U.S. patent number 3,726,967 [Application Number 05/037,318] was granted by the patent office on 1973-04-10 for dry, free-flowing hair bleaching composition.
This patent grant is currently assigned to Societe anonyme dite: L'Oreal. Invention is credited to Adolf Friedrich Risch, Fritz Artur Vorsatz.
United States Patent |
3,726,967 |
Vorsatz , et al. |
April 10, 1973 |
DRY, FREE-FLOWING HAIR BLEACHING COMPOSITION
Abstract
An essentially dry, free-flowing bleaching composition comprises
granules of an essentially homogeneous mixture of discrete
particles including a bleaching agent such as a per salt and a
binding agent such as polyvinylpyrrolidone or glucose.
Inventors: |
Vorsatz; Fritz Artur
(Karlsruhe, DT), Risch; Adolf Friedrich (Karlsruhe,
DT) |
Assignee: |
Societe anonyme dite: L'Oreal
(Paris, FR)
|
Family
ID: |
21893693 |
Appl.
No.: |
05/037,318 |
Filed: |
May 14, 1970 |
Current U.S.
Class: |
424/62;
252/186.22; 424/DIG.3; 8/111; 252/186.27 |
Current CPC
Class: |
A61K
8/22 (20130101); A61K 8/0225 (20130101); A61Q
5/08 (20130101); Y10S 424/03 (20130101) |
Current International
Class: |
A61k 007/12 () |
Field of
Search: |
;424/62,DIG.3 ;8/111
;252/186 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
466,172 |
|
May 1937 |
|
GB |
|
78,053 |
|
May 1955 |
|
NL |
|
Primary Examiner: Meyers; Albert T.
Assistant Examiner: Clarke; Vera C.
Claims
What is claimed is :
1. An essentially dry, free-flowing bleaching composition for use
in conjunction with water or aqueous hydrogen peroxide consisting
essentially of granules comprising an essentially homogeneous
mixture of (a) a bleaching powder consisting essentially of (i)
30-50 weight percent of said powder of a per salt selected from the
group consisting of sodium persulfate, potassium persulfate, sodium
perborate and potassium perborate (ii) 10-20 weight percent of said
powder of magnesium carbonate, and (iii) the remainder being inert
extenders and (b) a binding agent selected from the group
consisting of polyvinylpyrrolidone having a molecular weight of
about 40,000 to 400,000 and glucose, said binding agent being
present in amounts ranging from about 0.1 to 10 percent by weight
of said bleaching powder.
2. The bleaching composition of claim 1 wherein said granules have
a diameter ranging between about 1 to 6 mm.
3. The bleaching composition of claim 1, wherein said binding agent
is present in amounts of about 3 to 8 percent based on the weight
of said bleaching powder.
Description
The present invention relates to a novel hair-bleaching composition
and more particularly to a dry, free-flowing granular
hair-bleaching composition wherein the active bleaching agent is
essentially homogenously distributed throughout the granular
composition.
Heretofore, liquid hair-bleaching or oxidizing compositions have
been employed, which compositions comprise a solution of per salts
such as perborates, persulfates, and the like in hydrogen peroxide.
These liquid compositions, however, have certain disadvantages such
as poor shelf-life and cumbersome and expensive shipping
characteristics.
In an effort to overcome these disadvantages solid hair-bleaching
compositions were developed. Generally known solid hair-bleaching
compositions are fine-grained powders which are dissolved in
hydrogen peroxide just before use. While known bleaching
compositions in solid form thus eliminated the principal
disadvantages associated with liquid compositions, nonetheless
presently available solid compositions also exhibit certain other
disadvantages. Thus, these fine-grained powders, which comprise an
intimate mixture of discrete particles of the various ingredients
comprising the bleaching composition were found to exhibit a lack
of uniformity in the concentration of the bleaching composition
when dissolved in an appropriate solvent, such as hydrogen
peroxide. This lack of uniformity is attributed at least in part to
the fact that certain of the ingredients of the composition have
different apparent densities, which causes a separating out of the
different constituents of the powder in the course of
transportation and storage. As a result the heavier elements
exhibit a tendency to stratify and collect in the lower portion of
a mass of the composition while the lighter elements tend to be
found at the top thereof. Accordingly, an equal portion of the
powdered composition taken from the upper and the lower part of a
mass of the composition did not have the same chemical composition
and did not therefore exert the same bleaching effect. To obviate
this difficulty, it was found necessary to thoroughly mix the
powdered composition each time before using it. This was found not
only to be inconvenient and time-consuming, but often the user
neglected to perform this mixing operation with the result that a
bleaching operation in which such a composition was used was
generally unsatisfactory.
Moreover, it was noted that the measuring of the amount of powder,
generally done with a spoon, yields rather unlike results because
of different mechanical characteristics that a powder of a specific
composition may have.
It is therefore a principal object of the present invention to
provide a new bleaching composition that eliminates the above
mentioned disadvantages.
The novel bleaching composition of the present invention comprises
a dry, free-flowing product which is dissolved at the time of use
in a solvent such as water or hydrogen peroxide, the said
composition being characterized in that the different oxidizers in
powder form that are contained in the composition are agglomerated
as granules, after having previously been homogeneously mixed, by
means of a binding agent that is soluble in the medium in which the
composition is to be dissolved.
Binding agents that can be utilized for preparation of compositions
of the present invention must have the dual characteristic of (1)
being soluble in the solvent of the composition (generally an
aqueous solution of hydrogen peroxide) and (2) to provide granules
that do not stick, i.e. are free-flowing and exhibit uniform
storage and dispensing characteristics.
Representative binding agents usefully employed in the present
invention include polyvinyl pyrrolidone having a molecular weight
ranging from about 40,000 to 400,000 and a specific viscosity
ranging from about 0.22 to 1.7 and glucose.
The bleaching powder mixture to which the binding agent is added
includes as an active bleaching agent at least one water soluble
per salt such as sodium or potassium persulfate or their mixtures
in amounts of about 30-50 percent by weight of the total bleaching
powder mixture. Other conventional hair-bleaching per salts can be
employed such as sodium or potassium perborate and the like, alone
or in admixture with the persulfates. The bleaching powder mixture
also contains about 10-20 weight percent of magnesium carbonate.
The remainder of the bleaching powder mixture comprises such
conventional inerts or extenders as colloidal clay, thickeners such
as carboxymethyl cellulose or the like, perfumes, ammonium salts
such as ammonium sulfate and a wetting agent.
The proportion of a solvent-free binding agent to bleaching powder
mixture in the novel dry, free-flowing bleaching composition of
this invention ranges, generally, between about 0.1-10 and,
preferably, between 3-8 percent based on the weight of the
bleaching powder mixture. Prior to admixing the binding agent with
the bleaching powder mixture, the binding agent is dissolved in a
carrier such as water or a lower alkanol, for instance, ethyl
alcohol or isopropyl alcohol, or their mixtures to provide a
binding agent solution in which the concentration of the binding
agent ranges between about 0.5-10, and preferably about 5 weight
percent, of the resulting solution.
In preparing the granules which comprise the dry, free-flowing
bleaching composition of this invention and which, ocnveniently,
have an average diameter ranging between about 1-6 mm, the
ingredients constituting the bleaching powder mixture are
thoroughly and intimately mixed in any conventional mixing
apparatus, including a conventional granulating device, i.e. one
having a fitted rotatable drum provided with means to automatically
discharge the resulting granules on attainment of a specified size,
to provide an essentially homogeneous powdered mixture. Thereafter,
the binding agent solution is then thoroughly admixed with the
bleaching powder mixture in, for instance, the same granulating
apparatus to produce granules of a dry, free-flowing bleaching
composition. Generally, the production of the granules is effected
at atmospheric pressure and at a a temperature ranging from about
ambient temperature to about 40.degree. C, thereby eliminating
essentially the binding agent carrier such as water, alcohol or
their mixtures.
It has also been found, that when the carrier for the binding agent
is or contains water, and when the bleaching powder mixture
contains an ammonium compound, the elimination of the carrier
during the formation of the granules is often accompanied by a loss
of ammonia. Accordingly, it has been found convenient to include,
in such instances, about 0.05 to 0.2 weight percent ammonia in the
binding agent solution to compensate for any such ammonia losses
during this stage of the production of the granules. Alternatively,
the amount of ammonium compound present in the bleaching powder
mixture can be increased in the amount of the predicted ammonia
loss.
The granules comprising the dry, fee-flowing composition of this
invention are characterized in that they are generally uniform in
composition and size and thus do not exhibit deleterious
stratification or sedimentation properties. Accordingly, measured
amounts of the granules made in accordance with the present
invention provide more uniform concentrations than essentially an
equally measured amount of conventional fine powdered bleaching
ingredients not in the granulated or agglomerated form.
Additionally, it has surprisingly been found that the presence of
the binding agent, especially polyvinyl pyrrolidone, significantly
improves the dissolution characteristics of the solid constituents
in the hydrogen peroxide containing medium employed when the
bleaching composition is to be put into use. By comparison, a
bleaching composition formulated using essentially the same
bleaching powder composition but in the form of a simple mechanical
mixture of polyvinyl pyrrolidone obtained by stirring or mixing the
polyvinyl pyrrolidone into the bleaching powder, requires a
significantly longer time to effect dissolution of the resulting
composition in hydrogen peroxide. Further, the bleaching effect
using the composition of this invention has been found to be
markedly superior to the bleaching effect using essentially the
same bleaching powder mixture per se in powdered or ungranulated
form.
In order that the invention may be better understood, the following
examples are given which describe the dry, free-flowing bleaching
composition and a process for producing the same. Unless otherwise
specified, all parts and percentages are by weight.
EXAMPLE 1
In a commercial granulator there are placed 25 kg of a bleaching
powder mixture having the following composition:
Potassium persulfate 30 % Magnesium carbonate 20 % Magnesium oxide
15 % Ammonium sulfate 4 % Colloidal clay 28.5% Sulfonated partly
oxyethylene fatty alcohol, sodium salt , of the formula : R --
(C.sub.2 H.sub.4 O).sub.n O--SO.sub.3 Na in which R represents
lauryl and n is 3 0.3% Thickener, carboxymethyl cellulose 2 %
Perfume 0.2 %
25 kg of a 5 percent polyvinyl pyrrolidone solution in isopropyl
alcohol is sprayed onto the powder while the mixture is agitated at
ambient temperature. The mixture is then dried and the resulting
granules exhibit good composition uniformity characteristics and
can be stored without exhibiting any substantial tendency to stick
together. When these granules are mixed with hydrogen peroxide they
yield a very smooth paste that can readily be applied to the head.
The composition thus obtained allows good bleaching of the hair,
superior to that obtained if the bleaching powder mixture alone is
employed.
EXAMPLE 2
Granulation at ambient temperature is effected for 25 kg of a
bleaching powder mixture of the following composition:
Sodium persulfate 20 % Potassium persulfate 30 % Ammonium sulfate 4
% Magnesium carbonate 10 % Magnesia 5 % Colloidal clay 28.5 % Gum
tragacanth (thickener) 2 % Sulfonated partly oxyethylene fatty
alcohol, sodium salt, of the formula: R -- (C.sub.2 H.sub.4
O).sub.n O--SO.sub.3 Na in which R represents lauryl and n is 3 0.3
% Perfume 0.2 %
using 25 kg of a 5 percent solution of polyvinyl pyrrolidone K 30
(Molecular Weight 40,000 , specific viscosity 0.225) in water
containing 0.05 percent ammonia. Results comparable to those of
Example 1 are obtained.
EXAMPLE 3
Proceeding as indicated above, granulation of 25 kg of the
bleaching powder mixture of Example 1 is effected at ambient
temperature, using 30 kg of a 5 percent glucose solution in water
containing 0.05 percent ammonia. Results comparable to those
indicated in Example 1 are obtained.
EXAMPLE 4
Granulation of 25 kg of a bleaching powder mixture having the
following composition is effected at ambient temperature:
Sodium persulfate 20 % Potassium persulfate 30 % Ammonium sulfate 6
% Magnesium carbonate 10 % Magnesia 5 % Colloidal clay 26.5 % Gum
tragacanth (thickener) 2 % Sulfonated partly oxyethylene fatty
alcohol, sodium salt of the formula: R -- (C.sub.2 H.sub.4 O).sub.n
O -- SO.sub.3 Na in which: R represents lauryl and n is 3 0.3%
perfume 0.2 %
using 12 kg of a 10 percent polyvinyl pyrrolidone solution in a 50
percent lower alkanol (Et OH) mixture as the binding agent
solution. Results obtained are comparable to those described in
Example 1.
EXAMPLE 5
In a commercial granulator there are placed 25 kg of a bleaching
powder mixture having the following composition:
Potassium persulfate 30 % Magnesium carbonate 20 % Magnesium oxide
15 % Ammonium sulfate 4 % Colloidal clay 28.5 % Sulfonated partly
oxyethylene fatty alcohol, sodium salt, of the formula: R --
(C.sub.2 H.sub.4 O).sub.n O--SO.sub.3 Na in which R represents
lauryl and n is 3 0.3% Thickener, carboxymethyl cellulose 2 %
Perfume 0.2%
12.5 kg of a 5 percent polyvinyl pyrrolidone solution in isopropyl
alcohol is sprayed onto the powder while the mixture is agitated at
ambient temperature. The mixture is then dried and the resulting
granules exhibit good composition uniformity characteristics and
can be stored without exhibiting any substantial tendency to stick
together. When these granules are mixed with hydrogen peroxide they
yield a very smooth paste that can readily be applied to the head.
The composition thus obtained allows good bleaching of the hair,
superior to that obtained if the bleaching powder mixture alone is
employed.
EXAMPLE 6
Granulation at ambient temperature is effected for 12.5kg of a
bleaching powder mixture of the following composition:
Sodium persulfate 20 % Potassium persulfate 30 % Ammonium sulfate 4
% Magnesium carbonate 10 % Magnesia 5 % Colloidal clay 28.5% Gum
tragacanth (thickener) 2 % Sulfonated partly oxyethylene fatty
alcohol, sodium salt, of the formula: R -- (C.sub.2 H.sub.4
O).sub.n O--SO.sub.3 Na in which R represents lauryl and n is 3 0.3
% Perfume 0.2 %
using 25 kg of a 5 percent solution of polyvinyl pyrrolidone K 30
(Molecular Weight 40,000, specific viscosity 0.225) in water
containing 0.05 percent ammonia. Results comparable to those of
Example 1 are obtained.
* * * * *