U.S. patent number 3,724,465 [Application Number 05/165,134] was granted by the patent office on 1973-04-03 for tampon coated with insertion aid and method for coating.
This patent grant is currently assigned to Kimberly-Clark Corporation. Invention is credited to David V. Duchane.
United States Patent |
3,724,465 |
Duchane |
April 3, 1973 |
TAMPON COATED WITH INSERTION AID AND METHOD FOR COATING
Abstract
A compressed absorbent tampon provided with an improved
insertion-aid coating on at least the tip portion and a method for
applying the improved coating and similar coatings to the tampon.
The improved coating comprises a normally solid polyethylene glycol
containing at least one stabilizing agent. Suitable agents include
water-insoluble metal stearates and/or fumed silica.
Inventors: |
Duchane; David V. (Menasha,
WI) |
Assignee: |
Kimberly-Clark Corporation
(Neenah, WI)
|
Family
ID: |
22597568 |
Appl.
No.: |
05/165,134 |
Filed: |
July 22, 1971 |
Current U.S.
Class: |
604/363; 604/904;
604/364 |
Current CPC
Class: |
A61F
13/2051 (20130101); A61F 13/2082 (20130101); A61F
13/202 (20130101); A61F 2013/8455 (20130101); Y10S
604/904 (20130101) |
Current International
Class: |
A61F
13/20 (20060101); A61F 13/15 (20060101); A61f
013/20 () |
Field of
Search: |
;128/263,270,285 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Claims
What is claimed is:
1. An absorbent cylindrical tampon having a stabilized
insertion-aid coating on at least the tip portion thereof, said
tampon comprising a compressed self-sustaining body of absorbent
material and said coating comprising a molded cap of normally solid
polyethylene glycol having dispersed therethrough a minor portion
of a finely-powdered water-insoluble adjuvant selected from the
group consisting of metal stearates and fumed silica.
2. The coated tampon of claim 1 wherein said metal stearates are
selected from the group consisting of aluminum, calcium, magnesium
and zinc stearate.
3. The coated tampon of claim 1 wherein said adjuvant is present in
said mixture in the amount of from about 5 percent to about 15
percent by weight.
4. The coated tampon of claim 1 wherein said polyethylene glycol
has an average molecular weight in the range of about 1,000 to
about 6,000.
5. The coated tampon of claim 1 wherein said polyethylene glycol is
a methoxy polyethylene glycol with an average molecular weight of
about 750.
6. The coated tampon of claim 1 wherein said adjuvant comprises
fumed silica and a metal stearate selected from the group
consisting of aluminum, calcium, magnesium and zinc stearate.
Description
BACKGROUND OF THE INVENTION
In the manufacture of compressed absorbent tampons, and especially
those of the type which are inserted into body cavities without the
aid of an insertion tube or a lubricous cover and thus present an
inherently dry surface to the body, it is desirable to coat at
least the leading end or tip of the tampon with an insertion-aiding
lubricant. A problem which has long plagued the industry is to find
a suitable coating which will retain its lubricating ability under
the severe temperature variations to which tampons are subjected
during normal shipping and warehousing and yet which will dissolve
readily under use conditions. The patented art is replete with
proposed solutions to this problem. While some aspects are
successfully solved by the various proposals, others seem to appear
with vexing regularity. It is well known, for example, as described
in assignee's U.S. Pat. No. 3,428,044 of Feb. 18, 1969, that
normally solid polyethylene glycols of an average molecular weight
of about 1,000 and above, when coated on the tip of a precompressed
tampon will provide a surface lubricity suitable for use as an
insertion aid. However, it was found that at the elevated
temperatures which frequently occur in warehousing and shipping,
this type of coating softens enough to permit migration of the
coating into the body of the tampon. Under such conditions the
surface where the coating had been applied then eventually reverts
in appearance and feel to that of an uncoated tampon. As a result
the desired lubricity is lost. In assignee's U.S. application Ser.
No. 807,490 filed Mar. 17, 1969 and now U.S. Pat. No. 3,595,236 a
more stable polyethylene glycol coating is described in which the
stability and opacity of mixtures of specified molecular weight
polyethylene glycols are improved by the addition of starch. While
this composition was found to be an improvement over earlier type
coatings, it still lacked the desired long term stability. This
invention is directed to a polyethylene glycol coating formulation
which overcomes most of the disadvantages formerly encountered. A
preferred method of applying the coating to a tampon tip is also
disclosed.
Accordingly, an important object of the present invention is to
provide an improved insertion-aid coating for precompressed tampons
which coating remains stable during long term shipment and
storage.
Another object is to provide a suitable method for applying the
improved coating and similar coating materials to precompressed
tampons.
SUMMARY OF THE INVENTION
A polyethylene glycol lubricant material which is normally solid at
room temperature, is heated and thereby melted to a mobile fluid
state. An adjuvant material selected from the group consisting of
water-insoluble metal stearates and fumed silica or mixtures
thereof is dispersed in the melted polyethylene glycol. A small
metered amount of this melted mixture is injected into a
smooth-surface die having a cavity of a configuration conforming to
the configuration of the tip of a precompressed tampon which is to
be coated. The die is maintained at a temperature less than the
melting point of the mixture. When the mixture is injected into the
cooled die cavity it forms a bead which becomes partially congealed
on its outer surface due to contact with the cooled cavity, but the
major portion of the interior remains fluid and mobile. The tip of
the precompressed tampon is pressed into the cavity containing the
internally mobile mixture whereby the mixture is molded around the
tampon tip to form a smooth cast coating. When the tampon is
withdrawn, the molded coating readily releases from the cavity
without leaving residue. Apparently this is due to the lubricating
properties of the adjuvant as well as the slight shrinkage of the
coating as it hardens. The tampon tip is thus provided with a
smoothly molded coating. The tampon may also be axially rotated in
the die during the molding operation. This axial rotation step
speeds up the setting or hardening of the coating, which is
desirable when using lower molecular weight polymers. It also
results in a dull, matte surface rather than the smooth cast
surface noted above.
In addition to facilitating residue-free release from the cavity
the dispersed adjuvant has other functions which improve
performance and appearance of the finished tampons. One is that it
stabilizes the polyethylene glycol coating so that the coating
remains in fresh condition and does not migrate into the tampon or
leave a dry surface even after a prolonged exposure at temperatures
of 150.degree.F. Another is that it provides an opaque color and
cosmetic appearance to the coated surface.
BRIEF DESCRIPTION OF THE DRAWINGS
In the drawings:
FIG. 1 is a schematic illustration of a means suitable for carrying
out the method for coating tampons in accordance with this
invention.
FIG. 2 is a section of a die cavity taken at 2--2 of FIG. 1 showing
a metered amount of lubricant mixture disposed therein.
FIG. 3 is a section similar to FIG. 2 taken at 3--3 of FIG. 1
showing a tampon pressed into the die cavity with the lubricant
mixture molded around the tampon tip.
FIG. 4 is a perspective view of a tampon with a cast coating of
lubricant on the tip thereof.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
As indicated above, this invention is particularly directed to an
improved insertion-aid coating for precompressed self-sustaining
tampons and a method for applying the coating while in a mobile
condition to the tip portion of the tampon. The primary coating
material is a normally solid polyethylene glycol and the
improvement comprises the addition of particular stabilizing agents
to the polyethylene glycol.
As shown in FIG. 4 of the drawings, the preferred tampon 30
comprises a body of absorbent material compressed to a
self-sustaining cylindrical shape with a substantially hermispheric
frontal portion or tip, and having a withdrawal string 31 attached
to the rear portion. The tampon may be adapted for use for stick
insertion by having an axially extending socket 32 centrally
drilled part way into the rear portion into which a removable stick
33 may be seated. For digital insertion, the socket is not
required.
FIG. 1 illustrates one method for carrying out the invention. The
numeral 11 generally indicates a melting, mixing and injecting
device for the polyethylene glycol. The device as shown comprises a
heated tank 12 into which a normally solid polyethylene glycol is
melted to a fluid state as indicated at 13. A small amount of a
finely-powdered water-insoluble adjuvant selected from the group
consisting of metal stearates and/or fumed silica is introduced
into tank 12 through port 14 and dispersed in the melted
polyethylene glycol by mixing device 15 driven by motor 16.
Preferably the mixer is run continuously to provide a uniform
dispersion. Connected to tank 12 is an extruder or ejector means 18
which is also equipped with a metering device 17 for metering the
amount of the fluid polyethylene glycol mixture it is desired to
eject.
A rotatable turntable 19 is disposed beneath ejector 18. The upper
face of turntable 19 is provided with series of die cavities 20
disposed adjacent the circumference. Each die cavity 20 has an
interior configuration which substantially conforms to the shape of
the tampon it is desired to coat. The cavity shown is hemispheric
and conforms to the rounded tampon tip shown in the drawings. The
interior of turntable 20 is hollow and is preferably filled with a
circulating coolant fluid 21 (FIGS. 2 and 3) which surrounds the
outer wall of cavities 20 depending from the top wall of turntable
19 to maintain the dies 20 at a temperature below the melting point
of the polyethylene glycol mixture. The coolant is fed through
axially disposed tube 22 and removed at 23 through a concentric
channel as indicated.
In operation, a metered amount 24 of the melted polyethylene glycol
mixture containing the specified adjuvant is injected in timed
sequence into each of the cavities 20 on turntable 19 as each
cavity is rotated underneath ejector means 18. The turntable 19
may, of course, be rotated continuously or intermittently as
desired.
The ejected fluid 24 forms a bead 25 in the bottom of the cavity as
shown in FIG. 2. It will be seen that in this condition only a
small portion of the bead surface is in contact with the cooled
surface of the die cavity, so that only a small surface area of the
bead 25 will congeal or start to solidify while the major portion
remains mobile. After each cavity receives an injection of the
coating mixture, the turntable continues to rotate past the
ejection device, and the tip of a tampon 20 is pressed into the
mixture-containing cavity at station B. As the tampon tip is
pressed into the cavity it causes the polyethylene glycol mixture
to flow and mold itself around the tampon tip in the form of a thin
cast coating as shown at 34 in FIGS. 3 and 4. As the turntable 19
continues to rotate the cooling liquid 21 surrounding the die
cavity reduces the temperature of the molded polyethylene glycol
mixture below its melting point, causing the mixture to rapidly
congeal and harden into a solidified condition. The coated tampon
with a molded cap 34 of the polymer mixture on the tip thereof, as
shown in FIG. 4, is then removed at station C. If desired the
tampon may also be rotated axially on itself as turntable moves the
tampon from station B to station C. This axial rotation step speeds
up the hardening of the coating, but results in a dull, matte
finish.
In the above-described process, it was found that the use of the
specified adjuvant permits easy removal of the coated tampon from
the die, leaving no residue. This easy release may be attributed to
the additional lubricating ability contributed by the adjuvant, but
may also come from the fact that the polyethylene glycol takes a
firmer set with the adjuvant mixed therein.
The following Examples will set forth several specific embodiments
of the invention.
Tampons with hemispherical tips as shown in the drawings were
coated in the manner described with each of the formulations
described below. In these formulas, polyethylene glycol with an
average molecular weight of 1,000 is identified as PEG 1,000 and
polyethylene glycol with an average molecular weight of 4,000 is
identified as PEG 4,000. All parts are parts by weight. In each
instance, the PEG 1,000 was heated to about 158.degree.F. to reduce
it to a fluid state. The die cavity was maintained at about room
temperature.
Example A. PEG 1,000 alone.
Example B. Ten parts PEG 1,000, 1 part fumed silica.
Example C. Ten parts PEG 1,000, 1 part fumed silica, 1 part
magnesium stearate.
Example D. Ten parts PEG 1,000, 1 part fumed silica, 1 part
aluminum stearate.
Example E. Ten parts PEG 1,000, 1 part fumed silica, 1 part zinc
stearate.
Example F. Ten parts PEG 1,000, 1 part fumed silica, 1 part calcium
stearate.
Example G. Ten parts PEG 1,000, 1 part magnesium stearate.
Example H. Ten parts PEG 1,000, 1 part aluminum stearate.
Example I. Ten parts PEG 1,000, 1 part zinc stearate.
Example J. Ten parts PEG 1,000, 1 part calcium stearate.
After tampons were coated with each of these mixtures, they were
placed in a forced air oven at 150.degree.F. for 16 hours. At the
end of that time, the Example A coating consisting of PEG 1,000
alone had completely migrated into the tampon. The coating
formulations consisting of PEG 1,000 and fumed silica (Example B)
as well as those containing PEG 1,000, fumed silica and a metal
stearate (Examples C, D, E, F) all remained on the surface of the
tampons and retained essentially all of their original smoothness
and lubricity. Those formulations containing PEG 1,000 and a metal
stearate (Examples G, H, I, J) remained on the surface of the
tampon but appeared to lose some lubricity. However, this loss was
not enough to make the coating defective. The coatings containing
PEG 1,000 and the zinc stearate, the magnesium stearate, and the
calcium stearate were a little drier and stickier than similar
coatings which also contained fumed silica, while the coating
containing PEG 1,000 and aluminum stearate took on a somewhat
mottled appearance which was absent in the same coating containing
fumed silica. In each case, however, the desired stability was
present.
It will be noted therefore that while the metal stearate may be
used alone, the combination of stearates with fumed silica is
superior.
The above experiments were repeated except that in each of the
formulations PEG 4,000 was used instead of PEG 1,000. Each of the
coated tampons were heated for 16 hours at 150.degree.F to test
stability. The results were substantially the same as those
obtained when PEG 1,000 was used in the formulas.
In each case the metal stearate and fumed silica is added to the
coating by simply blending it into the hot PEG melt. The fumed
silica has been found to exert a thixotropic effect upon the
formulation. That is, the formulation containing fumed silica
remains very fluid while it is being stirred but when stirring
stops, the formulation begins to thicken, eventually reaching a
marshmallow type consistency. Upon stirring, the structure is
rapidly broken down and the formulation becomes very fluid once
more.
This thixotropic effect has been found to be advantageous for
tampon coatings. The tampon is coated with the formulation in the
hot fluid state so that the mixture readily flows around the tip as
it is pressed into the die. However, because it is thixotropic when
containing fumed silica, the coating does not become fluid when
similar temperatures are reached during storage of the coated
tampon due to the absence of physical agitation. It is believed
this phenomenon also aids in preventing migration of the coating
into the body of the tampon.
Fumed silica is silicon dioxide formed by the vapor phase
hydrolysis of silicon tetrachloride. It is supplied as a low
density water-insoluble powder with extremely small particle size
and a large surface area. Although it is insoluble, the powder
forms a clear, colloidal suspension in water. The grade of fumed
silica used in the Examples described is sold under the trademark
CAB-O-SIL by Cabot Corporation. It has been approved by the FDA for
use in foods and pharmaceuticals.
The metal stearates may be used in their conventional commercial
form which are water-insoluble powders. FDA approved grades should
of course be used.
As indicated above, the polyethylene glycol should be one that is
normally solid at room temperature. While PEG 600 has a melting
point range of about 68.degree.F to 77.degree.F and can meet the
definition, it is marginal in performance, and it is preferred that
polyethylene glycols with an average molecular weight of about
1,000 and above be used. The preferred range is from about 1,000 to
about 6,000. Lower molecular weight polymers may of course be used
in admixture with higher weight polymers to obtain average
molecular weights in the preferred range. Methoxy polyethylene
glycol with an average molecular weight of about 750 may also be
used.
While the description of the specific examples have been confined
to polyethylene glycol and adjuvant mixtures, it will readily be
seen that the method of application itself can readily be used for
other coatings which are solid at room temperature but fluid at
elevated temperature.
The described method has been found to be superior to the older
methods of dipping the compressed tampon tip into the molten
polyethylene glycol or of spraying partially congealed material
onto the tip. By the described method much better control over the
thickness and uniformity of the applied coating is possible. In
addition, less coating material is required, providing advantages
in both economy and performance.
While the resulting coating dissolves somewhat more slowly in body
fluids than fresh polyethylene glycol coatings lacking a
stabilizer, the fact that the method provides better control in
applying a smaller amount of stable coating in a small confined
area of the tip overcomes any disadvantage the slower solubility
may have. As a result, the overall absorbence of the tampon is not
deleteriously affected.
* * * * *