U.S. patent number 3,748,894 [Application Number 05/263,062] was granted by the patent office on 1973-07-31 for means and method for an on-line determination of the flash point of lube oil fractions.
This patent grant is currently assigned to Texaco, Inc.. Invention is credited to Charles R. Lynch, William D. White.
United States Patent |
3,748,894 |
White , et al. |
July 31, 1973 |
MEANS AND METHOD FOR AN ON-LINE DETERMINATION OF THE FLASH POINT OF
LUBE OIL FRACTIONS
Abstract
Apparatus provides for an on-line determination of the flash
point of lube oil fractions. The hydrocarbon is continuously
sampled by a viscosity analyzer and a density analyzer which
provides signals corresponding to the viscosity and the API gravity
of the lube oil fractions. A computer circuit provides a signal
corresponding to the flash point of the lube oil fractions in
accordance with the viscosity signal and the gravity signal.
Inventors: |
White; William D. (Port Arthur,
TX), Lynch; Charles R. (Port Arthur, TX) |
Assignee: |
Texaco, Inc. (New York,
NY)
|
Family
ID: |
23000226 |
Appl.
No.: |
05/263,062 |
Filed: |
June 15, 1972 |
Current U.S.
Class: |
73/36; 702/30;
700/67 |
Current CPC
Class: |
G01N
33/2888 (20130101) |
Current International
Class: |
G01N
33/26 (20060101); G01N 33/28 (20060101); G01n
025/52 () |
Field of
Search: |
;73/32,36
;235/151.12MO,151.34 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Goldstein; Herbert
Claims
What is claimed is:
1. A flash point analyzer comprising means for sensing the density
of lube oil fractions and providing a first signal representative
thereof, means for sensing the viscosity of the lube oil fractions
and providing a second signal corresponding thereto, means
connected to the density and the viscosity sensing means for
providing a signal corresponding to a flash point of the lube oil
fractions by combining said first and second signals in accordance
with a predetermined emperical relationship relating said flash
point with said density and viscosity.
2. An on-line analyzer for providing an output corresponding to a
flash point of lube oil fractions from a unit in a refinery,
comprising means for sensing the density of the lube oil fractions
and providing a first signal representative thereof, means for
sensing the viscosity of the lube oil fractions and providing a
second signal corresponding thereto, and means connected to the
density and the viscosity sensing means for providing the output
corresponding to the flash point of the lube oil fractions by
combining said first and second signals in accordance with a
predetermined emperical relationship relating said flash point with
the density and the viscosity.
3. A flash point analyzer as described in claim 2 in which the
signal from the density sensing means corresponds to the API
gravity of the lube oil fractions and the signal from the viscosity
sensing means corresponds to the Saybolt Universal Viscosity of the
lube oil fractions.
4. A flash point analyzer as described in claim 3 in which the
means for providing the flash point output provides the output in
accordance with the API gravity and Saybolt Universal Viscosity
signals and the following equation:
Flash Point = k.sub.1 + k.sub.2 /G - k.sub.3 /VG
where G is the API gravity, V is the Saybolt Universal Viscosity
and k.sub.1 through k.sub.3 are factors.
5. A flash point analyzer as described in claim 3 in which the
flash point signal means include means connected to the density
signal means and to the viscosity signal means for providing a
signal corresponding to a Watson-Nelson characterization factor F
in accordance with the API gravity signal, the Saybolt Universal
Viscosity signal and the following equation:
F = k.sub.4 + k.sub.5G - k.sub.6 /V
where G is the API gravity, V is the Saybolt Universal Viscosity,
and k.sub.4 through k.sub.6 are factors, and means connected to the
F factor signal means and to the API gravity signal means for
providing the output corresponding to the flash point in accordance
with the API gravity signal and the F factor signal from the factor
signal means in accordance with the API gravity signal, the F
factor signal and the following equation:
Flash Point = k.sub.7 F-k.sub.8 /G + k.sub.9
where k.sub.7 through k.sub.9 are factors.
6. A method for providing an output corresponding to a flash point
of lube oil fractions from a unit in a refinery, which comprises
the following steps: sensing the density of the lube oil fractions,
providing a first signal corresponding to the API gravity of the
lube oil fractions in accordance with the sensed density, sensing
the viscosity of the lube oil fractions providing a second signal
corresponding to the Saybolt Universal Viscosity in accordance with
the sensed viscosity, and deriving the output corresponding to the
flash point of the lube oil fractions by combining said first and
second signals in accordance with a predetermined emperical
relationship relating said flash point with said API gravity and
Saybolt Universal Viscosity.
7. A method as described in claim 6 in which the output providing
step includes providing the flash point output in accordance with
the API gravity signal, Saybolt Universal Viscosity signal and the
following equation:
Flash Point = k.sub.1 + k.sub.2 /G - k.sub.3 /VG
where G is the API gravity, V is a Saybolt Universal Viscosity and
k.sub.1 through k.sub.3 are factors.
8. A method as described in claim 6 in which the output providing
step includes providing a signal corresponding to the Watson-Nelson
characterization factor F in accordance with the API gravity
signal, the Saybolt Universal Viscosity signal and the following
equation:
F = k.sub.4 + k.sub.5G - k.sub.6 /V
where G is the API gravity, V is the Saybolt Universal Viscosity,
and k.sub.4 through k.sub.6 are factors, and providing the output
corresponding to the flash point in accordance with the API gravity
signal, the F factor signal and the following equation:
Flash Point = k.sub.7 F - k.sub.8 /G + k.sub.9
where k.sub.7 through k.sub.9 are factors.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to monitoring methods and systems in
general and, more particularly, to a method and system for
monitoring the flash point of lube oil fractions.
2. Description of the Prior Art
In the operation of a unit in a refinery which provides lube oil
fractions, it is economically important to maintain the quality of
the lube oil fractions within a relatively narrow range of
specification. This is done by monitoring the viscosity and flash
point of the lube oil fractions. Heretofore, two methods were used:
one method was to manually sample the lube oil fractions and
determine in a laboratory the viscosity and flash point of the lube
oil fractions. A decided disadvantage in this method is the
appreciable time lag which exists between the time when the samples
were taken and the time the results became available for control of
the unit.
Another way is to provide on-line viscosity and flash point
analysis. This is a relatively new area. The flash point analyzers
presently available provide results corresponding to the
Pensky-Martin flash point rather than the Cleveland Open Cup flash
point. The reproducibility of the commercial flash point analyzers
is considered to be poor. Also, the analyzers have an excessive
maintenance requirement due to the coking tendency of the lube oil
fractions.
The apparatus of the present invention substantially overcomes the
problems of maintenance and reproducibility while providing an
output corresponding to the Cleveland Open Cup flash point of lube
oil fractions being analyzed.
SUMMARY OF THE INVENTION
A flash point analyzer provides an output corresponding to the
flash point of lube oil fractions from a unit in a refinery. The
analyzer includes circuitry which senses the density and viscosity
of the lube oil fractions and provides a density signal and a
viscosity signal. A network provides the output corresponding to
the flash point of the lube oil fractions in accordance with the
density signal and the viscosity signal from the circuitry.
The objectives and advantages of the invention will appear more
fully hereinafter from a consideration of the detailed description
which follows, taken together with the following drawings wherein
two embodiments of the invention are illustrated by way of example.
It is to be expressly understood, however, that the drawings are
for illustration purposes only and are not to be construed as
defining the limits of the invention.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a simplified block diagram of apparatus, constructed in
accordance with the present invention, for providing an output
corresponding to the Cleveland Open Cup flash point of lube oil
fractions from a unit in a refinery being monitored by the
apparatus.
FIG. 2 is a simplified block diagram of another embodiment of the
invention .
DESCRIPTION OF THE INVENTION
In a preferred embodiment of the present invention, the Cleveland
Open Cup flash point of lube oil fractions is estimated in
accordance with the following equation:
1. Flash Point = k.sub.1 + k.sub.2 /G - k.sub.3 /VG
where V is the Saybolt Universal Viscosity, G is the API gravity at
60.degree. F and k.sub.1, k.sub.2 and k.sub.3 are factors. By way
of example k.sub.1, k.sub.2 and k.sub.3 may have the following
values: 437.2, 664.76 and 197579.2, respectively, when the
viscosity is measured at 100.degree. F. The values for k.sub.1,
k.sub.2 and k.sub.3 will differ for different viscosity
temperatures.
Referring now to FIG. 1, lube oil fractions leaving a unit (not
shown) in a refinery by way of a line 1, is sampled by a viscosity
analyzer 10 and a density analyzer 5. Analyzer 10 may be of the
type manufactured by the Hallikainen Company which is a continuous
viscometer model 1077S7 while density analyzer 1 may be a Dynatrol
density analyzer series 200G. Density analyzer 5 senses the density
of the lube oil fractions and provides a signal E.sub.1,
corresponding to the specific gravity of the crude wax distillate
in line 1. The API gravity is determined in accordance with the
following equation:
2. API = 141.5/Specific Gravity - 131.5
A divider 6 divides a direct current voltage V.sub.1, which
corresponds to the term 141.5, with signal E.sub.1 to provide an
output. Subtracting means 7 subtracts a direct current voltage
V.sub.2 from the output from divider 6 to provide a signal E.sub.15
corresponding to the API gravity G of the lube oil fractions. The
specific gravity of a hydrocarbon is a function of the density of
the hydrocarbon. Viscosity analyzer 10 provides a signal E.sub.2
corresponding to the Saybolt Universal Viscosity of the lube oil
fractions in line 1.
A multiplier 14 multiplies signals E.sub.15, E.sub.2 with each
other to provide a signal corresponding to the term VG in equation
1. A divider 21 divides a direct current voltage E.sub.3,
corresponding to the factor k.sub.3 in equation 1, provided by a
source 20 of direct current voltages by the signal from multiplier
14. Divider 21 provides a signal corresponding to the term k.sub.3
/VG in equation 1.
Source 20 also provides direct current voltages E.sub.4 and E.sub.5
corresponding to k.sub.1 and k.sub.2, respectively, in equation 1
as well as voltages V.sub.1, V.sub.2. A divider 22 divides voltage
E.sub.5 by signal E.sub.15 to provide a signal corresponding to the
term k.sub.2 /G. Subtracting means 28 subtracts the signal provided
by divider 21 from the signal provided by divider 22 to provide an
output to summing means 30. Summing means 30 sums the output from
subtracting means 28 with voltage E.sub.4 to provide signal E.sub.5
corresponding to the estimated Cleveland Open Cup flash point. A
conventional type recorder 31 records signal E.sub.5 to provide a
record of the flash point of the lube oil fractions.
In monitoring the properties of lube oil fractions, a useful
parameter is the Watson-Nelson characterization factor F. The
factor F may be determined in accordance with an equation 2 and
used to estimate the Cleveland Open Cup flash point of the lube oil
fractions in accordance with an equation 3.
3. F = k.sub.4 + k.sub.5 G - k.sub.6 /V,
and
4. Flash Point = (k.sub.7 F - k.sub.8)/G + k.sub.9
where k.sub.4 through k.sub.9 are factors.
The values for k.sub.4 through k.sub.9, associated with a viscosity
measurement made at 100.degree. F are shown in the following
table:
Factor Value Factor Value k.sub.4 10.04 k.sub.7 5369 k.sub.5 0.0794
k.sub.8 53240 k.sub.6 36.8 k.sub.9 11.1
Although the determination of the factor F is thoroughly discussed
in U.S. Pat. No. 3,557,609, which is assigned to Texaco Inc.,
assignee of the present invention, for convenience the
determination of the factor F will be discussed hereafter.
Referring to FIG. 2, viscosity analyzer 10 provides signal E.sub.2
to a divider 34. Divider 34 divides a direct current voltage
E.sub.8 corresponding to the factor k.sub.6 in equation 3 from
source 20 to provide a signal corresponding to the term k.sub.6 /V.
Source 20 provides direct current voltages E.sub.6 through E.sub.11
which correspond to factors k.sub.4 through k.sub.9, respectively,
in equations 3 and 4. Subtracting means 35 subtracts the signal
from divider 34 from voltage E.sub.6.
Signal E.sub.15 from subtracting means 7 is applied to a multiplier
36. Multiplier 36 multiplies signal E.sub.15 with voltage E.sub.7
to provide an output corresponding to the term k.sub.5 G in
equation 3. Summing means 37 sums the outputs provided by
subtracting means 35 and multiplier 36 to provide a signal E.sub.12
corresponding to the Watson-Nelson characterization factor F.
Signal E.sub.12 is applied to a conventional type recorder 42 and
to a multiplier 43. Multiplier 43 multiplies signal E.sub.12 with
voltage E.sub.9 to provide a signal, corresponding to k.sub.7 F in
equation 4, to subtracting means 44. Subtracting means 44 subtracts
voltage E.sub.10 from the signal provided by multiplier 43 to
provide a signal corresponding to the term k.sub.7 F-k.sub.8 in
equation 4. The signal from subtracting means 44 is divided by
signal E.sub.1 by a divider 48 to provide a signal corresponding to
the term (k.sub.7 F-k.sub.8)/G. Summing means 50 sums the signal
from divider 48 with voltage E.sub.11 to provide a signal E.sub.14
corresponding to the estimated Cleveland Open Cup Flash Point of
the crude wax distillate in line 1. Recorder 31 records signal
E.sub.14 to provide a record of the flash point of the lube oil
fractions.
The following table shows the relationship between an estimated
flash point for lube oil fractions from a unit in a refinery as
determined by apparatus of the preferred embodiment, as heretofore
described, and the flash point as measured in a laboratory. The
numbers in parentheses represent the number of laboratory
measurements upon which the average measured flash point is
based.
Sample No. Average Lab. Estimated Measured Flash Point (.degree.F)
Flash POINT (.degree.F) 1 391 (4) 388 2 385 (8) 390 3 392 (10) 394
4 393 (10) 394 5 403 (9) 402 6 405 (11) 406
the apparatus of the present invention, as heretofore described,
provides an output corresponding to the flash point of lube oil
fractions from a unit in a refinery. The apparatus senses the
density and viscosity of the lube oil fractions and uses the sensed
density and viscosity to determine the flash point.
* * * * *