U.S. patent number 3,751,778 [Application Number 05/187,407] was granted by the patent office on 1973-08-14 for process for the simultaneous texturing and dyeing or finishing of thermoplastic yarns.
This patent grant is currently assigned to Societe Rhodiaceta. Invention is credited to Pierre Grosjean, Rene Guillermin, Roger Vidal.
United States Patent |
3,751,778 |
Grosjean , et al. |
August 14, 1973 |
PROCESS FOR THE SIMULTANEOUS TEXTURING AND DYEING OR FINISHING OF
THERMOPLASTIC YARNS
Abstract
A process for the simultaneous texturizing, i.e. crimping, and
dyeing or finishing of thermoplastic yarns comprising packing and
compressing the yarns into a confined space through introduction of
a flow of a compressed fluid heated to a temperature sufficient to
set the yarns, allowing a portion of the compressed fluid to
provide movement of the yarns axially in the confined space with
the remainder of the fluid escaping laterally from the confined
space into further annular space under a pressure lower than the
pressure of the confined space, but higher than atmospheric
pressure; and simultaneously introducing at least one dyeing
solution or finishing agent into the confined space over the
compressed yarns, such process being characterized in that the
compressed yarn is continuously passed through at least one
expansion zone and thereafter through at least one zone in which a
further fluid is introduced under pressure. Such process allows for
the simultaneous dyeing or finishing of thermoplastic yarns in a
high speed texturizing process.
Inventors: |
Grosjean; Pierre
(Sainte-Foy-Les-Lyon, FR), Guillermin; Rene (Bron,
FR), Vidal; Roger (Champagne, FR) |
Assignee: |
Societe Rhodiaceta (Paris,
FR)
|
Family
ID: |
26215998 |
Appl.
No.: |
05/187,407 |
Filed: |
October 7, 1971 |
Foreign Application Priority Data
|
|
|
|
|
Oct 14, 1970 [FR] |
|
|
7037348 |
Jul 26, 1971 [FR] |
|
|
7127557 |
|
Current U.S.
Class: |
28/255; 8/494;
28/266; 101/172; 8/148; 8/497; 28/267 |
Current CPC
Class: |
D02G
1/122 (20130101); D06B 3/045 (20130101) |
Current International
Class: |
D02G
1/12 (20060101); D06B 3/00 (20060101); D06B
3/04 (20060101); D02g 001/12 () |
Field of
Search: |
;28/72.14,75WT
;8/17,148 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Rimrodt; Louis K.
Claims
What is claimed is:
1. In a process for the simultaneous crimping and dyeing
thermoplastic filament yarns at high speeds comprising packing and
compressing said yarns into a confined space by introduction of a
flow of a first compressed fluid, said first compressed fluid being
heated to a temperature sufficient to set said yarns; allowing a
portion of said first compressed fluid to provide movement of said
yarns axially in said confined space, the remainder of said fluid
escaping laterally from said confined space into a further space
under a pressure lower than the pressure of said confined space,
but higher than atmospheric pressure; and simultaneously
introducing at least one dyeing solution into said confined space
over the compressed yarns, the improvement wherein the compressed
yarn passes through at least one expansion zone and thereafter
through at least one zone in which a second fluid is introduced
under pressure.
2. The process of claim 1 wherein said first and second fluids are
the same fluid.
3. The process of claim 2 wherein said first and second fluids are
steam.
4. The process of claim 1 wherein said compressed yarn passes
through at least one expansion zone; thereafter through at least
one zone in which said second fluid is injected and thereafter
through at least one further expansion zone.
5. The process of claim 1 wherein said at least one dyeing solution
additionally contains a finishing agent.
6. The process of claim 1 wherein said compressed yarn passes
through a first expansion zone wherein said first compressed fluid
expands under a pressure close to atmospheric pressure; thereafter
said compressed yarn passes through an injection zone wherein said
second fluid is injected under a high pressure substantially equal
to the pressure of the first texturizing fluid, and finally said
compressed yarn passes through a further expansion zone maintained
at a pressure substantially the same as said first expansion
zone.
7. The process of claim 6 wherein said first and second fluids are
the same fluid.
8. The process of claim 7 wherein said first and second fluids are
steam.
9. In a process for the simultaneous crimping and finishing
thermoplastic filament yarns at high speeds comprising packing and
compressing said yarns into a confined space by introduction of a
flow of a first compressed fluid, said first compressed fluid being
heated to a temperature sufficient to set said yarns; allowing a
portion of said first compressed fluid to provide movement of said
yarns axially in said confined space, the remainder of said fluid
escaping laterally from said confined space into a further space
under a pressure lower than the pressure of said confined space,
but higher than atmospheric pressure; and simultaneously
introducing at least one finishing solution into said confined
space over the compressed yarns, the improvement wherein the
compressed yarn passes through at least one expansion zone and
thereafter through at least one zone in which a second fluid is
introduced under pressure.
10. The process of claim 9 wherein said first and second fluids are
the same fluid.
11. The process of claim 10 wherein said first and second fluids
are steam.
12. The process of claim 9 wherein said compressed yarn passes
through at least one expansion zone; thereafter through at least
one zone in which said second fluid is injected and thereafter
through at least one further expansion zone.
13. The process of claim 9 wherein said compressed yarn passes
through a first expansion zone wherein said first compressed fluid
expands under a pressure close to atmospheric pressure; thereafter
said compressed yarn passes through an injection zone wherein said
second fluid is injected under a high pressure substantially equal
to the pressure of the first texturizing fluid, and finally, said
compressed yarn passes through a further expansion zone maintained
at a pressure substantially the same as said first expansion
zone.
14. The process of claim 13 wherein said first and second fluids
are the same fluid.
15. The process of claim 14 wherein said first and second fluids
are steam.
Description
This application is directed to a process for the simultaneous
texturizing and dyeing or finishing of thermoplastic yarns at high
speed; more particularly, the present invention is directed to the
simultaneous crimping and dyeing of thermoplastic yarns at high
speed in a manner not heretofore possible with conventional
procedures.
Various processes have been proposed for the texturizing of
thermoplastic yarns including processes involving the simultaneous
texturizing and dyeing of the same. With regard to each of such
processes previously proposed, a particularly difficult problem to
be solved involves the setting of the crimp. This problem of
setting of the crimp during texturizing of thermoplastic yarns is
even more difficult when attempting to effect simultaneous
texturizing and dyeing.
In the case of high speed texturizing processes it has been
proposed to effect the texturizing by compressing and packing a
thermoplastic yarn into a confined space by means of a hot
compressed fluid, at least a portion of the fluid escaping
laterally into the atmosphere with the remainder providing the
axial movement of the packed yarn within the confined space. In
such proposal, the hot fluid is used as a crimp inducing and heat
treating agent and is generally saturated steam.
A more recent proposal has improved upon such texturizing process
by providing an improvement in the heat treatment associated
therewith. Such proposal, the subject of co-pending application
Ser. No. 56,880 filed July 21, 1971 assigned to the assignee of
this application, is one in which the hot fluid is allowed to
expand, not directly into the atmosphere, but rather into a space
which is maintained at a pressure higher than atmospheric pressure
but, obviously, lower than the pressure of the confined space in
which the thermoplastic yarn is compressed and packed. While such
proposal does provide an improvement in the heat treatment and
texturizing of the thermoplastic yarn, the same still fails to
solve problems associated with attempts to simultaneously texturize
and dye or finish the thermoplastic yarns.
It is additionally known that in the foregoing texturizing
processes one or more dyeing solutions can be inserted in the
texturizing chamber so as to effect simultaneous texturizing and
dyeing of the thermoplastic yarns. It is unfortunate, however,
that, particularly at high speeds, the absorption of the dyes by
the thermoplastic yarns is not always sufficiently fast.
Accordingly the lack of absorption of the dyes by the thermoplastic
yarns in the simultaneous texturizing and dyeing of the same is a
distinct disadvantage of such simultaneous processes.
In addition, it has long been recognized that at least a minimum
amount of water is necessary for sufficient migration of the dyes.
On the other hand, the effects of heat treatment are increased with
decreasing amounts of water, thereby leading to the conclusion that
lesser amounts of water provide for better development of the dyes.
These inconsistent parameters have again led to certain distinct
disadvantages in prior attempts and prior proposals for the
simultaneous texturizing and dyeing of thermoplastic yarns.
In attempts to carry out simultaneous texturizing and dyeing, it
was discovered that the packed yarn was receiving during dyeing too
much water for optimal operation under dyeing conditions. It was
proposed that the pressure of the texturizing fluid could be raised
so as to reduce the excess water, the raise in pressure of the
texturizing fluid, i.e. steam, thereby raising the temperature
thereof. However, such attempt to decrease the amount of excess
water by raising the pressure and temperature of the texturizing
fluid has not been particularly successful due to limitations
imposed thereon because of deterioration of the yarn at high
temperatures. Accordingly, until the development of the present
invention, no process for the successful simultaneous texturizing
and dyeing of thermoplastic yarns had been proposed. The process of
the present invention, however, as will be indicated hereinafter,
has eliminated all of the foregoing disadvantages and deficiencies
of prior art processes and proposals.
The foregoing defects and deficiencies of prior processes have been
overcome in accordance with the present invention wherein a process
for the simultaneous texturizing and dyeing of a thermoplastic yarn
has been developed comprising packing and compressing such
thermoplastic yarns into a confined space by introduction of a flow
of a compressed fluid, preferably steam, the compressed fluid being
heated to a temperature sufficient to set the yarns; allowing a
portion of the compressed fluid to provide movement of the yarns
axially in the confined space, the remainder of the fluid escaping
laterally from the confined space under a pressure lower than the
pressure of the confined space but higher than atmospheric
pressure; and simultaneously introducing at least one dyeing
solution or finishing solution into the confined space over the
compressed yarns, the improvement in accordance with the present
invention being in that the compressed yarn is continuously passed
through at least one expansion zone to effect expansion of the
fluid and thereafter through at least one injection zone wherein a
further fluid under pressure is injected. In this way, it is
possible to advantageously texturize, i.e. crimp, and dye or finish
thermoplastic yarns simultaneously, at high speeds.
Accordingly, it is a principal object of the present invention to
provide a novel process for the simultaneous texturizing and dyeing
or finishing of thermoplastic yarns in a manner eliminating the
various defects and disadvantages of prior proposals.
It is a further object of the present invention to provide a
process for the simultaneous crimping and dyeing of thermoplastic
yarns wherein the thermoplastic yarn is simultaneously dyed and
crimped in a confined space and thereafter continuously passed
through at least one expansion zone and thereafter through at least
one zone in which a fluid is introduced under pressure.
It is yet a further object of the present invention to provide a
novel improved process for the simultaneous crimping and dyeing of
thermoplastic yarns wherein the yarn is packed and compressed in a
confined space by introduction of a flow of a compressed fluid, a
portion of the compressed fluid allowing advancement of the yarn,
the remainder escaping laterally into a further space under a
pressure lower than the pressure of the confined space but higher
than atmospheric pressure, at least one dyeing solution being
simultaneously introduced into the confined space, the improvement
in accordance with the present invention comprising continuously
passing the compressed yarn through at least one expansion zone and
thereafter through at least one zone in which a further fluid is
introduced under pressure.
Still further objects and advantages of the novel process of the
present invention for the simultaneous texturizing and dyeing or
finishing of thermoplastic yarns will be more apparent from the
following more detailed description thereof.
The foregoing objects and advantages of the process of the present
invention are achieved by simultaneously texturizing and dyeing or
finishing a thermoplastic yarn through compression and packing of
the yarn into a confined space, by means of a flow of a compressed
fluid, heated to a temperature which permits the setting of the
yarn, a portion of the fluid providing advancement of the yarn
axially through the confined space with the remainder escaping
laterally into a further space under a pressure lower than the
feeding pressure but higher than atmospheric pressure, at least one
dyeing solution or finishing solution being inserted into the
confined space over the packed yarn, the process being particularly
characterized and the improvement residing in the feature that the
packed yarn passes into and through at least one zone of expansion
of the fluid and thereafter into and through at least one injection
zone wherein at least one further fluid under pressure is
injected.
As indicated throughout the instant specification, the expression
"thermoplastic yarn" is meant to embrace any continuous length of
substantially unidirectional thermoplastic textile material,
regardless of its specific structure, which can be utilized for
textile manufacture. According the thermoplastic yarns which are
simultaneously texturized and dyed or finished in accordance with
the present invention may consist of one or a number of continuous
filaments or of discontinuous (stable) fibers. The term
"thermoplastic yarn" as employed throughout the instant
specification includes such yarns obtained by spinning or extrusion
of polymers, copolymers, graft copolymers, mixtures thereof, or by
spinning and simultaneous extrusion of at least two of these
products arranged concentrically or side-by-side or dispersed in
one another to produce homogeneous or hetergeneous yarns having
properties depending upon the various components. Suitable
thermoplastic yarns which are utilizable in accordance with the
present invention include those of natural or synthetic origin
including such materials as polyesters, linear polyamides,
cellulose acetate yarns, polyvinyl chloride, etc. Any of these
forms of thermoplastic yarns can be advantageously employed in
accordance with the instant process and the present invention is
not in any way limited to any particular type or form of
thermoplastic yarn.
As indicated above, the process of the present invention is
applicable both to the simultaneous texturizing, i.e. crimping, and
dyeing of thermoplastic filament yarns as well as the simultaneous
texturizing and finishing of such yarns. The dyes which can be
utilized in accordance with the present invention and applied to
the packed yarn in the confined zone can be any of those
conventionally utilized for dyeing thermoplastic yarns. For
example, the dyes can be acid dyes, basic dyes, disperse dyes,
etc., as well as conventional pigments. In this regard, the process
of the present invention is not dependent upon any particular
dyeing solution and any conventional dyeing solution or solutions
can be advantageously utilized in accordance with the instant
process.
Similarly, the finishing agents which can be utilized in accordance
with the present invention include the well-known resist agents,
antistatic agents, soil retardant agents, optical brightening
agents, softeners, ultraviolet light absorbing agents fire proofing
agents as well as a variety of other conventional finishes. Here
again, the process of the present invention is not dependent upon
the utilization of any particular finishing agent and any of those
conventionally applied to thermoplastic yarns can be applied
simultaneously with the texturizing, i.e. crimping, in accordance
with the instant process.
In addition, while the foregoing and following descriptions are
directed primarily to simultaneous texturizing and dyeing or
simultaneous texturizing and finishing it is quite obvious that a
dyeing solution and finishing solution can be simultaneously
applied to the packed yarn during the texturizing operation.
Accordingly, it is possible to apply separate dyeing and finishing
solutions in the process of the present invention or if desired
include a finishing agent in a dyeing solution. Each of these
embodiments is well adapted to the process of the present
invention.
In accordance with the process of the present invention, the
thermoplastic filament yarns to be simultaneously texturized, i.e.
crimped, and dyed and/or finished are packed and compressed into a
confined space through introduction of a flow of a compressed
fluid, preferably steam, such compressed fluid being heated to a
temperature sufficient to set the yarns. The yarn is texturized in
this confined space by compression and packing under a first high
pressure associated with the introduction of the compressed fluid,
i.e. steam. A portion of the compressed fluid provides movement of
the yarn axially in the confined space with the remainder of the
compressed fluid escaping laterally into an annular space around
the confined space under a pressure which is lower than the
texturizing pressure but higher than atmospheric pressure. After
passing through the confined space, the thermoplastic yarn which is
packed or piled up then penetrates or passes into at least one zone
of relaxation wherein the compressed fluid may be expanded to a
lower pressure before the yarn passes into at least one zone
wherein a further fluid is injected under pressure. Preferably, the
yarn then passes into at least one further expansion zone under a
low pressure, preferably of the same order of magnitude of the
earlier expansion zone. The fluid which is injected in the
injection zone is also preferably steam.
The pressure of the compressed fluid in at least one injection zone
into and through which the packed yarn is passed is preferably high
so as to exert sufficient mechanical pressure on the yarn.
Generally and in a preferred manner, the pressure in at least one
injection zone is substantially equal to or slightly lower than the
pressure of the texturizing fluid. Generally, the pressure of the
texturizing fluid is from about 4 to about 12 kg/cm.sup.2, the
pressure in at least one injection zone therefore being
aproximately 1.5 to 8 kg/cm.sup.2. The pressure in the zones of
relaxation and expansion of the compressed fluid are generally
within the range of from about 1 to 3 kg/cm.sup.2 preferably close
to atmospheric pressure. In this regard, the packed yarn may be
passed into such zones of relaxation and injection under equal or
differing pressures, the zones being arranged in various
combinations. It should be clearly observable from the foregoing,
however, that while the various zones through which the yarn passes
in the process of the present invention are preferable maintained
within the foregoing pressure ranges, the particular pressure for
any specific zone can be varied within wide limits.
The process of the present invention allows for the texturizing and
simultaneous dyeing and/or finishing of a thermoplastic yarn at
high speeds. In this regard the process of the present invention
can be carried with high speeds compatible with the speeds utilized
in the overall process within which the texturizing process is
utilized. For example, when the process is integrated into a
spinning device or extruding-drawing device, the feeding means are
generally between 600 and 1,500 meters per minute with the windup
speeds generally within the range of 500 to 1,400 meters per
minute. The process of the present invention allows the
simultaneous texturizing and dyeing and/or finishing of the
thermoplastic yarn at speeds compatible with the above.
When the process of the present invention is carried out in a
discontinuous manner and it does not form a portion of an
integrated process as described above, the feeding speeds of the
yarn are generally within the range of 1,000 to 5,500 meters per
minute and the windup speeds between 800 and 5,000 meters per
minute. Certainly, however, slightly greater or lesser speeds for
both the feed and windup of the yarn can be employed in either a
discontinuous or integrated process.
It is unexpected that in accordance with the present invention the
simultaneous texturizing, i.e. crimping, and dyeing and/or
finishing permits a considerable reduction in the amount of water
maintained on the yarn, the water present being mainly due to the
aqueous dyeing solution since generally 100 grams of water are
provided in the aqueous dye solutions for 100 grams of yarn. The
elimination of water in accordance with the present invention
provides an improvement from the viewpoint of dyeing, specifically
in accordance with the present invention it is possible to obtain
much better control, migration and diffusion of the dyes in the
thermoplastic yarns.
The device or apparatus useful in carrying out the process of the
present invention includes a suction nozzle having a passage for
the thermoplastic yarn and an inlet pipe for the compressed fluid;
a tubular chamber which communicates with the nozzle and is
perforated with apertures so as to allow escape of some of the
fluid from the tubular chamber; means for injection of one or more
dyeing solutions into the tubular chamber; several closed
enclosures surrounding the tubular chamber at least over a certain
portion thereof associated with known systems for regulating the
pressure, the closed enclosures serving to provide at least one
injection zone and relaxation or expansion zone, the injection zone
having associated therewith at least one means for injection of a
fluid under pressure; and means for guiding and checking the
delivery of the treated thermoplastic yarn.
The closed enclosures forming the injection zones and zones of
relaxation and expansion of the fluid may be formed of several
separate enclosures placed side-by-side or may be formed of a
single enclosed space with water and air tight partitions. The
process of the present invention can be applicably carried out in
accordance with either of these embodiments. Moreover, as indicated
previously, it is a preferred feature of the present invention that
the thermoplastic yarn is first passed through at least one zone of
expansion, thereafter into and through at least one injection zone
wherein a fluid under pressure is injected over the thermoplastic
yarn and finally through at least one further zone of
expansion.
The process of the present invention will now be described by
reference to the drawings wherein:
FIG. 1 is a schematic representation of a device carrying out the
process of the present invention; and
FIG. 2 is a further schematic representation of an alternative
device carrying out the process of the present invention.
Referring to the figures wherein like numerals represent like
elements, FIG. 1 illustrates a device carrying out the process of
the present invention wherein a thermoplastic yarn 1 is inserted
into a longitudinal duct 2 of a nozzle 3, a texturizing fluid, e.g.
steam, being inserted through pipe 4. The thermoplastic yarn 1
penetrates into tubular chamber 5, a portion of the texturizing
fluid serving to advance the yarn axially, compressing and crimping
the same in tubular chamber 5. Tubular chamber 5 is perforated with
apertures 6 through which a portion of the texturizing fluid
escapes into a closed enclosure 7 which is maintained under a
pressure lower than the pressure of the texturizing fluid but
higher than atmospheric pressure by a known pressure regulating
device 8.
In tubular chamber 5, thermoplastic yarn 1 forms a pile of packed
yarn 9 which is subjected, in this case, to the action of two
dyeing solutions coming from tank 10 divided into compartments 11
and 12, the dyeing solutions being introduced over the packed yarn
9 through pipes 13 and 14. While two dyeing solutions are
illustrated in FIG. 1, it is quite obvious that one or more dyeing
solutions can be utilized or, a finishing solution can be employed
alone or together with other finishing solutions or in combination
with one or more dyeing solutions. Each of these embodiments is
well within the scope of the present invention.
As seen in FIG. 1, tubular chamber 5 thereafter passes through a
first expansion or relaxation chamber 15 equipped with a regulating
system or means 16 capable of maintaining the pressure in the
chamber to allow expansion and escape of the texturizing fluid. The
texturizing fluid escapes from tubular chamber 5 into the first
expansion or relaxation chamber 15 through apertures 17. While only
one expansion or relaxation chamber 15 is shown in FIG. 1, it is
quite possible as indicated previously that the tubular chamber may
pass through one or more expansion or relaxation chambers or
zones.
After passing through the expansion or relaxation chamber 15,
tubular chamber 5 then passes into a zone or chamber 18 equipped
with a pressure regulating device 19 and a fluid injection means,
not shown, the fluid being injected into chamber 18 through pipe or
tube 20. The compressed fluid, preferably the same as the
texturizing fluid, i.e. steam, is introduced into injection chamber
18 through pipe or tube 20 and passes over packed yarn 9 by passing
through apertures 21. Again, while a single injection zone or
chamber 18 has been shown in FIG. 1, as indicated previously, one
or more of such injection chambers can be utilized in carrying out
the process of the present invention.
After passing through injection zone or chamber 18, tubular chamber
5 passes through a further expansion or relaxation chamber 22,
generally of the same configuration and type as expansion or
relaxation chamber 15. Such further relaxation chamber 22 is also
equipped with a known pressure regulating device 23 and the fluid
escapes into the relaxation or expansion chamber 22 through
apertures 24. As seen in FIG. 1, the packed yarn which progresses
through tubular chamber 5 by the action of the texturizing fluid is
guided when it leaves relaxation or expansion chamber 22 by means
of a driven roller 26 and non-driven roller 27, the means for
driving the roller not being shown. In addition, as previously
indicated, the process of the present invention can be carried out
in a discontinuous manner or as a portion of an integrated process.
Other necessary elements of the integrated process or discontinuous
process including delivery and windup means for the thermoplastic
yarn are conventional and not shown in the figures.
FIG. 2 illustrates a further device or apparatus carrying out the
process of the present invention, the apparatus of FIG. 2 differing
from that of FIG. 1 only in that the means for guiding and
controlling the packed yarn 9 comprises a tube 28 with apertures 29
open to the atmosphere. Again, the conventional delivery and windup
means, etc., are not shown.
Again, with regard to FIG. 2, it is pointed out that while the same
illustrates passage of tubular chamber 5 through a single expansion
or relaxation zone or chamber, an injection zone or chamber and
thereafter through a further expansion or relaxation zone or
chamber, it is quite obvious that one or more of each of these
zones can be utilized in carrying out the process of the present
invention.
The present invention will now be described by reference to the
following examples. In such examples, "CI" refers to "Color Index",
2nd Edition, 1956 and supplement, published by "Society of Dyers
and Colorists" and the "American Association of Textile Chemists
and Colorists". Such examples are presented for purposes of
illustration only and the present invention is in no way to be
deemed as limited thereto.
EXAMPLE 1
In carrying out this example a device according to FIG. 1 was used,
with the following characteristics:
length of the unit formed by the closed container 7 and the
chambers or chests 15, 18, 22 500 mm length of the closed container
7 450 mm length of each of chests 15, 18, 22 15 mm diameter of the
tubular chamber 5 10 mm
The fluid used is saturated steam.
With this device, a polyhexamethylene-adipamide (Nylon 66) yarn,
with tetralobed cross-section, 2,300 dtex/136 filaments, is
texturized and dyed simultaneously, under the following
conditions:
Yarn feeding speed into nozzle 3 1075 m/mn Absolute steam feeding
pressure at the inlet of the texturizing chamber 8 kg/cm.sup.2
Absolute pressure of steam inside of closed enclosure 7 3
kg/cm.sup.2 Absolute feeding pressure in chest 18 3 kg/cm.sup.2
Chests 15 and 22 are the non-condensing type (free exhaust).
The packed yarn is dyed by bringing in contact with it an aqueous
solution of brilliant polar blue R A W L (CI 61 585), with a
concentration of 40 g/l, and a rate of flow of 70 cm.sup.3 /mn, and
an aqueous solution of milling yellow 2 R (CI 25 135), with a
concentration of 40 g/l, and a rate of flow of 70 cm.sup.3 /mn.
The amount of water brought in by these aqueous solutions is 73
percent with respect to the weight of the yarn.
To point out the influence of the process according to the
invention, the moisture content of the yarn in terms of weight was
measured.
At the entrance of the texturizing device, the moisture content of
the yarn is 17% At the outlet of the closed container 7 36% At the
outlet of chest 15 28.5% At the outlet of chest 22 23%
The presence of chests 15, 18 and 22 therefore causes a lowering of
the moisture content of:
[(36 - 23)36] .times. 100 = 36%
The mechanical properties of the yarn are as follows:
Resistance 2.4 g/dtex Elongation at break 42% Elasticity 30% Crimp
10.1 half- crimps per cm.
The elasticity is measured by the following test.
A skein of 10 meters of yarn to be tested is treated for 5 minutes
at 130.degree.C. in saturated steam in a steam oven. Then a load of
0.045 g/dtex (0.05 g/den) of the yarn prior to texturizing is
applied on a length of 50 cm of yarn taken from said skein. A
length L.sub.1 of yarn is then measured. The load is then replaced
by another smaller load of 0.0009 g/dtex (0.001 g/den) of the yarn
prior to texturizing. This load is maintained for 1 hour, then the
length L.sub.2 of the yarn is measured.
The elasticity is given by the formula:
[(L.sub.1 - L.sub.2)/L.sub.2 ] .times. 100
The value indicated corresponds to the average or mean of six
tests.
The foregoing example clearly shows the applicability of the
process of the present invention to the simultaneous dyeing and
texturizing of the thermoplastic yarn at high speeds. The process
allows good dye absorption and good fixation of the dye on the
yarn.
EXAMPLE 2
With the device used in Example 1 and illustrated in FIG. 1, a
Nylon 66, 2,300 dtex/120 filament yarn is texturized and
simultaneously a dyeing inhibitor or a resist agent is applied to
the yarn.
The operating conditions are as follows:
Yarn feeding speed in nozzle 3 1070 m/mn Absolute steam feeding
pressure at the inlet of the texturizing chamber 8 kg/cm.sup.2
Absolute pressure of steam inside closed enclosure 7 3 kg/cm.sup.2
Absolute feeding pressure in chest 18 3 kg/cm.sup.2
The treated yarn is wound up directly at a winding speed of 840
m/mn. Chests 15 and 22 are non-condensing type (free exhaust).
The resisting agent used is an aqueous solution at 20 g/liter of a
product known commercially under the name of "Sandospace R" which
is a colorless organic substance containing a sulfonic group and a
reactive group, and which is capable of modifying the appearance of
polyamide fibers for acid and cationic dyes.
This solution is injected through three nozzles with a flow of 130
cm.sup.3 per nozzle, for 265 g of yarn per minute.
The treated yarn is knitted and the knit obtained is dyed at
98.degree.C. with pH 5, buffered with 2 percent of Sandogene NH
(SANDOZ) and 0.8 percent of a blue acid dye CI 61,125. The shade
obtained is a very pale blue approaching total resist.
Spotted effects, i.e. with resists in places, can be obtained by
using only one of the three nozzles: in this case, 130 cm.sup.3 of
"Sandospace R" is fed once for 265 g of yarn per minute.
A knitted article made from the same yarn, without any inhibitor,
and dyed under the same conditions, has a deep blue shade.
EXAMPLE 3
The texturizing is effected under the same conditions, and with the
same yarn, as in Example 2, an antistatic agent being injected.
The product used is an aqueous solution at 38 g/liter of a product
known in commerce under the trademark "Tetronics 908"
(UGINE-KUHLMAN), which is a polyoxyalkylene-tetrol with
tertiary-amino functions which has then been sulfonated to permit
its fixation on the polyamide.
It is injected onto the yarn through three nozzles at the rate of
120 cm.sup.3 per nozzle for 265 g of yarn per minute.
The antistatic property is then measured by means of the Rotschild
electrometer.
According to this method, the period of half discharge of a sheet
previously charged with 100 volts is measured. The following
results are obtained:
Time of half-discharging untreated yarn 560 seconds
antistatic-treated yarn 100 seconds
It can be seen from the above examples that the process of the
present invention effectively allows the simultaneous crimping and
dyeing or finishing of thermoplastic textile yarns. The yarns which
are obtained in accordance with the process of the present
invention can be advantageously utilized in the production of
fabrics, knitted fabrics, non-woven articles, etc., utilized in the
production of floor coverings, wall coverings, upholstery,
clothing, etc., as they are produced through the process of the
present invention or after further processing.
While the present invention has been described primarily with
reference to the foregoing exemplifications it should be understood
that the present invention is in no way to be deemed as limited
thereto but, rather, must be construed as broadly as all or any
equivalents thereof.
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