U.S. patent number 3,730,668 [Application Number 05/145,728] was granted by the patent office on 1973-05-01 for combustion method of gas burners for suppressing the formation of nitrogen oxides and burner apparatus for practicing said method.
This patent grant is currently assigned to Tokyo Gas Company Limited. Invention is credited to Hirofumi Iida, Kazufumi Watanabe.
United States Patent |
3,730,668 |
Iida , et al. |
May 1, 1973 |
COMBUSTION METHOD OF GAS BURNERS FOR SUPPRESSING THE FORMATION OF
NITROGEN OXIDES AND BURNER APPARATUS FOR PRACTICING SAID METHOD
Abstract
The present invention relates to a novel method for suppressing
the formation of nitrogen oxides formed in the combustion of
gaseous fuels with air and a novel burner for practicing said
method. Said burner comprises a combustion chamber having a
converged nozzle portion formed at one end thereof and a draft tube
having an upwardly expanding vertical cross-section and spaced
ahead of said nozzle portion for guiding the combustion gases
exhausted from said combustion chamber.
Inventors: |
Iida; Hirofumi (Chiba City,
Chiba Prefecture, JA), Watanabe; Kazufumi (Yokohama
City, Kanagawa Prefecture, JA) |
Assignee: |
Tokyo Gas Company Limited
(Tokyo, JA)
|
Family
ID: |
11771549 |
Appl.
No.: |
05/145,728 |
Filed: |
May 21, 1971 |
Foreign Application Priority Data
|
|
|
|
|
Mar 3, 1971 [JA] |
|
|
46/11207 |
|
Current U.S.
Class: |
431/10; 431/12;
431/158 |
Current CPC
Class: |
F23C
9/006 (20130101); F23C 6/04 (20130101) |
Current International
Class: |
F23C
6/04 (20060101); F23C 6/00 (20060101); F23C
9/00 (20060101); F23m 003/04 () |
Field of
Search: |
;431/10,12,158 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: O'Dea; William F.
Assistant Examiner: Anderson; William C.
Claims
What is claimed is:
1. A combustion method for suppressing the formation of nitrogen
oxides issuing from gas burners, comprising introducing the
theoretical quantity of air for combustion into a combustion
chamber in its entirety, said combustion chamber being formed with
a nozzle portion and said combustion chamber having a
cross-sectional area 5-20 times that of said nozzle portion,
burning 60-90 percent of a fuel gas in said combustion chamber,
exhausting the combustion gases containing unburned fuel gas at a
high velocity through said nozzle portion and burning the unburned
fuel gas completely outside the burner apparatus by providing means
cooperating with said nozzle portion for drawing the combustion
gases in the furnace therefrom by said combustion gases jetting
from said nozzle portion.
2. A combustion method for suppressing the formation of nitrogen
oxides issuing from gas burners, according to claim 1, wherein a
secondary air supply in a quantity of 10 - 40 percent of the
theoretical quantity of air for combustion is passed along the
outer wall of said combustion chamber and the unburned fuel gas
contained in the combustion gases jetting from said nozzle port is
completely burned by said secondary air outside the burner
apparatus.
3. A burner apparatus so designed as to suppress the formation of
nitrogen oxides, comprising a combustion chamber having a converged
nozzle portion formed at one end thereof, said combustion chamber
having a cross-sectional area 5-20 times that of said nozzle
portion and a draft tube having an upwardly expanding vertical
cross-section and spaced ahead of said nozzle portion for guiding
the combustion gases exhausted from said combustion chamber.
4. A burner apparatus so designed as to suppress the formation of
nitrogen oxides, according to claim 3, wherein a secondary air
passageway is formed around said combustion chamber with one end
thereof open in the vicinity of said nozzle portion.
5. A burner apparatus so designed as to suppress the formation of
nitrogen oxides, according to claim 4, wherein one end of the
secondary air passage is closed in the vicinity of the nozzle
portion and the secondary air passage holes are formed in the
combustion chamber in the vicinity of said nozzle portion.
Description
This invention relates to a method for gas used in boilers, various
industrial heating furnaces, dryers, ovens, etc., whereby the
amount of nitrogen oxides contained in combustion gases are
minimized; and a burner apparatus for practicing said method.
As the major factors which have influence on the amounts of
nitrogen oxides contained in the combustion gases, there are
generally considered flame temperature, excess air ratio and
cooling velocity of flame. In this regard, various methods have
been employed in conventional fixed-type combustion apparatus for
suppressing the generation of nitrogen oxides, which are broadly
classified into the following two types: Namely, in one type, the
combustion gases are recirculated to lower the flame temperature,
and in the other type the amount of air required for the combustion
is fed slowly so as to control the combustion rate. However, the
former method has disadvantages in that the stability of the flame
is low, means must be provided for recycling the combustion gases
and thermal efficiency is low. On the other hand, the latter method
has the disadvantage that, since the mixing ratio of fuel gas and
air tends to be inconsistent, the excess air ratio must be made
slightly greater than with the ordinary combustion method, with the
result that the formation of nitrogen oxides is further promoted.
It has further disadvantages in that means must be provided for
supplying the secondary air and in that the combustion flame
becomes undesirably long.
The present invention has been achieved based on an entirely novel
concept of suppressing the formation of nitrogen oxides in the
oxidation of fuels such as hydrocarbons, e.g., natural gas, etc.,
with air, which as used here, includes air containing more or less
than the usual amount of oxygen. According to the invention, the
disadvantages of the conventional combustion methods can be
completely eliminated and the thermal efficiency can be markedly
enhanced.
The present invention will be described in detail hereinafter with
reference to the accompanying drawing which illustrate an
embodiment of the invention. In the drawings:
FIG. 1 is a vertical cross-sectional view illustrating an
embodiment of the burner apparatus according to the present
invention;
FIG. 2 is an enlarged-sectional view illustrating another
embodiment of the nozzle portion,; and
FIG. 3 is a diagram graphically showing the combustion
characteristic of the burner apparatus with respect to the amounts
of nitrogen oxides generated during combustion.
In FIG. 1, reference numeral 1 designates a combustion chamber
having a converged nozzle portion 2. The cross-sectional area of
the combustion chamber 1 is 5 - 20 times the cross-sectional area
of the nozzle portion 2. Reference numeral 3 designates a secondary
air passageway formed around the combustion chamber 1. One end of
the secondary air passageway 3 is provided secondary air passage
holes 4 and the other end thereof is open or closed in the vicinity
of the nozzle portion 2. With reference to FIG. 2, in case the
secondary air passage 3 is closed in the vicinity of the nozzle
portion 2, the secondary air passage holes 11 are formed in chamber
1. In such a case, the cooling air stream 12 is formed on the side
of the nozzle portion 2 which cools the nozzle portion 2 made from
a metallic material. The quantity of the secondary air passing
through the secondary air passageway 3 is 10 - 40 percent of the
theoretical air requirement and determined by the secondary air
passage holes 4. Reference numeral 5 designates a draft tube for
drawing the combustion gas in the furnace by the jetting combustion
gases stream. The draft tube 5 has an upwardly expanding vertical
cross-section so as to enhance the drawing effect of the combustion
gases in the furnace, and is suitably spaced ahead of the nozzle
portion 2. The combustion chamber 1, the secondary air passageway 3
and the draft tube 5 are respectively made from a metallic or
refractory material. Reference numeral 6 designates an air flow
equalizing plate having a large number of primary air passage holes
7 formed therein and connected integrally with a gas feed pipe 8,
and 9 designates a pilot burner concentrically mounted in said gas
feed pipe 8.
With the construction described above, air required for combustion
is supplied through an air inlet port 10 and part of the air, i.e.,
a quantity of air 60 - 90 percent of the theoretical air
requirement, is introduced in to the combustion chamber 1 through
the primary air passage holes 7 formed in the air flow equalizing
plate 6. The remaining part of the air enters the air passageway 3
through the secondary air passage holes 4 and reaches the end
extremity of the nozzle portion 2 after passing through said air
passageway 3. A fuel gas is fed into the combustion chamber 1 from
the fuel gas feed pipe 8, and intensely mixed with the primary air
and burned therein. Since the combustion chamber 1 has the
converged nozzle portion 2 as stated above, the load in the
combustion chamber reaches as high as about 5,000 - 10,000 .times.
10.sup.4 Kcal/m.sup.3 hr. The combustion gases contain some amount
of unburned fuel gas because only the primary air is introduced
into the combustion chamber 1, and is exhausted from the nozzle
portion 2 to the outside of the combustion chamber at a high
velocity of 50 - 200 m/sec. The combustion gases exhausted at such
a high velocity are mixed with the secondary air supply which has
cooled the outer wall of the combustion chamber 1, while moving in
parallel or at an angle to the secondary air supply, and enter the
draft tube 5, ahead of the nozzle portion 2, while undergoing
secondary combustion. When the combustion gases are mixed with the
secondary air supply and are burned, a negative pressure is created
around the nozzle portion 2 in accordance with the energy of
jetting combustion gases and the combustion gases within the
furnace are drawn under the effect of said negative pressure as
indicated by the arrows. The jetting combustion gases and the
combustion gases in the furnace are mixed so quickly that the high
temperature, high velocity combustion gases, containing some amount
of unburned fuel gas, are increasingly exhausted and cooled, and
the unburned fuel gas contained therein is completely burned. In
this case, since the amount of the jetting combustion gases is as
large as 10 - 200 times that of the accompanying gases within the
furnace, though variable, depending upon the flow resistance in the
furnace, an extremely large amount of combustion gas circulates in
the furnace.
Characteristic curve A in the chart of FIG. 3 represents the result
of combustion obtained by the method and apparatus of the instant
invention. It will be apparent from this characteristic curve that
according to the invention, that the amounts of nitrogen oxides can
be substantially decreased as compared with the conventional burner
apparatus, the characteristic of which is represented by a curve
E.
Although in the embodiment described above, the secondary air
passageway 3 is formed around the combustion chamber 1 and the
draft tube 5 is provided ahead of the nozzle portion 2, the amounts
of nitrogen oxides formed can be substantially decreased as
compared with the conventional burner E, by employing the
combustion chamber 1 only of the construction described without
providing said secondary air passageway 3 and said draft tube 5. In
this case, the theoretical quantity of air for combustion is
introduced into the combustion chamber 1 in its entirety but the
cross-sectional area ratio between the nozzle portion 2 and the
combustion chamber 1 must be made smaller and the residence time of
the air in the combustion chamber 1 must be made shorter than in
the case of providing the secondary air passageway 3, so that the
combustion may not be completed within said combustion chamber. The
combustion gases containing some amount of unburned fuel gas are
exhausted from the nozzle portion 2 at a high velocity. The
combustion gases jetting from the nozzle portion 2 suck and are
mixed with the combustion gases within the furnace, whereby the
amount thereof is increased and the temperature thereof is lowered,
and the unburned fuel gas contained therein is consumed in the
secondary combustion. In such case, the amount of the gases sucked
from the furnace is somewhat smaller than in the preceding case
because the air is not fed stepwise and the draft tube 5 is not
provided. However, as will be obvious from a curve D in FIG. 3, the
amounts of nitrogen oxides formed are very much smaller than in
case of the conventional burner E. Curve B in FIG. 3 represents the
combustion characteristics of a burner apparatus in which the draft
tube 5 is provided ahead of the combustion chamber 1 but the
secondary air passageway 3 is not provided, similar to the
preceding case. In this case, the secondary air is not supplied
but, since the amount of the gases withdrawn from the combustion
chamber 1 is increased by the existence of the draft tube 5, the
effect of suppressing the formation of nitrogen oxides is greater
than in the case of the burner apparatus comprising only the
combustion chamber 1. Curve C in FIG. 3 represents the combustion
characteristics of a burner apparatus in which the secondary air
passageway 3 is provided around the combustion chamber 1 but the
draft tube 5 is not provided ahead of said combustion chamber. In
this case, the amount of the combustion gases withdrawn from the
furnace is smaller than in case of the first-mentioned case but,
since the secondary air supply is through the secondary air
passageway 3 and is used for the secondary combustion, the amounts
of nitrogen oxides formed can be substantially decreased.
It will be understood, after all, that the present invention
achieves a remarkable effect in suppressing the formation of
nitrogen oxides, due to a combination of factors including the fact
that the primary combustion is a fuel-rich combustion, that the
combustion is effected stepwise by the primary and secondary
combustions, that the secondary combustion reaction is carried out
while the temperature of the fuel gas is being lowered by
combustion of the gases in the furnace, that the residence time of
the combustion gases within the furnace is long, and that the
length of the flame is short. Further, as will be understood from
FIG. 2, while in the conventional burner apparatus the amounts of
nitrogen oxides formed corresponding to the load factor (the
amounts of nitrogen oxide per unit quantity of heat) are
substantially constant, in the burner apparatus of the instant
invention an increasing load factor results in an increasing
velocity of the combustion gases jetting from the nozzle portion 2
and hence in an increasing amount of the gases being withdrawn from
the combustion chamber, so that the rate of formation of nitrogen
oxides is lowered.
According to the invention, as described above, it is possible not
only to substantially decrease the amounts of nitrogen oxides
formed, but also to improve the heat transmission rate, to make the
temperature distribution within the furnace uniform without
providing any special means, and to reduce the size of or eliminate
the combustion chamber of a furnace. Thus, by practicing the
invention, the general heating apparatus can be simplified.
* * * * *