U.S. patent number 3,736,769 [Application Number 05/158,828] was granted by the patent office on 1973-06-05 for cooling device.
This patent grant is currently assigned to Union Carbide Corporation. Invention is credited to Donald Edwin Petersen.
United States Patent |
3,736,769 |
Petersen |
June 5, 1973 |
COOLING DEVICE
Abstract
A cooling device is provided having a core of a cold storing
material sandwiched between two thin, flexible walls having
different heat transfer rates such that one side of the cooling
device is colder to the touch than the opposite side of the
device.
Inventors: |
Petersen; Donald Edwin
(Pleasantville, NY) |
Assignee: |
Union Carbide Corporation (New
York, NY)
|
Family
ID: |
22569891 |
Appl.
No.: |
05/158,828 |
Filed: |
July 1, 1971 |
Current U.S.
Class: |
62/530; 383/109;
607/112; 165/46 |
Current CPC
Class: |
F25D
3/00 (20130101); F25D 2303/0822 (20130101) |
Current International
Class: |
F25D
3/00 (20060101); F25d 003/08 () |
Field of
Search: |
;62/530 ;165/46 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Wye; William J.
Claims
What is claimed is:
1. A cooling device comprising at least one layer of a cold storing
material sealed within a container of two flexible thermoplastic
walls heat sealed to each other around their common periphery, one
of said walls being breathable film, and the other of said walls
being an air-impermeable film.
2. A device according to claim 1 wherein the walls are of
polyolefinic film.
3. A device according to claim 2 wherein the walls are of
polyethylene film.
Description
The present invention relates to cooling devices and more
particularly relates to devices for lowering temperature in the
treatment of animals and humans.
Cooling devices have been used for many years in the treatment of
animals and humans for relieving the discomfort of pain and
swelling and for injuries suffered accidentally in athletics or as
a result of other endeavors. Traditionally, these cooling devices
have been variations of the well-known ice pack which is merely ice
or a frozen water-alcohol mixture contained within a water
impermeable bag or merely wrapped in a towel.
More recently, improvements have been made in these cooling devices
such as by manufacturing a reusable container which contains a cold
storing material in separated compartments to render the cooling
device flexible at the joints between the compartments even when
the material contained therein is in a frozen state. This desire
for flexibly conforming the cooling device to the surface against
which it is to be used in order to gain highest efficiency in heat
transfer has also led to the use of various hydrophilic gels which
contain large quantities of water and yet retain some degree of
flexibility when frozen.
U.S. Pat. No. 3,545,230 to Morse is an example of one successful
attempt at forming a flexible cooling device. This patent discloses
that a hydrophilic gel containing a large quantity of water can be
coated on an inert flexible substrate and, when frozen, will retain
flexibility and can be conformed to the surface against which it is
to be used. A plurality of such gel-substrate layers can be stacked
and packaged within a flexible, liquid impermeable membrane to form
the completed cooling device.
Each of the cooling devices heretofore used has had either a single
cooling surface which could be placed against the surface to be
cooled or has had a plurality of surfaces of the same material and
thickness, each supplying the same degree of cooling. In using any
one device, therefore, the user has had no freedom of choice in the
amount of cooling to be applied while applications to different
parts of the body, for different purposes, and the preferences of
different individuals, would dictate that not the same degree of
cooling would be desirable in every instance.
It is, therefore, an obJect of the present invention to provide a
cooling device which has at least two surfaces providing different
amounts of cooling.
It is a further object to provide such a device which can be molded
in a frozen state to conform to various geometric shapes and which
retains the imparted configuration.
It is still a further object to provide such a device including a
securing means for easily attaching the device to the part of the
anatomy where it is to be used.
These and other objects will readily become apparent to those
skilled in the art in the light of the teachings herein set
forth.
In its broad aspect, the present invention relates to a cooling
device having at least one layer of a cold storing material sealed
within a container formed from two thin, flexible walls having
different heat transfer rates and which are secured to each other
around their periphery. The walls may be formed from different
thicknesses of the same material or from two different materials,
the only criteria for use being that one wall should transfer heat
at a lesser rate than the other thereby providing a cooling device
having one side which will feel colder to the touch than the
other.
The term "cold storing material" as used herein and in the appended
claims refers to any material which may be chilled or frozen and
will feel cold to the touch for a substantial time. This term
encompasses, but is not limited to, such materials as water and
water-alcohol mixtures, as well as the more recently used gel
materials.
The invention will be further understood by reference to the
accompanying drawing which is an isometric view, partially cutaway,
of a cooling device in accordance with one embodiment of the
invention.
Referring in detail to the drawing there is shown a cooling device
generally designated 10, comprising a relatively flat core of cold
storing material 12 packaged between walls of different thermal
conductivity.
The core of cold storing material 12 is a stack of four layers of
reinforced hydrophilic gel, usually referred to as hydrogel, 14
each separated by a film 16, such as polyethylene. The walls of
cooling device 10 exhibit different thermal conductivity due to
their fabrication from different materials and, in the embodiment
shown in the drawing, each comprises a different number of layers
of material. The bottom wall 18 is formed from a single layer of
thin air-impermeable film such as 4 mil thick polyethylene film.
The top wall 20 is formed from two thin films, an outer covering of
air-permeable film 22 such as Tyvek, an air-permeable polyethylene
film, and an inner layer 24 of thin air-impermeable film such as a
blown polyethylene film.
Inner layer 24 is required only in the instance where outer
covering 22 is air-permeable and it is necessary to keep the cold
storing material from drying out during storage and repeated
use.
Since each of the films used in the embodiment of the invention
shown in the drawing is a thermoplastic, the cooling device can be
conveniently sealed by forming the top and bottom walls of a length
and width slightly larger than the core of cold storing material 12
and joining the top and bottom wall around their entire periphery,
outside the periphery of the cold storing material, by a heat seal
26.
The heat sealing generally completes the fabrication of the cooling
device except in some instances where the size or intended use of
device dictates the desirability of including an attachment means
for convenience of use. One particularly preferred optional
attachment means is that shown in the drawing wherein two opposite
ends of the device are extended a short distance beyond heat seal
26 and are provided with circular holes 28 through which are passed
a flat elastic band 30 of a width substantially larger than the
diameter of holes 28. The differential in size between the width of
elastic band 30 and the diameter of holes 28 causes the elastic
band to be distorted where it passes through the holes and exert
sufficient friction on the holes to keep the band from slipping
through the holes without application of considerable force to
overcome the friction. A positive control is thereby exercised on
the continuous length of the elastic band between holes 28. It can
be tightened or loosened manually but will resist unwanted
loosening during use. For further ease of use one end 32 of the
band is folded upon itself transversely and sewn to prevent it from
being pulled through its respective hole while the opposite end 34
is folded upon itself longitudinally and is capped with a tube 36
of polyethylene heat shrunk around the end permitting easy
insertion into its respective hole.
To provide additional strength to the portion of the thermoplastic
surrounding holes 28 it is desirable to reinforce the extended ends
of the device such as by heat sealing to each end a strip of
relatively thick thermoplastic 38 such as a strip of 30 mil thick
polyethylene film.
The use of the cooling device shown in the drawings is quite
simple. The device may be kept frozen in the freezer compartment of
a refrigerator until required for use and can then be shaped to any
convenient geometric configuration with the elastic tie tightened
as much as desired. The device can then be applied where needed
with the colder wall against the surface to be cooled. If this wall
is found to be too cold, the device can be flexed in the opposite
direction and the elastic band reversed to permit placement of the
"warmer" side of the device against the surface to be cooled.
As will be apparent from the detailed description of the drawing,
the novel cooling device of the invention consists of only three
essential components, a front wall, a rear wall, and a cold storing
material sandwiched between the front and rear walls and completely
enclosed at the juncture of the front and rear walls around their
periphery. Optionally, components such as moisture barriers,
fasteners, etc., may be included as necessitated or dicated by the
materials of construction, size or intended use of the cooling
device.
The front and rear walls can be formed from one or more layers of
any thin flexible sheet material which may be water permeable or
water impermeable depending upon the nature of the cold storing
material used and whether or not a moisture barrier is provided
adjacent to the inside face of the wall. The front and rear walls
may be formed from the same material in varying thicknesses or from
different materials, the only criteria for selection being that one
wall should transmit heat at a different rate than the other
thereby rendering one surface of the device colder than the
opposite surface. Such materials as thermoplastic films, paper,
metal foils, woven and non-woven fabrics, natural and synthetic
rubbers, etc. will all be useful in forming the walls of the
cooling device of the invention, but thermoplastic films of
homopolymers and copolymers of olefins such as ethylene and
propylene, and vinyl chloride are particularly preferred since they
may conveniently be heat sealed around their periphery to form the
completed cooling device.
One particularly preferred pair of wall materials is that shown in
the drawings, namely, a wall of polyethylene film on the colder
side of the cooling device heat sealed to a wall of air permeable,
or so-called breathable, polyethylene film on the warmer side of
the cooling device. The air permeability of the warmer wall allows
for some heat loss through air entrapped in the pores of the film
and does not permit the high heat transfer rate which is possible
by conduction through a thin, non-porous polyethylene film. The
non-porous film side therefore feels colder to the touch than the
porous side of the device.
The cold storing material of the invention is likewise not limited
to any particular chemical composition and may be merely water or a
water-alcohol mixture sealed between the walls of the cooling
device. As stated previously, it is desirable that the cooling
device be plyable when frozen and have the ability to conform to
various geometric configurations. Since such properties are not
possessed by ice or a frozen water-alcohol mixture, unless a
cooling device comprising a plurality of individual, separated
compartments is used, gels similar to those of U.S. Pat. No.
3,545,230 are the preferred cold-storing materials of the
invention.
These gels possess many desirable advantages not available with
cooling devices containing water or other liquids. For example, the
cooling media does not melt to a liquid but remains as a gel which
can then be refrozen and used repeatedly. This is a particular
advantage since rupture of the outer enclosure will not result in
the spillage of any significant amounts of liquid. Moreover, porous
materials can be used in the outer walls of the cooling device
without liquid leakage. Useful gels are formed from a polymer,
including copolymers, and a liquid such as water which are combined
into an insoluble gel. The gel is preferably prepared in the form
of a continuous reinforced tape which can then be cut at
predetermined intervals, e.g., 12 inches, and if desired piled in
multiple layers. The product is then enclosed and sealed in its
flexible covering.
Since there is essentially no free water present in the finished
device, either before or after freezing, the configuration does not
change after repeated freeze-thaw cycling. For example, upon
melting, the material does not flow to the lowest part of the
package but remains in its original geometry. Due to the flexible
aspect of the cooling device it can be formed to the shape of the
surface to be cooled, which substantially improves heat transfer
rates. Moreover, as previously indicated, there is no danger from
the outer covering rupturing since there is essentially no liquid
phase to leak out. The material can be manufactured in many
different shapes without destroying flexibility so that the
physical dimensions of the product can be tailored to the
requirements for use.
The method of manufacturing and using specific hydrophilic gels in
flexible cooling devices is set forth in detail in previously
mentioned U.S. Pat. No. 3,545,230.
In practice, a wide variety of hydrophilic gels can be employed
with the only requirement for use being that the particular gel
selected be capable of retaining relatively large quantities of
liquid which can be easily transferred from a liquid to a solid
state by simple cooling procedures. If the liquid does not enter
the solid state then it is impossible to take advantage of its
latent heat of fusion, thereby reducing the efficiency of the
cooling device. Although numerous liquids can be employed, water is
preferred in order to take advantage of its large latent heat of
fusion (144 B.t.u. per pound). Water can be employed as the sole
liquid or mixtures of water and other liquids, such as alcohols, or
solutes can be employed.
Illustrative hydrophilic gels which are useful in the cooling
device of this invention can be prepared by appropriate techniques
from the following starting materials, among others: poly(ethylene
oxide), polyvinyl pyrrolidone, polyacrylamide, anionic
polyacrylamide, polyvinylalcohol, maleic anhydride-vinylether
copolymers, polyacrylic acid, ethylene-maleic anhydride copolymers,
polyvinylether, dextran, gelatin, hydroxy propyl cellulose, methyl
cellulose, carboxymethyl cellulose, hydroxyethyl-carboxymethyl
cellulose, hydroxyethyl cellulose, propylene glycol alginate,
sodium alginate, polyethyleneimine, polyvinyl alkyl pyridinium
halides, polyproline, natural starches, casein, proteins,
polymethacrylic acid, polyvinylsulfonic acid, polystyrene sulfonic
acid, polyvinylamine, poly-4-vinylpyridine, polymerized monoesters
of olefinic acids, polymerized diesters of olefinic acids,
acrylamide and difunctional polymerizable materials, and the
like.
It should be noted that the gels useful in the instant invention
are not limited to the use of the starting materials listed above,
but include copolymers of one or more of the aforementioned
compounds or materials similar to these. For example, copolymers of
ethylene oxide and minor or major amounts of other alkalene oxides
can also be used.
In most instances, the gel need only contain the insoluble swollen
polymer and liquid, e.g., water. If desired, however, it can also
include other materials to control the physical and chemical
properties of the gel such as freezing point, chemical stability,
color, smell, crystal size and growth rate.
Although a single reinforced layer exhibits optimum conformability
to the surface being cooled, it is sometimes necessary or desirable
to have a greater cooling capacity than can be conveniently
obtained in a single layer. This can be achieved by the formation
of a multi-layer cold storing material.
It has been observed that optimum flexibility and other desirable
features are exhibited when the layers of gel are separated from
each other by a thin film of an inert material. The frozen layers
are then permitted to slide easily over each other and contribute
even greater flexibility than that possessed by multi-layers of the
gel alone.
In practice, gels can be made of any practical thickness, width or
length. Cooling devices of 20 layers of gel and higher have been
made and found to have good flexibility.
The type of separator used to separate the gel layers is not
narrowly critical and a wide variety of materials can be utilized.
The only requirement of the separator is that it be flexible at
reduced temperature and compatible with the gel. The separator can
be applied to the surface of the gel and includes such materials as
silicone surfactants, cetyl alcohol and the like. Any of the
numerous products currently on the market can be employed with
satisfactory results. For example, separators can be composed of
polyethylene, polypropylene, polystyrene, polyvinylchloride,
polyethylene terephthalate, metal foils, and the like.
The flexible cooling device of the invention can be manufactured as
a single use disposable product or a reusable device. If the device
is meant to be disposable the outer enclosure can be a laminate
with insulating material such as cloth, polymer foams, paper, and
the like, on the outside.
As a reusable cooling device, the outer enclosure can be a pair of
thermoplastic films heat sealed around their edges. An attachment
device can also be provided for securing the cooling device to the
area to be cooled.
While the present invention is not limited to any particular
attachment device, it has been found that an inexpensive and
convenient attachment device can be formed, as shown in the
drawings, by providing circular holes at two opposite ends of the
cooling device and by passing through the holes a flat elastic band
which has a width substantially larger, preferably at least double,
the diameter of each hole. The elastic band should be somewhat
longer than the distance between the holes and can be provided on
one end with a knot, or similar stop, to prevent that end from
slipping its corresponding hole. The other end of the elastic band
can be tapered to allow it to pass easily through the hole on the
opposite end of the cooling device. The band can be adjusted by
pulling the tapered end through its hole until the desired length
of elastic band is provided between the holes. The elastic will
tend to maintain that predetermined length during use due to the
friction between the compressed elastic band and the hole which
maintains the flat band in a distorted shape.
If one or both of the walls of the cooling device are formed from a
porous material it may be desirable to include an inner wrapper of
an air and moisture impermeable material which will act to keep the
gel from drying out. A similar moisture barrier would also be
employed if water or other liquid material were used as the cold
storing material of the invention in combination with a porous
outer covering. This barrier can easily be provided by inserting a
thin thermoplastic, such as a polyvinylidene chloride film,
adjacent to the inner side of the porous wall. The barrier can then
be sealed with an appropriate water insoluble adhesive or heat
sealed around the periphery of the device to keep the cold storing
material of the device from contacting the porous outer wall.
For certain applications it might also be desirable to include a
strengthening or a reinforcing material either within the gel or
around the periphery of the cooling device. Such can be
accomplished by embedding in the hydrophilic gel materials such as
nylon gauze, rayon mesh, dacron, cellulose or other textile
products or fibers.
To provide additional strength for any securing means employed it
is usually desirable to extend two opposing edges of the cooling
device some distance beyond the encapsulated cold storing material
and to reinforce same, such as by heat sealing or gluing thereto a
sheet of material which is relatively more rigid than the materials
used in forming the walls of the cooling device.
The cooling device of the invention can be made in a wide variety
of sizes, thicknessess, and shapes ranging from 1 millimeter
thickness or less to several inches or more in thickness as well as
lengths and widths ranging from one inch or less to one foot or
more.
The cooling device of the invention can also be sterilized, if
desired, by many of the known techniques, for example, autoclaving,
irradiating, etc.
The following examples are intended to further illustrate the
invention and are not intended, in any manner, to limit its
scope.
EXAMPLE 1
A cooling device in accordance with the invention was fabricated
from a 5 ply core of poly (ethylene oxide) coated on a Mylar
backing and irradiated to produce a hydrophilic gel. The core
measured 2 1/2 .times. 9 inches and was packaged in a 3 1/2 .times.
11 1/9 inch envelope.
The completed cooling device consisted of, starting from the
outside of the warmer side, two layers of 3-4 mil Tyvek film, a
layer of 4 mil low density polyethylene film, a layer of 2 mil
Saranex, the core of gel, a layer of 2 mil Saranex, 2 layers of 1
1/4 mil low density polyethylene film and a layer of 4 mil low
density polyethylene film. The thermoplastic layers were all heat
sealed to each other around their periphery outside the edges of
the core in the manner shown in the drawings.
The completed cooling device was stored at about -10.degree.F. for
several days and the temperature of each side was measured upon
removal from the freezer.
The procedure for measuring the temperature involved the use of
matched thermocouples which were pressed against the sides of the
cooling device with equal pressure. The thermocouples were each
backed by a 2 mil polyethylene bag filled with 500 ml of water
warmed to 100.degree.F. The water bags acted as heat sinks and
simulated actual use conditions.
After 1 minute a temperature difference of 10.degree.F. was
recorded; the "warm" side reading 75.degree.F. and the "cold" side
reading 65.degree.F. After 4 minutes, the readings were
72.5.degree.F. and 64.5.degree.F., respectively.
EXAMPLE 2
The test described in Example 1 was repeated with a cooling device
measuring 8 .times. 3 inches, but otherwise identical to that of
Example 1. The initial temperature difference observed was
7.5.degree.F.
From the above it can be seen that the present invention provides a
cooling device which offers the user a choice of the amount of
cooling to be applied without sacrificing any of the desirable
convenience features, such as flexibility, of cooling devices which
were previously available.
While the present invention has been described with particularity,
it will be obvious that it is susceptible to changes, modifications
and alterations without departing from the scope of the invention
as defined in the appended claims.
* * * * *