U.S. patent number 3,727,512 [Application Number 05/016,366] was granted by the patent office on 1973-04-17 for process for the surface treatment of non metallic cases such as cartridges, and the so treated cases.
This patent grant is currently assigned to Les Forges De Zeebrugge S.A.. Invention is credited to Curt Berger.
United States Patent |
3,727,512 |
Berger |
April 17, 1973 |
PROCESS FOR THE SURFACE TREATMENT OF NON METALLIC CASES SUCH AS
CARTRIDGES, AND THE SO TREATED CASES
Abstract
The invention relates to a process for surface treating porous
combustible cartridge cases, said process consisting in applying a
first barrier layer on the outer surface of the case, and, on this
layer a water impervious layer so that the case is rendered
moisture- and waterproof without modification of its porous
structure.
Inventors: |
Berger; Curt (Sackingen,
DT) |
Assignee: |
Les Forges De Zeebrugge S.A.
(Herstal-Les-Liege, BE)
|
Family
ID: |
5727979 |
Appl.
No.: |
05/016,366 |
Filed: |
March 4, 1970 |
Foreign Application Priority Data
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|
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Mar 13, 1969 [DT] |
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P 19 12 727.6 |
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Current U.S.
Class: |
86/20.14;
102/700; 102/431 |
Current CPC
Class: |
F42B
5/196 (20130101); Y10S 102/70 (20130101) |
Current International
Class: |
F42B
5/196 (20060101); F42B 5/00 (20060101); F42b
005/18 () |
Field of
Search: |
;102/38,43,DIG.1,103
;86/1,20 ;264/3R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Stahl; Robert F.
Claims
What I claim is:
1. A process for the surface treatment of articles comprising
1. providing a porous combustible article,
2. covering said porous article on at least a portion of an
external surface thereof with a porous film of a dissolved water
swelling compound selected from the group consisting of natural
polymer, synthetic polymers and derivatives of synthetic and
natural polymers,
3. drying said porous barrier layer and
4. coating the said porous barrier with a film of a non-porous
moisture proof composition as an outer protective layer.
2. A process according to claim 1, wherein polyvinyl alcohol and
esters and ethers thereof admixed with dissolving or gel-forming
liquids are applied as a barrier layer.
3. A process according to claim 1, wherein the barrier layer is
applied as a low viscosity film to which, after drying, is applied
a second film eliminating the pores.
4. A process according to claim 1, wherein a rubber film forming
solution is applied as an outer protective layer.
5. A process according to claim 4, wherein small amounts of bitumen
or paraffin are added to the rubber solution.
Description
This invention relates to a process for the surface treatment of
non metallic cases such as cartridges. The term cartridge is used
herein to describe receptacles used in the ammunition techniques
for explosive propellent charges, it being possible to give to said
receptacles, shapes adapted to the weapons or their intended
purposes, used in connection with the projectile proper or
separated therefrom.
Such non metallic cartridges provided to burn with the propellent
charge provide a problem in that the desired porous structure of
the constituting material of the cartridge must have excellent
break strength and storage stability. This is obtained by using
synthetic materials or by solidfying combustible paper or cellulose
raw materials. However, most pores are then closed, thereby slowing
down the combustion process. An additional drawback results from
the fact that the synthetic materials, i.e., the pasting products,
are preventing a complete combustion of the constituting material
of the cartridge, thereby causing detrimental effects through the
barrel and a diminution of the initial velocity. It should be noted
that the coating of the combustible cartridges with a protective
lacquer layer against moisture action is detrimental in that said
layer penetrates the constituting material of the cartridge to such
a depth that the above drawbacks resulting from the manufacture
method, namely the combustion slowing down, are still
remaining.
It is an object of the present invention to protect such
combustible non metallic cartridges against moisture in such manner
that the cases will meet the strict requirements of the Military
Authorities as regards their strength and their moisture resistance
without any drawback when firing, i.e., without any detrimental
effect upon the weapon.
For this purpose, this invention comprises substantially coating
the cases made of porous combustible materials and more
particularly the external surfaces thereof with a film of natural
or synthetic swelling polymers or derivatives of such polymers,
said film forming a barrier layer and, when said layer is set,
coating it with a protective layer stable to moisture.
In preferred embodiments of the invention, the barrier layer is
obtained by affixing a water swelling cellulose film. In addition,
the barrier layer may be also made of synthetic or natural polymers
or derivatives thereof having a structure chemically similar to
that of cellulose, e.g., polyvinyl alcohol and esters and ethers
thereof. As swelling means for forming the barrier layer, not only
water, but also other gel-forming or dissolving liquids may be used
according to this invention.
The barrier layer consisting preferably of water swelling cellulose
or cellulose derivatives may be applied in high viscosity solution
in a single operation or also in a low viscosity film. After drying
of the first coating, the barrier layer is then made non porous by
a second film.
The surface layer is applied as a protective layer above the
barrier layer consists of a film forming rubber solution admixed
with small amounts of bitumen and/or paraffin.
As combustible elements of cartridges, porous receptacles of
cellulose derivatives, formed as known in accordance with the
intended purpose, may be used. The porous receptacle which may also
consist of nitrated fibers, is advantageous in that it has an
external surface protected by a barrier layer consisting of a non
porous film covering only the external surface and having
consequently no effect upon the porosity. The external protective
layer prevents the non metallic case from being damaged by any
action of air humidity, water vapour or sea water.
Cartridges according to the invention have shown such a moisture
resistance that after several hours in water at 20.degree. C or
after an extended storage under a relative humidity of 95 percent,
the ballistic requirements have been compltely fulfilled on test
firings without observing any slowing down or detrimental effect
upon the weapon.
As porous materials, there may be used also non combustible
materials which, when exploding, are leaving no residue and are not
damaging the weapon by corrosion or erosion.
The attached drawing shows by way of example a partial section of a
case embodiment.
Reference number 10 indicates the porous combustible material
forming a cartridge of corresponding sizes, e.g., a fuse case, a
mine body or the like. The external surface of the porous body 10
is covered with the non porous barrier layer 11 in such manner that
the barrier layer 11 forms a closed surface film. The protective
layer 12 according to the invention is then applied on the barrier
layer. The barrier layer and the external protective layer may be
made in any known manner, e.g., by spreading or dipping.
* * * * *