U.S. patent number 3,714,891 [Application Number 05/096,274] was granted by the patent office on 1973-02-06 for process of using multi-purpose lithographic solution.
This patent grant is currently assigned to Addressograph-Multigraph Corporation. Invention is credited to Paul Brown, Charles H. Van Dusen, Jr..
United States Patent |
3,714,891 |
Van Dusen, Jr. , et
al. |
February 6, 1973 |
PROCESS OF USING MULTI-PURPOSE LITHOGRAPHIC SOLUTION
Abstract
A multi-purpose lithographic solution is provided adapted for
use in concentrated form and in different ratios of aqueous
dilution as conversion, start-up, fountain solution, or the like
for a plurality of different types of planographic printing
masters, such as electrostatic, direct-image, and photographic
planographic masters, both projection speed and conventional. The
solution preferably comprises glycerin, monosodium phosphate,
potassium ferrocyanide, and water as solvent. The amounts of the
dissolved components in the concentrated form must be present
within fairly narrow ranges. Similarly, when the concentrated
solution is diluted for use, for example as a fountain solution,
the dilution with water must be carried out in definite ratios of
concentrated solution to water.
Inventors: |
Van Dusen, Jr.; Charles H.
(Willoughby, OH), Brown; Paul (Cleveland, both, OH) |
Assignee: |
Addressograph-Multigraph
Corporation (Cleveland, OH)
|
Family
ID: |
22256621 |
Appl.
No.: |
05/096,274 |
Filed: |
December 8, 1970 |
Current U.S.
Class: |
430/49.8;
101/465; 101/451 |
Current CPC
Class: |
B41N
3/08 (20130101) |
Current International
Class: |
B41N
3/08 (20060101); B41N 3/00 (20060101); B41m
001/00 (); B41m 005/00 (); B41n 003/00 () |
Field of
Search: |
;101/450,451,464,465
;96/33,1R,1.8 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Klein; David
Claims
What is claimed is:
1. In a process of printing with a photographic planographic master
having an image formed from a developable silver halide, the steps
of contacting said master with a solution consisting essentially in
weight per cent of:
2. In a process of using sequentially in any order desired on the
same printing press a plurality of types of planographic masters
including electrostatic, direct-image, and photographic
planographic masters without having to remove fountain solution
from said press or otherwise prepare it for a change from one type
of planographic master to another, the improvements comprising:
a. first applying to any of said masters a lithographic solution
consisting essentially in weight per cent of:
wherein said alkali metal ferrocyanide is selected from the group
consisting of potassium ferrocyanide and sodium ferrocyanide,
thereby causing temporary blindness in said photographic
master,
b. using said solution diluted about one volumetric part of
solution to about 0.5 to 1.5 volumetric parts of water as a rubbing
solution to remove said blindness, and
c. thereafter using said solution in dilution as a fountain
solution for any of said planographic masters.
Description
BACKGROUND OF THE INVENTION
Planographic printing involves the preparation of a printing plate
having water-receptive, non-image or non-print areas and
water-repellent, ink-receptive areas constituting the image to be
reproduced. In use, the plate is moistened by a water-base liquid
which is repelled by the image areas but maintains the non-image
areas ink repellent. When printing ink is applied to the plate, the
ink-receptive image areas are coated but the water-receptive,
non-image areas repel the ink. Ink from the image areas only is
then transferred to a suitable copy sheet to reproduce the image.
The process is repeated as often as desired up to the life of the
planographic plate.
Various lithographic solutions are used in the preparation and/or
treatment of planographic masters prior to a run on a printing
press as well as while the master is being used to print a desired
image as described. For example, start-up solutions are used to
prepare a master for subsequent printing, while fountain solutions
maintain the non-image areas moist to repel the ink during a
printing operation. At present, such solutions can differ
substantially in composition depending on how they are to be used
and on what type of master. It has long been an objective in the
planographic art to realize a single lithographic solution for
substantially universal application, that is, one which might be
applied to all types of planographic masters and for different
functions, such as a conversion, start-up, or fountain
solution.
There are in current use three basic types of planographic printing
plates or masters: electrostatic, direct-image, and photographic
planographic masters. To prepare an electrostatic planographic
master, for example, a recording element is prepared by coating a
surface of a suitable backing with a photo-conducting, insulating
material such as zinc oxide dispersed in an
electrically-insulating, film-forming, water-insoluble material
such as a silicone resin. An electrostatic charge is produced over
the entire surface of the material, and a light image is focused on
the charged surface, thereby discharging those portions irradiated
by the light rays while leaving the remainder of the surface in a
charged condition. This forms an electrostatic image. The image is
rendered visible by next applying a developer powder which is held
electrostatically to the charged areas of the sheet. The powder
image so formed may be fixed directly to the photo-conductive
coating, or it may be transferred to another surface upon which the
reproduced image may then be fixed.
The developer powder used to prepare the electrostatic planographic
master is a hydrophobic material. Upon fixing the powder image to
the photo-conducting coating, the resulting element may be used for
lithographic printing after treatment with a known converter
solution.
A direct-image planographic master usually comprises a paper or
plastic base having a coating of a finely divided filler or pigment
such as clay and an adhesive, hydrophilic colloid such as casein
which serves as a binder. The direct-image master is prepared for
printing by directly marking on the master as by typing, drawing,
marking, or the like, to form image areas.
An oleophilic design on a hydrophilic surface may also be obtained
by photographic means, for example, by differentially hardening a
light sensitive organic colloid layer on a lithographic surface
with actinic rays and removing the unhardened areas to bare
hydrophilic non-printing areas. A "projection speed" method for
preparing a photographic planographic printing plate is described
in Yackel et al. U.S. Pat. No. 3,146,104, issued Aug. 25, 1964,
which provides formation of a developable silver halide image, as
by exposure to a line or halftone subject, of a hydrophilic,
organic colloid-silver halide film such as a gelatino-silver halide
sensitized plate, followed by silver halide development. No
additional steps, such as etching or washing off the unhardened
areas, are required for producing the plate. Moreover, the process
in its various forms can be adapted to the production of positive
plates from either positive or negative subjects.
This process is popularly known by the trademark "PHOTO-DIRECT,"
owned and registered by Addressograph-Multigraph Corporation.
Hereinafter, the term "photographic master" is used to designate
this type of planographic master.
Previously, the fountain, conversion, rubbing, start-up solutions,
etc., were formulated for use with a particular type of printing
plate in mind and were not generally suitable for universal use on
all types of planographic masters and for different purposes. As a
result, solutions already present in a printing press must be
removed and replaced whenever a change to a different type of
planographic master is desired, causing loss of valuable down time
on the press.
SUMMARY OF THE INVENTION
In accordance with the present invention, a multi-purpose
lithographic solution is provided that can be compatibly used,
either in concentrated or diluted form, with various types of
planographic masters and especially with electrostatic,
direct-image, and photographic planographic masters. The present
solution can be used as a conversion solution or start-up solution
or a rubbing solution, where those are needed, as well as being
used as a fountain solution. It is, therefore, not necessary to
change a solution in a press each time it is desired to use a
different type of planographic plate.
In a preferred embodiment, the present lithographic solution
adapted for such interchangeable use comprises in concentrated
form, by weight per cent, an aqueous solution of 20 per cent
glycerin, 15 per cent monosodium phosphate, and 2 per cent
potassium ferrocyanide. These amounts can be varied only slightly,
as hereinafter described, and still obtain an effective solution as
herein contemplated. Similarly, when the concentrated form of the
solution is diluted with water for other lithographic applications,
the dilution must be made within relatively narrow ranges of
volumetric ratios of the concentrated solution to water.
The concentrated solution is used as a conversion solution for
electrostatic masters and as a start-up solution for direct-image
masters and photographic masters, even though the concentrated form
of the solution causes temporary blindness in photographic
masters.
The concentrated solution, diluted about one volumetric part of
solution to about 0.5 part to 1.5 volumetric parts of water, may be
used as a rubbing solution for blinded photographic masters which
surprisingly removes the temporary blindness.
The concentrated solution, diluted about one volumetric part of
solution to about 2.5 to about 3.5 volumetric parts of water, may
be used as a fountain solution for any of the electrostatic,
direct-image, or photographic planographic masters.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In accordance with the present invention, a solution having the
varied application and interchangeability sought comprises the
following in weight per cent:
Component Range
__________________________________________________________________________
Glycerin 18 to 22 Buffered, ionizable, hydrogen-containing alkali
metal phosphate 14 to 18 Alkali metal ferrocyanide 1 to 3 Water
Balance
__________________________________________________________________________
A preferred embodiment comprises the following in weight per
cent:
EXAMPLE 1
Component Per Cent
__________________________________________________________________________
Glycerin 20 Monosodium phosphate 15 Potassium ferrocyanide 2 Water
Balance
__________________________________________________________________________
Optionally, from about 0.1 to about 1.5 weight per cent of a
sequestering agent may be included to reduce the tendency of a blue
precipitate to form from the ferrocyanide radical on standing or
aging of the solution. Various materials may be used for this
purpose such as the tetrasodium salt of ethylene diamine
tetraacetic acid. Addition of a sequestering agent may be
accompanied by a corresponding reduction in the amount of water.
Another exemplary composition of the present solution and one which
includes a sequestering agent comprises the following in weight per
cent:
EXAMPLE 2
Component Per Cent
__________________________________________________________________________
Glycerin 20 Monosodium phosphate monohydrate 17.25 Postassium
ferrocyanide 2 Ethylene diamine tetrasodium acetate 0.10
__________________________________________________________________________
The ethylene diamine tetrasodium acetate may be purchased as a
powder under the trademark VERSENE.
The glycerin hydrophilic as a humectant. As such, in view of its
hygroscopic character and its aid to viscosity, the glycerin keeps
clean the hydrophilic non-image areas of a master. In the case of
direct-image masters having paper backs, the glycerin also retains
the solution on the surface of a master and prevents it from
soaking into the paper which can result in curling of the
master.
Similarly, the glycerin retains the phosphate ion of the alkali
metal phosphate, hereinafter described, on the non-image areas of a
master where it can perform its useful and intended functions.
Accordingly, it is desirable to have as much humectant present as
possible, as long as the functions of the other components are not
adversely affected. Particularly desirable is a high weight ratio
of the phosphate ion to a humectant, so that the best features of
both components are happily combined.
Although in some lithographic solutions and especially fountain
solutions, other materials have been substituted for glycerin, such
as ethylene glycol and diethylene glycol, such substitution is not
possible with the present solutions. The desired results are
obtained only when glycerin is used as the humectant.
It is known that the phosphate ion, .tbd.PO.sub.4, is admirably
suited for maintaining the non-image areas of a master in a
hydrophilic condition. The effect of the phosphate ion, as well as
the latitude of application of a solution containing it,
particularly a concentrate, are directly related to the amount of
phosphate ion that can be dissolved. Not many phosphate compounds
are water soluble. Those that are have such a limited solubility in
glycerin-water solution that for a relatively concentrated
solution, such as that contemplated for the present solution
concentrate, not enough phosphate can be dissolved to meet the
objective sought. On the other hand, phosphoric acid, H.sub.3
PO.sub.4, is readily soluble in water. In this case, however,
dissolving enough acid to produce the desired amount of phosphate
ion in a concentrate renders the solution so strongly acidic that
it is impractical for use.
To place by dissolution sufficient quantities of the phosphate ion
in the solution concentrate without unduly lowering the acid pH, a
buffered phosphate compound is used. Although U.S. Pat. No.
3,398,002 to Bondurant et al teaches that monoammonium phosphate
can be used in the fountain solution of that patent in place of
monosodium phosphate, monoammonium phosphate is not useful in the
present solutions. It cannot provide the phosphate solubility
requirements. More seriously, when ammonium phosphate contacts a
photographic master, the master picks up ink throughout the plate,
in both image and non-image areas.
Instead, in the present solutions, buffered alkali metal phosphate
salts, such as sodium and potassium phosphates, that still contain
an ionizable hydrogen atom, are used. Although di-substituted
phosphoric acid salts, such as disodium acid phosphate, may be
used, it is preferred to use the mono-substituted salts because of
the required pH values. The preferred buffered phosphate compound
is monosodium phosphate. The hydrated form of an alkali metal acid
phosphate may be used to promote the dissolving action.
Although the alkali metal ferrocyanide may be sodium ferrocyanide,
it is preferred to use potassium ferrocyanide. Usually potassium
ferrocyanide trihydrate is used to facilitate its dissolution in
the water solvent. As indicated, it is because of the ferrocyanide
component that a sequestering agent is desirably used if the
solution is apt to stand for an extended period of time. The
ferrocyanide ingredient is apt to decompose and form a
ferro-ferrocyanide compound which, in the absence of a sequestering
agent, can form a blue precipitate.
To prepare a solution of the present invention, the indicated
components may be added to water, which preferably is distilled
water, in any order desired with accompanying stirring until
solution is obtained. In general, the buffered, ionizable,
hydrogen-containing alkali metal phosphate, the alkali metal
ferrocyanide, and the sequestering agent, when one is used, are
added together to the water which is then stirred until all
components are dissolved. The glycerin is next added with continued
stirring until homogeneity is obtained. Preferably, the pH of the
solution is adjusted to about 4.0 at 25.degree. C. by adding either
ammonium hydroxide or phosphoric acid as may be necessary. One
solution prepared with the composition of Example 1 had a specific
gravity of 1.180 to 1.190 at 25.degree. c./4.degree. C. and a pH of
3.9 to 4.10 at 25.degree. C. For shipment to a point of use, the
present solutions may be packaged in translucent brown polyethylene
containers.
The amounts of the components of the present concentrated solutions
can be varied surprisingly little and still obtain the desired
universal applicability. The same is true with respect to the
volumetric ratios of concentrated solution to water in diluting the
former for various applications as herein described.
Arbitrarily beginning the use of the present solutions with an
electrostatic master, the solution is used initially in
concentrated form, that is, as first given, supra, to convert the
master. It is the ferrocyanide radical which converts an
electrostatic master for use in a printing press. Prior to
conversion, both the image and non-image areas of an electrostatic
master are hydrophobic and oleophilic. During conversion, the
ferrocyanide radical reacts with the photo-conductive metal in the
non-image areas, such as zinc oxide, which has not been affected by
the hydrophobic electrostatic developer powder, and renders the
non-image areas hydrophilic and oleophobic by depositing, for
example, zinc ferrocyanide. Thereafter, another portion of the
concentrated solution is diluted about one volumetric part of the
solution to about 2.5 to about 3.5 volumetric parts of distilled
water, and the resulting diluted solution operates well as a
fountain solution for the same electrostatic master. The preferred
ratio of concentrated solution to water for this purpose is 1 to 3,
respectively.
The acceptable use of a solution containing a ferrocyanide in
contact with a photographic planographic master is most surprising.
Indeed, such a master does go blind, that is, the image areas do
not pick up ink after initial contact with the present solutions.
More particularly, if a fountain solution of the present
concentrated solution, diluted about one volumetric part to about
2.5 to 3.5 volumetric parts of distilled water, is used on a
photographic planographic master, the master goes blind and does
not pick up ink. However, if the present concentrated solution is
diluted about one volumetric part of solution to about 0.5 to 1.5
volumetric parts of water, and the solution so diluted is worked as
by rubbing into the image areas of the photographic planographic
master; the master unexpectedly operates well thereafter even
though the same fountain solution is used, that is, the present
concentrated solution diluted with water in a volumetric ratio of
about 1:2.5 to 3.5. The preferred ratio for the rubbing solution is
one volumetric part of concentrated solution to one volumetric part
of water.
The reason for this reversal of results is not clear. It may be
that the rubbing operation works sufficient ink, which is on the
plate from the attempted start-up operation, into the image areas
without affecting the hydrophilic background and that the present
solutions, diluted 1:2.5 to 3.5 with water, are thereafter
compatible with the operation of such a plate. The dilution of the
rubbing or working solution into the approximate 1:0.5 to 1.5
volumetric ratio is important. If, for example, a concentrated
solution is used to rub the plate, or if such solution is diluted
1:2.5 to 3.5 as for a fountain solution, the described results for
a photographic planographic master are not obtained.
If a direct-image master is to be used, the concentrated solution
(undiluted) is used as a start-up solution. Thereafter, a
concentrated solution is diluted about one volumetric part of
solution per about 2.5 to 3.5 volumetric parts of distilled water,
and the solution so diluted then used as a fountain solution for
the direct-image master.
The following examples are intended to illustrate the invention and
should not be construed as limiting the claims. Percentages are by
weight.
EXAMPLE 3
An electrostatic master was mounted in a standard offset printing
press for planographic masters. The electrostatic master had a
paper back coated with a photo-conducting composition including
about 100 to 900 parts by weight of photo-conducting zinc oxide and
about 100 parts by weight of a vehicle consisting essentially of
about 5 per cent to about 25 per cent of zinc acetate and about 95
per cent to about 75 per cent of resinous polyvinyl alcohol. An
electrostatic image had been formed and developed in a known
manner.
The electrostatic master was contacted on the printing press with
the concentrated solution of Example 1. The potassium ferrocyanide
reacted with the zinc oxide in the non-image areas and converted
them to hydrophilic and oleophobic areas. The solution did not
change the character of the image areas which remained hydrophobic
and oleophilic.
Thereafter, the printing press was provided with a fountain
solution consisting essentially of the composition of Example 1
diluted about one part of the solution to about three parts of
distilled water by volume. The printing press ran continuously and
produced an acceptable long run of copies from the converted
electrostatic master.
EXAMPLE 4
The electrostatic master was removed from the printing press of
Example 3 and replaced by a photographic planographic master. This
master had been produced in accordance with the teachings of Yackel
et al U.S. Pat. No. 3,146,104 and involved the formation of a
silver halide image. The fountain solution was not drained from the
printing press of Example 3 but was allowed to remain. When the
press was started, the fountain solution and ink were sequentially
applied to the photographic master in the usual manner. As
anticipated the master ran blind after a few impressions because of
the presence of potassium ferrocyanide.
The press was then stopped and the photographic master rubbed with
a solution corresponding to the composition of Example 1 diluted in
substantially equal volumetric parts with distilled water. This
appeared to cause the image areas to take some of the ink which had
been left on the plate by the initial run. Thereafter, the press
was restarted and ran well, although the fountain solution was the
same which had been used in Example 3 and which was initially used
in this example, namely, the composition of Example 1 diluted about
one volumetric part to about three volumetric parts of water.
These results of a successful run were quite surprising, especially
in view of the fact that varying the amount of dilution or
concentration of the present solutions in either direction produced
undesirable results At higher concentrations of the solutions, the
entire master became ink-receptive; while at lower concentrations
than those described the image remained blind.
EXAMPLE 5
The photographic planographic master of Example 4 was removed from
the printing press of Examples 3 and 4 and replaced by a
direct-image master. This master comprised a kraft paper backing
having a coating of finely divided clay and an adhesive hydrophilic
colloid of finely divided clay and an adhesive hydrophilic colloid
of guar gum which served as a binder. The direct-image master
contained as an image typing legend extending across the master.
The master was first contacted with the concentrated solution of
Example 1, that is, undiluted, as a start-up solution. Thereafter,
the same fountain solution was used as that previously employed,
namely, the solution of Example 1 diluted one volumetric part to
three volumetric parts of distilled water. The printing press
produced many acceptable copies from the direct-image master.
For best results when interchanging the above-indicated types of
masters, it is recommended that the electrostatic master should be
converted in an Addressograph-Multigraph Converter. PHOTO-DIRECT
masters should be processed in the normal manner.
The present concentrate solution is a shippable commodity which can
be diluted, if and when desired, at a point of application for use
with a plurality of different types of masters without losing its
ability to perform in the manner indicated.
The present solutions, either in concentrated or diluted form as
described, serve as a converter solution for electrostatic masters;
as a start-up solution for direct-image and photographic masters;
as a rubbing solution to remove the temporary blindness imparted
thereby to photographic masters; and as a fountain solution for all
three types of planographic masters.
Although the foregoing describes several embodiments of the present
invention, it is understood that the invention may be practiced in
still other forms within the scope of the following claims.
* * * * *