U.S. patent number 3,702,610 [Application Number 05/138,742] was granted by the patent office on 1972-11-14 for flushable web containing flushability indicator, and absorbent pads wrapped therewith.
This patent grant is currently assigned to Kimberly-Clark Corporation. Invention is credited to William Leland Henderson, Milton R. Sheppard.
United States Patent |
3,702,610 |
Sheppard , et al. |
November 14, 1972 |
FLUSHABLE WEB CONTAINING FLUSHABILITY INDICATOR, AND ABSORBENT PADS
WRAPPED THEREWITH
Abstract
A means for indicating when a sanitary napkin or diaper wrapped
with a web bonded with a spaced pattern of water-dispersible
adhesive is in condition for flushing away after it is dropped in a
toilet for disposal. The indicating means is provided by including
a water-soluble coloring agent or dye in the water-dispersible
adhesive composition. As the water disperses the adhesive, the dye
migrates into the non-bonded area of the web or is diluted in the
excess water, and the adhesive pattern substantially disappears,
thus indicating that the adhesive has become softened sufficiently
to permit the wrapper to be broken up readily by the flushing
action of the water.
Inventors: |
Sheppard; Milton R. (Appleton,
WI), Henderson; William Leland (Neenah, WI) |
Assignee: |
Kimberly-Clark Corporation
(Neenah, WI)
|
Family
ID: |
22483428 |
Appl.
No.: |
05/138,742 |
Filed: |
April 29, 1971 |
Current U.S.
Class: |
604/361; 604/368;
604/375; 604/364; 604/372 |
Current CPC
Class: |
A61F
13/15211 (20130101); A61F 13/42 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61F 13/42 (20060101); A61f
013/16 () |
Field of
Search: |
;128/284,285,286,287,290,296,156 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Claims
What is claimed is:
1. In a flushable web comprising a fluid-permeable fibrous web
bonded at least in part by a pattern of water-dispersible adhesive,
the improvement wherein at least a portion of said adhesive
contains a water-activatable flushability indicator, said indicator
comprising a water-soluble coloring agent dispersed in said
adhesive, said coloring agent being compatible with said adhesive,
whereby when said web is immersed in water and as said adhesive is
dispersed by said water said coloring agent migrates from said
adhesive into said water and adjacent non-bonded portions of said
web causing said pattern to substantially disappear.
2. The web of claim 1 in which said adhesive is water-soluble.
3. The web of claim 1, in which said web comprises a non-woven web
of staple length fibers.
4. The web of claim 3 wherein the fibers in said web are rayon
fibers.
5. The web of claim 1 in which said web is bonded primarily with a
water-soluble adhesive and overprinted with a water-insoluble
adhesive, and said coloring agent is dispersed in said
water-soluble adhesive.
6. The web of claim 5 in which both said adhesives are in the form
of spaced adhesive patterns.
7. The web of claim 1 in which at least part of said adhesive is
selected from the group consisting of polyvinyl alcohol, polyvinyl
methylether, glycol cellulose, cellulose glycolate, and methyl
cellulose.
8. In a flushable absorbent pad comprising an absorbent
water-disintegratable core having at least its body-contacting
surface covered with a fluid-permeable fibrous web bonded at least
in part by a pattern of water-dispersible adhesive, the improvement
wherein at least a portion of said adhesive contains a
water-activatable flushability indicator, said indicator comprising
a water-soluble coloring agent dispersed in said adhesive, said
coloring agent being compatible with said adhesive, whereby when
said pad is immersed in water and as said adhesive is dispersed by
said water said coloring agent migrates from said adhesive into
said water and adjacent non-bonded portions of said web causing
said pattern to substantially disappear.
9. The pad of claim 8 in which said web comprises a non-woven web
of staple length fibers.
10. The pad of claim 8 in which said adhesive binding said web is
water-soluble.
11. The pad of claim 9 wherein the fibers in said web are rayon
fibers.
12. The pad of claim 8 in which said web is bonded primarily with a
water-soluble adhesive and overprinted with a water-insoluble
adhesive, and said coloring agent is dispersed in said
water-soluble adhesive.
13. The pad of claim 12 in which both said adhesives are in the
form of spaced adhesive patterns.
14. The pad of claim 8 in which at least a part of said adhesive is
selected from the group consisting of polyvinyl alcohol, polyvinyl
methylether, glycol cellulose, cellulose glycolate, and methyl
cellulose.
15. The pad of claim 8 in which said pad is a sanitary napkin.
16. The pad of claim 8 in which said pad is a diaper.
Description
BACKGROUND OF THE INVENTION
During recent years much emphasis has been placed upon developing
sanitary napkins and diapers and other single-use absorbent pads
with a completely flushable structure, so that they may be disposed
of in conventional toilets. The major problem encountered in
rendering these absorbent devices flushable has been to develop an
outer, fluid-permeable wrap which is strong enough to remain whole
while it is subjected to the normal stress, strain, and moist
conditions encountered during use, and yet which will break up
readily when deposited in the water of a toilet and flushed away.
One type of wrapper employed for such purposes is a non-woven web
bonded by spaced lines or patterns of water-dispersible adhesive.
However, in order to make such webs strong enough to hold together
in the moist environment encountered during use, it has been found
necessary to apply the adhesive in amounts such that the adhesive
will not dissolve in water instantaneously, or to modify the
adhesive in some way to slow down its solubility rate. When these
practices are used the adhesive disperses readily only after it has
been immersed in water for a short period of time. Ideally,
therefore, it would be desirable if the person who deposits the
product in water could be provided with some easily discernible
signal which would inform the user when the adhesive has been
immersed in the water for a sufficient time to insure that the
wrapper will disperse completely at the first flushing.
The main object of this invention therefore is to provide a
water-dispersible wrapper for absorbent pads with a means for
indicating when the adhesive binder in the wrapper is dissolved
sufficiently to permit ready dispersion of the wrapper in
water.
SUMMARY OF THE INVENTION
This invention is directed to a means for indicating when a
sanitary napkin or diaper wrapped with a non-woven web bonded with
a spaced pattern of water-dispersible adhesive is in condition for
disposal by flushing after it is dropped in a toilet. The
indicating means is provided by including a small percentage of
water-soluble coloring agent or dye in the water-dispersible
adhesive which is normally used to bond flushable wrappers. When a
pad wrapped in a fluid-permeable web bonded with such a
color-containing water-dispersible adhesive is deposited in water,
the color or dye gradually diffuses out of the adhesive and spreads
to the rest of the web and is diluted by the excess water whereby
the adhesive pattern substantially disappears. The change from
sharply defined adhesive pattern to an overall faded color in the
web is clearly visible to the eye, and as the color fades by
diffusing into the surrounding web and by water dilution, the user
is made visually aware of the fact that the adhesive is softened by
the water to a degree sufficient to destroy its bonding power and
to permit the wrapper to readily disintegrate during the flushing
action and thereby release the contained pad so that it, too, will
disintegrate and flush away.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
In making up a suitable wrapper in accordance with this invention,
rayon fibers of 1.5 denier and 1-9/16 inch staple length were
carded to form a non-woven fiber web weighing approximately 14
grams per square yard. The carded web was overprinted with a
pattern of a water-soluble adhesive containing a compatible
water-soluble red dye. The pattern comprised two sets of spaced
parallel lines of adhesive. One set extended diagonally of the web
in one direction at an angle of about 45.degree. while the other
set extended diagonally in the opposite direction and also at a
45.degree. angle. The sets of adhesive lines intersected to provide
an overall closed diamond pattern. This diamond style bonding
pattern is one of many commonly used for binding non-woven webs. In
this instance, the lines were about one-sixteenth inch wide and
spaced about one-quarter inch from each other. The adhesive was
applied in the form of a 10 percent solution and in the amount of
about 1 gram per square yard in the finished material.
The water-soluble adhesive used in this example comprised polyvinyl
alcohol of a type which was about 79-82 percent hydrolyzed, had a
viscosity of 22 cps (4 percent water solution at 20.degree. C.) and
was readily soluble in water.
The compatible water soluble dye was present in the polyvinyl
alcohol in the amount of about 1.0 percent by weight based on the
polyvinyl alcohol. In this instance the dye was of a dark red color
sold under the name EASTACRYL -- dark red -- LA by Eastman Kodak
Company.
The above-described bonded webs were used to construct sanitary
napkins by wrapping the webs around conventional absorbent pads
made up from layers of cellulose wadding and wood pulp fluff in the
conventional manner, leaving the customary fastening tabs extend
beyond each end of the pads.
The napkins comprising pads wrapped with the above-described web
were then dropped into the water of a toilet bowl. Shortly after
the pad immersed itself in the water there was a noticeable
migration of the color from the adhesive lines into the adjoining
areas of the web. As this migration took place the color in the
lines of the adhesive faded rapidly. In about 30 seconds the
pattern was no longer discernible, and the coloring matter had
distributed itself uniformly throughout the web. When the toilet
was flushed at this time, the web broke up immediately, releasing
the internal pad components and permitting the entire structure to
disintegrate into small pieces and individual fibers which passed
through the pipe lines of the disposal system without difficulty.
The pipe lines carrying the flushed material were made of
transparent material so that the condition of the materials as they
were carried therethrough was readily observable.
Another pad of the same structure was dropped in the water and
flushed immediately without waiting for any color change. In this
case when no time was allowed for the adhesive to dissolve, the
wrapper did not break up and it was observed that the whole
structure traveled down the drain and did not break up to any
extent until it had been carried a considerable distance down the
transparent pipe-line and around several bends therein.
As indicated above, the diffusion of the water-soluble dye or
coloring matter out of the adhesive and into the water and adjacent
areas of the web causes the originally sharp outline of the colored
adhesive pattern to substantially disappear. The color itself takes
on an overall lighter hue, thus providing a visual signal to the
user that the pad is ready for flushing, and also assuring the user
that the flushed pad will not travel through the pipe-line for any
distance in its bulky, undisintegrated form.
In addition to the dye described in the specific example, any
water-soluble dye or coloring agent which is compatible with the
particular adhesive employed may be used. It is understood of
course that the dye be non-toxic and non-irritating in contact with
the skin.
Other specific dyes which were found suitable for use with
polyvinyl alcohol are Pontamine Turquoise 8 GLP and Rhodamine B
Extra, both sold by the E. I. DuPont Company.
Amounts of coloring agent in the adhesive in the range of from
about 0.5 percent to about 1.5 percent by weight have been found
useful. A wide range of colors may be employed to identify various
types of napkins or the like. The coloring agent should be
non-pigmented and may be either an acid, a basic or a direct dye.
Vegetable dyes and water-soluble food colors may be used.
In addition to the specific polyvinyl alcohol mentioned above,
other cold-water soluble polyvinyl alcohols may be used. For
example, polyvinyl alcohols having a percent hydrolysis in the
range of about 79 to about 98 are generally cold-water soluble and
are suitable for the described use. Viscosities of about 21 to
about 28 are preferred. The adhesive pattern used may be in the
form of straight or wavy parallel lines which are transversely or
diagonally disposed, as well as other patterns including circles,
squares, dots and the like. The lines in the patterns may be
continuous or discontinuous.
The amount of polyvinyl alcohol used can also vary in the range of
about 5 to about 15 percent by weight, but should be regulated to
provide a suitable strength as well as softness and drape.
Excessive amounts should be avoided as they are inclined to become
sticky in use, which is undesirable.
While only polyvinyl alcohol is described in the specific example,
and is preferred as the water-soluble binder, other water-soluble
adhesives may be used, including such materials as polyvinyl
methylether, glycol cellulose, cellulose glycolate, methyl
cellulose and the like. The dye or coloring matter used should of
course be compatible with the particular adhesive selected.
The binder need not be completely water-soluble, but must be
water-dispersible, i.e., sufficiently water sensitive that after a
short time immersion in water the binder loses its binding power
thus permitting the web to disintegrate. Since the loss of binding
power takes longer when the binder is water-dispersible rather than
when it is completely water-soluble binder, the use of a dye or
coloring agent to serve as a visual dispersibility signal is
especially appropriate.
This invention is also applicable to webs in which combinations of
water-soluble and water-insoluble binders are employed. One example
of such structure may be found in assignee's copending application,
Ser. No. 9,261 to J. F. Champaigne, Jr. and H. A. Whitehead filed
Feb. 6, 1970 and now U.S. Pat. No. 3,616,797. In that patent the
wrapper comprises a non-woven fiber web bonded primarily by a
water-soluble adhesive and overprinted with a water-insoluble
adhesive, the latter being disposed in a predetermined pattern of
spaced segments. In such instances the water-soluble adhesive
should comprise the spaced pattern which contains the coloring
agent, since it is the eventual dissolution of the water-soluble
binder which provides flushability.
It will also be seen that instead of having all the adhesive
contain the coloring agent or dye, only certain designated portions
may contain it and still serve as the visual signal area. Small
spots of the adhesive-dye combination in strategically located
areas may be used.
While a carded rayon web is described in the specific example cited
above, other fibers including both natural and synthetic may be
used in the base web. However, cellulose fibers or fibers of
cellulosic derivation are preferred because they are biodegradable.
Also, while the fiber lengths in the specific example are 1-9/16
inch, fiber lengths in the usual staple lengths of 1/2 inch to
about 3 inches are useful. The longer fibers are, of course, less
desirable because they will not disperse as readily.
While a carded web is specified in the examples, other known means
of forming the web such as airforming and drafting of fibrous
material may also be employed.
The structure of the absorbent pad itself is not critical as long
as it is made up of the usual absorbent materials which break up
and disintegrate easily in excess water. Included among these are
wood pulp, cotton fibers, absorbent rayon and regenerated cellulose
fibers, multiple plies of cellulose wadding and the like or
combinations thereof.
While the specific examples described above are directed to
sanitary napkins it is understood that the invention is applicable
to other absorbent pads such as diapers and the like, and that the
entire pad need not be wrapped with the web since in some cases
only the body-contacting portion requires a covering web of the
nature described.
* * * * *