U.S. patent number 3,706,599 [Application Number 05/139,664] was granted by the patent office on 1972-12-19 for sugar drying method.
This patent grant is currently assigned to W. R. Grace & Co.. Invention is credited to Viggo S. Andersen, Edward T. Woodruff.
United States Patent |
3,706,599 |
Woodruff , et al. |
December 19, 1972 |
SUGAR DRYING METHOD
Abstract
In a process for drying droplets of sucrose-containing solution
in a current of heated air and in the presence of 0.5 to 4.0 parts
by weight of separately introduced recycled product solids per part
by weight of solids in said solution the improvement which
comprises controlling the average particle size of the recycled
product solids at about 200 microns or less and dispersing the
recycled fine-sized solids at the outer periphery of the drying
zone as an enveloping solids-bearing atmosphere around the solution
droplets. Apparatus is disclosed for carrying out the process
including a spray drying chamber, a centrally located liquid
atomizer, drying air inlet and outlet conduits, solids product
collection means, means for deagglommerating product solids, and
means for recycling product solids to the drying chamber and
introducing them tangentially as an enveloping curtain of solids
adjacent the walls of the drying chamber.
Inventors: |
Woodruff; Edward T. (Woodbine,
MD), Andersen; Viggo S. (Hackettstown, NJ) |
Assignee: |
W. R. Grace & Co. (New
York, NY)
|
Family
ID: |
22487734 |
Appl.
No.: |
05/139,664 |
Filed: |
May 3, 1971 |
Current U.S.
Class: |
127/62; 127/58;
159/4.2; 159/48.1; 127/16; 159/4.06 |
Current CPC
Class: |
C13B
30/028 (20130101) |
Current International
Class: |
C13F
1/00 (20060101); C13F 1/02 (20060101); C13f
001/02 () |
Field of
Search: |
;127/58,61,62
;159/4R,4S |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wolk; Morris O.
Assistant Examiner: Marantz; Sidney
Claims
What is claimed is:
1. In a process for continuously preparing dried, solid
sucrose-containing product from a sucrose-containing solution by
continuously drying droplets of the said solution in a current of
heated air and in the presence of 0.5 to 4 parts by weight of
separately and continuously introduced recycled product solids per
part by weight solids in the solution to be dried, the improvement
which comprises inhibiting or preventing accumulations on the dryer
walls and continuously providing crystalline, free-flowing product
directly from the dryer outlet and without any post dryer
crystallization treatment by continuously maintaining the average
particle size of the recycle solids at about 200 microns or less
and distributing the said separately introduced recycled product
solids at the outer periphery of the drying zone as an enveloping
solids-bearing atmosphere about the solution droplets.
2. Improvement as defined in claim 1 in which the size of the
recycle solids is maintained within the range of about 50 to about
150 microns.
3. Improvement as defined in claim 2 in which the size of the
recycle solids is maintained within the desired range by
deagglomeration of the product in the dryer recycle system.
4. Improvement as defined in claim 2 in which the said recycled
product solids are tangentially fed through plural distribution
inlets at the outer periphery of the drying zone.
5. Continuous process for preparing dry sucrose containing products
comprising:
a. continuously dispersing in a current of heated air and at the
outer periphery of a drying zone as an enveloping solids-bearing
atmosphere sucrose particles having an average particle size of
about 200 microns or less;
b. continuously and separately dispersing in the heated air, and
within the said enveloping solids-bearing atmosphere, spray
droplets of a sucrose-containing solution containing from about
0.25 to about 2 parts by weight of solids per part by weight of
said particles;
c. evaporating the water from the solution droplets;
d. continuously separating the resulting dry crystalline,
free-flowing product from the hot air stream;
e. reducing the average particle size of at least the necessary
amounts of said resulting dry product from step (d) to provide the
particles used in step (a) to about 200 microns or less;
f. continuously recycling the necessary amounts of reduced size
material from step (e) to the dispersion step (a); and
g. recovering, without any post dryer crystallization treatment,
the remainder of the dry product.
6. Process as defined in claim 5 wherein the size reduction in step
(e) is accomplished by deagglomeration of the dry product from step
(d) in the course of the recycle step (f).
7. Process as defined in Claim 5 wherein the size reduction in step
(e) is sufficient to provide an average particle size within the
range of from about 50 to about 150 microns.
8. Process as defined in Claim 7 wherein the sucrose-containing
solution is an affination syrup.
9. Process of Claim 7 wherein the sucrose-containing solution is a
last-strike liquor from conventional sugar refinery
crystallization.
10. Process as defined in claim 7 wherein the solids are dispersed
in step (a) by tangentially feeding through plural, spaced
distribution inlets at the outer periphery of the drying zone.
Description
This invention relates to improvements in the production of dried
sucrose-containing products from sucrose-containing solutions. In
one particular embodiment it relates to a procedure for ensuring
continuous operation of a process for spray drying
sucrose-containing solutions in the presence of recycled product
solids; and at the same time eliminating the need for any post
crystallization treatment of product solids between recovery from
the dryer outlet and recycle to the dryer solids feed inlet.
In the conventional methods of producing crystalline sucrose, the
virgin syrup, as extracted from sugar cane or sugar beets, is first
decolorized and deionized. The clarified syrup is then evaporated
and fractionally crystallized in a series of precisely controlled
steps, carmelization being reduced as much as possible by the use
of vacuum to reduce the evaporation temperature. Fractional
crystallization is essential since, during processing, inversion of
the cane sugar takes place, usually to the extent of about 15
percent by weight of the original sucrose content by the time
processing is completed. This invert sugar, which is substantially
uncrystallizable, is discarded together with up to about 20 percent
of non-recoverable sucrose and finds its way into commerce as
animal feed or other low grade sugar products generally referred to
as molasses.
Other methods for producing dry crystalline sucrose-containing
products proposed by the prior art include fluid energy milling
(Reimers et al. - U.S. Pat. No. 3,140,201) drying intimate blends
of sugar solids and sugar solutions (Oikawa - U.S. Pat. No.
3,271,194 and British Pat. No. 1,099,723) and simultaneous
centrifugal distribution and spray drying of sugar solids and a
sugar solution (Japanese Pat. publication No. 20384/69).
Agglomeration of pulverized sugar using a liquid sugar syrup binder
and drying of the agglomerated product is taught in Harding et al.
- U.S. Pat. No. 3,518,095. A similar agglomeration process is
disclosed in Gidlow et al. - U.S. Pat. No. 3,506,457. A process and
apparatus for spray-drying liquid substances in the presence of
small amounts of dust-like particles (e.g., recycled fines) is
taught by Bishop - U.S. Pat. No. 2,698,815. Molasses is one liquid
product suggested as suitably dried in this manner. Spray drying of
high D.E. glucose solutions in the presence of recycled solids is
disclosed by Repsdorph et al. in U.S. Pat. No. 3,477,874 and
corresponding British Pat. No. 1,075,161. A process and apparatus
for spray drying a foamed lactose syrup is disclosed in Nava et al.
- U.S. Pat. No. 3,533,805. Process and apparatus for preparing a
spray dried topping mix containing sucrose, some of which is added
in the dry state to the dryer, is disclosed in Nezbed - U.S. Pat.
No. 3,414,980.
Belgian Pat. No. 742,249 dated Jan. 30, 1970 discloses a process
for drying sucrose-containing solutions by dispersing sucrose
particles in a current of heated air, separately dispersing the
solution on the said particles, evaporating the water from the
solution coated on the particles and recovering the resulting dry
product from the hot air stream. In a preferred embodiment of the
disclosed process a portion of the dried product is recycled as the
solids dispersed in the drying zone. In the process of the Belgian
patent the use of sucrose particles, e.g., recycled dry product, is
necessary to the process of drying the sucrose-containing solution.
Attempts to directly spray dry the solution in the absence of such
solid particles results in caramelization and degradation of the
sugars in the solution and irreversible adhesion and sticking of
the freshly formed, incompletely crystallized solids to the walls
of the dryer.
The presence of recycle solids provides a practicable process for
spray drying sucrose-containing solutions. However, some problems
still remain in attempting to practice this process on a
commercial, high production rate, continuous basis. For example, in
pilot plant runs of the process described in the aforementioned
Belgian Pat. No. 742,249, the product coming from the dryer is
typically a plastic-like mass of incompletely crystallized
material. In a short period of time (e.g., 5 to 10 minutes)
crystallization of the product will be complete and a free flowing
product results, comprising agglomerates of sucrose microcrystals
with agglomerates ranging in size from about 1,000 microns (roughly
the size of the individual crystals of commercial white household
sugar) to as low as about 150 microns and made up of individual
microspheres ranging in size from about 25 to about 150 microns.
Average agglomerate particle size typically ranges from about 200
to 600 microns (i.e., 50 weight percent of the product will be
above and 50 weight percent below a given particle size in the
range of about 200 to 600 microns).
When the 200 to 600 micron product particles or agglomerates are
recycled to the drying step they tend to promote heavy accumulation
of the plastic mass on the dryer walls. Portions of this mass
"flake" off the walls and discharge from the dryer in a random
intermittent fashion. From time to time the size of the randomly
discharged portion is so large that it effectively blocks the dryer
outlet, forcing a shut-down and interruption of continuous
operation.
It is an object of the present invention to resolve these prior art
problems.
It is a specific object of the invention to provide a procedure for
inhibiting or preventing large build-ups of uncrystallized plastic
materials on the dryer walls, thus ensuring continuous operation
for a long period of time.
Still another object of the invention is the provision of a drying
procedure and apparatus which eliminates the need for any
post-crystallization steps or equipment.
Other objects and the advantages of the invention will be evident
from the following description thereof.
In accordance with the present invention, build-up of solids on the
dryer walls during the drying of sucrose-containing solutions in
the presence of recycled product solids is inhibited or prevented,
and crystalline free flowing product is obtained directly from the
dryer outlet (i.e., without the need for any post-crystallization
externally of the dryer) by maintaining the average particle size
(i.e., the size where 50 weight percent of the particles are large
and 50 weight percent are smaller), of the recycled solid product
at about 200 microns or less, preferably about 150 microns or less
and most preferably between about 50 microns and 100 or 150 microns
and by dispersing the recycled fine-sized product solids at the
outer periphery of the drying zone as an enveloping solids-bearing
atmosphere around the solution droplets. In this way wall
accumulation in the dryer is negligible and post-crystallization is
eliminated.
In a particular embodiment the invention is applied to the sucrose
solution spray drying process which has been described in the
aforementioned Belgian Pat. No. 742,249. In general, the process
involves atomization of the sucrose-containing solution to be dried
into the hot air flowing in the spray dryer while separately
feeding substantial proportions of solid sucrose particles. The
sucrose-containing solution may contain from about 60 to about 90
weight percent solids. Where appropriate or desirable, the solution
is pre-heated, e.g., to a temperature of 50.degree. to 100.degree.
C. to preclude premature crystallization and to aid in feeding and
atomization. The solid sucrose, preferably recycled product, is
separately and concurrently fed to the dryer in amounts sufficient
to provide a weight ratio of from 0.5 to 4.0, preferably about 1.5
to about 3 parts of solids, for each part by weight of solids in
the solution to be dried. Stated conversely, the weight ratio of
solids in the solution to the separately introduced product solids
ranges from about 0.25 to about 2, preferably from about 0.33 to
about 0.67. The drying temperature (i.e., the ambient temperature
in the dryer after substantially steady state conditions have been
established for continuous operation) will vary with other process
conditions and the particular sucrose-containing solution to be
dried but typically ranges from about 50.degree. to about
130.degree. C., preferably about 80.degree. to about 100.degree. C.
Temperature can be controlled by controlling the temperature or
feed rate of the incoming sugar syrup or the recycled solids or the
temperature of the incoming hot air, or the average residence time
in the dryer.
The particle size of the recycled solids is maintained in the
desired range by size reduction prior to the recycle. This can be
accomplished by an intermediate grinding step, by appropriately
designing the recycle system so that the product solids are
deagglomerated by attrition or impact in the course of being
returned to the dryer solids feed inlet, or in any other suitable
manner. In any event it is essential that the average particle size
of the recycled product solids be reduced to not greater than about
200 microns and preferably not greater than about 150 microns prior
to reintroduction into the dryer. For reasons of overall process
economy, dusting losses and the like, it is generally undesirable
to reduce the average particle size of the recycle product lower
than about 25 microns, particularly since no substantial further
improvement in results will be observed. In the presently preferred
embodiment of the present invention the product solids are
deagglomerated in the solids recycle system to an average particle
size within the range of from about 50 to about 100 or 150
microns.
Size reduction of recycle product solids particles as an
improvement, standing alone, is the subject of commonly owned,
concurrently filed U.S. Application Ser. No. 139,852.
In accordance with the present application still further
improvements are achieved by recycling the reduced size product
solids at the outer periphery of the drying zone as an enveloping
solids-bearing atmosphere around the atomized sucrose-containing
solution to be dried. This not only further inhibits accumulations
on the dryer walls but results in the further unexpected advantage
of providing directly from the dryer a dry, free-flowing
product.
There are several ways of introducing the recycled product in
accordance with the present invention. In one embodiment, the
recycled product is introduced into the dryer by means of a
centrally located centrifugal "powder" atomizer and is carried by
drying air currents to the dryer walls. In another, presently
preferred, embodiment the recycled product solids are recycled in a
current of conveying gas (e.g., in a pneumatic conveyor) and
introduced tangentially along the dryer walls at a plurality
(preferably from two to eight) of points spaced about the dryer
periphery. It is not necessary and may not be desirable for the
plural tangential inlets to be equally spaced about the dryer
periphery. In any event the sucrose-containing solution is
separately atomized in any suitable manner (e.g., centrifugally or
in a single or multiple fluid sprayer) centrally of the drying zone
and within the enveloping solids-bearing atmosphere.
The drawings schematically illustrate apparatus suitable for
practicing the present invention. In the drawings:
FIG. 1 is a schematic illustration of apparatus incorporating a
centrifugal "powder" atomizer.
FIG. 2 is a schematic illustration of apparatus in which recycle
solids are tangentially introduced at the dryer walls.
Ambient air from supply fan 1 passes through line 2 into indirect
heater 3 to raise the air temperature from ambient conditions to
proper spray drying temperature. The heated air continues in line 4
and enters the spray dryer 24 via annulus 5.
The sucrose syrup to be spray dried is received in feed tank 6.
From there it is pumped via pump 7 through heat exchanger 8 and
through line 9 entering the dryer through atomizer head 10.
Spray dried product drops from the chamber of dryer 24 and passes
through line 11 and into surge hopper 12. From there it is fed by a
volumetric feeder 13 into a pneumatic conveying system. The
pneumatic conveying system constitutes supply fan 15 and transfer
line 14 which conveys recycle product back to spray dryer 24.
Recycle product along with its conveying air enters the dryer
through centrifugal powder atomizer 16. From the atomizer 16 the
powder particles are carried by the drying air currents to the
walls of the dryer where an eveloping solids-bearing atmosphere,
generally designated 17, is formed about the atomized sucrose
solution spray droplets, formed by atomizer head 10. In the course
of recycle to the dryer the product particles are passed through a
grinder (not shown) or are otherwise suitably reduced to an average
particle size of about 150 microns or less prior to introduction
into the dryer. Some or all of the size reduction may be
accomplished in the powder atomizer 16. Product not recycled
overflows surge hopper 12 and is transferred to storage and
packaging via line 25.
Dryer off gases pass from line 18 into cyclone collector 19.
Separated product fines pass from collector 19 through line 20
where they enter line 14 and mix with product from feeder 13.
Solids-free off gas from collector 19 passes through line 21 and is
exhausted to the atmosphere via exhaust fan 22 and vent line
23.
In the apparatus of FIG. 2 ambient air from supply fan 31 passes
through line 32 into indirect heater 33 to raise the air
temperature from ambient conditions to proper spray drying
temperature. The heated air continues in line 34 and enters the
spray dryer 55 via annulus 35.
The sucrose syrup to be spray dried is received in feed tank 36.
From there it is pumped via pump 37 through heat exchanger 38 and
through line 39 and enters the dryer through centrifugal atomizer
40.
Spray dried crystaline free flowing product falls from drying
chamber 55 through line 41 into surge hopper 42. From there it is
fed by a volumetric feeder 43 into a pneumatic conveying system via
line 44. The material passes through a combination pneumatic
conveying and milling fan 45 which reduces the particle size of the
product. The material is then conveyed through line 46 and recycled
to spray dryer 55.
Recycle product enters dryer chamber 55 through tangential inlets
47. Having been placed in the dryer in such a manner the recycle
product flows along the dryer walls and forms a solids-bearing
enveloping atmosphere generally designated 48 between the dryer
walls and the syrup spray droplets from 40.
Product not recycled to drying chamber 55 overflows surge tank 42
and passes through line 56 to product storage and packaging.
Exhaust gas from drying chamber 55 passes through line 49 to
cyclone collector 50. Product fines from 50 are fed into pneumatic
recycle line 44 through line 51. Solids-free off gas from collector
50 goes through line 52 to exhaust fan 53 and discharge to the
atmosphere via line 54.
Any number of sucrose-containing solutions may be dried in
accordance with the present invention; including, for example,
refined sugar syrups, raw sugar syrups, affination syrups, syrups
resulting from various strikes (e.g., the second, third or
subsequent strikes) in conventional sugar crystallization
processes, remelt syrups, edible molasses, and the like; or
mixtures of the foregoing. The solutions are appropriately
decolorized, where required, if a white product is desired and are
concentrated or diluted to the desired solids content prior to
drying.
The invention will be further understood from the following
illustrative examples:
EXAMPLE A
(Comparative Example)
A pilot plant run was conducted utilizing the process and apparatus
described in Belgian Pat. No. 742,249. The spray dryer apparatus
had a 71/2 foot diameter with a 31/2 foot high cylindrical section
and a 60.degree. conical bottom giving an overall dryer capacity of
approximately 240 cubic feet. The liquid atomizer was a high vane
centrifugal wheel rotating at 22,900 revolutions per minute.
The sucrose solution feed was affination syrup from a commercial
cane sugar refinery. This syrup contained about 70.5 weight percent
solids. It was preheated and fed to the dryer at a temperature of
about 170.degree. F. and at a rate of 16.2 gallons per hour,
providing a syrup solids feed rate of about 128 pounds per
hour.
Dried, solid sucrose product from an earlier run was used for the
initial "recycle." This product had an average particle size of
about 300 microns. Thereafter product solids from the run, with an
average particle size of 300 to 400 microns, was used. The recycled
solids were fed via four 1-inch diameter tubes evenly spaced about
the outside of the centrifugal atomizer at a rate of 512 pounds per
hour (recycle weight ratio of 4).
Hot air was introduced into the dryer at about 1,000 cubic feet per
minute and a temperature of 336.degree. F. The temperature of the
outlet air was 161.degree. F. and the temperature of the product
exiting from the dryer was 138.degree. F.
While operating under the foregoing conditions a rapid build-up of
accumulated solids on the dryer walls was observed. Within an hour
the total wall accumulation amounted to 219 pounds and the
accumulated material had built up to a depth as high as 10 inches
at some locations on the dryer walls. There was a large mass of
flaked-off solids over the dryer solids product outlet. Conditions
were judged to be so poor that the run could no longer be
continued.
The following example illustrates the practice of the present
invention.
EXAMPLE 1
A subsequent run was conducted in the same equipment and under
similar conditions as those described in comparative Example A. In
this run the syrup feed rate was equivalent to 147.5 pounds of
syrup solids per hour via a centrally located single fluid spray
nozzle and the recycle solids were fed at a rate of 390 pounds per
hour (recycle weight ratio of about 2.65). The recycled solids were
made up from the product of a previous run for start-up and
thereafter from product of the run in progress. All recycle product
solids were deagglomerated to an average particle size within the
range from 50 to 150 microns prior to being fed to the dryer by
pneumatically conveying them through a circuitous recycle conduit
and introducing them to the dryer through a centrally located
centrifugal powder atomizer located above the syrup atomizer. The
inlet air temperature was 445.degree. F. and the outlet air
temperature was 194.degree. F.
The recovered product was highly agglomerated microspheres having
agglomerate particle size ranging up to 1/32 inch to one-sixteenth
inch.
During the course of this run the dryer walls remained very clean,
with only minor wall accumulations. No difficulty was experienced
with any large solids masses plugging the outlet. Total wall
accumulation after almost 3 hours operation was only about 15
pounds. The general condition of the dryer was judged to be quite
satisfactory for virtually unlimited continuous operation.
Furthermore, all product recovered from the dryer was dry and
free-flowing and could be directly recycled without requiring any
storage or other further post-crystallization treatment.
* * * * *