, 5, and 13 closed, and with valve 7 open, the vacuum pump is
started to de-aerate the system. Valve 7 is closed and the system
filled with hydrogen from hydrogen storage 11, valve 5 being
open.
The reactor is heated by the furnace 9 to the reaction temperature,
for example, from about 1,000.degree. to about 1,200.degree. F.
while purging slowly with hydrogen. The hydrogen flow rate is
increased until a fluidized bed is established. Hydrogen prior to
introduction into the reactor passes through a conventional
palladium catalyst to remove any impurities, such as oxygen in the
hydrogen. Vaporized metallic compound is discharged from the
vaporizing chamber 10, which may if necessary be heated by furnace
14, together with an inert gas, for example, argon from argon
storage 6, into the reaction chamber.
Preferably we desire to employ the volatile metal halides referred
to above, although, in some cases, we may use the carbonyls listed
in Table 1. Where the halide is employed, the reaction forms
hydrogen halide, which is passed through the bubble traps and is
absorbed in the absorber. Where the volatile compound employed is a
fluoride, the product formed is a hydrogen fluoride, and we may use
sodium fluoride for that absorption. We prefer to employ hydrogen
in stoichiometric excess.
The reaction deposits metal on the substrate and the effluent
material, being in the vapor state, is discharged, leaving no
contaminants on or in the metal. The metal is formed in its pure
state.
The rate of metal deposition depends on the temperature and flow
rate of the reactants, being the greater the higher the temperature
and the greater the flow rate of the hydrogen and volatile metals
compound.
After the deposit is formed, the valves 4 and 5 are closed and
argon is continued to pass into the reactor and the encapsulated
abrasive is allowed to cool to room temperature in the
non-oxidizing condition of the argon environment.
The conditions in the reactor, both because of the mesh size and
particle size distribution of the particles and because of the
velocity of the vapors and gases fluidizes the particles. As will
be recognized by those skilled in the art, a dense phase is
established in the lower part of the reactor in which the particles
are more or less uniformally distributed in violent agitation in
the dense phase. This results in a substantially uniform deposit
per unit of surface of the particles.
The reaction products and the carrier gases and excess hydrogen
enter the upper space termed the disengaging space where they are
separated from any entrained particles.
For purposes of illustration, not as limitations of our invention,
the following examples are illustrative of the process of
depositing a metal sheath upon a substrate.
The actual mesh size employed depends upon the service to which the
abrader is to be placed. We may use iron particles of size (Tyler
mesh) through a 16 and on a 400 mesh (-16 + 400). Preferably we
employ 30 to 100 mesh material, for example, -30 + 60 mesh. In
depositing tungsten, we may and prefer to employ tungsten
hexafluoride, which is contained and vaporized in 10. It is
volatile at atmospheric temperatures and need not be heated. In the
reactor employed after the system has been deaerated and
backfilled, hydrogen flow is established at a low flow rate of
about 100 ml/min; and as described above, the temperatures in the
reactor 1 having been adjusted to 1,150.degree. F., as measured by
the thermocouples, the hydrogen flow is increased to about
1,250-1,350 ml/min, and the flow of the tungsten fluoride vapor to
about 150 ml/min and the argon gas is adjusted to about 285 ml/min,
all as measured by the flow meters as indicated in FIG. 1, the
hydrogen being in stoichiometric excess over the tungsten
hexafluoride.
The thickness of the coat of the tungsten on the particle depends
on the duration of the treatment and suitably for the 40 to 50 mesh
diamonds described above, the coat will be 1 mil thick in about 1
hour. Suitable thickness deposit will run from about 0.1 to about
1.5 mils thick.
In the above example, the substrate surface is completely coated,
indicating that the process of vacuum chemical vapor deposition has
great throwing power. The outer surface of the coated particles is
topographically congruent to the outer surface of the underlying
substrate and reproduces it. The interlocked structure produces a
coating of high tensile and bending strength.
The preferred embodiment of the surface set drill bit, as
illustrated in FIGS. 2-4, may be formed in a graphite mold section
18, which is formed with sockets positioned in the interior surface
of the mold. Diamond particles 19 are placed in the sockets
positioned on the interior surface of the crown end of the
mold.
With mold cap 24', section 18b and 18a removed and core 25 with
vent holes 26 in position, a layer 20 of particles of tungsten
carbide, such as described above, is placed in the mold 18 to cover
the protruding diamonds and vibrated in position to compact the
powder.
The threaded steel shank 15 is then placed over the mold above the
powder 20, spaced from the surface of the mold 18, and held in
position with a suitable fixture not shown.
Secondary abrasive particles, such as tungsten carbide, which may
be but need not be encapsulated as described above, or, for
example, encapsulated alumina particles 17 are introduced into the
annulus at the exterior and in the annulus at the interior of the
shank 15. The layer of the particles 17 in the exterior annulus
reaches the level of the top of the mold section 18, but the powder
in the interior annulus may, if desired, reach a higher level as
shown.
The mold section 18a is then placed over the shank 15 and on the
mold section 18. A ring of tungsten-coated iron particles 21 is
placed in the exterior annulus over the particle section 17.
The mold section 18b is then set over the shank 15 and on the mold
section 18a; and infiltrant metal powder 22, for example, of 200
mesh size such as described above, is introduced into the annulus
on the exterior and the annulus at the interior of the shank 15
above the particles 21 and reaching into the space 23.
The ratio of the metal to the total void volume of the mold is
desirably such that when the infiltrant metal melts it may fill all
of the space between the secondary abrasive particles and cover the
exposed diamonds.
As previously described, in carrying out this procedure, we wish to
select a temperature of formation which will be below about
2,800.degree. F., in order not to expose the diamonds to an
excessive temperature. The binder metal will melt and percolate
through the interstices including those in the encapsulated iron
particles and those between the abrasive particles and fill all of
the voids as described above and will also wet the metallic shank.
If a metallic coating is placed upon the diamond as well as the
secondary abrasive particles, the binder metal will wet the
surfaces of the encapsulated particles, thus producing a tight bond
to the matrix.
The particle sizes of the abrasive particles are chosen to give
proper compaction and void area. A particle size through a 30 mesh
and on a 60 mesh (-30 + 60) is suitable.
The tungsten-coated iron powder 21 is used to provide a machinable
shoulder which acts as a barrier and cover to the exterior section
of the abrasive section 17.
The tungsten envelope of the iron acts to protect the iron metal
from escaping because its melting point will be below the
temperature at which the mold is fired and could if it reached the
unencapsulated diamonds or unencapsulated tungsten carbide attack
them. It also provides for a machinable mass since the tungsten
forms only a thin coat as described above.
The section is beveled as shown in FIGS. 3 and 5. This will assure
that there is no exterior ledge which would otherwise be formed by
the secondary abrasive section which is substantially unworkable to
provide for a bevel surface. In the absence of this beveled
section, there would be a danger that the drill bit could hang up
on the bore wall or be caught on a casing section in which the
drill string is to operate.
When the assembly has cooled, it is removed from the mold and the
section 21 is machined as shown in FIGS. 3 and 5, the interior box
threads can receive the pin and box connector 26 to assemble the
drill.
The drill is thus composed of a tubular shank 15 carrying a
threaded section 28. Bonded to the interior tubular surface and
exterior tubular surface of the shank 51 and over its crown end a
coating of abrasive particles 17 bonded by a metal matrix in the
form shown in FIG. 3, the crown of said bit carries spaced diamonds
embedded in said crown and protruding externally therefrom.
The encapsulation of the iron with the tungsten will prevent the
iron from melting and percolating through the mass to attack the
diamond and the tungsten carbide if used.
It will be understood that the iron may be any form of the iron,
such as powdered cast iron, steel or other ferrous alloy.
A particularly useful tungsten carbide when used in either layer 20
or 17 is one ranging from WC having 6.12 wt percent of carbon to
W.sub.2 C having a carbon content about 3.16 wt. percent. A useful
material is so-called sintered tungsten carbide and consists of
microsized WC crystals and cobalt metal bonded by liquid phase
sintering at high temperature. The cobalt content varies from 3 wt.
percent to over 25 wt. percent. This material has a hardness of
about 1,250 to 1,350 kg/mm.sup.2 (Knoop). Another form of eutectic
alloy containing about 4 percent by weight of carbon having a
hardness in the range of 1,900 to 2,000 kg/mm.sup.2 (Knoop) may
also be used.
The drill described above may also be produced by an impregnation
technique by mixing a primary abrasive, for example, diamonds with
a secondary abrasive described above, for example, tungsten
carbide.
In this case, the mold section 18a does not contain pockets for
insertion of diamonds but is smooth. In all other respects, the
mold is the same as the mold shown in FIG. 2. With the shank 15 and
core 25 in position in section 18, a mixture of the metal-coated
secondary abrasive and the primary abrasive, for example, diamonds
is introduced in the same manner as is the case of 17 in FIG. 2.
This forms a layer 26 extending part way up the exterior annulus of
15 and to a higher level in the annulus in the interior side of
15.
The section 18a is then placed in position and the layer 21
introduced. The section 18b is then placed in position and the
infiltrant metal 22 is introduced into the space 23 and the cap 24
placed in position. The same procedure is then followed as
described in connection with FIG. 2.
The mesh size of the infiltrant metal is suitably through a 200
mesh; and in both forms, the metal may be of the kind previously
described as suitable for infiltrant purposes.
The mesh size of the secondary abrasive particles employed in the
form shown in FIGS. 2 and 3 as well as in FIGS. 4 and 5 may be the
same, and the size diamond particles employed in the mixture with
the secondary abrasive used in forming the layer 26 may be equal to
that of the secondary abrasive particles. The quantity of the
diamond particles may be that of the secondary abrasive particles.
The diamond particles and the secondary abrasive are intimately
mixed to produce a uniform distribution.
Instead of employing a mixture of diamonds and secondary abrasive
to form the entire layer shown at 26, we may proceed as in the case
of the form described in connection with 2 and 5 employ an initial
crown layer formed of the mixture of diamonds and secondary
abrasive particle described for forming the crown layer 20 in FIG.
2. We may then introduce on top of the crown layer the material 17
and the layer of tungsten-coated iron as described in connection
with FIG. 2 and complete the operation as described for the
formation of the drill in connection with FIGS. 2 and 3.
The drill shown in FIG. 3 and also 5 is composed of a threaded
shank 15 having a core 30 to act as the conduit for mud or other
drilling fluid. The shank carries the abrasive coating 17 or 26
welded to the shank by the bonding metal which wets the shank at
the high temperatures of the process. The abrasive coating extends
part way along the exterior and interior surface of the shank and
over the lower end of the shank away from the threaded free end 28,
to form the hollow crown end 29 of the drill. In the form shown in
FIG. 2, embedded in the abrasive coating at the crown end of the
drill are a plurality of closely spaced diamonds 19 embedded in and
protruding from the crown end. This is termed a surface set diamond
drill.
Where the impregnated type of drill shown in FIG. 5 is formed, the
diamonds are not positioned in the crown end but are distributed
uniformally throughout the abrasive body carried by the shank, or
in a layer adjacent the crown end and the remainder of the abrasive
body bonded to the shank.
* * * * *