U.S. patent number 3,743,355 [Application Number 05/188,594] was granted by the patent office on 1973-07-03 for method of withdrawing hazardous gases from subterranean formations.
This patent grant is currently assigned to Esso Production Research Company. Invention is credited to Robert J. Blackwell, Alton R. Hagedorn, Gerald D. Ortloff.
United States Patent |
3,743,355 |
Blackwell , et al. |
July 3, 1973 |
METHOD OF WITHDRAWING HAZARDOUS GASES FROM SUBTERRANEAN
FORMATIONS
Abstract
Disclosed herein is a method for withdrawing hazardous gases
from a water saturated subterranean formation containing a minable
mineral deposit. In the method, wells are drilled through the
subterranean formation and water is withdrawn from the subterranean
formation to establish permeability to gas within the subterranean
formation. Gas is then withdrawn from the formation by means of the
wells. This method has particular applicability in reducing the
influx of radon into a mine contained in a mineral deposit.
Inventors: |
Blackwell; Robert J. (Houston,
TX), Hagedorn; Alton R. (Houston, TX), Ortloff; Gerald
D. (Houston, TX) |
Assignee: |
Esso Production Research
Company (Houston, TX)
|
Family
ID: |
22693801 |
Appl.
No.: |
05/188,594 |
Filed: |
October 12, 1971 |
Current U.S.
Class: |
299/12;
166/370 |
Current CPC
Class: |
E21F
7/00 (20130101); E21C 45/00 (20130101) |
Current International
Class: |
E21F
7/00 (20060101); E21C 45/00 (20060101); E21c
035/04 () |
Field of
Search: |
;299/2,12 ;98/50
;166/268,314 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Purser; Ernest R.
Claims
What is claimed is:
1. A method of reducing the hazard to miners from the danger of
hazardous gases which are produced from a water saturated
subterranean formation containing a mineable mineral deposit and
which is penetrated by a plurality of wells, said wells being in
pressure communication with said mineral deposit through said
subterranean formation, which comprises withdrawing water from and
injecting air into said subterranean formation by means of said
wells to establish permeability to gas within said mineral deposit,
and withdrawing hazardous gases from said mineral deposit by means
of said wells.
2. A method as defined in claim 1 in which air is introduced into
said subterranean formation by means of said wells while water is
withdrawn from said formation.
3. A method as defined by claim 1 wherein water is withdrawn from
said subterranean formation while said hazardous gas is being
withdrawn from said subterranean formation.
4. A method as defined in claim 1 further comprising opening a mine
working within said mineral deposit subsequent to establishing
permeability to gas within said subterranean formation and
introducing air into said mine working at a pressure greater than
the pressure existing at said wells to cause the flow of air and
hazardous gases from the mine to said wells.
5. A method of ventilating a mine in a mineral deposit contained in
a water saturated subterranean formation comprising drilling a
plurality of wells into said subterranean formation in locations
which are offset from said mine, said wells being in pressure
communication with said mine by means of said subterranean
formation, withdrawing water from said subterranean formation by
means of said wells to establish permeability to gas within said
subterranean formation between said mine and said wells,
introducing air into said formation, withdrawing hazardous gas from
said formation by means of said wells, and introducing air into
said mine working at a pressure greater than the pressure existing
at said wells to cause the flow of air and hazardous gases from the
mine to the wells.
6. A method of reducing the influx of radon into a water saturated
mineral deposit within a subterranean formation which comprises
drilling a plurality of wells into said subterranean formation at
locations which are spaced from a mine location within the mineral
deposit, said wells being drilled to a depth below the subterranean
formation and having a casing string, a tubing string extending
below the bottom of the subterranean formation, an annular space
defined by the tubing strings and casing strings which is in fluid
communication with the subterranean formation, and pumping means
disposed within the tubing string, withdrawing water from the
formation by means of the pumping means and tubing, introducing air
into the formation until permeability to gas is established within
the water saturated mineral deposit, withdrawing gas containing
radon from the formation by applying a vacuum to the annular space,
and continuing to withdraw water from the formation through the
tubing to maintain a pumping fluid level within the annular space
which is below the top of the formation.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to the use of wells to withdraw fluids from
a subterranean formation. More particularly, this invention relates
to a method for reducing the influx of hazardous gases into mine
workings in a water saturated subterranean formation by withdrawing
water from the subterranean formation until permeability to gas is
established within the formation.
2. Description of the Prior Art
Many naturally occurring substances such as coal, metal ores, and
the like, are obtained from subterranean formations by mining which
can present a variety of problems. One problem of wide occurrence
in mining these mineral deposits is the influx of gases into the
mine shafts and drifts within the subsurface formation. Gases such
as methane, hydrogen sulfide, and radon can be particularly
hazardous to the mine workers. They can lead to explosions,
asphyxiation of the miners, and poisoning, including radiological
poisoning.
Radon gas can be a serious problem. While radon itself is
relatively harmless, it is naturally radioactive and its decay
products are believed to be cancer producers. It has been noted
that there is a high incidence of lung and bronchial cancer in
miners working in environments containing radon gas. As a result of
these studies of the effects of radon gas, it is now required that
the concentration of this gas and its decay products in the mines
be reduced to permissible levels or the period of exposure by
miners be shortened. Although radon is generally associated with
the mining of radioactive ores, such as uranium deposits, it can
also be associated with the mining of other minerals. In other
words, this problem is not limited solely to the mining of
radioactive ores but can be more widespread.
A number of methods have been used or suggested to combat the
problem of hazardous gases, including radioactive gases such as
radon, in mine workings. One such method is forced air circulation.
In this method ventilation shafts are sunk to the mine drifts; air
is drawn in one or more inlet shafts, circulates through the mine
workings, and discharges through one or more exit shafts. The means
employed for circulation of air in such a method are generally fans
which are employed as a means of suction or discharge for the
circulating air. This method simply reduces the concentration of
the gases within the mine. It does nothing to prevent the initial
entering. Moreover, the method has detrimental side effects; it
increases the problem of airborne particles or dust within the mine
drifts. This in itself can be a health hazard. Also, where the
forced air circulation system employs only discharge fans, the
influx of gases into the mine workings can actually be increased.
In such a system, the pressure within the mine is reduced which
increases the tendency of the gases to diffuse from the
subterranean formation into the mine working.
It has also been suggested that a positive pressure be maintained
within the mine working to reduce the influx of hazardous gases. It
has been shown that moderate increases in the air pressure within
the mine can reduce the quantity of gas that will enter the mine by
diffusion. However, this method presents the very practical problem
of maintaining an adequate pressure seal within the mine. In
addition, positive pressure maintenance can be a short-term
benefit. As the air which is introduced into the mine diffuses into
the matrix of the minable deposit, the pressure between the mine
and deposit will tend to equalize. Once these pressures are
equalized, the gas will once again diffuse into the mine.
Another suggestion that has received some attention is the use of
core holes around the minable deposit to create a pressure sink and
thereby establish a pressure gradient within the formation to cause
the flow of gas away from the mine and toward the core holes. In
the suggested method, suction would be applied at the core holes to
lower the pressure at these locations and thereby increase the
differential pressure between the mine and the core holes. While
the suggested method appears to have some merit in dewatered
subterranean formations having a high permeability to gas, it would
be generally inapplicable to the more common situation where the
subterranean formation has a high water saturation and a
corresponding low permeability to gas.
DESCRIPTION OF THE INVENTION
This invention has general applicability to the problem of gas
influx into mines which have been sunk into mineral deposits within
subterranean formations. However, for convenience, and to assist in
the understanding of the invention, it will be described in terms
of a specific problem -- radon gas influx into a mine in a uranium
deposit.
Prior to discussing the invention in detail, it may be helpful to
discuss the problems associated with radon gas. Radon is an inert
gas which is produced by the natural disintegration or decay of
radioactive substances. Its most commonly occurring isotope,
Radon-222, is produced in the earth as the result of a very slow
radioactive decay in a series of isotopes beginning with
Uranium-238, the principal isotopic component of natural uranium.
The radioactive decay series begins with Uranium-238 and proceeds
ultimately to the formation of stable (non-radioactive) Lead-206.
For the purposes of this discussion, the portion of the uranium
decay series of interest begins with Radium-226 and continues
through Polonium-214. This portion of the uranium disintegration
series including the common name of the decay products, the name of
the isotope, the principal radiations of the decay, and the half
life of each of the decay products is shown below in Table I.
TABLE I
Common Principal Name Isotope Radiations Half Life Radium
Radium-226 Alpha 1,622 years Radon Radon-222 Alpha 3.825 days
Radium A Polonium-218 Alpha 3.05 minutes Radium B Lead-214 Beta and
26.8 minutes Gamma Radium C Bismuth-214 Beta and 19.7 minutes Gamma
Radium C' Polonium-214 Alpha 2.73.times. 10.sup..sup.- 6 min.
It is recognized that from a health standpoint the short-lived
alpha energy emitters in the uranium decay series are of primary
concern. As was previously stated, Radon-222 is not particularly
hazardous in and of itself. Radon is chemically inert and is
gaseous under ordinary conditions. Because of these characteristics
and its relatively long half life, radon can be inhaled and exhaled
before it is able to emit any appreciable amounts of alpha energy.
The decay products of radon, the so-called radon daughters, are
clearly more hazardous. These substances have the tendency to
interact with dust particles within a mine. When the mine air is
breathed, a portion of the dust is trapped in the respiratory
system and when the attached radon daughters decay, the soft lung
tissue is irradiated by the alpha particles emitted. Of the radon
daughters, Radium A and Radium C' are particularly hazardous since
they are alpha particle emitters and have relatively short half
lives.
Because of the chemically reactive nature of the radon daughter
products, they are unlikely to travel through the matrix of the
mineral deposit and into the mine atmosphere. Radon-222 being
gaseous and chemically inert is much more likely to reach the
atmosphere of the mine workings than its daughter products. The
radon then decays within the mine atmosphere to form the more
hazardous radon daughters.
There are three principal mechanisms by which radon can enter the
open working spaces of a mine. These mechanisms include gaseous
diffusion, dissolved gas contained in water flowing through the
mineral deposits and into the mine, and emanation from freshly
exposed mine wall surfaces and crushed ore.
Where the mineral deposit is porous and permeable to gas, the
chemically inert and relatively long-lived radon gas has the
ability to diffuse through the interstices of the mineral deposit
and into the mine working. The rate of radon influx is dependent
among other things on the permeability of the deposit to gas, the
concentration of radon existing within the mineral deposit, the
concentration existing within the open atmosphere of the mine, and
the pressure differential existing between the mine atmosphere and
the mineral deposit.
In additon, radon enters the mine by emanation from freshly exposed
mine surfaces and broken ore. When a mine wall has been exposed to
the atmosphere of the mine for an appreciable period of time, the
radon concentration within the mineral deposit will be low near the
wall of the mine and will increase with distance away from the
wall. When a new wall is formed by mining into the mineral deposit,
the portion of the deposit containing a higher concentration of
radon is exposed to the mine atmosphere. Thus, the newly exposed
mine wall will have a higher tendency to emanate radon into the
mine atmosphere.
Radon can also enter the mine in solution in water flowing into the
mine. If the pore spaces of the mineral deposit are filled with
water, radon gas emanating from the host crystal will go into
solution in the water and its concentration in this water will be
approximately equal to the concentration which would be present if
the void had been filled with air. Because the flow of water toward
and into the mine may be more rapid than the diffusion process
which occurs in the dry deposit, the net transport of radon into a
wet mine may be greater than into a dry mine where the major
transport mechanism for radon is gaseous diffusion.
Radon carried into the mine workings by water is released almost
completely to the air in the workings. By application of Henry's
Law for the solubility of gases in liquids and Dalton's Law of
partial pressure of gases, it can be shown that the distribution
coefficient ratio for radon between air and water is approximately
3.0 for the temperatures normally prevailing in mine workings. As
the radon-ladened water flows into and through the mine, it can
release radon until the concentration in the air above the water is
about three times the radon concentration in the water. Since the
equilibrium concentration of randon in water within the pore spaces
of the deposit can be several thousand times greater than a
tolerable concentration level in the mine atmosphere, the
percentage of the radon carried by the water that is released to
the air within the mine at equilibrium is very nearly 100 percent.
At this point it should be noted that the transport of radon gas by
water flowing into a mine can be a severe problem, even though the
mineral deposit being mined is not radioactive. A high incidence of
lung cancer has been noted in miners in a fluorspar mine in
Newfoundland and has been attributed to radon and its decay
products. However, no appreciable quantities of radioactive
substances were present in the deposit being mined; the radon was
apparently carried into the mine in ground water.
The influx of hazardous gases including radon into a mine can be
radically reduced through the practice of this invention. In the
practice of this invention, a plurality of wells are drilled from
the surface of the earth to a point below the subsurface formation
containing the mineral deposit. These wells and their operation
serve a number of purposes, all of which are directed to the
primary function of reducing the influx of hazardous gases into a
mine working. The wells are used to withdraw water from the
formation to establish permeability to gas between the location of
the mine and the wells. The withdrawal of this water from the
subterranean formation also reduces the quantity of water
containing dissolved gas which might otherwise enter the mine. A
vacuum is also applied to the wells to cause the flow of gas from
the location of the mine workings to the wells once permeability to
gas has been established. Flow of the gas in this direction will of
course reduce the quantity of gaseous influx into the mine
workings.
The wells used in the practice of this invention may be of a
conventional type having a bore hole which is lined with a large
diameter metal conduit or casing and a string of smaller diameter
pipe or tubing disposed within the casing string. Preferably the
tubing hangs free in the hole. That is to say, no packer would be
employed in the annular space between the casing and the tubing,
thus there would be fluid communication between the subterranean
formation and the surface of the earth by means of the annular
space between the tubing and the casing as well as through the
tubing string itself. The tubing string should extend to a point
below the bottom of the subterranean formation to permit depression
of the fluid level in the well to a point below the bottom of the
subterranean formation, if desired.
The wells employed in the practice of this invention will be spaced
around the periphery of the area to be mined within the mineral
deposit. The location of the mineral deposit is generally
determined by coring from the surface of the earth to determine the
concentration of the ore at that location. Taking into
consideration such economic factors as the depth of the
subterranean formation, transportation costs, processing costs and
the like, an economic limit is established for the minimum
concentration of ore which is considered to be minable. Taking
these factors into consideration as well as known principles of
mining engineering, the expected location of the mine workings
within the deposit can be determined. Where the minable deposit is
small and the expected mine workings are not extensive, withdrawal
wells can be drilled which will substantially surround the area to
be mined. Where the deposit is more extensive and the mining is to
be done in stages, it may be preferable and more economical to
drill the withdrawal well in stages. That is, an initial set of
withdrawal wells would be drilled around the periphery of the
initial area to be mined and additional withdrawal wells would be
drilled as the mine workings are extended.
The number of wells to be drilled around the periphery of any area
to be mined can be determined using known principles of fluid
hydraulics and the flow of fluid through porous media. Naturally,
the maximum benefit could be attained by surrounding the area to be
mined with wells which are spaced as closely to one another as
possible. However as a practical matter fewer wells are employed in
the practice of this invention. It has been estimated that 16 wells
evenly spaced on the circumference of a circle having a radius of
3,500 feet will withdraw two-thirds of the theoretical maximum
amount of fluid which could be withdrawn from a subterranean
formation by an infinite number of wells on the circumference of
this circle.
In the operations of the wells, water is withdrawn from the wells
by suitable means such as pumping through the tubing. The tubing of
course is in fluid communication with the mineral bearing deposit
by means of perforations through the casing, setting the casing
above the mineral bearing deposit, the use of a slotted liner at
the location of the mineral deposit or the like. The tubing should
extend beneath the bottom of the mineral bearing deposit and the
pump will be set within the tubing at or near its bottom. This will
permit the pumping fluid level within the well to be depressed
beneath the bottom of the deposit to expose the entire deposit
interval to air within the tubing-casing annulus.
It will of course be preferred to expose the entire deposit to air
during the pumping-dewatering operation. However, it should be
understood that this is not absolutely necessary to the practice of
this invention. Some benefit can be realized if only a portion of
the deposit is exposed to air.
During the preliminary pumping, the tubing-casing annulus at the
surface is preferably open to the atmosphere. This will permit air
to travel down the tubing-casing annulus and enter the mineral
deposit as it is being dewatered by the pumping operation. At this
point it should be noted that a porous and permeable formation
which is saturated with water, as is the instance in many deeply
buried mineral deposits, is not permeable to gas. Until the gas
saturation within the formation reaches some finite value, gas
cannot flow through the formation. However, in the preferred manner
of practicing this invention, water is withdrawn from the formation
by means of the wells and simultaneously air is introduced into the
formation by means of the tubing-casing annulus of the well. After
operating in this manner for a period of time, permeability to gas
can be established within the area of interest in the subterranean
formation.
Preferably, the dewatering-pumping operation should start prior to
opening the mine shaft within the deposit. If it is possible to
pump for a sufficient period of time prior to opening the mine
drift, the formation will have permeability to gas between the mine
locations and the wells at the time the mine drift is opened. This
initial permeability to gas will permit the flow of air from the
mine atmosphere, through the deposit, and to the wells when the
drift is first opened. In this manner the quantity of hazardous
gases which would enter the mine when it was first opened would be
reduced since there would be an immediate counterflow of air
through the deposit which would reduce the diffusion of gas into
the mine. Also since the flow path for the gas would be dewatered,
less water would flow into the mine with entrained or dissolved
gases.
This preliminary pumping is of course determined by conditions
existing at the time the pumping is initiated and economics. For
example, preliminary pumping quite naturally could not be
accomplished where the mine existed prior to drilling the
withdrawal wells. This condition would prevail in many older mines.
In those mines where permeability to gas cannot be established
prior to opening the drift, the quantity of air used for
ventilating the mines will be initially at a higher level to reduce
the concentration of hazardous gases within the mine atmosphere.
Once permeability to gas is established between the mine and the
wells, however, the quantity of ventilation air within the mine can
generally be reduced.
In those cases where the mine drift is opened within the deposit
prior to establishing gas permeability between the mine and the
wells, the mine itself can serve as a source of air to establish
gas permeability. This air from the mine can be used in supplement
to or in lieu of air which is introduced through the wells.
Once permeability to gas has been established within the
subterranean formation between the wells and the mine location, a
vacuum is applied to the tubing-casing annulus. The purpose of
establishing the vacuum within the tubing-casing annulus is to
create a differential pressure in the gas phase within the
subterranean formation between the mine location and the wells.
This differential pressure will cause the gas to flow from the mine
to the wells and thereby reduce the influx of hazardous gases into
the mine atmosphere.
The vacuum can also be applied prior to establishing gas
permeability within the formation; however, in such a case no
appreciable amount of gas will flow from the formation until there
is a continuous gas phase existing between the mine and the wells
which will thereby establish permeability to gas between these
locations.
The magnitude of the vacuum which is applied to the annulus may
vary depending upon the number of wells employed around the minable
deposit and the pressure within the atmosphere of the mine. Water
will continue to be withdrawn from the well during the periods the
vacuum is applied to further dewater the formation and reduce its
influx into the mine.
It is interesting to note that there can be a substantial reduction
in the total influx of hazardous gases into a mine working with a
relatively small countercurrent flow of air at the mine wall. For
example, with air moving at a velocity of 2 feet per day the flux
of radon into a mine can be reduced to approximately one-third of
the level which would exist with no countercurrent air flow. With
this countercurrent air velocity increased to 4 feet per day, the
flux of radon can be reduced to approximately 20 percent of the
level which would otherwise exist. Further increases in the
countercurrent air flow produce lesser results; the diffusional
flux of radon into the well would still be at five percent of the
level which would otherwise exist with a countercurrent air flow
velocity of 14 feet per day.
EXAMPLE
The benefits of the practice of this invention can perhaps best be
shown by considering an example mine working within a subterranean
formation. The mineral deposit in this instance is uranium ore
contained in four sand bodies separated by impermeable shale
barriers. The top of the uppermost of the four sand bodies is 400
feet below the surface of the earth and the bottom of the lowermost
sand lies approximately 600 feet below the surface. The water table
at the location of the minable deposit is approximately 270 feet
below the earth's surface and each of the uranium bearing sands is
initially saturated with water. The average porosity of the sands
is approximately 30 percent and the sands have an average
horizontal permeability to water of 460 millidarcies.
It has been determined that the minimum concentration of uranium
which can be economically mined is approximately 0.05 weight
percent U.sub.3 O.sub.8. (U.sub.3 O.sub.8 is a conventional
expression used to describe a mixture of uranium oxides.) From
cores taken from these subterranean deposits, it has been
determined that the ore body is roughly circular in horizontal
cross section, and that the minable ore containing at least 0.05
weight percent U.sub.3 O.sub.8 is in an annular ring within this
circle. The innermost limit of minable ore is approximately 1,750
feet from the center of the deposit and the outermost limit is
approximately 3,500 feet from this center.
Sixteen wells are drilled around the deposit at approximately
uniform spacing and at distance of approximately 3,500 feet from
the center of the deposit. The wells are drilled to a depth of 675
feet and completed in a conventional manner with the casing set at
650 feet. The tubing string extends to a depth of 625 feet and the
casing is perforated opposite each of the sand bodies to establish
fluid communication between these sands and the interior of the
casing.
Using known principles of mining engineering it is determined that
the optimum method of mining the annular deposit is to sink a shaft
at the center of the deposit and extend drifts from the shaft to
the minable ore. Lateral shafts would then be used to withdraw the
high-grade ore from the sand bodies.
Pumping of the withdrawal wells is started two years prior to
developing the lateral drifts within the minable ore deposits.
After two years of withdrawing water from the ore bearing sand
bodies, permeability to gas has been established in these sand
bodies throughout the circular deposit. At this time a lateral
drift having a length of 1,400 feet and a rectangular cross section
of 10 feet by 6 feet is opened at atmospheric pressure in the
high-grade ore deposit. Table II shows the estimated radon influx
in curies per day into this mine working under various
conditions.
TABLE II
Radon Influx, Curies/Day By Solution By Gaseous in Water Diffusion
After 1 Year of Mining Without Wells 0.294 0.107 Wells at
Atmospheric 0.181 0.104 Pressure Wells with 4 psi Vacuum 0.164
0.035 in Annulus After 5 Years of Mining Without Wells 0.221 0.141
Wells at Atmospheric 0.082 0.115 Pressure Wells with 4 psi Vacuum
0.057 0.020 in Annulus
As can be seen from Table II, the practice of this invention can
result in radical decrease in radon influx into a mine. After 1
year of mining, the rate of radon influx into a mine by solution
and gaseous diffusion is approximately one-half of the influx which
would exist in the absence of the withdrawal wells with vacuum.
After 5 years of mining, the radon influx of wells operating with
the 4 psi vacuum in the annulus is less than one-fourth of the
radon influx in the absence of such wells. Moreover, there is an
even more pronounced reduction in the radon influx due to gaseous
diffusion by the practice of this invention. As can be seen from
Table II, after 5 years of mining without wells the radon influx by
gaseous diffusion has actually increased. However, with the wells
operating at a vacuum the rate of gaseous diffusion into the mine
decreases to a level which is less than 15 percent of the amount
diffusing into the mine in the absence of withdrawal wells.
The principle of the invention and the best mode in which it is
contemplated to apply that principle have been described. It is to
be understood that the foregoing is illustrative only and that
other means and techniques can be employed without departing from
the true scope of the invention as defined in the following
claims.
* * * * *