U.S. patent number 3,735,599 [Application Number 05/104,986] was granted by the patent office on 1973-05-29 for process for automatic control of air separation apparatus.
This patent grant is currently assigned to Kobe Steel, Ltd.. Invention is credited to Tetsuo Izumichi, Matsuzi Miyazaki, Sadayuki Nakanishi.
United States Patent |
3,735,599 |
Izumichi , et al. |
May 29, 1973 |
PROCESS FOR AUTOMATIC CONTROL OF AIR SEPARATION APPARATUS
Abstract
In an air separation apparatus which comprises a reversing heat
exchanger, an air liquefier, a single column rectifier provided
with a condenser-evaporator and a cold generation device and
wherein air is cooled in the reversing heat exchanger and liquefied
in the air liquefier, the liquefied air is rectified in the single
column rectifier to separate into liquid air abundantly containing
oxygen and highly pure nitrogen gas, the liquid air being subjected
to heat exchange in the condenser-evaporator, the resulting
gasified air being subjected to heat exchange in the air liquefier
and sent through the reversing heat exchanger to the cold
generation device and the resultant liquefied air being sent
through the air liquefier and the reversing heat exchanger to
release, a process for controlling the generation of cold which is
characterized in that a by-pass channel is provided for
communicating a position on a passage between the
condenser-evaporator and the air liquefier and a position on a
passage between the cold generation device and the air liquefier, a
control valve is provided on the by-pass channel and the opening
degree of the control valve is automatically controlled so as to
regulate appropriately the flow volume of the gaseous air passing
through the by-pass channel whereby the level of the liquid air in
the condenser-evaporator is kept constant and the rectification of
the liquefied air in the single column rectifier is carried out
under stable conditions.
Inventors: |
Izumichi; Tetsuo (Takarazuka,
JA), Nakanishi; Sadayuki (Kobe, JA),
Miyazaki; Matsuzi (Kobe, JA) |
Assignee: |
Kobe Steel, Ltd. (Kobe-shi,
Hyogo-ken, JA)
|
Family
ID: |
11539431 |
Appl.
No.: |
05/104,986 |
Filed: |
January 8, 1971 |
Foreign Application Priority Data
Current U.S.
Class: |
62/651;
62/656 |
Current CPC
Class: |
F25J
3/044 (20130101); F25J 3/04284 (20130101); F25J
3/04793 (20130101); F25J 2205/24 (20130101); F25J
2250/40 (20130101); F25J 2250/42 (20130101); F25J
2280/02 (20130101); F25J 2290/10 (20130101); F25J
2205/84 (20130101); F25J 2200/72 (20130101); F25J
2250/52 (20130101) |
Current International
Class: |
F25J
3/04 (20060101); F25j 003/00 (); F25j 003/02 ();
F25j 003/04 () |
Field of
Search: |
;62/13,14,15,21,27,28,29,39,40,37 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Yudkoff; Norman
Assistant Examiner: Purcell; Arthur F.
Claims
What is claimed is:
1. In an air separation apparatus which comprises a reversing heat
exchanger, a single column rectifier connected to said reversing
heat exchanger for receiving cooled air therefrom, said rectifier
having a condenser-evaporator, an air liquifier connected to said
rectifier for receiving gaseous air therefrom and returning it to
said rectifier after cooling it, a vaporized air line from the
rectifier on the evaporater side of said condenser evaporator to
said air liquifier, a cold generation device coupled to said air
liquifier for receiving air from the air liquifier through the
reversing heat exchanger and expanding it, and an expanded air line
from said cold generation device to said air liquifier, the
liquified air from the air liquifier being rectified in the
rectifier to separate into liquid air rich in oxygen and highly
pure nitrogen gas, the liquid air being subjected to heat exchange
in the condenser-evaporator and the resulting vaporized air being
subjected to heat exchange in the air liquifier and cooled in the
cold generation device and again being subject to heat exchange in
the air liquifier, and then being sent through the reversing heat
exchanger and discharged, that improvement comprising means for
controlling the cold generating device comprising a by-pass line
connected between the vaporized air line downstream of said
rectifier and the expanded air line from the cold generation
device, a control valve in said by-pass line and control means
connected between said control valve and the rectifier and
responsive to the liquid air level in the condenser-evaporator
portion of said rectifier for moving said control valve toward the
open position when said level rises and moving said control valve
toward the closed position when said level falls, whereby the level
of liquid air in the condenser evaporator is kept constant and the
rectification of the liquified air in the rectifier is carried out
under stable conditions.
2. The improvement as claimed in claim 1, wherein the control means
stops the control valve at the time when the pressure on the
evaporation side of the condenser-evaporator has varied to a
certain extent from a set value so as to control the time lag
during recovery of the liquid level.
3. A method for automatic control of an air separation apparatus
having a single column rectifier provided with a
condenser-evaporator which comprises flowing vaporized air from the
evaporator side of said condenser-evaporator through an air
liquifier, a heat exchanger and an expansion type cold generation
device and then back through said air liquifier, by-passing a
portion of the vaporized air through a control valve from the
evaporator condenser to the output side of the cold generation
device, changing the degree of opening of the control valve in
response to the level of liquid air on the evaporation side of the
condenser-evaporator for controlling the flow of the bypassed part
of the vaporized air to adjust the flow ratio of said part relative
to that of the other part of said vaporized air which is passed
through a cold generating device and fixing the amount of opening
of the control valve when the pressure on the evaporation side has
varied to a predetermined extent from the pressure existing before
the change of the degree of opening of the valve.
Description
The present invention relates to a process for automatic control of
an air separation apparatus. More particularly, it relates to a
process for automatically controlling the rectifying conditions in
a single column rectifier and the cold generating conditions of a
cold generation device with the stabilized operation of an air
separation apparatus.
In an air separation apparatus comprising a single column rectifier
provided with a condenser-evaporator and a cold generation device
such as an intermediate pressure expansion turbine, the starting
material, i.e., air, is liquefied using the cold generated in the
cold generation device, the liquefied air is rectified in the
single column rectifier and the waste gas formed in the
condenser-evaporator is sent to the cold generation device for
utilization as the source of cold. Among various factors for
generation of cold in the cold generation device such as the
pressures at the inlet and the outlet, the temperature and the flow
volume, the pressure at the inlet and the flow volume are closely
related to the pressure on the evaporation side and the evaporation
volume in the condenser-evaporator of the single column rectifier.
The over-and-under rate of the cold in the entire air separation
apparatus is judged on whether the liquid level of the evaporation
side in the condenser-evaporator is in an ascending direction or in
a descending direction. When the cold has run short and accordingly
the liquid level begins to show a descending tendency, the pressure
at the inlet of the cold generation device is required to rise or
the flow volume in the cold generation device must be increased.
When the cold is in excess and hence the ascending tendency of the
liquid level is recognized, the pressure at the inlet of the cold
generation device is required to fall or the flow volume in the
cold generation device should be decreased. In order to carry out
rectification under stabilized conditions, however, the pressure
and the volume of air being treated in the single column rectifier
should not be abruptly changed. As stated above, the waste gas
formed in the condenser-evaporator provided on the single column
rectifier is supplied to the cold generation device. Therefore, the
raising or lowering of the pressure at the inlet of the cold
generation device results in raising or lowering of the pressure at
the evaporation side of the condenser-evaporator. Such variations
in the pressure will inevitably cause a considerable change in the
pressure and the volume of air being treated in the single column
rectifier so that stabilized conditions for rectification can not
be assured.
If the variation of the pressure on the evaporation side of the
condenser-evaporator is permitted, the maintenance of the pressure
on the condensation side constant will result in a change of the
temperature difference between the condensation side and the
evaporation side whereby the heat exchange is increased or
decreased, i.e., the volume of air being treated in the single
column rectifier will change. If the volume of air being treated is
kept constant, then the pressure on the condensation side must be
varied so as to make constant the temperature difference between
the condensation side and the evaporation side.
The above facts can be expressed in terms of concrete numerical
values by way of an example where the operation is supposed to be
according to the following conditions:
volume of air: W = 1,000 Nm.sup.3 /h;
Pressure on the condensation side: 6.4 atg (condensation
temperature of gaseous nitrogen: -173.5.degree.C);
Pressure of liquefied air containing 49 percent oxygen on the
evaporation side: 3.4 atg (evaporation temperature:
-175.5.degree.C);
Temperature difference between the condensation side and the
evaporation side of the condenser-evaporator: .DELTA.T =
2.degree.C;
Rate of heat transfer: Q = 33,200 Kcal/h.
Under the above conditions, a change of the pressure on the
evaporation side by 0.2 kg/cm.sup.2 corresponds to a change of the
evaporation temperature of liquid air on the evaporation side by
0.5.degree.C. Thereupon,
a. Pressure on the condensation side being constant:
The temperature difference of the condenser-evaporator is .DELTA.T
= 2 .+-. 0.5.degree.C. In the equation Q = UA.DELTA. T wherein U is
the overall heat transfer coefficient and A is the heat transfer
area, A is constant and U is also approximately constant, and the
rate of heat transfer Q is varied. Accordingly, the volume of air
treated will become W = 1,000 .+-. 250 Nm.sup.3 /h and thus the
rate of variation of treated air will come to .+-. 25 %.
b. Volume of treated air being constant (i.e. heat exchange being
constant)
Since Q is constant, the pressure on the condensation side is
changed so that T will become constant and also the temperature on
the condensation side changes by .+-.0.5.degree.C, pursuant to the
temperature change of 0.5.degree.C on the evaporation side. The
change of pressure corresponding to the afore-mentioned temperature
will come to 0.35 kg/cm.sup.2 and, in turn, with the magnitude of
pressure being 6.4 .+-. 0.35 atg, the rate of variation of pressure
on the condensation side becomes .+-. 5.5 percent.
As will be understood from the above explanation, the pressure
variation on the condensation side of the condenser-evaporator
exerts a great influence on the rectifying conditions in the single
column rectifier. For carrying out the rectification under
stabilized conditions, it is necessary to preclude variations of
the pressure and the volume of air being treated in the rectifier
as much as possible. On the other hand, it is indispensable to
regulate the pressure on the evaporation side, i.e., the inlet
pressure of the cold generation device, when the heat balance of
the entire apparatus is taken into consideration.
According to the present invention, there is provided a method for
controlling the generation of cold in an air separation apparatus
comprising a single column rectifier provided with a
condenser-evaporator, a cold generation device and a passage
connecting the condenser-evaporator and the cold generation device,
the passage having a by-pass channel connected to the outlet side
of the cold generation device, where the starting air is liquefied
with the cold generated in the cold generation device, the
liquefied air is rectified in the single column rectifier, and the
waste gas formed in the condenser-evaporator is partly supplied to
the cold generation device through the passage and the remaining
waste gas to the by-pass channel, which is characterized in that
the flow volume of the waste gas to the by-pass channel is
controlled by the variation of the liquid level on the evaporation
side of the condenser-evaporator.
The present invention will be illustrated in detail by way of an
example referring to the accompanying drawings wherein
FIG. 1 is a flow sheet showing a nitrogen producing apparatus as a
preferred embodiment of the invention and
FIG. 2 is a diagram with curves showing an example of the
controlling of the liquid level and the pressure on the evaporation
side of the condenser-evaporator by the opening of a control valve
provided on the by-pass channel.
In FIG. 1, the starting air is supplied through tube 1 and
compressed in a compressor 2. When the production of gaseous
nitrogen alone is carried out, for instance, compression can be up
to around 6 to 7 kg/cm.sup.2. When the simultaneous production of
liquid nitrogen is desired, compression up to around 8 to 9
kg/cm.sup.2 can be effected. The compressed air goes through a
conduit tube 3 to the higher temperature portion 4 and the lower
temperature portion 5 of a reversing heat exchanger where heat
exchange with returning gas is performed. The air thus cooled
nearly to the liquefying temperature is sent through a check valve
6 and a conduit tube 7 and enters into the bottom portion of a
single column rectifier 8 where the air is liquefied and separated
into liquefied air containing an abundant amount of oxygen and
gaseous air containing nitrogen in a high concentration. The
gaseous air taken out through a conduit tube 10 is heat exchanged
with returning gas in an air liquefier 9 and the resulting
liquefied air is returned through a conduit tube 11 to the bottom
portion of the rectifier 8.
The liquid air at the bottom portion of the rectifier 8 is sent
through a conduit tube 12 to a filter 13 where impurities such as
CO.sub.2 and hydrocarbons are absorbed and eliminated. Then, the
filtered liquid goes on through a flow control valve 14 where the
pressure is reduced to around 3 to 4 kg/cm.sup.2 and enters into
the evaporation side 15 of a condenser-evaporator 16. In the
condenser-evaporator 16, the liquid air is heat exchanged with the
nitrogen gas of high purity from the top portion of the rectifier 8
through a conduit tube 17 whereby the nitrogen gas is liquefied.
The liquefied nitrogen flows through a conduit tube 18 to the top
portion of the rectifier 8. On the other hand, the liquid air is
vaporized as the result of the heat exchange and goes on through a
conduit tube 19 for utilization as returning gas.
A major portion of the above vaporized air flowing through the
conduit tube 19 is sent through a conduit tube 20 to the liquefier
9 and flows through a conduit tube 21 where it is separated into
two portions, one of them going through a control valve 22 and a
conduit tube 23 to the lower temperature portion 5 for heat
exchange with the starting air coming from the compressor 2 to
liquefy CO.sub.2 therein and then flowing through a conduit tube 24
and a control valve 25 to an expansion turbine 26. The other
portion is sent from the conduit tube 21 through a control valve 27
and combined with the above returning gas. The combined gas is
expanded in the expansion turbine 26 nearly to atmospheric pressure
whereby any thermo-dynamic exterior work is performed and the
temperature is lowered remarkably to generate the cold sufficient
to fulfill the demand for the apparatus. The expanded gas flows
through conduit tubes 28 and 29 to the liquefier 9 and then goes
through a conduit tube 30 and the check valve 6 to the reversing
heat exchanger. The gas is warmed to room temperature as the result
of the heat exchange with the starting material air and then
discharged through a conduit tube 31.
A minor residual portion of the vaporized air flowing through the
conduit tube 19 flows through a by-pass channel 33 and a control
valve 32 and, after being combined with the gas from the conduit
tube 28, goes on through the conduit tube 29. The control valve 32
regulates the flow volume and the pressure at the inlet of the
expansion turbine 26 and thus controls the generation of cold. When
the liquid level of the liquid air on the evaporation side 15 of
the condenser-evaporator 16 drops lower than a set level, the
control valve 32 moves toward the closed position whereby the flow
volume in the expansion turbine 26 is increased and the level of
the liquid air in the condenser evaporator increases toward the set
level. When the liquid level goes higher than the set level, the
control valve 32 is operated to move toward the open position
whereby the flow volume in the expansion turbine is decreased and
the level of the liquid air decreases toward the set level.
It should be noted that, when the control valve 32 is moved toward
the closed position in such a manner that the pressure on the
evaporation side 15 of the condenser-evaporator 16 is increased
abruptly, there is a danger of disturbing the stabilized rectifying
conditions of the single column rectifier; and besides, there will
be a considerable time lag from the action of the control valve 32
to the actual return to the set liquid level.
For preventing the overrunning of the control valve 32, it is
recommended to provide a mechanism which permits the pressure on
the evaporation side 15 of the condenser-evaporator 16 to deviate
within certain upper and lower limits from the pressure level
before the control valve 32 starts extreme corrective action.
In FIG. 2 which shows the operation of the apparatus under the
control of such a mechanism, there are shown the relative
variations of the liquid level L of the liquid air on the
evaporation side 15 of the condenser-evaporator 16, the pressure P
on the evaporation side 15 and the degree of opening V of the
by-pass control valve 32 with the time t. In the case where the
liquid level varies, starting from the time t.sub.1, to drop lower
than the set limit value Lo, the pressure on the evaporation side
15 of the condenser-evaporator 16 is raised from the set valve Po
upwards by .theta.', which corresponds to the degree of level
displacement .theta.; and at the same time, the control valve 32 is
activated to move toward the closed position so as to increase the
flow volume in the expansion turbine 26. While .theta.'/.theta. is
optionally adjustable, the controlling arrangement should be such
that a drastic pressure variation does not occur with respect to
the liquid level. When the control valve 32 is moved toward the
closed position, if the liquid level restores itself as indicated
at e in the diagram and, along with it, the pressure P as well as
the degree of valve opening V also respectively move up to the
initial values Po and Vo, then the control is deemed satisfactory.
In the event, however, that the liquid level lowering still
continues and does not cease and, in turn, the pressure raises to
P.sub.H, then a control measure is taken to maintain the degree of
valve opening at V.sub.L which is the degree of opening for
pressure P.sub.H. An appropriate value for P.sub.H may be Po +
0.05.about. 0.1 kg/cm.sup.2. By establishing this condition, the
cold balance is successfully achieved without allowing the pressure
on the evaporation side 15 to go through a large change in the time
lag from the start of movement of the control valve 32 to the
actual recovery of the liquid level; in other words, the cold
balance can be maintained without impairing or disturbing the
rectifying conditions. If during the time the degree of valve
opening is maintained at V.sub.L, if the liquid level shows a
tendency to be restored as shown at d in the diagram, then the
pressure which has been maintained at P.sub.H until the recovery of
the liquid level to Lo will start to return towards Po as the valve
starts opening. If the liquid level still continues to fall, then a
control measure is taken to close the valve further so that the
pressure P goes up at the time when the liquid level has dropped to
L.sub.L. If the liquid level still continues to fall and the
pressure also continues to rise almost reaching the set limit in
spite of the above valve actuation, such trend is detected by means
of an alarm device or the like so that the initial set value of the
pressure or the value of .theta.'/.theta. can be appropriately
changed to achieve the restoration of the liquid level. When the
liquid level has once gone beyond the set limit degree of value
L.sub.L and come back to the same, the valve opening is kept at a
constant so as to maintain the pressure at the value at the moment
that the liquid level has reached L.sub.L ; afterwards, when the
liquid level reaches the initial set value L.sub.O or a certain
period of time elapses, the degree of valve opening is allowed to
change freely again and the regulation is continued depending on
the variation of the liquid level at that moment. The above
developments are shown by way of the symbols a, b and c in the
diagram.
When the apparatus is in a stable stage of operation, the liquid
level generally restores itself at the time t.sub.2 or t.sub.3 and
further supplementary control is seldom needed unless the heat
balance is disturbed by some external factor. But, the set value
may be appropriately changed depending on the temperature change
with the seasons after the time t.sub.3.
The above illustration is for the case where the liquid level falls
but the same may be applied to the case where the liquid level
ascends.
* * * * *