U.S. patent number 3,732,079 [Application Number 05/112,234] was granted by the patent office on 1973-05-08 for disposable plastic syringe for use in colorimetry.
This patent grant is currently assigned to Sterilizer Control Royalties. Invention is credited to Ward B. Davis.
United States Patent |
3,732,079 |
Davis |
May 8, 1973 |
DISPOSABLE PLASTIC SYRINGE FOR USE IN COLORIMETRY
Abstract
A disposable plastic syringe particularly for use in colorimetry
is formed by embossing a sheet of transparent synthetic plastic, or
otherwise forming in it, a bulbar cavity, and subsequently closing
the cavity by adhering a plane synthetic plastic sheet over the
cavity, the two sheets being either heated sealed or adhesively
joined together at the margins around the cavity. The cavity is
connected to the outside edge of the device by an embossed groove
which when attached to the plane sheet forms a tubular inlet or
outlet. The cavity is shaped as a truncated pyramid with a turret
closing the top, this turret forming a finger-pressable "button" by
which the syringe will draw in or expel liquid through the tubular
connection to the margin of the device. The volume of liquid drawn
into each specimen syringe is relatively accurately measured. A
partial coating, such as a stripe or spot, inside the bulbar cavity
using a color-change-indicator composition provides means for
making a colorimetric determination of the acidity or the content
of some individual constituent of the liquid drawn into the syringe
device.
Inventors: |
Davis; Ward B. (Glendale,
CA) |
Assignee: |
Sterilizer Control Royalties
(North Hollywood, CA)
|
Family
ID: |
26809721 |
Appl.
No.: |
05/112,234 |
Filed: |
February 3, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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800887 |
Feb 20, 1969 |
3620676 |
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Current U.S.
Class: |
422/408;
206/459.1; 422/944; 600/584; 116/206; 206/525; 422/430 |
Current CPC
Class: |
B01L
3/505 (20130101) |
Current International
Class: |
B01L
3/00 (20060101); G01n 001/14 (); G01n 031/22 () |
Field of
Search: |
;23/253,253TP,259
;206/43,17.5,56AA ;128/2R,231,232 ;116/114.19,114.20
;73/425.4,425.4P,441,442,443,446 ;222/215 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wolk; Morris O.
Assistant Examiner: Reese; R. M.
Parent Case Text
REFERENCE TO RELATED APPLICATIONS
This is a continuation-in-part of my pending application for
patent, Ser. No. 800,887 filed Feb. 20, 1969 now U.S. Pat. No.
3,620,676.
Claims
I claim:
1. A disposable syringe for use in making chemical analyses of
liquids comprising a molded resilient plastic body having a bulbar
cavity, and an inlet tube open at one end and communicating at the
other end with said cavity, said bulbar cavity being
finger-pressure-constrictable in volume so that upon release of the
pressure, a fixed volume of liquid is drawn into said cavity; and a
sufficient amount of a color-changing indicator composition is
enclosed within said cavity to effect a colorimetric analysis
therein when a liquid is drawn into it.
2. The syringe defined in claim 1 in which the color-changing
indicator composition is applied as a printed spot on the inside of
said cavity.
3. The syringe defined in Claim 1, in which at least a portion of
the body is transparent.
4. The syringe defined in claim 3, in which said body comprises a
plane backing sheet of plastic adhered to plane margins around a
figure embossed in a second sheet of plastic, said figure
consisting of an enlarged truncated rectangular pyramidal cavity,
and a tubular cavity extending from said pyramidal cavity to the
edge of said second sheet.
5. The syringe defined in claim 4 in which a rectangular turret is
formed atop said pyramidal cavity, said turret having upright walls
and being closed on top to provide a finger-pressable surface.
6. The syringe defined in claim 5, in which at least some of the
upright walls of said turret are provided with vertical reinforcing
flutes.
Description
BACKGROUND OF THE INVENTION
This invention relates to a portable disposable syringe made of
transparent plastic by which a sample of a liquid may be withdrawn
from a larger quantity, and the withdrawn sample may be
colorimetrically tested, either within the syringe itself, or in
another vessel into which the withdrawn sample is discharged. In
certain types of colorimetric measurements, for example in
measuring the concentration of free chlorine in an aqueous
solution, the volume of the sample in the syringe must be
accurately measured, and the volume must be the same from one
syringe to another in the same lot. The plastic syringe device,
generally, consists of an inlet tube open at one end, and at its
other end communicating with a finger-compressible bulb to draw in
and expel the contained fluid, after which the inherent resilience
of the material of the syringe restores the bulb to its original
volume. If the open end of the inlet tube is submerged in a liquid
sample, a measured portion is drawn into the bulb upon release of
the compressive finger pressure. If it is desired to make the
colorimetric analysis in the syringe, a suitable color-change
reagent is disposed in the bulb prior to filling it with the sample
of liquid to be tested. The color change reagent may be a dried
coating inside the bulb, which preferably is applied as a printed
spot of reagent upon the plastic sheeted material which constitutes
the back face of the device. The color-change reagent may be in
liquid form and injected into the bulb either before sucking in the
sample of liquid to be tested, or after the liquid has been
inspirated.
The principal object of the invention is to provide an inexpensive
syringe fabricated from sheet plastic, or otherwise formed, for the
purposes above stated. Another object is to provide a syringe-like
device which will, after compressive distortion, draw in a liquid
sample of known volume, and which may act as a reactive vessel for
colorimetric analyses, or which will subsequently expel a fixed
volume of the liquid to be tested into another reaction vessel.
These and other objects are attained by my invention, which will be
understood from the following description, reference being made to
the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a top plan view of the syringe-like device;
FIG. 2 is a side elevational view of the same;
FIG. 3 is an elevational view from the inlet tube end of the
device;
FIG. 4 is an elevational view from the end opposite the tube;
FIG. 5 is a bottom elevational view; and
FIG. 6 is a cross-sectional view taken on the line 6--6 of FIG.
1.
DESCRIPTION OF A PREFERRED EMBODIMENT
Referring to the drawings which show a preferred embodiment of the
invention, the syringe-like device consists of a rigid base 11,
which is a plane piece of plastic coated hard cardboard 12 to which
the formed bulb 13 may be attached (as by heat sealing) at its
outwardly projecting flanges 14, to form a water-proof container or
bulb. The bulb 13 consists of a rectangular pyramidal-shaped body
15 with its walls 16, 17, 18 and 19 tapering upwardly and joined to
the walls of a rectangular turret 20 which constitutes the "button"
upon which finger-pressure is applied in the operation of the
device. The side-walls 21 and 22 of the turret are preferably
stiffened by two vertical indented flutes 23. The flutes 23
strengthen the structure of the turret so that it moves downwardly
as a unit upon applying pressure of the finger, to constrict the
total volume of the bulb, and, upon releasing the finger pressure,
is restored to its original position because of the inherent
resiliency of the synthetic plastic material, for examples
polyvinyl chloride or styrene, from which the device is molded.
Other sheeted plastic materials having similar properties may be
used. The sheet thickness is preferably in the range of 6 to 10
mils.
An inlet tube 24 connecting the bulb 13 to the outer edge (of a
single cut-out unit) is formed by molding a rounded groove in the
flange 14 adjacent the end wall 16, and this groove forms a tubular
opening when the bulb molding is sealed to the base sheet.
A plurality of bulb cavities may be molded from large sheets, and
subsequently be die cut into the individual units before or after
heat-sealing the formed sheet at the flanges between units to the
plastic coated cardboard base. The base sheets before assembly may
be printed, flexographically, in spots or stripes, with a printing
ink comprising a color-change indicator composition. Other methods
of forming the complete bulb with inlet tube may be employed.
The indicator spot 25 or a stripe may be printed by any suitable
printing process, for example flexographically, on the inside face
of the base using a water soluble ink containing a colorimetric
reagent. One such composition consisted of the following essential
ingredients, in the approximate proportions which are not
critical:
Methanol 8 parts by weight 2 Ethoxyethanol 2 parts by weight Phenol
red dye 0.1 to 1.5 parts by weight.
* * * * *