U.S. patent number 3,736,104 [Application Number 05/143,853] was granted by the patent office on 1973-05-29 for oxygen generator cell.
This patent grant is currently assigned to Life Support, Inc.. Invention is credited to John P. Churchill, Tommy Lewis Thompson.
United States Patent |
3,736,104 |
Churchill , et al. |
May 29, 1973 |
OXYGEN GENERATOR CELL
Abstract
Chemical oxygen generators in the form of disposable tin plated
steel cans housing a chlorate candle, a starter, and filters where
needed to remove contaminants and also serve as shock absorbing
means. The cans have oxygen delivery outlets and starter actuators
which can be at one end of the can or separated at both ends of the
can. The preferred oxygen generating chemical is sodium chlorate,
the decomposition of which is catalyzed by sodium peroxide.
Inventors: |
Churchill; John P.
(Indiatlantic, FL), Thompson; Tommy Lewis (Melbourne,
FL) |
Assignee: |
Life Support, Inc. (Melbourne,
FL)
|
Family
ID: |
22505960 |
Appl.
No.: |
05/143,853 |
Filed: |
May 17, 1971 |
Current U.S.
Class: |
422/120;
128/202.26; 102/477; 222/3; 423/579; 422/126 |
Current CPC
Class: |
C01B
13/0218 (20130101); A62B 21/00 (20130101); B01J
7/02 (20130101); C01B 13/0296 (20130101) |
Current International
Class: |
C01B
13/02 (20060101); B01J 7/02 (20060101); B01J
7/00 (20060101); A62B 21/00 (20060101); B01j
007/00 () |
Field of
Search: |
;23/281,284,252 ;102/57
;128/191,203 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Tayman, Jr.; James H.
Claims
We claim as our invention:
1. A gas generator cell which comprises a conventional tin-plated
steel can having an outlet orifice in one end thereof, a seal
closing said orifice, a fuel free chlorate candle body composed of
sodium chlorate and a sodium oxide catalyst effective to generate
oxygen at temperatures well below those effective to weaken the can
or cause a fire hazard, resilient mats clamping the candle body
between the ends of the can in spaced relation from the can
sidewall and providing an unfilled space between the candle body
and sidewall, said candle body having a varying cross-sectional
area along its length sized and shaped to maintain a steady oxygen
generating rate as burning progresses along the length of the body,
ignition material in one end of the can for igniting the candle,
and means in the can activated from outside of the can to ignite
the ignition material for initiating generation of oxygen by the
candle to flow through said space between the candle and side wall
of the can and through a resilient mat to the outlet oriface in the
end of the can.
2. The cell of claim 1 wherein the means for igniting the ignition
material is an electric match.
3. The cell of claim 1 wherein the ignition material for the candle
is activated by water and the means for igniting the ignition
material is a device for releasing water to the ignition
material.
4. The cell of claim 1 wherein the means for igniting the ignition
material is a percussion pellet in the can.
5. The cell of claim 1 wherein the orifice in an end of a can is a
ring of spaced holes and the means for igniting the ignition
material is surrounded by said ring of holes.
6. A disposable oxygen generating cell which comprises a
conventional metal can having an outlet in an end thereof and a
chlorate candle activator in an end thereof, a chlorate candle body
clamped in the can between the ends thereof and spaced from the
side of the can to provide therebetween a passage along the length
of the candle body for flow of oxygen from the candle to the
outlet, an ignition material cone at one end of the candle, means
in the can activated from outside of the can to ignite the ignition
cone for burning the candle to discharge oxygen through said
passage to said outlet, and said candle body being sized and shaped
to deliver oxygen at a steady rate as burning progresses through
the length of the candle.
7. A disposable oxygen generating cell adapted to be dropped into a
dispensing receiver for feeding oxygen to a tube which comprises a
conventional tin plated steel can, a compressed fuel free sodium
peroxide catalyzed chlorate candle pellet in the can releasing
oxygen by catalytic decomposition at low temperatures, resilient
filter mats overlying the ends of the pellet in the can clamping
the pellet between the ends of the can in fixed relation to the
can, water activated ignition material on one end of the pellet, a
water filled container in said can in sealed adjacent relation to
said ignition material, and means actuated from outside of said can
for piercing said container to release water to said ignition
material for activating the pellet to generate oxygen.
8. An oxygen generator cell which comprises a metal can having a
top lid with a depending thimble, a plunger having peripheral ribs
sealingly slidable in the thimble, a piercing needle depending from
the plunger effective to pierce the bottom of the thimble when the
plunger is depressed, said thimble and plunger adapted to confine
fluid material therebetween to eject the fluid through the pierced
end of the thimble into the can, an oxygen generating candle in the
can having an ignition cone adapted to received said fluid from the
pierced thimble, and discharge orifice means in the can for
releasing oxygen generated by the candle.
9. The canister of claim 6 wherein the candle is clamped between
resilient ceramic mats in the central portion of the can and held
is spaced relation from the side wall of the can.
10. The canister of claim 6 wherein the material for igniting the
candle is water initiated and the activator is a water filled
container for releasing water to the material.
11. The canister of claim 6 wherein said outlet is covered by a
removable seal.
12. The canister of claim 6 wherein both the outlet and the
activator are in one end of the can.
13. The canister of claim 6 wherein the outlet and the activator
are in opposite ends of the can.
14. An oxygen generator cell which comprises a metal can having a
top lid with a depending thimble, a plunger slidable in the
thimble, a piercing needle depending from the plunger effective to
pierce the bottom of the thimble when the plunger is depressed,
said thimble and plunger adapted to confine fluid material
therebetween to eject the fluid material through the pierced end of
the thimble into the can, an oxygen generating chlorate candle in
the can, ignition material on one end of the candle adapted to be
ignited by fluid received from the pierced thimble, and a ring of
holes surrounding the thimble providing a discharge outlet for
oxygen generated by the candle.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to the art of chemical oxygen generators and
is particularly concerned with the use of conventional thin-walled
tin plated steel cans as housings for chlorate candle type oxygen
generators having a formulation which will maintain a self
sustaining low temperature reaction which will not damage the
cans.
2. Description of the Prior Art
Chemical oxygen generators are known in the prior art as for
example in the Geffroy et al. U.S. Pat. No. 2,775,511 dated Dec.
25, 1956; the Jackson et al. U.S. Pat. No. 2,558,756 dated July 3,
1951; and the Moni et al. U.S. Pat. No. 3,276,846 dated Oct. 4,
1966. These generators operate at high temperatures and are
expensive and cumbersome. It is not economically feasible to
discard them after use and they are not adapted for instantaneous
use after a long shelf life.
SUMMARY OF THE INVENTION
The present invention now provides chemical oxygen generators in
the form of sealed non-pressured disposable tin cans capable of
being actuated to instantly generate oxygen suitable for breathing
at a steady low pressure rate for a predetermined time period.
The preferred embodiments of this invention include conventional
tin cans of standard sizes selected to deliver sufficient oxygen
for breathing over a predetermined time period and housing a
chlorate candle, an igniter for the candle, and an activator for
the igniter. The activator may take the form of a nichrome wire
heated to ignite a pyrotechnic mixture, a percussion cap or a
chemical injected into the starter material. The chlorate candle
preferably is tapered to provide a decreasing reaction area as the
reaction progresses, thereby maintaining a steady delivery rate and
the chlorate candle is preferably clamped between shock absorbing
filters which are also effective to filter out contaminants.
In one preferred form of the invention, one end of the can has an
insulated contact point extending therefrom connected to a nichrome
bridge wire grounded in the can. When the contact point receives an
electrical charge from a battery, the nichrome wire is heated to
ignite a pyrotechnic starter for the chlorate candle.
In another preferred form of the invention, one end of the can has
a metal thimble suspended therefrom partially filled with a
starting chemical and slidably supporting a sealing piston from
which depends a piercing point. When the piston is depressed in the
thimble, the pin punctures the end wall of the thimble and the
piston injects the chemical into starter material on the
candle.
The oxygen generating cans of this invention have outlet orifices
in an end thereof which are conveniently covered by an overlying
seal in a dispensing unit to deliver the oxygen to a canula or
breathing mask.
An important feature of the invention is the low cost of mass
producing the oxygen generator cans of this invention and the long
shelf life of the cans without loss of oxygen generating capacity
or danger of exploding. The cans are easily sealed by pressure
sensitive impervious tapes, will not freeze, and cannot be
activated even at very high temperatures until properly
triggered.
It is then an object of this invention to provide safe disposable
chemical oxygen generator cans with self-contained starters.
Another object of this invention is to provide an oxygen generator
cell capable of delivering oxygen suitable for breathing at a
controlled steady rate and sufficiently inexpensive to be discarded
after use.
A still further object of this invention is to provide a
lightweight, convenient oxygen generating canister having a long
safe shelf life, capable of being instantly triggered for use and
inexpensive enough to be discarded after use.
A specific object of this invention is to provide an oxygen
generator cell in the form of a conventional tin can having an
easily sealed delivery orifice and an externally actuated
starter.
Another object of the invention is to provide a chlorate candle
oxygen generator housed in a conventional tin can and protected
against shock by end filter pads.
A further specific object of this invention is to provide a
chlorate candle of tapered configuration in a standard tin can
having a delivery orifice at one end thereof and an igniter
chemical initiating decomposition of the large end of the candle
with the taper of the candle developing a diminishing reaction area
to maintain a steady oxygen delivery rate as the reaction
progresses at increasing temperatures.
Another specific object of this invention is to provide an oxygen
generator cell easily dropped into a dispensing unit and activated
to deliver medically pure oxygen to a canula or oxygen mask.
Other and further objects of this invention will be apparent to
those skilled in this art from the following detailed description
of the annexed sheets of drawings, which by way of preferred
examples illustrate several embodiments of this invention.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of one form of oxygen generator cell
of this invention;
FIG. 2 is a vertical cross-sectional view along the line II--II of
FIG. 1;
FIG. 3 is a view similar to FIG. 2 but illustrating the condition
of the cell after ignition and during oxygen generation;
FIG. 4 is a perspective view similar to FIG. 1 but illustrating
another form of the cell of this invention;
FIG. 5 is a cross-sectional view taken along the line V--V of FIG.
4;
FIG. 6 is a view similar to FIG. 5 but illustrating the condition
of the cell after ignition and during oxygen generation;
FIG. 7 is an enlarged fragmentary cross-sectional view of the
thimble and plunger detail of the unit of FIGS. 4-6;
FIG. 8 is a vertical cross-sectional view similar to FIGS. 2 and 5
but illustrating another modification of the cell;
FIG. 9 is a somewhat diagrammatic sectional view with parts in
elevation illustrating the manner in which the units of FIGS. 1-3
or 8 may be mounted in a dispensing apparatus for discharging
oxygen to the inlet tube of an oxygen mask or the like;
FIG. 10 is a view similar to FIG. 9 but illustrating the manner in
which the unit of FIGS. 4-7 may be mounted in the dispensing
apparatus;
FIG. 11 is a fragmentary cross-sectional view of another form of
igniter for the generator cells of this invention.
BRIEF DESCRIPTION OF THE PREFERRED EMBODIMENTS
The unit 10 of FIGS. 1 to 3 includes a tin-plated steel can 11
having a cylindrical body 12, a flat circular lid 13 and a flat
circular bottom 14 sealed to the cylindrical body with the
conventional rolled peripheral edges or rims 15. The can 11 may be
of any convenient size to house a predetermined supply of oxygen
generating chemicals. A preferred can size is 2 inches in diameter
and 4 inches in length.
The lid 13 has a central aperture closed by an electrical insulator
plug 16 having a contact pin 17 extending through the center
thereof. The bottom 14 of the can has a circular central aperture
18 providing an outlet orifice. A sealing cover 19 composed of
pressure sensitive impervious tape or label material is cemented
over the orifice 18 and can be easily peeled from the bottom face
of the end wall 14 to expose the orifice for use.
As shown in FIG. 2, the contact pin 17 has one end of a bridge wire
20 soldered thereto inside of the can, while the other end of the
wire 20 is soldered to the inner face of the lid 13. This wire 20
is composed of electrical resistance material that will heat up
when current is flowed therethrough. Nichrome wire is
satisfactory.
A bead 21 composed of pyrotechnic chemicals is placed on the wire
20 to insure rapid ignition when the wire is heated. A mixture of
zirconium, nickel and potassium perchlorate is useful and only a
small amount need be used to provide an "electric match" causing
ignition when current flows through the bridge wire 20.
A pair of ceramic mats 22 and 23 composed of fiberglass or the like
inert felt-like material surround the "electric match" and have
apertures 24 therethrough freely embracing the "electric match."
The mats are somewhat resilient and have good heat insulation
properties.
An oxygen generating pellet 25 underlies the mat 23 and has a
generally inverted frusto-conical configuration. The pellet 25 has
a top layer 26 of "first fire" material overlying a slower burning
pyrotechnic material layer or "cone" 27 which in turn overlies the
main chlorate candle body 28. The layer 26 is relatively thin and
may be composed of a conventional first fire zirconium/barium
chromate mixture containing about 21 percent zirconium by weight.
Some of this same mixture 26 may fill or partially fill the
apertures in the mats 22 and 23. The "first fire" mixture ignites
the "cone" 27 which may have the following composition:
iron powder 20% by weight NaClO.sub.3 42% by weight Na.sub.2
O.sub.2 8% by weight Fe.sub.2 O.sub.3 14% by weight Cu.sub.2 O 12%
by weight Super-floss (product of Johns-Manville, New York, N.Y. 4%
by weight
The main chlorate candle body 28 is composed of an intimate mixture
of sodium chlorate (NaClO.sub.3) and a sodium oxide catalyst,
preferably sodium peroxide, although sodium monoxide may be used in
place of some of the peroxide since it will oxidize to the
peroxide. The catalyst content is controlled to regulate the
burning rate of the candle and may widely vary from 0.5 to 20
percent by weight. The entire pellet 25 is compressed into a solid
self-sustaining inverted frusto-conical shape with the small end at
the bottom to decrease the area of the burning front as temperature
increases during the burning of the candle, thereby maintaining a
steady oxygen generating rate.
The maximum temperature developed during the burning of the candle
is well below any temperature that would weaken the can or cause a
fire hazard. Heretofor chlorate candles contained added fuels such
as iron, charcoal, magnesium and the like to maintain the reaction
and commercial "tin cans" could not be used as housings because
they would not withstand the reaction temperatures. Maximum
operating temperatures of 400.degree. F. or less are now
provided.
The small end of the pellet 25 rests on a thin mica disk 29 loosely
fitted in the can above the bottom wall 14 thereof and another
ceramic mat 30 which underlies this mica disk and in turn overlies
a layer of sodium peroxide 31 bottomed by a thin ceramic mat 32. A
layer of odor absorbing pellets 33 underlies the layer 31. The
pellets 33 can be "Purafil" (a product of Marbon Chemical Co.,
Washington, W. Va.). Another filter mat 34 underlies the pellets 33
and rests on the bottom 14 of the can covering the orifice 18.
Glass wool is a suitable material for the filter mats.
From the above description, it will be understood that the oxygen
generating pellet 25 is clamped between the ends of the can on
resilient filter mats effective to protect the candle against shock
and maintain it centered in spaced relation from both the top and
bottom of the can.
As shown in FIG. 3, when the "electric match" is fired, the first
fire layer 26 burns away leaving some ash 26a and ignites the cone
27 which burns rather slowly to maintain a reaction temperature for
the sodium chlorate candle body 28. The candle will react
downwardly, releasing oxygen to flow as indicated by the arrows
around the mica disk 29 and through the stack of ceramic mats and
filter layers to discharge out of the orifice 18. The seal cover 19
for the orifice 18 is, of course, removed.
It should be understood that the sodium chlorate/oxide candle
yields pure oxygen and the filter material removes any contaminants
that might initially be formed from the starting materials.
The oxygen generating unit 40 of FIGS. 4 to 6 is also housed in the
same "tin can" type housing 41 as the unit 10. The housing 41 has a
cylindrical main body 42 with a flat disk top 43 and an imperforate
flat disk bottom 44. The conventional sealing rims or beads 45
connect the cylindrical body with the top and bottom.
A ring of small diameter holes 46 are formed through the lid 43
surrounding a central large diameter hole or opening 47 and a
pressure sensitive sealing cover 48 is adhesively secured to the
top of the lid 43 overlying the holes 46 and 47.
As shown in FIGS. 5 to 7, an open topped, closed bottom metal
thimble 49 mates with the central hole 47 in the lid 43 and has an
out-turned flange 50 soldered or brazed to the underface of the lid
in sealed relation as at 51.
As shown in FIG. 7, the thimble 49 is of slightly larger diameter
than the hole 47 so that the peripheral margin of the hole 47 will
overlie the open top mouth 52 of the thimble. The cylindrical side
wall of the thimble is of a desired length to house a sufficient
amount of ignition inducing chemical 53 under a plunger or piston
54 slidable in the thimble and having sealing ribs 55 sealingly
engaging the cylindrical wall of the thimble. A pin 56 with a
pointed end is anchored in the piston 54 and depends therefrom with
its point 57 resting on the relatively thin bottom 58 of the
thimble. When the piston 54 is depressed in the thimble, the pin
will puncture the thin bottom 58 and the piston head or plunger
will eject the fluid 53 into the upper portion of the housing 41
releasing the chemical for its function in igniting the candle, as
will be more fully hereinafter described.
As shown in FIGS. 5 and 6, the thimble 49 is surrounded by a pair
of ceramic mats 59 composed of fiberglass, glass wool or the like
and these mats in turn overlie the main pellet body 60 of the
oxygen generating candle. This pellet 60, like the pellet 25 of the
FIG. 1 to 3 embodiment, is of inverted frusto-conical shape with
the small end thereof resting on a thin mica disk 61 which in turn
overlies another ceramic mat 62 resting on the bottom 44 of the
can.
The pellet itself has a central cone 63 of material that will react
with fluid ejected from the thimble 49 to generate heat sufficient
for igniting the main oxygen generating body 64 of the pellet.
The starting cone 63 is composed of a loose powder mixture of
sodium iodate (NaIO.sub.3), sodium monoxide (Na.sub.2 O) and barium
perchlorate Ba(ClO.sub.4).sub.2. The iodate constitutes about
one-half of the mixture, the sodium oxide about 35% of the mixture,
and the barium perchlorate the balance. This formulation may be
varied using calcium perchlorate Ca(ClO.sub.4).sub.2 in place of
the barium and adding around 10 percent of zinc peroxide. In
general, the cone 63 can be composed of from 10-85 percent by
weight of an alkali metal or alkaline earth metal iodate from 10-70
percent of sodium monoxide, and from 10-70 percent of an auxiliary
oxidizer such as calcium or barium perchlorate, zinc peroxide and
the like.
The fluid 53 for igniting the cone 63 may be water, which will
initiate an exothermic reaction of the iodate mixture developing
sufficient heat to ignite the body material 64 of the chlorate
candle pellet 60. From 10-20 grams of the iodate mixture are
sufficient to ignite the candle body 64 and only about 0.1 cc of
water is needed to activate the cone. A freezing depressant such as
calcium chloride may be added to the water.
It will be noted that no chemical filtration is used in the water
activated unit 40 since the chemical starting material does not
produce contaminants.
The water activated unit 40 of FIGS. 4 to 6 may be modified as
shown in FIG. 8 to provide for electric match ignition in place of
water ignition. In FIG. 8, the unit 70 has the same components as
the unit 40 and identical parts have been marked with the same
reference numerals. The unit 70 like the unit 10 has a bottom
outlet orifice 18. In place of the thimble 49, an electric match
bridge wire arrangement 71 is provided similar to the electric
match arrangement of FIGS. 1 to 3. The match is surrounded by a
first fire mixture of zirconium and barium chromate 72. Plugs of
iodate ignition mixtures 73 and 73a underlie the first fire
material and are separated by a thin copper foil barrier 74. The
iodate ignition cone 75 overlies the generator body 69. The copper
foil barrier serves to prevent contaminants from the electric match
and first fire material from entering the oxygen generating zone of
the can 70. The first fire material and the plug of the iodate
mixture overlying the copper foil will heat the foil sufficiently
high to ignite the underlying iodate ignition cone 75.
In still another modification the unit 70 may be revised as in FIG.
11 where a unit 70a is partially shown as having a percussion cap
igniter in place of the electric match type igniter. In FIG. 9 a
heavy central brass washer 76 is spun into the center of the lid 43
and has a percussion cap 77 pressed into its aperture. This cap
when struck by a pin will ignite the underlying first fire material
78 which may be first fire or the iodate plugs of the unit 70. The
candle 60 underlying the ignition cone 75 will discharge oxygen
through a bottom outlet 18 as in the unit 70.
As shown in FIG. 9, the unit 10 of FIGS. 1 to 3 may conveniently be
dropped into an oxygen dispensing apparatus 80 which has an upright
cylindrical side wall 81 with a perforate bottom 82 and a perforate
lid 83 hinged to the body 81 at 84. The bottom 82 carries upwardly
projecting wire guide fingers 85 into which the unit 10 may
conveniently be dropped and held in position in spaced relation
from the side wall 81 in the unit 80. The cover 83 carries an
ignition contact member 86 engaging the contact point 17 of the
unit when the lid is closed. The orifice 18 in the bottom of the
unit 10 is surrounded by a rubber lip seal 87 discharging to an
outlet tube 88 which may be connected with an oxygen mask or the
like. When electric current is flowed through the contact point 86
to ignite the unit 10, oxygen will flow from the outlet 18 into the
tube 88 with the can sealingly clamped against the resilient
support 87 by the lid 83. Of course, the sealing cover 19 is
previously removed from the orifice 18. The apparatus 80 of FIG. 9
will also accommodate the modified unit 70 of FIG. 8 and has a
battery charged electrical circuit for energizing the contact point
86 to fire the electric match.
The apparatus 80 can be modified to accommodate the unit 70a by
replacing the contact 86 with a percussion cap striking pin.
The apparatus 90 of FIG. 10 will accommodate the chemical actuated
unit 40 of FIGS. 4-6 and it has a cylindrical side wall 91 with a
perforate bottom 92 and a perforate hinged lid 93 connected to the
top of the body 91 by a hinge 94. The lid 93 has a resilient lip
seal 95 depending therefrom adapted to surround the orifices 46 in
the top of the unit 60. A push-button 96 is carried by the lid 93
and has a depending pin 97 to engage the plunger 54 forcing its pin
to puncture the thimble 49 and inject the chemical fluid into the
ignition cone 63. The lip seal arrangement 95 discharges into the
feed tube 98 of an oxygen mask or the like.
It will be understood that the receivers 80 and 90 of FIGS. 9 and
10 are illustrative only of the type of receiver or dispensing
apparatus that can be used to dispense the gas from the units of
this invention.
The oxygen generators of this invention operate at sufficiently low
temperatures so that no fire hazards are involved and inexpensive
"tin can" housings can be used. The oxygen producing candle is
shock insulated on mats in the can and chemical filters or
separators are provided in the can if the starting materials yield
some gaseous contaminants or are eliminated if the starter
materials do not contaminate the oxygen. Thus only pure oxygen is
discharged.
* * * * *