U.S. patent number 3,736,492 [Application Number 05/106,376] was granted by the patent office on 1973-05-29 for film treating method.
This patent grant is currently assigned to Union Carbide Corporation. Invention is credited to Donald A. Davis, Louis A. Rosenthal.
United States Patent |
3,736,492 |
Rosenthal , et al. |
May 29, 1973 |
FILM TREATING METHOD
Abstract
A method is disclosed for the surface treatment of a plastic
body by exposure to a high intensity voltage accompanied by corona
discharge wherein said voltage is a sequence of
alternating-directional, sonic frequency pulses of electrical
voltage.
Inventors: |
Rosenthal; Louis A. (Highland
Park, NJ), Davis; Donald A. (Somerville, NJ) |
Assignee: |
Union Carbide Corporation (New
York, NY)
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Family
ID: |
22311070 |
Appl.
No.: |
05/106,376 |
Filed: |
January 14, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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862412 |
Sep 30, 1969 |
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Current U.S.
Class: |
250/326; 250/324;
422/186.05 |
Current CPC
Class: |
H02M
7/523 (20130101) |
Current International
Class: |
H02M
7/505 (20060101); H02M 7/523 (20060101); H02m
007/48 () |
Field of
Search: |
;250/49.5 ;321/45,45C
;204/312 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Principles of Inverter Circuits, Bedford & Hoft, 1964, John
Wiley & Sons, Inc., New York-London-Sydney, pp. 141, 165, 166,
184, 185, 186, 208, 263. .
"A Silicon-Controlled Rectifier Inverter With Improved
Commutation," W. McMurray & D. P. Shattuck, Reprint from
Communication & Electronics, Nov. 1961. .
Principles of Inverter Circuits, Bedford & Hoft, John Wiley
& Sons, Inc., New York-London-Sydney 1964, pp. 90-92..
|
Primary Examiner: Shoop, Jr.; William M.
Parent Case Text
This application is a continuation-in-part of application Ser. No.
862,412, filed Sept. 30, 1969 and now abandoned.
Claims
What is claimed is:
1. A process for the surface treatment of a plastic body with an
alternating voltage of high intensity accompanied by corona
discharge, wherein the treatment zone constitutes a capacitive
load, comprising exposing said surface to an
alternating-directional sequence of pulse waveform electrical
voltage in the sonic frequency range and accompanying corona
discharge, whereby the rapid change of electrical voltage is
maximized and the application of electric stress on all circuit
components is minimized.
2. The process in accordance with claim 1, wherein said sequence of
pulse waveform electrical voltage has a frequency in the range
20-5,000 Hz.
Description
BACKGROUND OF THE INVENTION
Exposing the surface of a polymer body, such as polyethylene film,
to a high voltage gaseous discharge having corona characteristics
is known to improve the affinity of the surface for adhesives, inks
and other polar substrates. The treatment zone of a typical system
comprises a relatively large ground electrode separated from one or
more relatively sharp high voltage electrodes by two and preferably
three dielectrics. The essential dielectrics are an ionizable
gaseous dielectric, normally air, and the polymeric body to be
treated. Normally, the ground electrode is covered with a "buffer"
dielectric, such as rubber or a polyester film, which acts to
preclude an arc from bridging the gap at weak points in the polymer
body. The high voltage electrode, which may consist of one or more
treater bars in series or in parallel, runs the length of the
ground electrode and is in circuit with a high voltage
generator.
Most commercial treating systems employ alternating current
supplied at frequencies up to 500 kHz or more. Gap voltages up to
15 kv or more are employed to effectively treat a polymer film
which is continuously passed through the gap at speeds up to 500
feet per minute or more. In practice, an energy density-to-film
surface of the order of about 1 watt-minute per square foot of film
surface or more is sought to achieve good surface adhesion
characteristics.
While every component of a film treating system has come under
investigation from time to time, the waveform of the high voltage
employed in the treating system has generally been neglected. The
spark-gap generators and motor alternators now in use are
inefficient and suffer from many inherent deficiencies.
In addition to interfering with radio reception due to the presence
of radio frequencies in the spark-gap generator output wave, that
generator has a short duty cycle. The range of output power for a
given generator is severely limited since the gap breakdown voltage
sets the minimum voltage.
The motor alternator, on the other hand, is cumbersome in size and
subject to frequent mechanical failure. Further, its output is
sinusoidal which is far from the ideal waveform.
In a typical high voltage film treating system, an alternating
current line voltage is fed to a high voltage generator and the
generator alternating current output is fed through an output
transformer to the treating circuit load.
The load should be viewed as a lossy capacitor wherein the
electrodes, in their area and spacing, define the capacitance and
the dielectric is a composite made up of an air gap, the film and
the buffer dielectric all in series. As the corona voltage
threshold level is reached, the losses of this system vary in a
nonlinear manner. It is the loss component which is effective in
treatment and the recognition of the capacitive reactive behavior
of the load is important.
The concept of variable frequency has been only recently recognized
as the all important parameter for load adjustment and optimization
in film treating operations. Looking at the corona treating region
as a lossy capacitor system, the power would be proportional to
frequency just as, for a given input voltage, the current entering
a capacitor is linear with frequency. This concept is disclosed and
claimed in our copending application, filed of even date herewith,
and entitled "Film Treating Process."
SUMMARY OF THE INVENTION
The present invention relates to the high voltage surface treatment
of a plastic body with an alternating voltage of high intensity
accompanied by corona discharge, wherein the treatment zone
constitutes a capacitive load, comprising exposing said surface to
an alternating-directional pulse waveform electrical voltage in the
sonic frequency range and accompanying corona discharge.
It has been found that a broad range of sonic frequency (20-20,000
Hz) treating voltages may be employed, where frequency is varied to
effect surface treatment under optimum load conditions.
Accordingly, a treating system providing a broad frequency
variation of treating voltage over a range of 20 to 5,000 Hz is
desired.
The pulse waveform is desired since corona current flows only
during the time of voltage change according to i = C(dv/dt). For
example, a pulse with its rapid positive and negative change will
result in corona current. The square wave during the flat top
region results in no corona current and merely applies an
electrical stress on all components. The nature of a corona load is
such that charges residing on the dielectric surfaces inhibit
further corona discharge during the constant voltage region. Thus,
the square wave is of no value and only the swing from positive to
negative and negative to positive extremes is useful in generating
corona. Similar arguments can be applied to the sine wave waveform.
It has been discovered that the transient aspect is the essential
part of any waveform and the most desirable from the point of view
of efficacy and utilization.
In the drawings:
FIG. 1 is a schematic view of apparatus circuitry capable of use in
the practice of the process of the invention;
FIG. 2 (a) and (b) are schematic representations of the treating
circuit voltage and load current waveforms, respectively, for
apparatus of the type shown in FIG. 1;
FIG. 3 is a graphical representation of the relationship between
treating load power and frequency employed for varying electrode
lengths in the process of the present invention.
An improved film treating system is shown schematically in FIG. 1
of the drawings. As there shown, a suitable variable direct current
source is provided comprising a variable autotransformer 10 having
an alternating current supply, the output of which is rectified by
a full wave rectifier 12 and filtered by capacitor 14 connected
across the output terminals of rectifier 12. The dc voltage output
E.sub.dc which is a direct function of the applied auto transformer
voltage is fed to the high voltage pulse output circuit 15.
Polyphase rectifiers and the like can also be used to provide
adjustable dc voltages. It should be noted, however, that the
employment of means for varying input voltage and consequent
selected output voltage to a desired constant level constitutes
merely an apparatus convenience but does not constitute a point of
criticality or novelty in the present invention.
The high voltage pulse output circuit 15 comprises a high voltage
transformer 16 having a high voltage secondary winding and a low
voltage primary center tapped at 18 where voltage E.sub.dc is
applied. At least two power thyristors 20 and 22 are coupled at
their cathodes and respectively connected at their anodes to the
end taps 24 and 26 of the primary of the transformer 16. As
described in the article "Thyristors: Semiconductors for Power
Control" by V.W. Wigotsky in Design News, Vol. 22, No. 18, page 26,
which is incorporated by reference, thyristors are super switches
for electrical power as is their function in the solid state high
voltage generator of this invention. The preferred power thyristors
are silicon controlled rectifiers but any solid state device or
combination of devices which function equivalent to a thyristor or
switch can be used. Ordinarily, a thyristor, particularly a
silicon-controlled rectifier in a high conductive state, continues
to conduct after the gate signal is removed until the anode current
is interrupted or diverted for a time sufficient to permit the
rectifier to regain its forward blocking condition.
At least one capacitor 28 is connected across the end taps 24 and
26 of the primary of the transformer and consequently between
thyristors 20 and 22.
The high voltage transformer 16 is an important integral part of
the high voltage pulse generator circuit. It is center-tapped with
end return taps in the primary while the secondary is a high
potential winding. Its core must not saturate at operating
frequencies and voltages.
At least one pair of diodes 34 and 36 are, respectively, connected
at their cathodes to the end taps 24 and 26 of the primary of the
transformer 16. The anodes of diodes 34 and 36 are commonly
connected to the cathodes of thyristors 20 and 22. Inductor 38 is
positioned between filtering capacitor 14 and pulse output circuit
15. The diodes 34 and 36 act as anti-parallel or reverse conduction
diodes to allow for reversed current flow.
The rate at which power thyristors undergo gating is controlled by
a timing circuit 40 which is typically a multi-vibrator, preferably
a free-running, astable, solid state oscillator or a unijunction,
astable oscillator which generates trigger pulses of any desired
frequency. If coupled with another triggering circuit, monostable
and bistable oscillators may also be used. The multivibrator 40 is
coupled to the gate of thyristor 20 by a capacitor 42 and resistor
44 and to the gate of thyristor 22 by capacitor 46 and resistor 48
networks, respectively.
Variation of the output frequency of the multivibrator circuit 40
is obtained by the employment of variable resistors 49 and 50
(ganged at 51) which are, respectively, positioned in each of the
base circuits of the transistors. Such variable control of
multivibrator output frequency produces a consequent controllable
output from the pulse output circuit 15 which results in output
frequency control of power delivered to the treating load circuit
52.
The output of the transformer thyristor section of the high voltage
generator is essentially a pulsed wave of variable frequency. Such
output is produced by sequentially gating thyristors 20 and 22 by
timing pulses applied to the gates thereof by the timing circuit
40. More particularly, when thyristor 20 is closed, thyristor 22 is
maintained in a blocked or open condition and current from the
power supply will then flow through the inductor 38 and one half of
the transformer. The capacitor 28 is across the whole transformer.
This series combination of inductor 38 and capacitor 28 oscillate
(at a frequency higher than the gating frequency) to provide a
single cycle of oscillation. The thyristor 20 is self-extinguished
during the time that diode 34 is conducting (i.e., the negative
portion of the cycle). Each thyristor is independently turned off
by this procedure.
When thyristor 22 is closed, the same sequence occurs using the
other half of the transformer in a sequential manner. By this
action, current from the power source alternately flows through the
two sides of the transformer primary as the thyristors are
sequentially fired.
Since the direction of current flow through the two halves of the
primary is opposed, an alternating, variable frequency, pulse wave
output having an amplitude of about [N.sub.2 /N.sub.1 ] 2 E.sub.dc,
wherein N.sub.2 is the number of windings on the secondary of the
transformer and N.sub.1 is the number of windings on each half of
the primary, will be created in the secondary having the waveform
shown schematically in FIG. 2(a) of the drawings. This voltage is
applied to the treater circuit load and produces a treater load
current having a pulse waveform as shown schematically in FIG. 2(b)
of the drawings.
The waveshape of the voltage output from the secondary of the
transformer is an alternating pulse superimposed on a residual
pedestal. This pedestal is due to the charge remaining on the
system capacitance at the end of each pulse. The load current in
the treater circuit has the waveform of a series of
alternating-directional, sonic frequency, single oscillation
pulses. There is a natural resonant ring due to the transformer
following the useful load current burst. This ring does not
contribute to corona. Comparing the waveforms of FIGS. 2a and 2b in
proper time sequence one can see that the current (2b) is a
derivative function of the voltage (2a).
The solid state high voltage generating system disclosed herein is
especially suited for use in polymer film treating systems. As
shown schematically in FIG. 1, the system as a whole consists of
the high voltage generator whose output is connected to the film
treating work cell 52 comprising a treater electrode 54 which is
normally separated from ground electrode 56 by an air gap 58, the
polymeric film 60 and a buffer dielectric 62.
To effectively modify or treat the surface of a polymeric film, the
solid state, variable frequency, high voltage generator must cause
a rapid sequence of high voltage gaseous discharges to occur in gap
58 during passage of a polymeric film therethrough.
In carrying out treating tests in accordance with the present
invention, a high slip polyethylene film 70 inches wide, 1.5 mil
thick, traveling at 50 feet per minute, was exposed to the corona
discharge provided by the pulse generator of FIG. 1. It was
possible to operate over an extremely wide frequency range. The
voltage fed to the corona generator was maintained at 120 volts dc
and the input current varied with variations in frequency as a
criterion of loading. By taking the product of dc voltage and dc
current, the power input to the generator is indicative of
loading.
The observed data is presented as the curves of FIG. 3. In the
curves, the number associated with each curve indicates the length
(in inches) of the electrode employed for treating.
The load is continuously controllable down to essentially zero. The
impulsive waveshape has resulted in lower harmonic currents and
their associated resonances. It would be expected that in avoiding
any resonance absorption, circulating currents and the associated
internal heating would be reduced and it was noted that certain
components operated cooler.
Tests were carried out at desired energy densities and the
treatment was satisfactory for ink adhesion at commercial
levels.
The term "high voltage gaseous discharge," as used herein, applies
to the discharge phenomenon observed during the treatment of
polymer films. Although essentially a suppressed arc which
possesses aspects of corona glow and arc discharges, the
predominant visual indicia is the corona which has caused the art
to term the phenomenon a "corona discharge."
To generate the high voltage discharge in the gap 58, the high
voltage generator is capable of supplying to a sharp knife-edge
electrode at least 2,000 volts ac. Commercial units with larger
radius electrodes require from about 5,000 to 50,000 volts or more
ac which for a dc power supply having an output up to about 120
volts dc will require a transformer having at least 20, preferably
70 or more, windings for each half primary winding. It will be
appreciated, however, that the number of secondary windings could
vary depending on the magnitude of the selected supply voltage. The
solid state high voltage generator should also be capable of
providing a power output of from about 5 to about 25 watts per
linear inch of electrode 54 to effectively treat the surface of a
polymeric film.
Since polymer film treating systems operate at gap film speeds in
order of about 100 to 200 feet per minute or more, the astable
timing circuit should preferably operate at a frequency of about 20
to 5,000 Hz to closely space the discharges on the film surface. As
used herein, the term "Hz," or Hertz, is the currently accepted
abbreviation for cycles per second.
While not critical to the operation of a polymer film treating
system, gap spacings in the order of about one-sixteenth to
three-sixteenth inch are most commonly employed and contemplated
within the ambit of this invention.
In addition to an efficient duty cycle, and the ability to obtain
maximum loading conditions through frequency control over an
extremely broad range of frequency, the solid state high voltage
generator of the invention possesses several characteristics which
are deficient in prior generators.
Radio frequency interference is essentially nonexistent because the
fundamental waveshape is lacking in radio frequency components.
This avoids the use of expensive shielding devices and allows its
use in areas where regulations have forbidden the use of other
generators.
dc Input voltage variation offers a convenience over existing
units. Since the timing circuit operates independently of the
voltage supply, output voltage is not dependent on the frequency of
the timing circuit and any desired output voltage is available at
any selected frequency of operation of the timing circuit by
variation in dc input voltage. Therefore, for any selected dc input
voltage, the output voltage of the generator will be constant and
independent of frequency variation.
* * * * *