U.S. patent number 3,747,364 [Application Number 05/161,738] was granted by the patent office on 1973-07-24 for new freezing chamber with refrigeration storage.
Invention is credited to Nikolaus Laing.
United States Patent |
3,747,364 |
Laing |
July 24, 1973 |
NEW FREEZING CHAMBER WITH REFRIGERATION STORAGE
Abstract
A freezing chest or freezing shelf comprising a compressor, heat
exchangers and a heat storage arrangement with a heat storage
material having a crystallization temperature above the temperature
of the evaporator and below the maximum permissible temperature of
the goods to be refrigerated. The heat storage material is arranged
in containers formed from thin walled plastics, and the containers
are disposed between the container of the goods to be refrigerated
and the insulating layer, and are in contact with the wall of the
former over approximately half the total surface. Further, the
containers of the heat storage material have recesses for the
evaporator tubes which are equally in contact with the wall of the
container of the goods.
Inventors: |
Laing; Nikolaus (7141 Aldingen
bei Stuttgart, DT) |
Family
ID: |
3585751 |
Appl.
No.: |
05/161,738 |
Filed: |
July 12, 1971 |
Foreign Application Priority Data
Current U.S.
Class: |
62/430; 62/433;
62/434; 62/439 |
Current CPC
Class: |
F25D
11/006 (20130101); C09K 5/063 (20130101); F25D
3/005 (20130101); F25D 2303/085 (20130101); F25D
2400/10 (20130101); Y02E 60/147 (20130101); Y02E
60/14 (20130101); F25D 2303/0822 (20130101) |
Current International
Class: |
F25D
3/00 (20060101); F25D 11/00 (20060101); C09K
5/00 (20060101); C09K 5/06 (20060101); F25d
011/00 () |
Field of
Search: |
;62/431,432,439,438,430,433,446,530,457 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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|
|
|
|
|
665,731 |
|
Jan 1952 |
|
GB |
|
1,185,811 |
|
Mar 1970 |
|
GB |
|
Primary Examiner: Wye; William J.
Claims
I claim:
1. A refrigerated compartment having an outer wall member, an inner
wall member spaced from said outer wall member, insulation material
between said wall members, a plurality of evaporator tubes
positioned between said members for cooling said compartment, and a
coolant circulating in said tubes; the improvement comprising
including a heat storage element between said wall members where
said element has a plurality of individual flat containers joined
end to end positioned between and contacting said insulation
material and said inner wall, the heat storage material in said
containers having a crystallizing temperature above the temperature
of evaporation of said coolant and below the maximum permissible
working temperature of said compartment, and said tubes being
positioned along the side edges of said containers.
2. A refrigerated compartment according to claim 1 wherein said
containers are formed from thin flexible tubes.
3. A refrigerated compartment according to claim 1 wherein the heat
storage element comprising the containers joined end to end is
spirally wound around the compartment and between said tubes.
4. A refrigerated compartment according to claim 1 wherein said
containers are in addition joined side to side along their edges to
form a container sheet.
5. A refrigerated compartment according to claim 4 wherein the
sheet is positioned along the vertically extending inner walls of
said compartment.
6. A refrigerated compartment according to claim 1 wherein said
heat storage material comprises a water-methanol mixture.
7. A refrigerated compartment according to claim 1 wherein the heat
storage material includes in addition a thickner substance to
provide a supporting structure to said material.
8. A refrigerated compartment according to claim 7 wherein said
thickner comprises long fiber silicone-dioxide hydrate
crystals.
9. A refrigerated compartment according to claim 7 wherein the heat
storage material comprises ionogenic compounds and water and having
in addition seed crystals uniformly distributed in the storage
material wherein said thickner substance prevents the crystals from
segregating out of the storage material.
10. A refrigerated compartment according to claim 1 wherein the
storage material comprises a cryohydrate of approximately 42
percent by weight of NH.sub.4 NO.sub.3.
11. A refrigerated compartment according to claim 1 wherein said
storage material comprises a cryohydrate of approximately 37
percent by weight of NA NO.sub.3.
12. A refrigerated compartment according to claim 1 wherein the
storage material comprises a cryohydrate of approximately 40
percent by weight of (NH.sub.4).sub.2 SO.sub.4.
13. A refrigerated compartment according to claim 1 wherein the
storage material comprises a cryohydrate of approximately 23
percent by weight of Na Cl.
14. A refrigerated compartment according to claim 1 wherein said
heat storage element comprises a water vapor impermeable sheet of
multi-layer construction with one of said layers comprising a
metal.
Description
THE PRIOR ART
It is known to provide storage bodies in freezing chests, from
which heat of crystallization is withdrawn during operation, so
that for example in the event of electric power failure an
adequately low temperature is maintained for prolonged periods
without the operation of the refrigeration plant. Eutectic
cryohydrates which are liquid at normal temperature while
crystallizing during compressor operation, are used as storage
masses. These masses are accomodated in containers which are at the
same time traversed by the heat exchanger tubes of the coolant
evaporator.
The advantages to be expected are, however, counteracted by
appreciable disadvantages, so that refrigeration storage apparatus
has not caught on in this field, because it was found that all
cryohydrates -- these are eutectic systems consisting of ionogenic
compounds and water -- experience a large change of density as they
crystallize, so that the walls of the containers are subjected to
large alternating mechanical stresses. It has more ever been found
that the substances which crystallize in the course of
refrigeration operation frequently no longer work in the
appropriate temperature ranges, even after only a few month of
operation. The reason for this is that the seed crystals added for
the purpose of preventing supercooling of the storage mass and also
the ingredients of the eutectic of higher specific gravity collect
on the floor of the vessel, so that either the supercooling which
is prevented during normal operation by seed crystals uniformly
distributed through the storage mass is no longer prevented, i.e.,
that the temperature of crystallization drops to lower values, or
that the eutectic temperature is no longer reached by reason of a
change in the weight ratio of the ingredients forming a eutectic,
i.e., that the temperature of crystallization changes in the
direction of higher values.
A further disadvantage of known solutions consists in that the
evaporator tubes are surrounded by the storage mass. Thereby the
heat transfer between the evaporator tubes and the wall of the
container for the goods to be refrigerated is made considerably
worse, so that newly introduced such goods require a substantially
longer period for freezing.
SUMMARY OF THE INVENTION
The invention relates to storage bodies which are not subject to
the aforesaid disadvantages. According to the invention the storage
mass container consists of plastics sheets which are sufficiently
deformable at least for compensating the variation in density,
which form resilient hollow vessels by welding along predetermined
seams and, if desired, also spots, in which the storage mass is
enclosed. Preferably the double walled sheet is provided over the
entire exterior surface of the container for the goods to be
refrigerated, so that the mean required thickness of the layer of
storage mass amounts to only a few millimeter. By means of this
arrangement, the high grade heat contact between the evaporator
tubes and container for the goods to be refrigerated is not
adversely affected. The metallic wall of the container for the
goods to be refrigerated serves not only the purpose of a heat
conduit for heat from the said goods and from the insulation, but
also for conducting the heat from the double walled vessel with the
storage mass.
Homogeneous mixtures, e.g. methanol + water, are used as the
storage mass. The storage may, however, also, in a manner known per
se, consist of meltable eutectic mixtures. In accordance with the
invention, this mass has then seed crystals, whose position is
fixed by a substance providing a supporting structure, e.g., a
gel-forming mixture additive, added to it in a uniform spatial
distribution. In accordance with the invention, the storage body is
arranged between the wall of the container for the goods to be
refrigerated facing the said goods and the elastically deformable
insulating layer consisting of foamed plastics. Thereby the
metallic wall of the container for the goods to be refrigerated,
which is in good heat conductive communication with the evaporator
tubes, is utilized at the same time for heat distribution between
the evaporator tubes of not directly adjacent regions of the
cooling body and furthermore for fixing the storage bodies. The
first sheet which is secured to the metallic wall of the container
for the goods to be refrigerated by an adhesive maintains its
position during crystallization which entails volumetric expansion.
The change in density causes a displacement of the second wall,
which bounds the elastic insulating layer. Since the mean thickness
of the layer of storage mass amounts to only a few millimeters,
when the entire surface of the container for the goods to be
refrigerated is coated with the storage body described, the
movement only has the order of magnitude of 1 millimeter. The
storage body is preferably suspended by being secured by an
adhesive to the wall of the container for the goods to be
refrigerated, the regions between the evaporator tubes preferably
being filled in. It is sufficient to provide temporary fixing or
adhesion, since the storage bodies are held between the evaporator
tubes after foaming of the insulating layer by the adaptation of
its shape to the spaces between the evaporator tubes.
As a result of the melt being thickened by a substance providing a
supporting structure, the invention avoids ageing of the storage
mass and the latter becoming ineffective, since the seed crystals,
salt and water remain in isotropic distribution and thus at an
adequately small relative spacing. At the same time hydrostatic
pressures in the lower regions of the container are prevented,
since the thickened liquid behaves similarly to a solid body. By
using plastics sheet for storage mass containers and the
arrangement between the rigid wall of the chamber containing the
goods to be refrigerated and the insulation, non-permissible
deformation of the material is prevented. Since all the suitable
storage masses have considerably lower heat conductivity in the
liquid phase than in the crystalline phase, the storage mass which
has been protected against heat transfer convection by the
substance forming the supporting structure, acts as additional
insulation when heated above the temperature of
crystallization.
In order that damage to the refrigeration storage device as a
result of damage to the thin walled sheets does not result in loss
of storage capacity, the invention provides for the subdivision of
the storage mass vessel into a large number of independent
individual chambers, by welding seams on the sheets. Thereby, in
the event of damage, a proportion of the total storage capacity
amounting to only a few percent is lost.
It has been found that, by the use of suitable storage masses
hereinafter described, extraordinarily small layer thicknesses of,
for example, 5 - 8 mm result in storage capacities which permit a
bridging period of many hours, for example, in the event of
electric power failure.
The invention provides, as a special further instance of its
application, the combination of the storage bodies with a
refrigeration plant, whose rating is such that the refrigeration
effect required in the course of a day can be produced basically
during the off-peak night time period. This has the advantage that
the "charging" takes place only during the cool hours of night, in
which the Carnot efficiency is better than during the day, so that
during normal operation less energy is consumed. At the same time
the mechanical efficiency of the installation increases with an
increase in the size of the refrigeration plant, which provides
further saving. The invention preferably provides the uniform
distribution of the storage mass over all vertical walls. Thereby a
considerable reduction in energy with optimum heat transfer
conditions is created, which permits rapid freezing even in the
case of large quantities to be refrigerated, e.g. the sudden demand
for refrigeration of large quantities of goods during fruit harvest
or slaughtering.
Suitable storage masses comprise alcohol-water mixtures, e. g.
methanol-H.sub.2 O as well as cryohydrates, whose thermodynamically
active constituent consists of 37 % NaNO.sub.3 or 40 %
(NH.sub.4).sub.2 SO.sub.4 or 23 % NaCl or 42 % NH.sub.4 NO.sub.3,
all the said percentages being by weight. Suitable thickening
substances comprise aerosiles of high-polymer swellable
hydrocarbons, particularly alginates.
The disadvantage of storage mass vessels of large area consists in
the possibility of loss of the substance in view of the vapor
permeability of the majority of plastics sheets, particularly for
the sheet which is not secured by adhesive to the wall of the
container for the goods to be refrigerated. The invention therefore
provides a multi-layer sheet, in which one layer consists of a
metal, e.g., aluminum.
The arrangement according to the invention is suitable not only for
the containers for the goods to be refrigerated of freezing chest,
but also for refrigerators and particularly freezing shelves of
refrigerators.
The invention will be explained in greater detail with reference to
the following description of the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a section view of a refrigerated compartment constructed
according to the invention;
FIG. 1A is an enlarged section of a portion of FIG. 1 illustrating
the positioning of a heat storage element with respect to the inner
wall of the compartment;
FIG. 2 is a graph illustrating change of temperature of a
compartment constructed according to the invention with respect to
time;
FIG. 3 is a side view of a further embodiment of a heat storage
element constructed according to the invention; and
FIG. 3A is an enlarged sectional view of a portion of FIG. 3
illustrating the attachment of the heat storage element to an inner
wall of a refrigerated compartment.
DETAILED DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates diagrammatically in section a refrigerated
compartment 1 having an outer wall member 1' and an inner wall
member 3. Evaporator tubes 2 which are in good heat conductive
communication with the inner wall member 3 extend spirally around
the compartment. The tubes 2 contain a coolant which is adapted to
be circulated therethrough in order to cool the interior of the
compartment. Between wall 3 and insulation material 4, heat storage
elements 5 are arranged which are surrounded by a thin flexible
tube 6. The thin flexible tube is connected to the wall 3, e.g., by
means of an adhesive, along the seam 7 and is held in this position
by shape adaptation after foaming of the insulation 4. The thin
flexible tube 6 is sqeezed together at regular intervals and welded
up along the seam 8 to form individual containers 9.
FIG. 2 shows the heating curve 20 for refrigerated compartments
without a storage mass and 21 for freezing chests with a storage
mass. The horizontal region 23 corresponds to the temperature of
crystallization of the storage mass. This lies above the
temperature of evaporation 24 of the coolant circulated in the
evaporator tubes and below the temperature 25 which must not be
exceeded from the point of view of maintenance of the storability
of the goods to be refrigerated. Only after completion of the
crystallization, does the temperature increase along the curve
26.
FIG. 3 shows a further embodiment of the invention. The storage
element here consists of a coherent sleeve, whose wall 30 facing
the insulation extends outside the evaporator tubes 2 along an
approximately level plane, while the wall 31 facing the wall 3 has
bulges 32, which enclose the evaporator tubes. The sleeve shown is
intended for compartment 1 for goods to be refrigerated, as shown
in FIG. 1, and is laid around the vertical edges of the compartment
along the fold lines 33/33', 34/34', 35/35' and preferably secured
to protrusions 37 by means of eyes 36 and the straps 39' and 39"
are held together by means of eyes 38 and a cord.
Preferably, the heat storage material may comprise alcohol water
mixtures, for example methanol-H.sub. 2 O as well as cryohydrates
the thermodynamically active constituent of which may comprise
either 37% NA NO.sub.3, 40% (NH.sub.4).sub.2 SO.sub.4, 23% Na Cl,
or 42% NH.sub.4 NO.sub.3, all of said percentages being by weight.
In addition, thickening substances may be added to the heat storage
material to provide a supporting structure, as for example,
aerosiles of high-polymer swellable hydrocarbons, particularly
alginates, or long-fiber silicon dioxide-hydrate crystals.
* * * * *