U.S. patent number 3,716,356 [Application Number 05/074,825] was granted by the patent office on 1973-02-13 for rhenium containing gold alloys.
This patent grant is currently assigned to The J. M. Ney Company. Invention is credited to Arthur Peter Burnett.
United States Patent |
3,716,356 |
Burnett |
* February 13, 1973 |
RHENIUM CONTAINING GOLD ALLOYS
Abstract
There is disclosed a novel and improved gold alloy containing at
least about 5.5 per cent of palladium and about 0.03 to 1.0 per
cent by weight of rhenium, and either or both of platinum and iron
when the palladium content is less than 25.0 per cent.
Inventors: |
Burnett; Arthur Peter
(Tariffville, CT) |
Assignee: |
The J. M. Ney Company
(Bloomfield, CT)
|
[*] Notice: |
The portion of the term of this patent
subsequent to May 30, 1989 has been disclaimed. |
Family
ID: |
22121904 |
Appl.
No.: |
05/074,825 |
Filed: |
September 23, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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764589 |
Oct 2, 1968 |
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665995 |
Jul 26, 1967 |
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Current U.S.
Class: |
420/508;
420/509 |
Current CPC
Class: |
C22C
5/02 (20130101) |
Current International
Class: |
C22C
5/00 (20060101); C22C 5/02 (20060101); C22c
005/00 () |
Field of
Search: |
;75/165,134V,172 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Rutledge; L. Dewayne
Assistant Examiner: Weise; E. L.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATIONS
The present application is a continuation-in-part of copending
application Ser. No. 764,589 filed Oct. 2, 1968, now abandoned,
which in turn was a continuation-in-part of then copending
application Ser. No. 665,995, filed July 26, 1967, now abandoned.
Claims
Having thus described the invention, I claim:
1. A gold alloy consisting essentially of about 5.5 to 40.0 percent
palladium, 0.0 to 10.0 percent platinum, 0.03 to 1.0 percent
rhenium, 0.0 to 2.0 percent silver, 0.0 to 1.0 percent iron, 0.0 to
1.5 percent zinc, 0.0 to 2.0 percent tin, 0.0 to 1.0 percent
indium, and the balance gold, said gold being present in an amount
of about 59.0 to 94.47 percent, the total palladium and platinum in
said alloy not exceeding 40.0 percent with said platinum being less
than said palladium, all based upon the total weight of said alloy,
provided that when said palladium is less than about 25.0 percent
of said alloy there is present at least one modifying metal
selected from the group consisting of iron and platinum to produce
fine grain structure, said platinum modifying metal being present
in an amount of at least about 1.0 percent, and said iron modifying
metal being present in an amount of at least 0.3 percent.
2. The gold alloy of claim 1 wherein said rhenium is present in the
amount of about 0.08 to 0.3 percent by weight.
3. The gold alloy of claim 1 wherein said palladium is present in
the amount of 5.5 to 15.0 percent by weight, platinum is not
present and iron is present in the amount of 0.3 to 1.0
percent.
4. The gold alloy of claim 1 wherein said palladium is present in
the amount of 5.5 to 12.0 percent by weight and said platinum is
present in the amount of 2.0 to 7.0 percent by weight.
5. The gold alloy of claim 4 wherein iron is present in the amount
of about 0.3 to 1.0 percent.
6. The gold alloy of claim 1 wherein there is present at least 1.0
percent by weight platinum.
7. The gold alloy of claim 1 wherein the ratio of rhenium to gold
is within the range of 0.0005 to 0.017:1.0 and the ratio of Group
VIII metals to gold is in the range of about 0.03 to 0.67:1.0.
8. The gold alloy of claim 1 wherein palladium is present in the
amount of about 25 to 40 percent.
Description
BACKGROUND OF THE INVENTION
It is generally known that the metals of Group VIII of the Periodic
Table affect the morphology or grain structure of gold alloy
castings. Use of ruthenium, rhodium, palladium, platinum and indium
in gold alloys in amounts of up to about 3.0 percent total or the
solubility thereof produces grain refinement with castings
containing such elements evidencing a grain size several times
smaller than the grain size of comparable alloys which do not
contain such alloying elements.
However, as the content of the Group VIII metals increases to above
about 3.0 percent by weight of the gold alloy, the grain structure
thereof becomes progressively coarser. Initially, the increasing
amounts produce irregular grains and then a dendritic structure.
Coarse grain structure is generally undesirable because it tends to
severly affect the quality of castings and the workability of the
alloy. As is known, coarse grain dendritic alloys are significantly
susceptible to increased porosity in the cast condition and tend to
develop intergranular cracking during cold working.
Accordingly, it is an object of the present invention to provide
novel equiaxed grain gold alloys containing palladium, with or
without platinum and/or iron, in relatively large quantities and
which may be cast without close control over the amount of
superheat and rate of cooling.
It is also an object to provide such an alloy which evidences a
fine grain structure upon casting and which is readily adapted to
working.
A further object is to provide such an alloy for producing castings
which exhibit low shrinkage porosity and highly desirable balanced
properties.
SUMMARY OF THE INVENTION
It has now been found that the foregoing and related objects can be
readily attained in a gold alloy consisting essentially of about
5.5 to 40.0 percent palladium, 0.0 to 10.0 percent platinum, 0.03
to 1.0 percent rhenium, 0.0 to 2.0 percent silver, 0.0 to 1.0
percent iron, 0.0 to 1.5 percent zinc, 0.0 to 2.0 percent tin, 0.0
to 1.0 percent indium, and the balance gold. The gold is present in
an amount of about 59.0 to 94.47 percent and the total of palladium
and platinum in the alloy does not exceed 40.0 percent by weight
thereof with the platinum being less than the palladium, all based
upon the total weight of said alloy.
When the palladium content is less than about 25.0 percent of the
alloy, there is present at least one modifying metal selected from
the group consisting of iron and platinum to produce an equiaxed
grain structure; the platinum modifying metal is present in an
amount of at least about 1.0 percent and the iron modifying metal
being present in an amount of at least about 0.3 percent.
By the present invention, highly desirable gold alloys containing
relatively large quantities of palladium and platinum may be
prepared for use both as castings and in worked forms such as foil
and wire. Although gold alloys containing more than about 3.0
percent by weight of the Group VIII metals tend to evidence a
coarse grain structure, far larger quantities of palladium and
platinum may now be employed while at the same time obtaining a
fine equiaxed grain structure.
The palladium and platinum may be present in varying amounts,
although the total thereof must not exceed 40.0 percent. Generally,
the palladium may comprise from 5.5 to 40.0 percent by weight of
the alloy. It may be used alone or in combination with platinum
which may be used in amounts of up to 10.0 percent by weight of the
alloy but less than the palladium content. Although rhodium may be
used in small amounts in conjunction with palladium, it is
generally less desirable because of its possible effect upon other
properties of the alloy.
When palladium is employed alone, it will preferably be present in
the amount of about 5.5 to 15.0 percent by weight. When palladium
and platinum are utilized in combination, the palladium is
preferably in the range of about 5.5 to 12.0 percent by weight, and
the platinum is preferably in the range of about 2.0 to 7.0 percent
by weight but less than the palladium content. The weight ratio of
the Group VIII metals to gold must be in the ratio of about 0.03 -
0.67:1.0 in order to obtain the desired equiaxed grain structure.
Similarly, the ratio of rhenium to gold should be controlled so as
to fall within the range of about 0.0005 - 0.017:1.0.
Other compatible alloying elements conventionally employed in gold
alloys may be incorporated in the compositions of the present
invention such as silver up to about 2.0 percent by weight, iron up
to about 1.0 percent by weight, zinc up to about 1.5 percent by
weight, tin up to about 2.0 percent by weight, and indium up to
about 1.0 percent by weight. The total amount of these optional
alloying elements should not exceed 10.0 percent by weight of the
alloy. Hardeners, such as iron, have proven particularly
advantageous in the alloys produced in accordance with the present
invention. However, a relatively large amount of any element in
which rhenium exhibits extensive solubility should be avoided since
it would seriously impair the efficacy of the rhenium in accordance
with the present invention.
The mechanism of the rhenium in this alloy is not fully understood,
although its effect is most obvious. Although the rhenium may be
employed to advantage over the relatively wide range of 0.03 to 1.0
percent by weight, it is preferably employed in the range of about
0.08 to 0.3 percent by weight for optimum balance of properties,
but larger amounts may be desirable where the gold content is
higher. The rhenium is preferably added after the remaining
alloying elements have been melted together and thereafter the
alloy may be remelted without any detriment to the benefits
obtained thereby.
Moreover, when the palladium content is less than about 25.0
percent, it has been found that reliable results in obtaining an
equiaxed structure require the presence of at least one or both of
platinum and iron as modifying metals. The function of these metals
in promoting the equiaxed structures is not understood but the
presence of as little as 1.0 percent platinum will greatly improve
the reliability of the alloy. Iron in an amount of 0.3 - 1.0
percent also improves the reliability of the alloy in giving rise
to an equiaxed grain structure in the cast product, and the
preferred alloys with less than 25.0 percent palladium contain both
platinum and iron.
It has been found that the alloys of the present invention do not
require critical control of superheat or cooling rates. As a
result, fine-grain castings have been obtained with superheats of
as much as 500.degree. C.
Castings of the alloys have been found to be uniformly sound and
free from shrinkage porosity and to possess an equiaxed fine-grain
structure. Working of these alloys into nugget and wire form has
established the higly desirable workability thereof and freedom
from intergranular cracking. Hardening mechanisms common to
gold-platinum alloys are effective in the presence of the rhenium
additive. Thus, the alloy of the present invention evidences
significant utility and obvious advantages.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Illustrative of two specific alloy compositions are the following
wherein one contains a hardening system and the other does not:
Alloy No. One
Percent by Weight Gold 91.4 Palladium 5.5 Platinum 3.0 Rhenium
0.1
Alloy No. Two
Gold 79.4 Palladium 10.8 Platinum 5.9 Rhenium 0.1 Iron 0.8 Tin 1.0
Silver 2.0
Exemplary of the efficacy of the present invention are the
following specific examples wherein all parts and percentages are
by weight unless otherwise indicated.
A series of gold-base alloys containing at least various of the
elements palladium, platinum, iron and rhenium were prepared and
cast into 700.degree. C. phosphate-bound investment molds. As a
measure of grain size in the solidified alloys, the number of grain
boundaries observed to intercept a line was determined and
expressed as grain boundaries per millimeter, the greater number of
boundaries being indicative of the smaller-sized grains. Table One
which follows indicates the grain size of cast alloys containing
the various elements in the weight percentages specified.
Example Au Pd Pt Fe Re Other Grain per mm. ies One 60.0 40.0 11 Two
59.7 39.8 0.50 23 Three 59.4 39.6 1.0 30 Four 71.4 28.6 19 Five
71.0 28.5 0.5 46 Six 81.1 11.0 6.0 0.8 1.1 Sn 1.8 Seven 81.0 11.0
6.0 0.8 0.1 1.1 Sn 57 Eight 89.9 10.0 0.1 13 Nine 89.4 10.0 0.5 0.1
37 Ten 87.9 6.0 6.0 0.1 40 Eleven 79.4 10.8 5.9 0.77 0.09 1.08 Sn;
1.96 Ag 57 Twelve 80.2 10.9 5.9 0.8 0.1 1.1 Sn; 1.0 In 53 Thirteen
79.6 10.8 5.9 0.8 0.1 1.08 Sn; 0.98 Ag; 0.74 Zn 50 Fourteen 87.5
12.0 0.5 11 Fifteen 87.5 6.0 6.0 0.5 0.1 37
As can be seen from Table One, the alloy of Example One contained
only gold and a large amount of palladium; the grains of the alloy
were relatively large. Inspection of the grains also indicates that
they were irregularly shaped. For comparison, the alloys of
Examples Two and Three, which contained essentially the same amount
of gold and palladium as the alloy of Example One were prepared,
but 0.50 and 1.0 percent rhenium were included respectively in the
latter two alloys. As the table shows, adding 0.50 percent of
rhenium decreased the size of the grains by about one-half. Adding
1.0 percent caused a further decrease so that the size of the
grains was almost one-third of the size of the grains contained in
the alloy of Example One. In addition, the grains in the alloys of
Examples Two and Three were found to be much more equiaxed than
those of the alloy of Example One.
The increased effectiveness of rhenium in alloys containing a
greater gold:platinum ratio is demonstrated by the comparison of
the alloys of Examples Four and Five. Here it found that the grains
are refined by the inclusion of 0.48 percent rhenium to an average
size which is about two-fifths the size of the comparable alloy
containing no phenium.
The alloys of Examples Six and Seven demonstrate not only the
effectiveness of the inclusion of rhenium in alloys containing even
higher gold:palladium ratios, but also the effectiveness of rhenium
alloys containing a combination of palladium and platinum. Small
amounts of iron were also present in these alloys. It is seen that
a dramatic decrease in grain size results from the inclusion of a
very small amount of rhenium. Inspection of the alloys also showed
that the alloy of Example Six had a dendritic morphology whereas
the grains of the alloy of Example Seven, which contained the
rhenium, were nondendritic. Thus, by comparing the alloys of
Examples Six and Seven, the effect of rhenium on grain formation is
clearly demonstrated.
In Examples Eight through Ten, the effect of iron or platinum in
obtaining a high level of grain refining is demonstrated. In
Examples Fourteen and Fifteen, the effect of iron with and without
rhenium may be seen.
Other alloys were prepared which contained in addition to gold,
platinum, and/or iron, palladium and rhenium small amounts of the
elements tin, silver, zinc and indium as set forth in Examples Ten
through Thirteen. All such alloys exhibited fine grain structure
and none exhibited dendritic morphology.
Thus, it can be seen that the present invention provides novel gold
alloys containing significant amounts of palladium (and platinum)
while at the same time evidencing equiaxed fine-grain structure.
The alloys produce castings free from shrinkage porosity and are
readily workable to provide structures free from inter-granular
cracking. Hardening mechanisms are optionally employed in
connection therewith so that alloys of a most desirable balance of
properties may be obtained.
* * * * *