U.S. patent number 3,744,496 [Application Number 05/201,837] was granted by the patent office on 1973-07-10 for carbon filled wrapper for smoking article.
This patent grant is currently assigned to Olin Corporation. Invention is credited to Stuart W. McCarty, Donald T. Owen, William F. Owens, Jr..
United States Patent |
3,744,496 |
McCarty , et al. |
July 10, 1973 |
CARBON FILLED WRAPPER FOR SMOKING ARTICLE
Abstract
A carbon filled wrapper for smoking articles such as cigarettes,
cigars and the like which significantly reduces the total
particulate matter yield and organic vapor phase constituents in
the mainstream smoke therefrom while simultaneously reducing the
visible sidestream smoke. The carbon filled wrapper is preferably
used as an inner wrapper for the tobacco column in combination with
an outer wrapping of conventional cigarette paper or cigar wrap.
The carbon content of the wrapper may vary over a wide range
depending upon the effect desired. Various types of carbon, either
activated or unactivated, may be used. Increased effects may be
obtained if calcium carbonate is incorporated in the carbon filled
sheet and the effects are further enhanced if the paper is treated
with an oxidation catalyst such as the alkali metal hydroxides,
bicarbonates and carbonates. The paper is also particularly suited
as a means for introducing various flavorants to the cigarette
since the carbon holds the flavor until released by the heat of the
burning zone.
Inventors: |
McCarty; Stuart W. (Brevard,
NC), Owen; Donald T. (Hendersonville, NC), Owens, Jr.;
William F. (Pisgah Forest, NC) |
Assignee: |
Olin Corporation (Pisgah
Forest, NC)
|
Family
ID: |
22747512 |
Appl.
No.: |
05/201,837 |
Filed: |
November 24, 1971 |
Current U.S.
Class: |
131/342; 131/353;
131/358; 131/365 |
Current CPC
Class: |
A24D
1/02 (20130101); A24B 15/12 (20130101) |
Current International
Class: |
A24D
1/00 (20060101); A24B 15/00 (20060101); A24D
1/02 (20060101); A24B 15/12 (20060101); A24d
001/02 () |
Field of
Search: |
;131/15,17,2 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
davis "Manufacture of Paper"(text) page 581 cited entitled Improved
Cigarette Paper pub by Henry Carey Baird and Co. 1886.
|
Primary Examiner: Rein; Melvin D.
Claims
What we claim is:
1. A smoking article of generally cylindrical form comprising a
tobacco charge, an intermediate wrapper for said tobacco charge,
said intermediate wrapper comprising a combustible porous paper
sheet of cellulosic fibers and finely pulverized carbon particles,
said carbon particles constituting at least 5 percent by weight of
said sheet, and an outer wrapper for said tobacco charge selected
from the group consisting of conventional cigarette paper and cigar
wrap having good combustibility, said outer wrapper encircling and
in contact with said intermediate wrapper, whereby upon burning of
the smoking article a substantial decrease in the visible
sidestream smoke emanating therefrom is manifested while also
reducing the constituents in the mainstream smoke as compared to a
smoking article of the same composition without said intermediate
wrapper.
2. The smoking article of claim 1 in which said intermediate
wrapper contains an alkaline earth metal carbonate, said carbonate
constituting at least 5 percent by weight of the intermediate
wrapper.
3. The smoking article of claim 2 in which the alkaline earth metal
carbonate is calcium carbonate.
4. The smoking article of claim 1 in which the finely pulverized
carbon used in said intermediate wrapper is medium to highly
activated.
5. The smoking article of claim 1 in which the intermediate wrapper
contains a flavorant absorbed by the carbon.
6. A composite wrapper adapted to encircle a tobacco charge in a
smoking article, said wrapper constituting two superposed sheets,
the first of said sheets comprising a porous paper sheet of
combustible cellulosic fibers and finely pulverized carbon
particles, said carbon particles constituting at least 5 percent by
weight of the paper sheet, and the second of said sheets selected
from group consisting of conventional cigarette paper and cigar
wrap having good combustibility, whereby when the composite wrapper
is employed as the wrapper for a tobacco charge, with the first
said sheet positioned intermediate the tobacco charge and the
second said sheet, a substantial decrease in the visible sidestream
smoke emanating from the smoking article is manifested during
burning while also reducing the constituents in the mainstream
smoke as compared to a smoking article of the same composition
without said intermediate wrapper.
7. The composite wrapper of claim 6 in which the first said sheet
contains an alkaline earth metal carbonate, said carbonate
constituting at least 5 percent by weight of the first said
sheet.
8. The composite wrapper of claim 7 in which the alkaline earth
metal carbonate is calcium carbonate.
9. The composite wrapper of claim 6 in which the finely pulverized
carbon used in the first said sheet is medium to highly
activated.
10. The smoking article of claim 6 in which the first said sheet
contains a flavorant absorbed by the carbon.
Description
BACKGROUND OF THE INVENTION
This invention relates generally to smoking articles such as
cigarettes, cigars and the like, and the wrapper for the tobacco
column thereof, and more particularly to an improved wrapper for
such smoking articles which when used either by itself or as an
inner liner in combination with conventional wrappers significantly
reduces particulate and vapor phase constituents in the smoke drawn
through the smoking article as well as reducing the amount of
visible sidestream smoke that normally emanates therefrom.
It has been the practice for a number of years to use various smoke
filtering devices in cigarettes and other smoking articles to
reduce the amount of certain constituents in the smoke. While some
of these devices have been relatively successful, they still leave
much to be desired in the way of reducing many of the materials
found in cigarette smoke. Cigarette papers are conventionally
modified by the addition of various burning chemicals to improve
the burning rate and ash characteristics of cigarettes as disclosed
in U.S. Pat. Nos. 2,580,611, 2,652,834, and 2,733,720, but such
papers have little, if any, effect upon the content of the
cigarette smoke. Also, it is well known to use a calcium carbonate
filter in the production of cigarette paper to improve the
appearance and properties of the paper as the above patents
disclose. However, such conventional cigarette papers do not have a
significant effect upon the reduction of undesirable constituents
in the cigarette smoke.
A composite wrapper for cigarettes is disclosed in U. S. Pat. No.
3,395,714 in which the outer wrapper is conventional cigarette
paper and the inner wrapper next to the tobacco column is a
low-temperature melting point, heat-insulating plastic sheet
material. Such a combination is stated to decrease the burning zone
temperature of the cigarette resulting in a lengthening of the
cigarette's low temperature distillation zone and an increase in
the nicotine and flavor content of the smoke.
Various metal coated cigarette papers have also been suggested in
the prior art. For example, U.S. Pat. No. 3,586,005 proposes a
cigarette paper wrapper in which the paper is coated on either or
both surfaces with a thin layer of a metal such as aluminum or
aluminum-base alloys. The patentee asserts that cigarettes made
with such wrappers have a higher peak burning temperature and form
a relatively continuous and unbroken sheath or tube around the
burned and burning tobacco. This tube is stated to oppose air
entering the burning zone radially and acts as a lengthwise conduit
for the air so that more air passes through the burning zone over
its entire cross section making more oxygen available for more
complete combustion and higher burning temperatures. However, the
use of such metal coated paper as a wrapper for cigarettes is
impractical since the long ash produced tends to pull the burning
cone out of the cigarette when the ash is knocked off during
smoking.
SUMMARY OF THE INVENTION
It is an object of this invention to provide a means for reducing
the particulate and gaseous ingredients in the smoke of cigarettes,
cigars and the like. A specific object is to provide a means for
reducing the quantity of gaseous components in cigarette and cigar
smoke as well as reducing the particulate constituents thereof as
the smoking article is consumed without impairing the smoking
characteristics thereof. A more specific object is to provide a
wrapper for the tobacco column of cigarettes, cigars and the like
which accomplishes the foregoing objects.
In accordance with this invention we have found that by using a
carbon filled wrapper for the tobacco column of a cigarette, cigar
or similar smoking article that the mainstream smoke therefrom
contains a reduced quantity of organic vapor phase components, and
total particulate matter normally found in the smoke of such
smoking articles made with conventional wrappers. In addition, the
visible sidestream smoke from the cigarette or cigar is
substantially reduced giving the appearance of a smokeless
cigarette or cigar during static burning.
The carbon filled wrappers of this invention may be made using an
ordinary paper furnish such as pulped wood or flax fibers to which
is added a sufficient quantity of pulverized carbon filler. The
furnish of fiber pulp and carbon filler is then used to make a
paper sheet on conventional paper-making machines. The particular
fiber furnish from which the carbon filled wrapper is made is not
critical and any of the cellulosic fiber pulps used in paper making
can be employed. The fiber pulps customarily used to make paper
wrappers for cigarettes or the tobacco materials used to make cigar
wrap are preferred. Thus, in addition to wood and flax fibers, the
furnish may be pulped tobacco stalks or stems to which is added the
carbon filler or the carbon may be added to the furnish used in
making reconstituted tobacco sheets for cigar wrap.
Ideally, the carbon filled paper is used as an inner wrap under a
normal outer wrap for the tobacco column of the cigarette or cigar.
Conventional cigarette paper or cigar wrap is used as the outer
wrapping for the smoking article. Such a combination reduces the
tobacco weight necessary to make a satisfactory product, increases
the tobacco rod firmness and does not alter the appearance of the
cigarette or cigar since the outer wrap of conventional cigarette
paper or cigar wrap hides the grey carbon filled inner liner.
In the case of cigarettes the construction is such that the carbon
filled paper inner wrap can be sealed or unsealed. If left
unsealed, the sealed outer wrap holds the inner wrap around the
circumference of the cigarette.
The carbon content of the wrapper may vary over a wide range
depending upon the reduction of vapor phase and particulate matter
desired. Carbon amounts of at least 5 percent by weight based upon
the weight of the paper will give satisfactory results and amounts
as high as 90 percent can be used successfully. Higher amounts of
carbon filler tend to produce greater reductions in particulate and
vapor phase constituents. Either activated or unactivated carbon
can be used in the carbon filled wrapper, although activated
carbons are preferred. Carbons ranging from pulverized coal to very
high activity coconut shell charcoal have been used successfully.
Other typical examples are activated wood carbons, activated mill
waste carbons, activated coal and petroleum base carbons,
unactivated bituminous coal, and pulverized charcoal
briquettes.
From an appearance standpoint, the particle size of the carbon
should be small enough so that visible lumps do not show in the
paper. This is generally more important when the filled sheet is
used as an inner wrap in cigarettes since larger carbon particles
produce visible lumps under the cigarette paper outer wrap. With
cigars such lumps would be less noticeable and therefore not
objectionable. Preferably, the carbon is finely pulverized and we
have found that particulate carbon that will pass through an 80
mesh screen or smaller is a desirable size range.
The carbon filled wrapper produces the desired effect without the
addition of any of the commonly used cigarette paper or cigar wrap
burning chemicals. However, the use of burning chemicals appears to
act synergistically with the carbon to provide enhanced results in
reduction of vapor phase components and total particulate matter in
the smoke in addition to providing better burning rate control. The
most efficient burning chemicals that we have found are the alkali
metal hydroxides, bicarbonates and carbonates, although there are
many other commonly known burning chemicals that can be used such
as citrate, phosphate and nitrate salts. It is also possible to use
burning retardants in combination with the carbon filler to modify
the combustion properties of the wrapper.
As discussed above, carbon in the wrapper alone provides most of
the beneficial effects in smoking articles. However, the use of an
alkaline earth metal carbonate such as calcium or magnesium
carbonate as an additional filler material in the wrapper stock
further enhances the effects obtained over the use of carbon as the
sole filler material. Total particulate matter yield and the major
organic vapor phase yield are significantly reduced by the addition
of calcium carbonate to the carbon filled paper even when as little
as 5 percent calcium carbonate by weight of the paper is added.
Maximum reductions appear to be obtained with a total filler level
of approximately 50 percent to 80 percent by weight in the wrapper
using carbon as the sole filler or a carbon/calcium carbonate
filler mixture containing at least 5 percent calcium carbonate by
weight of the finished paper. Carbon/calcium carbonate ratios may
be varied as desired to produce different yields of total
particulate matter, major organic vapor phase components in the
mainstream smoke, or the degree of visibility of the sidestream
smoke.
The porosity of the carbon filled paper can be tailored to fit the
requirements of the finished cigarette or cigar such as the air
dilution of the smoke desired. When the carbon filled paper is used
as an inner wrap, the porosity can vary over a wide range since
porosity of the total wrapper in the finished cigarette or cigar
can be controlled with the regular outer wrap.
This invention also provides an excellent method for the addition
of flavorants to a cigarette or cigar since they are easily added
to the carbon filled paper. The carbon holds the flavorant until it
is released by the heat of the burning zone to go into the
sidestream or mainstream smoke. Menthol, vanillin, and glycyrrhiza
are examples of common flavorings for cigarettes and cigars that
have been added to the carbon filled paper and used with very
satisfactory results.
Greater than 50 percent reductions in the total particulate matter
yield and major organic vapor phase yield in cigarette smoke have
been achieved in cigarettes made with carbon filled paper wrappers
in accordance with this invention. Similar dramatic effects are
obtained in reducing the visible sidestream smoke. While we do not
know with certainty why such reductions occur, it has been
determined that the carbon filled wrapper normally increases the
burning temperature of the smoking article. It is believed that
this increase in burning temperature, particularly at the skin of
the cigarette or cigar, is important in reducing yields in the
smoke from cigarettes or cigars employing carbon filled paper
wrappers, also the carbon in the wrapper downstream from the
burning zone may tend to adsorb certain constituents in the
smoke.
PREFERRED EMBODIMENTS
Typical results demonstrating the effects obtained in accordance
with this invention are described in the following examples which
are illustrative of the invention only and are not in limitation
thereof.
EXAMPLE I
Sample cigarettes were prepared using a carbon filled paper inner
wrap for the tobacco column and a regular cigarette paper outer
wrap. All samples were 70mm in length and approximately 8mm in
diameter. The carbon filled paper inner wrap was made
conventionally from flax fiber pulp using an activated wood pulp
carbon filler. The particle size of the carbon was such that it
would all pass through an 80 mesh screen and approximately 25 to 50
percent would pass through a 325 mesh screen. The final carbon
filled sheet had a basis weight of 60 g/M.sup.2 and contained about
70 percent by weight carbon. In half the samples prepared, the
carbon filled paper for the inner wrap was further treated with an
oxidation catalyst consisting of 5 percent solution of sodium
carbonate. For control purposes, identical cigarette samples were
prepared without a carbon filled paper inner wrap using the same
tobacco and cigarette paper. The following table sets forth the
results obtained given as a per cent of the property measured as
compared with the control cigarette having no carbon filled paper
inner wrap, measuring the smoke obtained from burning 60mm of the
tobacco column of each cigarette. ##SPC1##
As the results in the above table clearly show, the total
particulate matter yield and major organic vapor phase yield in the
mainstream smoke from cigarettes with the carbon filled inner wrap
are substantially reduced when compared with the control cigarettes
having a conventional cigarette paper wrapper. Very substantial
reductions were also obtained in the visible sidestream smoke.
EXAMPLE II
A number of carbon filled papers were prepared with different
activities, types and amounts of carbon filler, both with and
without additional calcium carbonate filler. Some of the papers
were also additionally treated with oxidation catalysts. The
particle size of each of the carbons tested was such that they
would pass through an 80 mesh screen or smaller. The carbon filled
papers were made by conventional papermaking techniques using flax
pulp as the basic fiber and the weight of each of the finished
sheets was approximately 60 g/M.sup.2. Each of the carbon filled
sheets was then used in making a cigarette 70mm long and
approximately 8mm in diameter with the carbon filled sheet as the
inner wrap for the tobacco column under a conventional cigarette
paper outer wrap. Identical control cigarettes were prepared from
the same tobacco and using the same cigarette paper wrapping but
without any carbon filled paper inner wrap. In the following table
the results are given as a per cent of the property measured
compared with the control cigarettes having no carbon filled paper
inner wrap. All results are based on the smoke obtained from
burning 60mm of each cigarette with approximately 10 standard 35cc
puffs per cigarette.
TABLE 2
---------------------------------------------------------------------------
Comparison of Activated and Unactivated Carbons
Vapor Phase Side- Description T.P.M. Acrolein stream Carbon filled
paper inner wrap Yield Yield T.P.M. containing 70% carbon by weight
Main- Main- Yield stream stream
__________________________________________________________________________
High Activity Wood Carbon; 72 mg Carbon per Cigarette 73% 61% 64%
Medium Activity Mill Waste Carbon; 72 mg Carbon per cigarette 77%
54% 55% Unactivated Bituminous Coal; 72 mg Carbon per Cigarette 89%
98% 78% Unactivated Pulverized Charcoal Briquettes; 72 mg Carbon
per Cigarette 85% 89% 77%
__________________________________________________________________________
TABLE 3
---------------------------------------------------------------------------
Effect with Addition of Calcium Carbonate Filler
Vapor Phase Side- T.P.M. Acrolein stream Description Yield Yield
T.P.M. Carbon filled paper inner wrap Main- Main- Yield stream
stream
__________________________________________________________________________
Medium Activity Mill Waste Carbon; Paper contained 70% Carbon by
weight; 72 mg Carbon per Cigarette, No CaCO.sub.3 77% 54% 54%
Medium Activity Mill Waste Carbon; Paper Contained 50% Carbon by
weight; 52 mg Carbon per Cigarette, 20 mg CaCO.sub.3 74% 61% 67%
Medium Activity Mill Waste Carbon; Paper Contained 30% Carbon by
weight; 31 mg Carbon per Cigarette, 41 mg CaCO.sub.3 74% 59% 72%
Medium Activity Mill Waste Carbon; Paper Container 10% Carbon by
weight; 10 mg Carbon per Cigarette, 62 mg CaCO.sub.3 tj 74% 60% 78%
__________________________________________________________________________
TABLE 4
---------------------------------------------------------------------------
Effects with Calcium Carbonate and Burning Chemical
Vapor Phase Side T.P.M. Acrolein stream Description Yield Yield
T.P.M. Carbon Filled Paper Inner Wrap Main- Main- Yield stream
stream High Activity Wood carbon; Paper Container 70% Carbon by
weight; Paper Treated with 2.0% Solution of Na.sub.2 CO.sub.3 ; 72
mg Carbon per Cigarette, No CaCO.sub.3 66% 44% 32% High Activity
Wood Carbon; Paper Contained 50% Carbon by weight; Paper Treated
with 1.5% Solution of Na.sub.2 CO.sub.3 ; 52 mg Carbon per
Cigarette, 20 mg CaCO.sub.3 73% 19% 40% High Activity Wood Carbon;
Paper Contained 30% Carbon by weight; Paper Treated with 1.0%
Solution of Na.sub.2 CO.sub.3 ; 31 mg Carbon per Cigarette, 41 mg
CaCO.sub.e 81% 13% 52% High Activity Wood Carbon; Paper Contained
10% Carbon by weight; Paper Treated with 0.5% Solution of Na.sub.2
CO.sub.3 ; 10 mg Carbon per Cigarette, 62 mg CaCO.sub.3
__________________________________________________________________________
3 83% 56% 65%
similar beneficial results are obtained using carbon filled
wrappers made from wood pulp both with and without the additon of
calcium carbonate as the filler. Also, while all of the above
cigarettes tested employed the carbon filled paper as an inner wrap
under the conventional cigarette paper outer wrap for the tobacco
column, other samples tested using the carbon filled paper as the
sole wrapper produced similar reductions in the particulate and
vapor phase yields of the cigarettes. Likewise, comparable results
are obtained with carbon filled wrappers used as cigar wrap.
The effectiveness of the carbon filled wrapper of this invention
for cigarettes and cigars is quite apparent from the foregoing
illustrative examples. Many variations will become apparent to
those skilled in the art, and the invention is not limited to the
preferred embodiments shown. Various modifications and changes may
be made without departing from the spirit and scope of the
invention as defined in the following claims.
* * * * *