U.S. patent number 3,735,010 [Application Number 05/283,018] was granted by the patent office on 1973-05-22 for skull-melting crucible.
This patent grant is currently assigned to The United States of America as represented by the United States Atomic. Invention is credited to John N. Turpin.
United States Patent |
3,735,010 |
Turpin |
May 22, 1973 |
SKULL-MELTING CRUCIBLE
Abstract
This invention is directed to an improved crucible for skull
melting metals and alloys by employing consumable electrode
arcmelting procedures. The crucible is formed of a housing
containing a removable, relatively thin, cup-shaped liner and a
substantially conforming enclosed chambered volume through which
liquid metal is channeled and circulated for uniformly cooling the
liner.
Inventors: |
Turpin; John N. (Oak Ridge,
TN) |
Assignee: |
The United States of America as
represented by the United States Atomic (Washington,
DC)
|
Family
ID: |
23084133 |
Appl.
No.: |
05/283,018 |
Filed: |
August 23, 1972 |
Current U.S.
Class: |
373/76; 266/242;
266/232 |
Current CPC
Class: |
F27B
3/12 (20130101); F27B 3/085 (20130101); F27B
14/10 (20130101); F27D 9/00 (20130101) |
Current International
Class: |
F27B
3/12 (20060101); F27B 3/08 (20060101); F27B
3/10 (20060101); F27B 14/10 (20060101); F27B
14/00 (20060101); F27D 9/00 (20060101); F27d
001/12 () |
Field of
Search: |
;13/9,35 ;263/11,14,48
;266/39,43 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Envall, Jr.; Roy N.
Claims
What is claimed is:
1. An improved crucible within which metal can be skull melted and
cast by electric arc melting, comprising a housing having an end
wall and a tubulation laterally projecting therefrom, an open-ended
substantially hemispherical liner disposed within said tubulation
in spaced relation to said end wall and said tubulation and affixed
to latter adjacent the end thereof remote to said end wall for
defining an enclosed volume between said housing and said liner,
volume dividing means disposed within said volume intermediate said
liner and housing and encircling said liner for forming first and
second radially spaced apart chambers in said volume, passageway
means through said volume dividing means at a location adjacent the
end of tubulation remote to said end wall for placing said chambers
in registry with one another, conduit means penetrating said
housing and communicating with said first chamber as defined by the
liner and the volume dividing means at a location intermediate said
end wall and said liner for conveying a coolant into said volume in
a heat exchange relationship with said liner, and further conduit
means penetrating the housing and communicating with said second
chamber as defined by the tubulation and the volume dividing means
for removing coolant from the volume.
2. The improved crucible claimed in claim 1, wherein said volume
dividing means comprises an annular partition having a
configuration generally corresponding to the configuration of said
liner and disposed about and spaced from the latter for providing
said first chamber uniform cross-sectional area over the axial
length thereof with respect to the direction of coolant flow for
uniformly cooling the entire periphery of the liner encompassed by
the partition, and wherein support means are disposed in said
volume for maintaining said partition in position about said
liner.
3. The improved crucible claimed in claim 2, wherein a cylinder is
disposed in said volume in a contacting relationship with said end
wall and said liner and projecting through said partition at a
central location thereof, the first mentioned conduit means in
registry with the interior of said cylinder, and wherein
passageways in said cylinder provide the communication between the
first mentioned conduit means and said first chamber.
4. The improved crucible claimed in claim 3, wherein a portion of
said support means is provided by an annulus disposed in said
volume at a location adjacent to said passageway means and
separated from the latter by said further conduit means and in a
contacting relationship with said partition and said tubulation for
defining therewith said second chamber.
5. The improved crucible claimed in claim 4, wherein drain means
penetrate said housing and communicate with said volume for
draining coolant from the latter, and wherein said cylinder and
said annulus have apertures therethrough for placing said chambers
in registry with said drain means.
6. The improved crucible claimed in claim 1, wherein the liner is
formed of wrought copper, the liner is of an essentially uniform
thickness in the range of 0.5 to 1 inch, and wherein the coolant is
a liquid metal consisting of a mixture of sodium and potassium.
Description
BACKGROUND OF THE INVENTION
The present invention relates generally to a crucible in which
metals and alloys are skull melted and cast by consumable electrode
arc melting, and more particularly to such a crucible having an
improved construction including a relatively-thin, removable liner
which is uniformly cooled. This invention was made in the course
of, or under, a contract with the U. S. Atomic Energy
Commission.
Alloys and metals of high purity can be produced by melting the
alloy forming metals or the metal to be purified in a crucible by
employing well known electric arc-melting procedures. The crucibles
used for such arc-melting procedures are often those which provide
for a type of operation commonly known as skull melting and
casting. These crucibles are formed of a good electrical and
thermal conducting material such as copper and may be internally
cooled with a liquid metal having good electrical conducting
properties such as provided by a mixture of sodium and potassium
(NaK). As the arc melting occurs, the molten metal contacting the
relatively cool crucible wall cools and solidifies to form, in
effect, a shell or skull for containing the subsequently melted
metal. Ideally, the temperature difference between the cooled
crucible wall and the molten metal prevents fusion of the latter
with the crucible prior to forming the skull, but allows the
accumulation of liquid metal within the skull. Thus, upon
completion of the electrode melt and solidification of the metal
skull the liquid metal contained therein may be removed by tilting
the crucible.
While skull casting by arc melting has proven to be a highly
desirable technique of preparing alloys and purifying metal,
several shortcomings and drawbacks are present in the previously
known liquid-metal-cooled crucibles employed for skull casting. For
example, the vessels of such previous liquid-metal-cooled crucibles
are cast around the coolant channels which results in variable
effective wall thicknesses typically in the range of 0.5 to 4
inches. These thickness variations in the walls of the cast
crucible result in a concentration of thermal stresses and shocks
which crack the inner surface and with such cracks penetrating
through the vessel after a limited number of cycles. The coolant
channel arrangement of the prior art makes it difficult, if not
impossible, to thoroughly examine the thermodynamics of the heat
exchange process during melting and also causes troublesome
heterogeneity in the temperature profile of the vessel during
melting and casting operations. Further, the inadequate and
non-uniform cooling of the inner vessel surfaces often results in
fusion of the arc-melted metal skull with the crucible, which
condition significantly hampers the removal of the skull from the
vessel so as to substantially detract from the value of the
skull-casting procedure. Another drawback attendant with the
previously known crucibles is that the inner surface is integral
with the outer shell or housing so as to necessitate the removal of
the entire heat exchange system to effect repairs on any part of
the crucible. This structural design also limits the crucible to a
fixed, definite size. Since optimum crucible size is related to
electrode size and power input level, a crucible must be matched,
dimensionally, to the particular melting operation. Further, such
integral crucibles are difficult to repair, have a low melt
capacity total weight ratio, produce a thick skull requiring more
electrical power for arc melting, and have a lower overall
effective thermal efficiency.
SUMMARY OF THE INVENTION
It is the primary aim or objective of the present invention to
obviate or substantially minimize the above and other shortcomings
by providing an improved crucible for use in skull melting and
casting operations employing arc melting. The improved crucible
comprises a housing having an end wall and a tubulation laterally
projecting therefrom, an open-ended substantially hemispherical
liner disposed within said tubulation in spaced relation to said
end wall and said tubulation and affixed to latter adjacent the end
thereof remote to said end wall for defining an enclosed volume
between said housing and said liner, volume dividing means disposed
within said volume intermediate said liner and housing and
encircling said liner for forming first and second radially spaced
apart chambers in said volume, passageway means adjacent the end of
tubulation remote to said end wall for placing said chambers in
registry with one another, conduit means penetrating said housing
and communicating with the first chamber as defined by the liner
and the volume dividing means at a location intermediate said end
wall and said liner for conveying coolant into said volume in a
heat exchange relationship with said liner, and further conduit
means penetrating the housing and communicating with the second
chamber as defined by the tubulation and the volume dividing means
for removing coolant from the volume.
Other and further objects of the invention will be obvious upon an
understanding of the illustrative embodiment about to be described,
or will be indicated in the appended claims, and various advantages
not referred to herein will occur to one skilled in the art upon
employment of the invention in practice.
A preferred embodiment of the invention has been chosen for the
purpose of illustration and description. The preferred embodiment
illustrated is not intended to be exhaustive or to limit the
invention to the precise form disclosed. It is chosen and described
in order to best explain the principles of the invention and their
application in practical use to thereby enable others skilled in
the art to best utilize the invention in various embodiments and
modifications as are best adapted to the particular use
contemplated.
BRIEF DESCRIPTION OF THE DRAWING
In the accompanying drawing the FIGURE is a somewhat schematic,
perspective view showing, in section, the improved crucible
construction of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
As shown, the crucible generally indicated at 10 comprises a
housing 12 of stainless steel, or the like, and formed of an
open-ended tubulation 14 having an end wall or base 16 closing one
end thereof. A liner 18 of a generally hemispherical open-ended
configuration for containing the melt is disposed within the
housing in spaced relation to the end wall and the tubulation. The
liner 18 may be formed of wrought or spun copper with an
essentially uniform wall thickness in the range of about 0.5 to 1
inch. The liner is maintained within the housing by a flange 20
disposed about the bearing against or affixed to the periphery of
the liner at the uppermost or open end thereof. This flange is
secured to a lateral projection or shoulder 22 on the tubulation 14
by a bolting arrangement such as generally indicated at 24. A
gasket 26 of a suitable heat-resistant material such as asbestos
may be disposed between the flange and the housing projection 22
for sealing the liner to the housing.
With the liner disposed within the housing a volume 28 is formed
between the liner and the housing for holding the liquid metal
coolant, as will be described below. This volume 28 is, in turn,
divided into chambers 30 and 32 by an annular partition or baffle
34 which is positioned adjacent to the liner and has a shape
generally conforming to the configuration of the liner so as to
provide the chamber 30 with dimensions suitable for uniformly
cooling the entire periphery of the liner as will be described in
greater detail below. The partition 34 may be supported in position
within the housing by a ring 35 in contact with the base 16 and
carrying the partition and by an annulus 36 disposed near the top
of the partition and contacting the tubulation 14. The partition 34
has an aperture therein adjacent the base 16 for receiving a
centrally disposed cylinder 37 which provides support for the liner
as well as a manifoldlike structure for distributing the coolant
into the chamber 30. The communication between the cylinder 37 and
the chamber 30 may be provided by suitable passageways or openings
38 in the cylinder 37 which place the interior of the cylinder in
registry with the chamber 30. A coolant inlet conduit 40 projects
into the housing and into the interior of cylinder 37 for conveying
the coolant into the housing from a suitable source (not shown).
The partition 34 terminates at a location near the flange 20 on the
liner 18 so as to define a passageway 42 between chambers 30 and 32
whereby the coolant flowing within the chamber 30 can be diverted
from the latter and the housing through a suitable outlet once its
cooling function is completed. While the communication or
passageway between chambers 30 and 32 is shown as being provided by
the space between the flange 20 and the top of the partition 34, it
is to be understood that such communication may readily be provided
by openings in the partition similar to the openings 38 in the
cylinder 37. The coolant is removed from the housing by an outlet
conduit 44 which penetrates the housing and is in registry with the
chamber 32. In order to divert the coolant from chamber 32 into the
outlet conduit 44 the annulus or ring 36 is disposed about the
partition 34 at a location contiguous with the lower end of the
outlet conduit 44. The metal coolant in the volume 28 and chambers
30 and 32 may be removed by a drainage pipe 46 which communicates
with the volume 28 at a location near the base 16. Openings 48 in
the ring 36 and openings 50 and 52 in the cylinder 37 and ring 35,
respectively, provide relatively small passageways for the coolant
into the drain pipe 46. During the melting operation, metal coolant
is continually flowing through these openings but the quantity of
this flow represents only a minor portion of the total coolant flow
and is readily compensated for to assure adequate cooling of the
liner. The width of chamber 30 between the partition 34 and the
liner 18 is gradually decreased with respect to the axial direction
of coolant flow by the position of the partition 34 so as to
provide the chamber 30 with uniform cross-sectional area over the
axial length thereof. This decreasing width of the chamber 30
increases the velocity of the coolant as it flows through the
chamber 30 to insure uniform cooling of the liner.
In a typical skull-casting operation employing the crucible
constructed in accordance with the teachings of the present
invention uranium alloy can be prepared from scrap material with
the resulting casting having a weight in the range of about 100 kg
to 1,000 kg. To initiate the skull-casting operation the liner 18
is preferably thoroughly cleaned and dried. Loose pieces of the
desired alloy material having a thickness of about one inch are
then placed in the crucible for forming a surface against which the
electric arc may be struck. Normally, for the large castings about
150 kg of the scrap material may be employed for forming the
crucible skull and adequately provides a surface for the initial
arc strike of the consumable electrode. Of course, if a smaller or
larger casting is desired, less or more loose charge material may
be used. For a 1,000-kg melt, the consumable electrode may be
prepared by welding together pieces of melt stock material totaling
about 1,000 kg. The electrode is connected to a suitable high
current and low voltage electric power source through a movable
ram. After the inner shell of the crucible is charged with loose
pieces of metal and the consumable electrode prepared, the vacuum
arc-melting furnace is subjected to an inert (argon) atmosphere at
a pressure less than atmospheric, e.g., about 10 microns absolute
pressure. The crucible is then cooled with a NaK mixture with the
coolant flowing through the crucible coolant channels at a rate of
about 150 gallows per minute to maintain the surface temperature of
the crucible inner liner below about 200.degree.C. To start melting
the electrode, an arc is established between the metal charge and
the consumable electrode with a current of 10,000 amperes and 50
volts. Then, the current is increased to 25,000 amperes and 60
volts which rapidly melts the charge metal. As the molten metal
contacts the cooled liner, the molten metal contracts and
solidifies to form a thin crust or skull. The temperature of the
inner shell is maintained at 200.degree.C. or less whereas the
molten metal contained in the skull is about 1,600.degree.C. The
consumable electrode of scrap alloy is melted in the crust or skull
at a rate of about 40 kg/min. Upon completion of the melt the
molten metal in the skull is poured into a mold, cooled, and then
removed from the mold and cleaned.
With the afore-described construction the liner 18 may be readily
removed and replaced without necessitating the extensive expenses
heretofore required such as described above. Further, with this
construction, internal resistances can be designed so that the
coolant flow about the liner is at all times essentially uniform
and controlled so as to negate the aforementioned hot spots and
thermal stresses. The relatively thin liner and the uniform cooling
of the latter provide uniform heat removal during melting
operations to prevent a build-up of thermal stress and shock so as
to eliminate premature fractures and cracks in the liner as
heretofore suffered.
This coolant is preferably a liquid metal such as the NaK mixture
mentioned above which may be formed of 22 weight per cent sodium
and 78 weight per cent potassium for providing a melting point of
about -12.degree.C.
The improved crucible generates a thin skull which increases
melting efficiency of the crucible by lowering the required amount
of electrical power. Further, the high chill rate of the liner
immediately shrinks the molten metal in contact therewith which
effectively inhibits adhesion of the skull to the inner surface of
the crucible. This absence of adhesion limits the heat transfer
from the skull to the wall to insure a thin skull and provides for
relatively easy skull removal. Also, the absence of skull weldments
has prevented the contamination of the melt metal by the crucible
wall metal.
* * * * *