U.S. patent number 3,728,428 [Application Number 05/151,749] was granted by the patent office on 1973-04-17 for process for producing hollow filaments.
This patent grant is currently assigned to Allied Chemical Corporation. Invention is credited to Garland L. Turner.
United States Patent |
3,728,428 |
Turner |
April 17, 1973 |
PROCESS FOR PRODUCING HOLLOW FILAMENTS
Abstract
A spinnerette for spinning hollow filaments having a maximum
amount of hollow space in relation to the outer dimensions of said
filaments. The filaments are extruded from a group of preferably
three slots and corresponding three round openings or dots. The
polymer occluding area defined by the arrangement of the slots
forms substantially an equilateral triangle. The round openings are
arranged near or at the ends of the slots, but not in communication
with the slots. Filaments melt spun from the nested embodiment of
this spinnerette consistently have above 35 percent hollow space.
The spinnerette is much less subject to breakage than similar
designs. Specific parameters for spinning with such as orifice
configuration are set forth.
Inventors: |
Turner; Garland L.
(Chesterfield County, VA) |
Assignee: |
Allied Chemical Corporation
(New York, NY)
|
Family
ID: |
26848934 |
Appl.
No.: |
05/151,749 |
Filed: |
June 10, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
881806 |
Dec 3, 1969 |
3635641 |
|
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Current U.S.
Class: |
264/177.14;
264/177.19; 428/398; 264/209.1 |
Current CPC
Class: |
B29C
48/345 (20190201); B29C 48/05 (20190201); D01D
5/24 (20130101); B29C 48/09 (20190201); Y10T
428/2975 (20150115); B29C 48/12 (20190201) |
Current International
Class: |
B29C
47/30 (20060101); D01D 5/00 (20060101); D01D
5/24 (20060101); B28h 021/54 (); B29f 003/00 () |
Field of
Search: |
;161/178 ;425/461
;264/177F,209 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Woo; Jay H.
Parent Case Text
This is a division of application Ser. No. 881,806 filed Dec. 3,
1969 and now U.S. Pat. No. 3,635,641.
Claims
I claim:
1. Process for extruding molten fiber-forming polycaproamide to
provide triangular hollow shaped filaments comprising
extruding said polycaproamide at a rate of from about 0.4 to about
0.6 lb./hr./hole at a temperature of about 240 to about
290.degree.C. through a plate containing at least one group of
three slots and three dots arranged with said slots being spaced in
close proximity to form a triangle, each of said dots spaced in
close proximity to the ends of said slots near the apex of said
triangle, said slots and dots being spaced so that air is admitted
to the inside of said triangle during extrusion and coalescence
occurs between the streams of polymer exiting said slots and dots
to form triangular shaped hollow filaments
and cooling the extruded polymer.
Description
BACKGROUND OF THE INVENTION
This invention is related to a spinnerette hole configuration for
producing shaped hollow filaments from synthetic fiber-forming
compositions.
The textile industry has long been interested in hollow filaments
because of the special attributes of such fibers and the several
novel effects which may obtained with them. It is well recognized
that hollow filaments have certain advantages over solid filaments
having the same outer diameters. Some of the advantages which
hollow filaments have over solid filaments include: improved
insulation properties, increased bouyancy, reduced pilling, special
optical effects, and greater covering power per unit weight. Hollow
filaments also have less tendency to fibrillate under flexing
conditions than corresponding solid filaments.
While hollow filaments are highly desirable by the textile
industry, it has proved to be extremely difficult to manufacture
these filaments in a commercially feasible manner by melt-spinning.
Considerable time and effort have been spent on attempts to adapt
existing methods to the production of hollow filaments on a
commercial scale. Processes which have been devised for this
purpose have necessitated the use of special and often expensive
processing conditions and equipment.
Most of the problems involved with the spinning of hollow filaments
are related to the spinnerette. Unfortunately, the spinnerettes
that have been designed thus far are difficult to construct and are
subject to frequent break-downs which may be attributed at least in
part to their complex construction.
One type of spinnerette commonly used to produce hollow filaments
employs orifices containing an internal obstructing member which
causes the orifice to function as an annulus. The obstructive
members are usually joined to the spinnerette body by internal
support members upstream from the extrusion face of the
spinnerette. This type of spinnerette is difficult to make and
presents a major problem in repair and cleanliness.
There are other spinnerettes available that employ a multitude of
unobstructed orifices grouped in a perimeter. For example see
British Pat. No. 1,009,625. See also copending U. S. application
Ser. No. 687,710, filed Dec. 1, 1967. The orifices exist in various
cross-sectional shapes such as tri-slot modified triangular,
circular, rectangular, crescent shape or other curvi-linear or
polygonal shapes spaced in close proximity to essentially
circumscribe an area of the spinnerette plate. The circumscribed
area blocks the flow of extrudate as the molten polymer streams
emerging from the closely spaced orifices coalesce to form hollow
filaments. These spinnerettes require very close spacing between
adjacent orifices to permit proper coalescence of the extrudate
streams with the result that the thickness of the web of
intervening metal between orifices is so small as to cause
structural weakness and difficulties with fabrication. Thus, the
weakened nature of these spinnerettes is particularly significant
in the melt-spinning of synthetic fibers because the extrusion
pressures required will often cause distortion or actual rupture of
spinnerettes which are not properly designed. Another serious
problem encountered with orifices spaced too closely is that
polymer coalescence may occur too close to the spinnerette face
thus preventing the entrance of air into the hollow cavity of the
filament. Therefore, the resultant vacuum within the filament
causes internal coalescence of the molten polymer which minimizes
or completely eliminates the central cavity.
SUMMARY OF THE INVENTION
The principal objective of the present invention is to provide a
spinnerette for producing hollow filaments having the maximum
internal cavity obtainable within a given filament. It has been
found that these objects among others can be achieved through the
use of a spinnerette having at least one group of at least three
slots, and a corresponding equal number of round openings or dots
arranged so that a substantially equilateral polygonal area is
circumscribed by the slots which produce an orifice. The round
openings or dots are spaced from the slots at or near the apex of
each angle. The preferred configuration is three slots and three
dots used to form a triangle. Because the orifice configuration of
this invention permits entry of air from at least six points, this
invention also overcomes the problem of vacuum within the cavity of
the filament. Spinnerette capillaries made from combinations of
slots and round holes offer a more simple geometrical form which
are easier to manufacture than intricate designs which are now
used. This combination can be fitted to any design to give better
flow and fusing of the individual parts than the tri-slot type due
to the minimizing of the "end effects" which are present in long,
narrow slots.
The round opening or dot portion serves several functions. Because
the round openings or dots relieve pressure at corner stress
points, the spin head holes of this invention very seldom explode,
implode or sink at one corner portion. Another important function
is the fact that the proper amount of air enters the cavity of the
hollow filament while maintaining superior fusing or coalescing of
filament sides and proper polymer flow. Also using the preferred
embodiment as an example, a substantially equilateral triangular
polymer occluding area is formed which contributes to the maximum
amount of open or hollow space within the filament cross-section.
Another important result achieved by this particular arrangement
and configuration of slots and openings is the fact that the walls
of the hollow filaments are quite uniform. Because of the round
openings at or near the apex of each angle there are no large areas
formed at the apices or points where coalescence occurs.
The product obtained from the practice of this invention is a
synthetic filament consisting of a polygonal-shaped sheath and an
internal, longitudinally extending polygonal cavity centrally
disposed with respect to the filament axis and the peripheral
contour of the cross-section of the cavity being the shape of the
area occluded at the die face.
The shapes of both the cavity and sheath will be essentially
constant along the length of the filament. The cavity may occupy up
to about 60 percent of the entire cross-sectional area of the
filament depending upon the width and length of the slots. Even
with low viscosity polymers a high percent hollow filament can be
formed.
The slot-dot configuration of this invention can provide a filament
having a cross-sectional variance in polymer crystal orientation
due to the different attenuations through the slots as compared to
the dots. This makes an easily crimpable fiber by merely stretching
the filament.
The filaments produced by the slot-dot configuration have
potentially desirable optical properties for uses in apparel and
carpeting.
Thermoplastic polymers suitable for use in the present invention
include most of the fiber-forming melt-spinnable compositions.
These compositions which are preferred include polyesters, such as
polyethylene terephthalate and polyhexahydro p-xylylene
terephthalate; polyamides such as a polyhexamethylene adipamide and
polycaproamides; polyolefins, such as polyethylene and
polypropylene, polyurethanes; polyesteramides; polyethers; and
other synthetic polymers and mixtures thereof.
Filaments produced by the spinnerette of the present invention have
been found to be extremely useful for floatation materials because
of their low density cross-section. They may be used in the form of
monofilament and multifilament yarn, tow, cords, and staple spun
yarns. The filaments may be blended with other fibrous materials,
and may be employed in crimped or uncrimped conditions.
Other typical textile applications include apparel products such as
woven suitings, shirtings, sheeting and lingerie, tricot, circular
knitted fabrics, broadcloths, satins, and the like. In view of
their relatively high stiffness, strength, and low weight, the
filaments of this invention are further useful in textile
applications such as sewing thread, tire cord, fiber-reinforced
laminates, upholstery, carpeting, drapery, curtains, ducks,
parachutes, reinforced belts and hoses, marine lines, ropes and
netting, and other applications. The filaments may be admixed with
solid core filamentary structures of various modified cross-section
of the same or different denier and the same or different chemical
composition to produce various special effects.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a fragmentary section of a spinnerette plate illustrating
the preferred arrangement and configurations of a group of slots
and nested round openings or dots forming an orifice in accordance
with this invention.
FIG. 2 is another fragmentary section of a spinnerette plate
illustrating another embodiment with the dots in an end-on
configuration with the slots.
TERMINOLOGY
Following are some terms which will be used here in slightly
different form than in common usage.
Hole -- An opening or set of openings which are common to a single
counterbore and produce a monofil.
Web -- A narrowed solid portion of a spinnerette hole area which
lies between adjacent openings. For example, the narrowest
dimension between a slot and a dot shown as t in FIG. 1 and FIG.
2.
Slot -- A part of a spinnerette hole which has a greater length
than width.
Capillary or Dot -- A part of a spinnerette hole which is
round.
Configuration -- Spinnerette holes of this invention are formed by
combinations of slots and capillaries or dots, and preferably take
the form of an equilateral triangle, See FIGS. 1 and 2. The
capillaries (dots) may be end-on to the slots (FIG. 2) or nested
between slots (FIG. 1). The slots are labelled 1, and dots 2 in
both figures. The dimensions are shown as:
h = width of slot
t = width of web at narrowest portion
D = diameter of dot
C = distance between centers of dots
W = length of slot
The nested dots type hole (FIG. 1) has consistently produced
filaments of greater than 35 percent void area. Ease of fabrication
of these holes has been very good.
Flow and velocity ratios of hole components have been found to be
fairly critical. The following equations have been used in defining
these ratios.
Q dot = (.pi.R.sup.4/ 8L) .sup.. (P/.mu.); Q slot = (Wh.sup.3/ 12L)
.sup.. (P/.mu.) (1)
When determining the ratios of dot/slot it is assumed that P/.mu.
is a constant.
V slot = (h.sup.2 P/12L.infin.) ; V dot = R.sup.2 P/8L.mu. (2)
q = mass flow W = Length V = Velocity h = width of slot K =
constant L = depth of slot: dot P = pressure drop .mu.= viscosity
of melt R = radius of dot = D/2
it has been found that (Q slot/Q dot) should be between 1 and 3, (V
dot/V slot) must not exceed 3. The preferred ratios are:
(Q slot/Q dot) = about 2 and (V dot/V slot) = about 2.
SPINNERETTE HOLE PARAMETERS FOR POLYCAPROAMIDE
Webs
Width -- It has been found that the web width (t) i. e., narrowest
dimension between slots and dots, must be between 1 and 10 mils.
and preferably between 2 and 4 mils. The low end has two
determining factors: (1) enough spinnerette web material has to
remain to provide support for the center section against the
extrusion pressure, and (2) enough space has to be provided for the
passage of sufficient air to prevent collapse of the center cavity.
As the upper limit is approached problems of closure become more
acute. About 3 mils. thickness has been found to be the
optimum.
Number -- While it has been seen that the more webs there are, the
larger hollow area one may obtain; it can be said that probably not
more than six are desirable or needed. First of all in the
"slot-dot" spinnerette where there are six webs, there was a gain
of 7 percent to 10 percent in hollow area when the sides are in a
similar position (dots end-on as in FIG. 1) to a spinnerette which
has only three webs. Then if the dots are placed in a "nested"
position relative to the dots, an additional 10 percent hollow is
obtained (consistently 35-37 percent). A hollow area of more than
35 percent may not be very useful; since the walls of the filament
become very thin, and the filaments are subject to deformation in
subsequent operations of drawing and texturizing. An additional
reason for not exceeding six webs is that manufacturing costs would
increase and uniformity decrease due to the increasing complexity
of the spinnerette hole. In determining web thickness (t), it is
necessary to balance (1) amount of air passing to the hollow cavity
of the filament across the web, (2) ability of the sides of the
filament to close by coalescence or continuous fusing to each
other, and (3) strength of the die face. It has been found that the
web thickness (t) should be about one-half of the slot width
(h).
Slots
Length -- The limits of length (W) in practice have been between 30
and 100 mils. At the low end of this range a very rounded filament
with a very low amount of void area resulted Above 100 mils. the
possibility of collapse increases and the stack draw down to
standard filament dimensions would become prohibitive due to
increased orientation with a resultant loss of drawability.
Width -- Limits for width (h) fall between 3 mils. and 10 mils.
Slots which are less than 3 mils. wide are very difficult to
fabricate and also present spinning problems due to potential
blockage by contaminants or other particulate matter which is often
present in an extrudate. Slot widths of between 4 and 7 mils. are
preferred.
Length-Width Ratio -- WIthin the limits of slot length and width
discussed, it has been found that probable operating ranges of the
ratio of slot length to width are between 10 to 20 for a slot-dot
configuration (6 webs). For ratios below 10 the resulting filament
becomes rounded with a reduced hollow area. Above the upper limit
mentioned, an inward collapse of the walls may occur, again
resulting in a reduced hollow area and loss of cross-section
identity.
Dots -- It has been determined empirically that the radius (D/2) of
the dots is preferred to be substantially equal to the slot width
(h); but can vary between 2 and 12 mils., preferably 2 and 8
mils.
Summary of Spinnerette Hole Parameters
Certain spinnerette hole parameters have been determined
empirically. When designing spinnerette holes it is necessary to
consider the uniformity of fabrication for large numbers of holes
as well as whether the spinnerette will produce the proper
cross-section on a smaller scale project. Typical dimensions for an
end-on configuration as shown in FIG. 2 would be:
t = 0.003 in.
h = 0.005 in.
D = 0.013 in.
W = 0.070 in.
In the configuration of FIG. 2 the centers of the dots 2 are
aligned directly with the inside edge of the slot 1. The dots 2
could be arranged in any end-on configuration, such as aligned with
the slot 1 center line, or the outside edge or beyond.
The preferred configuration is the nested arrangement shown in FIG.
1. Typical dimensions would be:
t = 0.0028 in.
h = 0.006 in.
D = 0.013 in.
W = 0.095 in.
C = 0.090 in.
In FIG. 1 the dots are preferably arranged with each circumference
within the sides of the angle described by the inside edges of
adjacent slots. Particularly preferred is the configuration shown
in FIG. 1, i. e., the circumference of each dot is tangent to an
imaginary line between the nearest adjacent corners of the slots,
and equidistant therefrom. The arrangement of slots in relation to
dots is essential to proper operation. For example, by extending
the slots beyond the nested dots it was found that good closure
(coalescence or fusing sides to each other) is assured but that the
cavity collapses because insufficient air is drawn into the hollow
portion of the filament and a resultant vacuum is formed.
The parameters determined are applicable to all polyamides.
However, for other polymers the ratios and dimensions can be
determined according to the melt characteristics during spinning.
For example, polypropylene s known to have a very pronounced bulge
at the spinnerette hole, requiring larger width.
PROCESS CONDITION EFFECTS
Melt Temperature/Melt Viscosity -- Within the practical process
boundaries of a given polymer/spinnerette system, melt temperature
can be varied to produce closure and exhibit some control over the
targeted void area. A low melt temperature may help in closure, in
increasing void area, and to produce a better defined
cross-section; but one must not go so low as to affect the
drawability of the product. As the melt temperature is increased
the melt becomes more mobile producing some smoothing of the
cross-section and reduction in void area, which in many cases is
desirable. For polycaproamide, a temperature of from about
240.degree. C to about 290.degree.C, preferably 255.degree.C to
275.degree.C is used.
Quench -- The quenching medium can be utilized in conjunction with
the melt temperature effect as a process control of apparent melt
viscosity to control void area. In order to be effective in this
respect for polyamide the quench medium must be introduced near the
spinnerette face. Quench medium temperatures of 0.degree. to
40.degree.C are used.
Throughput -- The major effect of throughput is that an increased
flow has the same effect as a temperature increase. This is
evidenced by a rounding of the cross-section and a decrease in void
area. Therefore quench becomes more difficult, but more necessary
if the desired hollow area is to be obtained. With certain designs
of spinnerettes the increased jet velocity may lead to doglegging
of the melt stream as the throughput is increased. Thus at high
throughput rates it is mandatory that spinnerette quality be
rigidly maintained. For polyamide a throughput of 0.1 lb./hr./hole
to 0.75 lb./hr./hole and preferably 0.4 to 0.6 lb./hr./hole is
used.
Additives -- Additives cause effects that tend to affect the melt
viscosity and surface tension of the melt.
Drawing -- As the amount of void area increases the amount of
filament deformation increases. This is not a really serious
problem at void areas less than 30-35 percent.
Summary of Process Conditions -- During the spinning of hollow
cross-section filaments, process conditions must be set on the
basis of their rheological effect on the filament. In subsequent
treatments such as drawing and texturizing possible mechanical
effects must be considered.
Process conditions determined are applicable to polycaproamides.
For other polymers, the conditions can be determined according to
melt characteristics during spinning. For example, nylon 6,6
(polyhexamethylene adipamide) spinnerette temperature would range
from about 280.degree. to 310.degree.C.
Examples -- The following table shows examples of this invention.
Conditions were conventional for melt spinning nylon, at
conventional extrusion rates, 250.degree.-290.degree.C head
temperature, 70.degree.F., 65% RH co-current quench air.
##SPC1##
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