U.S. patent number 3,719,049 [Application Number 04/873,755] was granted by the patent office on 1973-03-06 for corrosion preventing apparatus and method.
This patent grant is currently assigned to Donald W. Durant. Invention is credited to Clarence W. Shaw, George R. Smith.
United States Patent |
3,719,049 |
Shaw , et al. |
March 6, 1973 |
CORROSION PREVENTING APPARATUS AND METHOD
Abstract
The present invention pertains to a splash zone coating system
for the protection of metallic surfaces subject to active
corrosion. More specifically, the present invention pertains to
novel means for covering and coating metallic structures, e.g.,
pipe leg supports of an offshore oil well structure, from seawater
corrosion in the splash zone of the structure which is that area
subjected to intermittent contact by seawater.
Inventors: |
Shaw; Clarence W. (Metairie,
LA), Smith; George R. (Ponchatoula, LA) |
Assignee: |
Durant; Donald W. (Covington,
LA)
|
Family
ID: |
25362245 |
Appl.
No.: |
04/873,755 |
Filed: |
December 22, 1969 |
Current U.S.
Class: |
405/216 |
Current CPC
Class: |
B63B
59/00 (20130101); C23F 11/00 (20130101); E21B
41/02 (20130101); E04B 1/642 (20130101) |
Current International
Class: |
C23F
11/00 (20060101); E04B 1/64 (20060101); B63B
59/00 (20060101); E21B 41/02 (20060101); E21B
41/00 (20060101); E02d 005/60 (); E04b
001/64 () |
Field of
Search: |
;61/54 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Shapiro; Jacob
Claims
We claim:
1. Means for corrosion proofing a metallic structure subject to
intermittent contact by seawater, said means comprising:
a. a flexible membrane covering the metallic structure over that
area subjected to intermittent contact by seawater so as to define
a cavity between said flexible membrane and the metallic structure;
a body of a water immiscible liquid rust inhibitor, lighter than
water, in but not completely filling the cavity whereby the said
area of the metallic structure will be periodically completely
coated by the rust inhibitor upon the rise and fall of the seawater
due to wave action and/or tidal changes and the resulting flexure
of said membrance;
b. closure means fixedly attached to said flexible membrane and
metallic structure and sealing off the portion of the metallic
structure subject to intermittent contact by seawater; and
c. sealing means for sealing the ends of said flexible membrane to
the metallic structure.
2. The corrosion proofing means of claim 1 further characterized as
comprising:
d. filling means attached to said flexible membrane adjacent the
top thereof whereby said water immiscible liquid rust inhibitor can
be injected in the cavity defined between said flexible membrane
and the metallic structure.
3. The corrosion proofing means of claim 2 wherein:
e. said filing means comprises inlet valve means connected to said
flexible membrane whereby the cavity defined between said flexible
membrane and the metallic structure can be pressurized; and
f. outlet valve means connected to said flexible membrane adjacent
the bottom thereof for venting the cavity defined between said
flexible membrane and the metallic structure.
4. The method of corrosion proofing a metallic structure subjected
to intermittent contact by sea water at the surface of a body of
said water, comprising the steps of:
establishing a zone around said structure, by flexible confining
means, at said seawater surface of a size to extend throughout the
range of change of level of said surface;
confining a body of liquid, water-immiscible corrosion inhibiting
material in said zone within said confining means and in contact
with said metallic structure;
excluding sea water from said zone; and
maintaining said confining means in contact with said body of water
at said surface whereby movement of sea water at said surface
distorts said confining means and the outer boundary of said zone
and thereby agitates and produces flow of said corrosion inhibiting
material along the surface of said metallic structure.
5. The corrosion proofing means of claim 1 further characterized in
that said flexible membrane comprises a rubber-fabric composition.
Description
BACKGROUND OF THE INVENTION
The present invention pertains to that field of the art concerned
with means for protecting a metallic surface subject to active
corrosion by the intermittent wetting and/or splashing of water.
More particularly, the present invention is concerned with the
combination of novel means for covering a metallic surface subject
to the corrosive action of seawater whereby the surface is
constantly treated with a rust inhibiter.
A metallic structure erected in water is subject to considerable
corrosion especially in those instances where the water has any
degree of salinity. That part of such a structure subjected to the
intermittent or frequent contact of water, either due to splashing
or by tidal changes, experiences the most severe corrosion. This
zone which is normally referred to as the splash zone, is defined
as that existing between the highest point reached by the water due
to either wave action or splashing, to the lowest point reached by
air. Corrosion in this splash zone is usually most severe and
difficult to protect. As is well known, for surfaces located above
the splash zone, various well known corrosion systems can be
employed, e.g., conventional paints, plastic coatings, and the
like. Below the splash zone, corrosion can be effectively combated
by cathodic protection.
There are various well known techniques and/or means for protecting
a metallic structure, such as an oil well rig, from the effects of
active corrosion caused by seawater which mainly attacks the
supports of the structure that are located in the splash zone. For
example, in the case of offshore oil rigs, their steel pilings,
pipe legs, or conductor pipes can be coated with a sacrificial
metal layer over its length defined within the splash zone. Or,
such a surface can be covered over with a rust resistant metal
coating. In either case, it can be appreciated that the initial
expense of the rust resistant coating or the subsequent maintenance
of the sacrificial coating is costly. The present invention
provides a relatively inexpensive manner of covering such surfaces
as above described whereby they can be constantly subjected to
corrosion proofing by well known rust inhibitors. Further
advantages and features of the present invention will become
apparent as the discussion proceeds.
SUMMARY
The present Splash Zone Coating System basically comprises a
flexible membrane adapted to operably fit over and around the
surface of a metallic structure over its area that is subjected to
intermittent contact of water. The flexible membrance defines a
cavity between its inner surface and the surface of the metallic
structure. Closure means are provided which is attached to the
flexible membrane whereby the membrane can be conveniently attached
to, over, or around the metallic structure. Sealing means operably
connected to the flexible membrane are provided for sealing the
flexible membrane to the metallic structure. A suitable rust
inhibitor is injected into the cavity defined by the flexible
membrane whereby the surface of the metallic structure is kept
constantly coated with the inhibitor.
Preferred embodiments include means for filling and venting the
flexible membrane, as well as means for attaching the membrane to a
cylindrical surface to be protected.
DESCRIPTION OF THE DRAWING
FIG. 1 in the drawing represents an elevation view of a preferred
form of the present invention as adapted for protecting a
cylindrical structure.
FIG. 2 represents a sectional view taken along the line A--A of
FIG. 1 showing the cavity created between the flexible membrane and
the surface to be protected from corrosion by a surrounding aqueous
environment.
FIG. 3 depicts a partial sectional view taken along the line B--B
of FIG. 1 showing a preferred manner of sealing and protecting the
end portion of the flexible membrane as it is adapted to fit around
and protect a cylindrical structure.
PREFERRED EMBODIMENT
The present Splash Zone Corrosion proofing means 10 comprises the
flexible membrane 11 which as shown in FIG. 1 is adapted to fit
over and around the external surface of a specific metallic
structure to be protected. The wrapper or jacket 11 is made of a
flexible material that is capable of withstanding the elements.
Additionally, the wrapper 10 is preferably a tenacious material
capable of withstanding battering by vessels or objects floating in
the water. A fabric reinforced synthetic rubber, such as neoprene,
or a chlorosulfonated polyethylene, are preferred materials of
construction. However, many other types of flexible materials can
be employed as long as they are compatible with the elements and
the rust inhibitor employed in the cavity between the wrapper and
the metallic structure.
The jacket 11 is preferably provided with the slide fastener means
12 which extends along its edges parallel to the longitudinal axis
of the oil rig pipe support 13. The slide fastener means 12 can be
any suitable heavy duty slide fastener closure means which is
essentially water-tight. Such means are well known and available in
the art. The slide fastener means 12 can be either glued to the
membrane 11 or sewn thereto with nylon thread or the like.
As shown in FIG. 2, the flexible member 11 and the metallic
structure 13 form the cavity or annulus 14 therebetween. In the
installation of the assembly 10, a suitable rust inhibitor is
injected into the cavity 14 in the manner described hereinafter.
The rust inhibitor can be any suitable material that is capable of
floating on water and which has a higher affinity for metal than
water. In such manner, the material will coat the metallic surface
of the membrane 13 forcing the water away. The inhibitor is
preferably a petroleum base hydrophobic cationic material which is
readily available in the art. These materials are generally black
liquids which combine mineral oils with wetting agents and rust
inhibitors. Such materials will generally penetrate existing rust
and displace water; adhere to and give full protection to either
wet or dry surfaces; will not dry out, harden, or crack; they float
as a liquid layer on top of water; and resist water washing once
applied.
The present corrosion proofing means 10 also preferably comprises
the inlet valve assembly 15 which is operably connected to the
member 11 in any conventional or well known manner. For example,
the wrapper 11 can be provided with a rubber jacketed conduit
connector that is glued or sewn to the wrapper 11. Thereafter, a
suitable hand operated valve is attached for achieving the mode of
operations brought out below. The valve outlet assembly 16 is also
preferably provided and which functions in a similar manner as the
assembly 15. Likewise, it can be operably connected to the jacket
11 in a similar manner. The valve portion of the assembly 16
preferably comprises a flow check valve whereby any material in the
cavity 14 can flow outwards at any time to avoid rupturing of the
wrapper 11 due to over pressurization, yet avoid the re-entry of
seawater, as well as acheive the mode of operation described
below.
As shown in FIG. 1, the jacket 11 is also preferably provided with
the inlet slit or opening 17 which in turn preferably further
comprises a zipper construction 18 similar to the slide fastener
means 12. The inlet 17 is provided for injecting or pouring the
liquid rust inhibitor into the cavity 14. However, the inlet 17 can
be dispensed with and the rust inhibitor injected in the cavity 14
via the valve assembly 15. Such an operation would naturally
require more expensive equipment, consequently, the separate
filling opening 17 is preferred.
Referring to FIG. 3, the flexible membrane 11 is preferably
provided with the additional section 18 which is generally made up
of the same material of construction as the membrane 11. The
resilient member 19, preferably a sponge rubber, is provided so as
to foem a seal between the membrane 11 and the external surface of
the metallic structure 13. The resilient member 19 in combination
with the portion 18 define the radial width of the cavity defined
between the members 11 and 13. The member 18 also serves to
reinforce the end portion, generally over a width of about 4
inches, from the mechanical forces induced by the strap means 20.
The strap means 20 is preferably a corrosion resistant material,
e.g., monel, stainless steel, or the like, which is banded around
the end portion of the membrane 11 and operably clinched in
position by use of various well known banding devices. Of course
suitable screw operated clamping devices could be employed in lieu
thereof. Moreover, the assembly could actually be glued into
position with a suitable adhesive, such as an epoxy resin, or the
like.
In operation, the flexible membrane 11 is first wrapped around the
surface to be protected which is that area generally known as the
splash zone. The slide fastener 12 is then brought together and the
wrapper 11 fastened tight, for further protection the end portions
are wrapped with a heavy tape, e.g., polyethylene, or the like. The
band or strap means 20 is then applied. In such manner, the
assembly 10 forms the enclosed cavity 14 between the external
surface of the member 13 and the inner surface of the membrane 11.
Since a part of the jacket 11 will extend beneath the surface of
the water, it is necessary to employ a diver to secure and clamp
the lower portion.
When the jacket 11 is initially placed into position and fastened
shut, water will natrually be trapped between the jacket 11 and the
structure 13 at a level essentially equal to that of the
surrounding water. A rust inhibitor is then added to the cavity 14,
preferably via the opening 17 after which the slide fastener 18 is
closed.
Next, compressed air or some other suitable medium is then
introduced into the jacket 11 by through of the valve assembly 15.
The pressurizing medium need only be of sufficient pressure to
force the water out of the cavity 14 through the exit valve
assembly 16. In other words, the pressure must be sufficient to
overcome the head established by the depth to which the valve
assembly 16 is immersed beneath the surface of the water. The
pressure forces the rust inhibitor to flow down and coat the steel
to the depth established by the valve assembly 16. The valve
assembly 16 being a check valve, allows the water to flow out, yet
prevents back-flow thereafter.
The source of pressure is then cut off and disconnected from the
valve assembly 15. Where the member 11 is tightly sealed to the
structure 13, the valve assembly 15 should preferably thereafter be
opened to the atmosphere. This allows the rust inhibitor to rapidly
return upwards depending upon the amount of leakage back into the
cavity 14. It can be appreciated that if and when water does force
itself back into the cavity 14, the above sequence of operations
can be repeated at desired intervals which again coat the surface
of the structure 13. Recoating of the metallic surface can also be
effectuated by massaging the wrapper 11 with a suitable means such
as a garter spring. The massaging action will also naturally occur
as the water level outside of the jacket rises above the water and
rust inhibitor level inside the jacket whereby the outside water
pressure will squeeze the jacket against the structure 13. This
action forces these fluids within the space 14 to rise.
It will be apparent to one skilled in the art that considerable
changes and modifications can be made in the above described
embodiment of our invention without departing from its true scope
and spirit. For example, the wrapper 11 can be made in a number of
separate parts, all of which can be zippered together to form the
desired diameter of wrapper. Moreover, the wrapper 11 could be
binded to the structure 13 in diverse manners. Additionally, where
the splash zone is defined over a considerable length, a series of
superposed or stacked jackets 11 could be utilized.
* * * * *