U.S. patent number 3,706,670 [Application Number 05/102,046] was granted by the patent office on 1972-12-19 for bleaching composition.
This patent grant is currently assigned to Colgate-Palmolive Company. Invention is credited to Frederick William Gray.
United States Patent |
3,706,670 |
Gray |
December 19, 1972 |
BLEACHING COMPOSITION
Abstract
This disclosure relates to bleaching laundry compositions
comprising a chlorine bleach, an optical brightener, preferably of
the sulfonated triazole class, and a reducing agent such as
inorganic sulfites, organic sulfinates, water-soluble phosphites,
and inorganic alkaline materials combined with hydrogen peroxide.
The presence of the reducing agent enables the composition to
enhance brightening of the fabric being cleaned without adversely
affecting the bleaching thereof to any appreciable extent. The
optional addition of a detergent or surface active agent, also
beneficially affects the brightener intensity.
Inventors: |
Gray; Frederick William
(Summit, NJ) |
Assignee: |
Colgate-Palmolive Company (New
York, NY)
|
Family
ID: |
26798934 |
Appl.
No.: |
05/102,046 |
Filed: |
December 28, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
679506 |
Oct 31, 1967 |
|
|
|
|
Current U.S.
Class: |
510/307; 8/648;
510/108; 510/513; 510/381; 510/379; 252/186.22; 252/186.43;
252/187.34 |
Current CPC
Class: |
C11D
3/3955 (20130101); C11D 3/395 (20130101); C11D
3/39 (20130101); C11D 3/42 (20130101); C11D
3/0042 (20130101) |
Current International
Class: |
C11D
3/40 (20060101); C11D 3/42 (20060101); C11D
3/395 (20060101); C11D 3/39 (20060101); C11D
3/00 (20060101); C11d 007/54 () |
Field of
Search: |
;252/95,99,105,186,187,188 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Weinblatt; Mayer
Parent Case Text
This application is a continuation of Serial No. 679,506, filed
October 31, 1967, now abandoned.
Claims
I claim:
1. A powdered bleaching composition consisting essentially of a
chlorine bleaching agent capable of liberating chlorine ions in an
aqueous medium, about 0.05 to 1.0 percent of a chlorine resistant
optical brightener of the sulfonated triazole class, and a water
soluble reducing salt readily oxidizable in an aqueous medium by
said chlorine bleaching agent, the ratio of said reducing agent to
said bleaching agent ranging from 0.03:1 to 0.8:1 on a
Stoichiometric basis, said reducing salt being more readily
oxidizable by said chlorine bleaching agent than said
brightener.
2. A composition in accordance with claim 1, wherein the reducing
salt is sodium sulfite.
3. A composition in accordance with claim 1, wherein the reducing
salt is sodium thiosulfate.
4. A composition in accordance with claim 1, wherein the reducing
salt is sodium perborate.
5. A composition in accordance with claim 1, wherein the chlorine
bleach is selected from the class of di or tri chlorinated
isocyanurates and mixtures thereof.
6. A composition in accordance with claim 1, wherein the amount of
reducing salt is from 5 to 25 percent of the stoichiometric
requirement for complete reaction with the bleach compound.
7. A composition in accordance with claim 1, which also contains an
alkaline, water-soluble inorganic salt and mixtures thereof, other
than said reducing agent.
8. A composition in accordance with claim 1, wherein the reducing
salt is sodium or potassium hypophosphite.
9. The composition of claim 1 wherein the amount of chlorine
bleaching agent provides in an aqueous medium 40 to 400 ppm
available chlorine.
10. A composition in accordance with claim 1, which also contains a
water-soluble organic surface active agent stable in the presence
of the chlorine bleaching agent.
11. A composition in accordance with claim 2, wherein the chlorine
bleach is a di or tri chlorinated isocyanurate and mixtures
thereof.
12. A composition in accordance with claim 5, wherein the chlorine
bleach is a mixture of potassium dichloroisocyanurate and
trichloroisocyanuric acid in a ratio of 4:1.
13. A composition in accordance with claim 5, wherein the reducing
salt is sodium or potassium hypophosphite.
14. A composition in accordance with claim 5, wherein the chlorine
bleach is potassium dichloroisocyanurate.
15. A composition in accordance with claim 6, wherein the reducing
salt is sodium sulfite and the chlorine bleach is a di or tri
chlorinated isocyanurate and mixtures thereof.
16. A composition in accordance with claim 7, wherein the surface
active agent is a C.sub.8 to C.sub.22 alkyl benzene sulfonate.
17. A powdered bleaching composition consisting essentially of a
chlorine bleaching agent capable of liberating chlorine ions in an
aqueous medium, a chlorine resistant optical brightener of the
sulfonate triazole class and a water soluble reducing salt readily
oxidizable in an aqueous medium by said chlorine bleaching agent,
said chlorine bleaching agent being present in an amount to provide
in aqueous medium from 40 to 400 ppm available chlorine, said
optical brightener being present in an amount to provide in aqueous
medium 3 to 10 ppm thereof and said reducing salt being present in
an amount from 5 to 25 percent of the Stoichiometric requirement
for complete reaction with said bleaching agent, said reducing salt
being more readily oxidizable by said chlorine bleaching agent than
said brightener.
Description
The present invention relates to a bleaching composition containing
a chlorinated bleach, and a stabilized optical brightener
system.
The use of optical brighteners in chlorine bleach compositions to
effect brightening on clothes is common practice. However, the
problem of incompatability of brighteners of desirable hue with the
chlorine bleach compound is well recognized in the art. This
difficulty has been overcome in the past by the use of specific
classes of optical brighteners. However, it has been found that
chlorine bleach compositions, particularly chloroisocyanurate
bleach is non-compatible with most brighteners of desirable hue and
of reasonable cost, the neutral blue fluorescence being
preferable.
Another problem encountered with the optical brighteners is its
instability towards the chlorine bleach in the wash solution,
whereby it is destroyed by the chlorine prior to its adherence to
the fabric. This difficulty has been solved in the past by the use
of ultra-marine blue pigment which attempts to mask any yellowing
due to repeated bleaching or the inherent color of the fluorescent
brightener. Another solution to this problem involves the
compounding of a solid core of bleach with an outer contiguous
coating which contains the optical brightener, detergent and other
additives; whereby the outer coating dissolves first and permits
the attachment of the brightener to the fabric before it can be
destroyed by the chlorine bleach. The destroyed action of the
bleach resulting from the aforementioned solid composition has only
limited utility in view of the fact that the fabric must be present
in the wash solution prior to the dissolution of the bleach
therein. There must be a fabric onto which the brightener can
adhere, otherwise the effectiveness of the brightener is destroyed
by the chlorine bleach. Thus, it is apparent that the many
solutions to the problem of a stabilized optical brightener
coexisting with a chlorine bleach have been partial and
incomplete.
It has now been found that the addition of a reducing agent to a
chlorine bleach composition containing an optical brightener
effects improved whiteness of fabric. Presumably the reducing agent
provides a more easily oxidizable substance than the brightener for
the initial action taken by the chlorine bleach, thereby protecting
the brighteners until it is absorbed onto the fabric. Moreover, in
addition to the protection afforded to the brightener it is
conceivable that dye and fabric damage as evidenced by localized
bleaching and weakness of fiber would also be diminished by the
presence of a reducing agent.
Accordingly, the present novel bleaching compositions containing
optical brightener and reducing agent have the advantage of being
suitable in a laundering medium even though the introduction of
textile materials be delayed for a reasonable time. It permits the
addition of the fabric to the wash solution which is the
conventional method of home laundering, without appreciable, if
any, loss in the whitening by bleach and with appreciable increased
brightening effect by the brightener. The small, if any, loss in
whitening by the bleach due to the presence of reducing agent is
more than compensated by the appreciable increase in the efficiency
of the brightener.
More specifically, the instant invention relates to a bleaching
composition comprising a chlorine bleach, an optical brightener,
and a reducing agent readily oxidizable in aqueous medium.
Any chloride bleaching agent, organic or inorganic (e.g. calcium
hypochlorite and the like) capable of liberating chlorine ions in
an aqueous medium is suitable for use in the instant novel
compositions. Particularly efficient are dry, granular, organic
bleaching compounds such as trichloroisocyanuric acid (TCCA),
dichloroisocyanuric acid (DCCA) and the sodium and potassium salts
of dichloroisocyanuric acid (NaDCC and KDCC). The weight of
chlorine bleaching agent to be used in a dry composition will be
dependent upon the available chlorine content of the bleach
ingredient selected. Compositions of this invention can be
formulated to provide aqueous wash solutions with a wide range of
available chlorine content, and mixtures of these. Preferably, the
compositions to be used in aqueous solution will deliver between 40
to 400 ppm of available chlorine.
The optical brightener which is an essential ingredient in a wash
solution, are fluorescent materials that are substantive to cloth
and provide thereby a desirable hue, preferably blue. They are
commonly used in heavy duty laundry products. Unfortunately, not
all fluorescent brighteners are compatible for use with a chlorine
bleaching agent. Consequently, this difficulty is one of the major
reasons for the use of a mixture of optical whitening agents in
laundry products. In this respect the 2-stilbymonotriazole,
benzimidazole, and dibenzothiophene dioxide type brighteners are
characterized by a significant degree of resistance to chlorine
bleach. On the other hand, the less expensive and exceptionally
strong cotton brighteners having the trizinyl stilbene structure
are generally classified as being ineffective in the presence of a
chlorine bleach.
The optical brightener is an essential ingredient in the instant
composition since it enhances the brightness of textiles and
counteracts the yellowing of fabric due to repeated bleaching.
Although any optical brightener characterized above as being
possessed of a significant degree of resistance to chlorine bleach
can be utilized herein, the sulfonated triazoles are preferred. An
example of a 2-stilbemonotriazole type brightener is sodium
2-sulfo-4-(2-naphtho-1,2 triazole) stilbene of the following
formula: ##SPC1##
Also, the presence of a small amount of sodium sulfite in a wash
solution containing certain triazinyl type brightener and chlorine
bleach will effect a significant improvement in the deposition of
brightener onto fabric. For this class of brightener, the disodium
salt of 4,4'-bis (4-anilino-6-morpholino-S-triazin-2-yl-amino) 2,2'
stilbenedisulfonate is preferred. It is represented by the
following formula: ##SPC2##
A small but significant amount of brightener is necessary to effect
the brightness onto the fabric, about 0.05 to 1.0 percent of the
total composition. Preferably the brightener-bleach composition
will provide a wash solution containing about 3-10 ppm of the
2-stilbyltriazole brightener.
The chloroisocyanurates are usually mixed with dry, water soluble
salts preferably alkaline salts as carrier agents to provide bulk
and alkalinity to the bleaching compound when dissolved in water.
Sodium tripolyphosphate and sodium carbonate are commonly used to
provide desirable alkalinity and sodium sulfate or sodium chloride
are often used as filler. Such compositions in the presence of
certain brighteners as for example the monosulfostilbene
naphthomonotriazole, sodium 2-sulfo-4(2-naphtho-1,2 triazole)
stilbene, are able to whiten clothes by reason of the bleaching
agent and also the optical whitener. However, the magnitude of the
fluorescent intensity on fabric is dependent upon the conditions of
use and the formulation of the product. For example, in a hand
soaking operation or mechanical washing machine, the brightener
effectiveness is related to the time of bleach and brightener
contact prior to the addition of fabric and to whether an organic
surfactant detergent, preferable of the anionic sulfonate or
sulfate class, is present in the solution in a sizable amount.
Minimum time elapse prior to addition of textile materials to the
bleach solution and the presence of a substantial amount of an
organic detergent in the solution provides for better overall
whitening of the textiles being cleaned. To omit the organic
detergent from a wash solution containing otherwise the same
concentration of brightener, bleach and inorganic builders will
invariably result in less brightener substantivity on fabric being
washed. Moreover, the effect of sodium tripolyphosphate
concentration toward brightener substantivity on fabric being
washed in a bleach-brightener solution not containing anionic
detergent indicates that brightener ability is not dependent, at
least entirely, on pH conditions. Instead, the behavior of
bleach-brightener systems suggests the possibility that an
initially fast reacting and strong oxidizing material or medium
associated with initial hydrolysis of the chloroisocyanurate tends
to destroy the small amount of brightener present before it adheres
to the fabric unless a more easily oxidizable substance, presumably
the alkylbenzene sulfonate, is present. Indeed, as shown in the
examples of this invention, by the use of a small amount of
reducing agent in a brightener-bleach solution containing inorganic
salts, the same or better fluorescent intensity on fabric can be
obtained as would be achieved by use of a substantial amount of a
detergent composition containing organic surfactant.
In addition to sodium tripolyphosphate, sodium carbonate, sodium
sulfate and sodium chloride, other suitable inorganic salts may
serve to adjust pH and also to act as carrier or dispersion medium
for the bleaching agent or brightener, such as: potassium
carbonate, sodium and potassium silicate, borax, trisodium
phosphate, tetra sodium pyrophosphate, disodium hydrogen phosphate,
pentapotassium tripolyphosphate, and nitrilotriacetic acid
(including alkaline metal salts).
The proportion of inorganic build salts which is used may vary
widely. Most desirably, sodium tripolyphosphate and sodium sulfate
comprise the bulk of the inorganic salt content. Formulated
compositions without or with minor amounts of organic surfactant
should preferably deliver under use condition between 150-450 ppm
of sodium tripolyphosphate to the wash solution.
The reducing agent which is another essential ingredient of the
instant invention may be any water soluble salt that is easily
oxidizable such as sodium and potassium sulfite, sodium and
potassium hypophosphite, sodium thiosulfate, sodium
dodecylbenzenesulfinate, sodium toluenesulfinate, sodium
benzenesulfinate, sodium perborate and sodium percarbonate. In
solution, sodium percarbonate and sodium perborate release oxygen
in the presence of chloroisocyanurate and the resulting
effervescence aids in the disintegration or dissolution of the
product.
Depending on conditions and desirable degree of fluorescence
relative to bleaching the quantity of reducing agent used may vary
considerably. An effective amount of reducing agent is related to
the bleaching composition used, particularly to the selected
chlorine compound used therein. The purpose of the reducing agent
may be to enhance brightener intensity on textiles with appreciable
loss in bleaching of the fabric or its purpose may be to obtain
optimum fluorescent intensity while obtaining a lower though
satisfactory level of bleaching by the chlorine compound.
Accordingly, the effectiveness of the brightener-bleach composition
to brighten textiles will be related to the moles quantities of
reducing agent and chlorine compound that could theoretically react
completely in solution. In general the amount of reducing agent
will vary from about 30 percent to about 80 percent and preferably
from about 5 percent to about 25 percent of the stoichiometric
requirement for completing reaction with the bleach compound. To
exemplify the specific system such as sodium sulfite-KDCC, it will
be noted that the stoichiometric quantities are 2 moles of sodium
sulfite to 1 mole of KDCC. Preferred system for use in this
invention would employ on a molar basis 0.06 to 0.40 moles of
sodium sulfite per mole of KDCC.
The bleaching compositions of the instant invention are dry,
water-soluble powders, which may be packaged in bulk in assorted
containers or in individual, premeasured water-soluble packets. The
water-soluble polyvinyl alcohol film is particularly useful as
packet material since it has long shelf life and is resistant to
gases, oil and grease.
The compositions suitably may contain additional constituents such
as water-soluble organic surface active agents which are stable in
the presence of the chlorine-liberating compounds. Such surface
active agents may be anionic detergent salts having alkyl group of
eight to 22 carbon atoms such as the water-soluble olefin
sulfonates, paraffin sulfonates and the higher fatty acid alkali
metal soaps, e.g. sodium myristate and sodium palmitate;
water-soluble sulfated and sulfonated anionic alkali metal and
alkaline earth metal detergent salts containing a hydrophobic
higher alkyl moiety (typically containing from eight to 22 carbon
atoms) such as alkyl mono- or poly-nuclear aryl sulfonates having
from 10 to 16 carbon atoms in the alkyl group (e.g. sodium
dodecylbenzenesulfonate, magnesium tridecylbenzene sulfonate,
lithium or potassium pentapropylene benzene sulfonate); alkali
metal salts of higher alkyl naphthalene sulfonic acids, sulfated
higher fatty acid monoglycerides such as the sodium salt of the
sulfated monoglyceride of coconut oil fatty acids and the potassium
salt of the sulfated monoglyceride of tallow fatty acids; alkali
metal salts of sulfated fatty alcohols containing from 10 to 18
carbon atoms (e.g. sodium lauryl sulfate and sodium stearyl
sulfate); alkali metal salts of higher fatty acid esters of low
molecular weight alkylol sulfonic acids, e.g. fatty acid esters of
sodium salt of isethionic acid; the fatty ethanolamide sulfates;
the fatty acid amides of amino alkyl sulfonic acids, e.g. lauric
acid amide of taurine; as well as numerous other anionic organic
surface active agents such as sodium toluene-sulfonate, sodium
xylene-sulfonate, sodium napthalene sulfonate; and mixtures
thereof. In general these organic surface active agents are
employed in the form of their alkali metal salts or alkaline earth
metal salts as these salts possess the requisite stability,
solubility, and low cost essential to practical utility. It has
been found that a long chain alkylbenzene-sulfonate is particularly
effective in the enhancement of brightener intensity. The amount of
organic surface active agent utilizable herein may vary from 0 to
35 percent of the composition.
Minor amounts of optional ingredients which do not interfere with
the bleaching and brightening action of the composition may be
included such as coloring materials, perfumes, corrosion
inhibitors, binders, suds suppressors, etc.
The following examples are illustrative of the invention and it
will be understood that the invention is not limited thereto.
EXAMPLES I AND II
Ingredients Examples
__________________________________________________________________________
I II
__________________________________________________________________________
alkylbenzenesulfonate detergent* - 1.5 g. Potassium
dichloroisocyanurate 0.4 g. 0.4 g. Sodium tripolyphosphate (NaTPP)
0.4 g. 0.4 g. Sodium sulfate 1.0 g. 1.0 g. Sodium sulfite (reducing
agent) 75 mg. 75 mg. Monosulfostilbene naphthomonotriazole
brightener I 3.0 mg. 3.0 mg. pH (completion of Wash) 7.4 8.5
*Contains: 21% Sodium tridecylbenzenesulfonate, 35% sodium
tripolyphosphate, 27% sodium sulfate, 7% sodium silicate, 1% Borax,
9% moisture.
Each of the dry powder compositions given in Examples I and II was
dissolved in a liter of water and pre-agitated in a tergotometer at
120.degree.F for two minutes. Then, to each test solution was added
6 cotton, 3 nylon, and 3 dacron non-soiled swatches having the
dimensions of 3 .times. 6 inches. These test fabrics were subjected
to a 10-minute wash cycle in the brightener-bleach solution and
then rinsed and dried at 140.degree.F for 2 hours in a forced draft
oven. After a period of about 18 hours at room temperature,
fluorescent intensities (F.I.) of the test fabrics treated in each
of the test solutions were obtained by means of a fluorimeter. The
results clearly showed that the fluorescent intensity of the above
treated fabrics was far greater than that of fabrics washed with
bleach-brightener compositions containing no reducing agent.
EXAMPLE III
Ingredients Amounts
__________________________________________________________________________
Sodium tridecylbenzenesulfonate detergent 2.0 g. Potassium
dichloroisocyanurate 0.4 g. Sodium tripolyphosphate 0.6 g. Sodium
sulfate 1.0 g Monosulfostilbene naphthomonotriazole, brightener I
3.0 mg. Sodium sulfite (reducing agent) 50.0 mg.
This dry powder composition was dissolved in a liter of water and
pre-agitated in a tergotometer at 120.degree. for 5 minutes,
conditions which are far more severe for chlorine and brightener
stability than ordinarily experienced under actual use. Test
fabrics, either 12 sulfur dyed swatches (3 .times. 6 inches) or 12
white cotton swatches (3 .times. 6 inches) were introduced into the
receptacle containing the brightener-detergent bleach solution and
subjected to a 10 minute wash cycle (pH 8.6). The fabrics were
rinsed, dried and tested for brightness and bleaching improvement.
The fluorescent intensity measurements with fluorimeter of the
above treated fabrics were far greater than that of fabrics washed
with bleach-brightener compositions containing the same ingredients
except that the reducing agent was omitted. Reflectance
measurements taken with Gardner Color Difference Meter on sulfur
dyed swatches showed that the small amount of sulfite used to
improve the brightener intensity has little, if any, adverse effect
on bleaching.
EXAMPLE IV
The sodium sulfite content of Example III was doubled and the
composition then evaluated as before. Fluorescence intensity of the
white cotton fabric was superior to those treated in Example III.
The reflectance value for the sulfur dyed fabric was slightly lower
than obtained in Example III but the bleached fabric had the same
fluorescent intensity as in Example III.
EXAMPLE V
The composition given in Example I was dissolved in a liter of
water and pre-agitated in a tergotometer at 120.degree. for either
0-, 2-, or 5 minutes prior to the addition of 12 white cotton
swatches (3 .times. 6 inches). After a 10 minute wash period, the
fabrics were rinsed, dried and compared against fabrics subjected
to the same treatment with the exception that sodium sulfite was
omitted from the composition. Average fluorimeter readings for test
fabrics treated with a solution of composition containing sulfite
were 86, 88, 90 for 0, 2 and 5 minute pre-wash times respectively
versus only 33, 25 and 12 readings on fluorimeter for fabrics
treated with solution not containing sulfite. At the end of the
wash cycle with 5 minute pre-wash pH of sulfite solution was 7.5
and available chlorine loss amounted to 18 percent. The pH of
solution without sulfite was 7.9 and available chlorine loss
amounted to 8 percent.
EXAMPLE VI
The disodium salt of (dimorpholino s-triazin-2-ylamino)
stilbenedisulfonic acid (Brightener II) was used in place of the
triazole brightener in Example V. Fabric treated with this
brightener-bleach sodium sulfite solution exhibited superior
brightness both visually and when measured on the fluorimeter.
EXAMPLES VII, VIII AND IX
Ingredients VII VIII IX
__________________________________________________________________________
anhydrous sodium sulfate 0.997g. 0.997g. 0.997g. Brightener (the
triazole of Example I) 0.003g. 0.003g. 0.003g. Potassium
dichloroisocyanurate 0.4g. 0.4g. 0.4g. Sodium thiosulfate 0.1g.
0.08g. 0.15g. Sodium tripolyphosphate 0.6g. 0.6g. 0.6g.
The use of sodium thiosulfate as the reducing agent in the
bleach-brightener composition yielded similarly superior brightness
in fabrics treated therewith as in the previous examples.
EXAMPLE X
Ingredients Compositions
__________________________________________________________________________
Potassium dichloroisocyanurate 0.4 g. Sodium tripolyphosphate 0.4
g. Sodium sulfate 1.0 g. Sodium hypophosphite monohydrate 50.0 mg.
Monosulfostilbene naphthomonotriazole brightener I 3.0 mg.
In a tergotometer at 120.degree.F, a solution of this composition
was agitated for 5 minutes prior to addition of test fabrics. The 6
white cotton, 3 coffee/tea stained and 3 sulfur dye stained
swatches were washed in the solution for 10 minutes and then
evaluated for brightening and bleaching as described in previous
examples. By visual observation and by measurements taken on a
Gardner Color Difference Meter, the coffee/tea stained and sulfur
dyed fabrics were strongly bleached to the same extent as were
fabrics washed under the same conditions but no hypophosphite.
However, the fluorescent intensity on the white fabric treated with
the solution containing hypophosphite was considerably higher,
measured on a fluorimeter than white fabric treated with a solution
of this composition that did not contain sodium hypophosphite. The
pronounced difference was discernible to the eye in the presence of
ultraviolet light. This demonstrates inter alia, that in a mixed
load of stained and unstained goods, equivalent bleaching is
achieved on the stained goods (i.e. vis-a-vis treatment with no
reducing agent) along with superior brightening of the unstained
goods.
On completion of the wash cycle, the solution had a pH of about 7.6
and available chlorine loss of about 19 percent, which was similar
to the result obtained by a solution minus the hypophosphite
reducing agent. ##SPC3##
The presence of organic sulfinates as the reducing agent is a
brightener-bleach composition improves brightener intensity on
fabric, similarly to the compositions of Examples I thru X.
Moreover, the effectiveness of the organic sulfinates for cleaning
and brightening efficiency is particularly noticeable when the
solution contains from 0.2 to 0.5 g. of organic sulfinate and the
same type and quantity of brightener, bleach and phosphate as given
in Example III but the sulfonate detergent is not present.
EXAMPLES XXIV - XXX
The organic sulfinates of the previous examples were replaced by
0.025, 0.05, 0.075, 0.1, 0.2, 0.3, 0.4 g. of sodium perborate
(H.sub.2 O.sub.2 content, 21 percent) with similarly superior
brightness results, the fluorescent intensity increasing
progressively as the concentration of the perborate increased.
EXAMPLES XXXI - XXXVII
The perborates of the previous examples were replaced by 0.025,
0.050, 0.075, 0.10, 0.20, 0.30 and 0.40 g. of sodium percarbonate
(H.sub.2 O.sub.2 content 25 percent). The treated fabrics were
whiter and brighter as clearly evidenced by the fluorescent
intensities measured on a fluorimeter which progressively increased
with an increase in the concentration of the percarborate.
EXAMPLE XXXVIII
The following composition is prepared:
KDCC 0.145 g. TCCA 0.036 g. NaTPP 0.400 g. K.sub.2 CO.sub.3 0.050
g. Na.sub.2 SO.sub.3 0.050 g. Na.sub.2 SO.sub.4 0.050 g. Brightener
I 0.003 g.
The results are comparable to Example I.
The compositions of all the aforementioned examples may be packaged
in individual substantially water-soluble packets. These dry,
powdered compositions may also be bulk-packaged in suitable
containers such as cardboard boxes, plastic containers, etc. The
powder may also be pressed into tablet form and suitably packaged.
The reducing agent can be incorporated into detergent composition
for separate addition to any brightener-bleach solution.
Although the present invention has been described with reference to
particular embodiments and examples, it will be apparent to those
skilled in the art that variations and modifications of this
invention can be made and that equivalents can be substituted
therefor without departing from the principles and true spirit of
the invention.
* * * * *