U.S. patent number 3,741,716 [Application Number 05/238,846] was granted by the patent office on 1973-06-26 for heater for use in the manufacture of plastics filaments.
This patent grant is currently assigned to Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Bruning. Invention is credited to Max Bechter, Rudolf Johne.
United States Patent |
3,741,716 |
Johne , et al. |
June 26, 1973 |
HEATER FOR USE IN THE MANUFACTURE OF PLASTICS FILAMENTS
Abstract
A heater for use in the manufacture of spun plastics filaments
which compes two portions each having a truncated right polygonal
pyramidal or truncated right conical internal surface that is open
ended, the internal surface of one of the portions is heated while
the internal surface of the other portion is thermally reflective
and at the smaller end of the heated portion a screen is arranged
to reduce the effective area of the said smaller opening. With the
use of the heater spun filaments can be produced having a low
degree of preorientation and a satisfactory uniformity.
Inventors: |
Johne; Rudolf (Haunstetten,
DT), Bechter; Max (Bobingen, DT) |
Assignee: |
Farbwerke Hoechst
Aktiengesellschaft vormals Meister Lucius & Bruning
(Frankfurt/Main, DT)
|
Family
ID: |
5803215 |
Appl.
No.: |
05/238,846 |
Filed: |
March 28, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Mar 30, 1971 [DT] |
|
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2115312 |
|
Current U.S.
Class: |
432/59 |
Current CPC
Class: |
D01D
5/084 (20130101) |
Current International
Class: |
D01D
5/08 (20060101); D01D 5/084 (20060101); F27b
009/28 () |
Field of
Search: |
;432/8,59,64
;165/133 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Camby; John J.
Claims
What is claimed is:
1. A heater for use in the manufacture of spun plastics filaments
which comprises two portions each of which has a truncated right
polygonal pyramidal or truncated right conical internal surface
that is open ended, the perimeters of the larger ends of the
internal surfaces being congruent and the two portions meeting at
their larger ends with the perimeters of the larger ends of the
internal surfaces in register with one another, wherein the
internal surface of one of the portions is heated and the internal
surface of the other portion is thermally reflective.
2. A heater as claimed in claim 1, wherein there is provided at the
smaller end of the said one portion a screen arranged to reduce the
effective area of the said smaller opening.
3. A heater as claimed in claim 1, wherein the internal surface of
each of the said portions is a truncated right conical surface.
4. A heater as claimed in claim 1, wherein the largest cross
sectional area is at least twice the cross sectional area of the
bundle of filaments.
5. A heater as claimed in claim 1, wherein the diameter d.sub.4 of
the smaller opening in the said other portion is in the range of
from 0.4 to 1.0 times the total height L, of the heater.
6. A heater as claimed in claim 1, wherein the length H of the
internal surface of the said one portion and the apex angle .phi.
are such that a perpendicular drawn from the said point of the
internal surface of the said one portion meets the internal surface
of the said other portion, and
arcsin H/2d.sub.3 < .phi./2 <arcsin (H/2.cuberoot. (d.sub.3 +
d.sub.4 /2).sup. 2 + L.sub.1.sup.2) + arccot d.sub.3 +d.sub.4
/2L.sub.1
where:
L.sub.1 is the total height of the heater,
d.sub.3 is the largest diameter of the heater taken at right angles
to the axis, and
d.sub.4 is the diameter of the smaller opening in the said other
portion.
7. A heater as claimed in claim 1, wherein the internal surface of
the said other portion is highly polished or coated with a
reflective foil.
Description
The present invention relates to a heater for use in the
manufacture of macromolecular plastics filaments having a low
degree of pre-orientation for the production of high strength
threads.
High strength threads can only be produced when the material spun
to make the threads is drawn to a very high degree. A high degree
of drawing can only be obtained, however, with material which, when
spun, has a low pre-orientation. In the manufacture of high
strength threads, as used, for example, for tire cord, the spinning
process has to be carried out in such a manner that the spun
filaments should have as low a preorientation as possible. A
further problem arises in achieving the necessary uniformity,
because the filaments can only be drawn to a high degree when, in
the spinning process, each of the many capillaries has been
uniformly treated. Irregularities which may, for example, occur by
unsuitable cooling cannot be remedied by further processing and
detrimentally affect the quality of the finished thread.
It has been discovered that the pre-orientation of the filaments
during spinning can be reduced when a heating zone is provided
below the spinneret to retard cooling of the filaments. British
Pat. No. 580,832 describes a process and a device for heating
freshly spun filaments produced by the dry spinning process. The
spun filament is drawn off in a direction parallel to the axis of a
tube having a vertical axis and heated by means of horizontal
radiation. In one embodiment the tube is ellitical in cross section
and the inner wall of the tube has good reflecting properties. To
achieve good focusing of the rays, the source of heat radiation is
situated at one principal focus of the ellipse while the filament
is at the other principal focus. It is stated that the heating of
the spun filaments thus obtained proved to be advantageous also in
melt spinning polyamides. In this manner the filaments are
maintained in a plastic or semi-plastic state so that drawing is
facilitated. The device described in the aforesaid patent is,
however, very large and difficult to handle.
According to German Offenlegungsschrift No. 1,435,512 a long,
heated, cylindrical or rectangular tube serves as heating zone
which surrounds for a considerable distance the freshly spun
filaments below the spinneret. In this specification the minimum
temperature T.sub.G around the filaments is given by the
equation
T.sub.G = T.sub.D - 9X + 30
where:
T.sub.D stands for the temperature of the spinneret
X = 10.sup.4 . D/F .sup.. V.sub.sp
D represents the distance in feet from the spinneret
F indicates the denier value of the filaments
V.sub.sp is the winding speed in feet per second and
T.sub.G .ltoreq. T.sub.D + 100.degree. C
In this process the degree of pre-orientation could be kept low in
multifilament yarns.
French Pat. No. 1,347,986 provides a process according to which the
freshly spun polyester or polyamide filaments pass through a
cylindrical heated tube the gas temperature around the filaments
being determined according to the following condition
0.001 .ltoreq..sub.-.sub.X.sup.Y .ltoreq.0.08
where:
Y = (T.sub.GO - T.sub.G)/T.sub.D
X = 10.sup.4 . D/V.sub.sp .sup.. F
T.sub.GO = gas temperature directly on the spinneret in .degree. C
with 270.degree. C.ltoreq.T.sub.GO .ltoreq.700.degree. C
T.sub.G = gas temperature in .degree. C at distance L vertically
below the spinneret
T.sub.D = temperature of spinneret in .degree. C
D = distance from the spinneret in meters
V.sub.sp = draw-off speed of the spun filaments in m/sec
After having left the cylinder the filaments are rapidly cooled by
a horizontal air current. Subsequently, they are treated with a
preparation, hot steam is blown on to them for warming, they are
drawn and wound off.
In the known processes heating devices are used which heat the
filaments over a long distance after they have left the spinneret.
In this manner cooling and solidification of the filaments takes
place very slowly so that their pre-orientation is reduced. It has
been found, however, that this method does not give filaments of
optimum quality. The regularity of the filaments obtained is not
satisfactory and the blowing step carried out after the filaments
have passed the radiator involves sticking together of the
capillaries because with the construction of the heating radiator
used the blowing air gets into the heating zone where it whirls
together the still plastic filaments. A further drawback resulting
from the irregularity is the reduction of the tensile strength.
It is an object of the present invention to provide a heater which
permits the production of spun filaments having a low degree of
pre-orientation and having satisfactory uniformity, which filaments
are suitable for the manufacture of threads of high tensile
strength.
The invention provides a heater for use in the manufacture of spun
plastics filaments which comprises two portions each of which has a
truncated right polygonal pyramidal or truncated right conical
internal surface that is open ended, the perimeters of the larger
ends of the internal surfaces being congruent and the two portions
meeting at their larger ends with the perimeters of the larger ends
of the internal surfaces in register with one another, wherein the
internal surface of one of the portions is heated and the internal
surface of the other portion is thermally reflective.
Advantageously, there is provided at the smaller end of the said
one portion a screen arranged to reduce the effective area of the
said smaller opening. The internal surface of each of the said
portions is, preferably, a truncated right conical surface.
One form of heater constructed in accordance with the invention
will now be described in detail by way of example with reference to
the accompanying drawings in which:
FIG. 1 is a perspective view of the heater;
FIG. 2 is an axial cross-section of the heater shown in FIG. 1;
and
FIG. 3 illustrates the variation in temperature along the axis of
the heater.
Referring to the accompanying drawings, a heater comprises two
parts 1 and 2, each of which has the shape of a hollow truncated
cone, which are attached to each other at their larger circular
openings. The lower part 2 is heated while the inside wall of the
upper part 1 reflects the heat emitted by the lower part. Hence,
part 1 has the function of a reflector while part 2 has the
function of a radiator. The lower opening 3 of the heater is
protected by an annular screen 4 preventing air blown onto
filaments after they have left the heater entering the space below
the spinneret and disturbing the course of the capillaries while
they are still plastic. The diameter d.sub.1 of the opening in the
screen is larger by only 5 to 30 millimeters than the diameter
d.sub.F of a bundle of capillaries, that is to say,
d.sub.F + 5.ltoreq.d.sub.1 .ltoreq.d.sub.F + 30
The diameter d.sub.4 of the upper opening of upper part 1 is larger
than the diameter of the bundle of capillaries. The height L of the
radiator is in the range of from 1.0 to 2.5 times the diameter
d.sub.4 of the opening of the upper part. That is to say:
1.0 d.sub.4 .ltoreq. L .ltoreq. 2.5 d.sub.4
Between the bundle of capillaries and the walls of the heater air
streams upward and replaces the air entrained by the bundle of
capillaries. The cross sectional area of flow should be as large as
possible so that the compensation of air can take place at a low
speed. The largest cross sectional area of the heater should be at
least twice the cross sectional area of the bundle of capillaries,
that is to say,
d.sub.3.sup.2 >2 d.sub.F.sup.2
The side line H of the heated part 2 of the heater and the cone
angle .phi. should be chosen in such a manner that the said
perpendicular 5 drawn on the wall of part 2 points to the opposite
wall of part 1; and
arcsin H/2d.sub.3 <.phi./2 < arcsin (H/2.cuberoot.(d.sub.3 +
d.sub.4 /2).sup.2 + L.sub.1.sup.2) + arccot d.sub.3 + d.sub.4 /2
L.sub.1
The biconical shape of the heating radiator allows concentric
thermal radiation. The reason why this shape was chosen is that
only a minor part of the thermal rays hits the spinneret while the
major part is reflected by the conical reflector into the space
below the spinneret. In a preferred embodiment of the radiator
according to the invention the reflector 1 is, therefore, provided
with a highly polished surface or coated with a reflecting foil.
The heating elements of radiator 2 preferably consist of ceramic
plates with inserted heating spirals.
The device according to the invention can be used in melt spinning,
preferably spinning of high molecular weight polyesters, more
preferably polyethylene terephthalate, and copolyesters, the acid
components of which preponderantly consist of terephthalic acid.
With the use of the radiator of the invention spun filaments of a
very low degree of pre-orientation can be obtained, which permit
the production of high strength threads. It is likewise possible to
increase the throughput of molten polyester since the higher
pre-orientation resulting from a higher draw-off speed of the spun
filaments can be compensated for in the heater. The device
according to the invention is also suitable for the continuous spin
drawing of filaments from highly viscous material.
With the aid of the short biconical heating radiator according to
the invention a narrow temperature variation with respect to time
and space as indicated in FIG. 3 can be obtained below the
spinneret in the solidification zone of the filaments, whereby the
solidification is very favourably influenced. The temperature is
within the indicated limits
110 - 1.7 .times. 10.sup.3 .vertline.D/L -0.4 .vertline..sup.3
<T.sub.G -T.sub.D <125 - 2 .times. 10.sup.3 (D/L -
0.5).sup.4
at a distance 0 < D/L.ltoreq.1
where:
L = height of the heating radiator, measured in the same units of
length as the vertical distance D from the spinneret
T.sub.G = the gas (air) temperature and
T.sub.D = the temperature of the spinneret
In the direct vicinity of the spun filaments from the spinneret in
downward direction the air temperature first increases, it passes a
maximum and then decreases rapidly with a growing distance from the
spinneret. Owing to the fact that a screen narrows the lower
opening of the heating radiator to such an extent that it has just
the size necessary for an undisturbed running of the filaments, the
air blown onto the filaments for cooling them does not enter the
space below the spinneret, this being extremely important for
obtaining an optimum filament quality. The still soft and very
sensitive capillaries could otherwise be entangled by air whirls so
that they would stick together and uniform cooling would be
impossible.
Moreover, a heater as described above permits a higher draw-off
speed of the spun filaments whereby the production rate can be
considerably increased. As compared with known heating devices used
in the manufacture of filaments, the short biconical heating
radiator according to the invention is not only more effective but
also considerably smaller and thus more handy and easier to
use.
The following examples illustrate the invention.
EXAMPLE 1
Polyethylene terephthalate having an intrinsic viscosity of 1.23,
measured at 25.degree. C in a mixture of phenol and
tetrachloroethane in a ratio of 3 : 2, was spun at 304.degree. C at
a rate of 220 g/minute through a spinneret with 200 orifices each
having a diameter of 0.5 mm and the filaments were wound off with a
speed of 320 m/minute. Directly below the spinneret a biconical
heater was mounted having the following dimensions:
d.sub.1 = 140 mm, d.sub.2 = 170 mm, d.sub.3 = 225 mm, d.sub.4 = 135
mm, H = 70 mm, L = 150 mm, L.sub.1 = 85.6 mm, .phi. =
46.degree.
It had an installed filament power of 2,000 watts at 220 volts and
was operated with 150 volts. Immediately after having left the
heater, the filaments passed an air blowing zone having a length of
about 2 meters with a blowing speed of the air of 0.8 m/sec.
As measurement for the molecule orientation the spun filaments
produced in this manner have a double refraction DR of (1.6 . . .
2.0). 10.sup..sup.-3, measured according to the compensation method
of Ehringhous with quartz or calcite compensators. The DR value is
calculated from the ratio of the path difference and the capillary
diameter.
The filaments had a very good uniformity over their length. For the
variation of titer of the spun filament composed of 200 capillaries
there is given as measurement of non-uniformity U the average
linear deviation of the titer T from the means titer value T:
##SPC1##
For this purpose the titer T is measured as a function of the
filament length 1. L is the total filament length measured. The
mean titer value is ##SPC2##
With the use of the heating radiator according to the invention
filaments were produced having a titer non-uniformity U of 0.8%.
The spun filaments did not stick together.
The spun filaments obtained in this manner could be drawn in a
ratio of 1 : 6.5, their strength then being 82 g/tex.
COMPARATIVE EXAMPLE
In an analogous spinning process a known cylindrical heater was
used. The heater had a diameter of 205 millimeters, a length of 875
millimeters and a wall temperature of 245.degree. C. Into the upper
part of the heating tube air having a temperature of 245.degree. C
was concentrically blown in through an annular slit. The amount of
air could only be increased to 80 litres per hour, as otherwise a
large degree of sticking of the capillaries did occur.
Double refraction DR = (1.6 . . . 2.0).10.sup..sup.-3 uniformity of
titer U = 1.6% possible draw ratio 1 : 6.4 strength obtained 79
g/tex
EXAMPLE 2
A heater according to the invention was used in the spinning
process of high strength filaments from a material having an
intrinsic viscosity of 0.73. In this case it can be used either for
reducing the molecule orientation with the same draw-off speed of
the spun filaments or for maintaining the degree of molecule
orientation with an increased draw-off speed. The present example
is intended to illustrate the former possibility. The positions of
the heater and spinning chamber were the same as in Example 1.
Spinning temperature 290.degree.C Spinning rate 325 grams/minute
number of orifices in spinneret 200 diameter of orifice 0.35
millimeter winding speed 500 meters/minute heating radiator (2,000
watts with 220 volts) 150 volts blowing length 2 meters speed of
air current 0.8 meter/second non-uniformity of titer 0.7% double
refraction 1.2-10.sup..sup.-3
COMPARATIVE EXAMPLE
The same material as used in Example 2 was spun under the
conditions of Example 2, with the exception that no heating
radiator according to the invention was used. The filaments
obtained had the same degree of titer non-uniformity but a higher
degree of pre-orientation characterized by a double refraction of
1.6 .sup.. 10.sup..sup.-3.
* * * * *