U.S. patent number 3,701,379 [Application Number 05/160,184] was granted by the patent office on 1972-10-31 for process of casting utilizing magnesium oxide cores. This patent grant is currently assigned to United Aircraft Corporation. Invention is credited to Norman E. Brinker, Michael H. Fassler.
United States Patent | 3,701,379 |
Fassler , et al. | October 31, 1972 |
A metal casting having internal passages and apertures can be formed by pouring molten metal into a mold having a magnesium oxide core disposed therein. The core can be made by forming a mixture of magnesium oxide and an evanescent resin and shaping this mixture by suitable molding techniques. The evanescent resin is then slowly volatilized to leave a core of substantially pure MgO which can be sintered to form a carbonaceous material-free, self-supporting body. After a casting is made around the core, it can be removed by washing the casting in a non-corrosive media such as water or dilute acetic acid. BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the manufacture of metal castings having internal passages and apertures disposed therein. Specifically, the present invention relates to the manufacture of superalloy metal castings by investment casting techniques in which small and narrow passages and apertures are internally disposed. 2. Description of the Prior Art In investment casting, a disposable pattern, which is a replica of the part to be cast and which includes any necessary gates and risers, is usually dipped in a refractory slurry which hardens to form a smooth coating that serves as the mold face. The precoating or dipcoating of the pattern usually is carried out by immersing the pattern in a suspension of a fine refractory powder in a suitable liquid binder that is capable of hardening during drying at room conditions. Following dipping, the excess slurry is drained from the pattern and the coating is stuccoed while wet with coarser refractory particles which help to set the coating. A ceramic shell-mold is usually prepared by repeating the dipping and stuccoing operations described above until a shell having a sufficient thickness to resist the stresses occurring in subsequent operations is built up around the pattern. The usual thickness range is from one-eighth of an inch to one-half of an inch, although thinner or heavier shells may be formed for special situations. After forming the refractory shell-mold, the disposable pattern is removed from the shell-mold which is then prepared for the casting operation. The typical pattern materials used in the process have been either wax blends or plastics such as polystyrene and, occasionally, polyethylene. It is sometimes desirable to form hollow articles and particularly ones with very small and narrow passages by these investment casting techniques. Commonly, to make such articles, a ceramic core, usually formed of pressed silica as the major constituent, is disposed within the mold at an appropriate location. While these silica cores are quite useful, they are difficult to remove with a non-corrosive leaching media after the casting has been made. It can be appreciated that when very small or fine apertures or interstices are filled with an insoluble core material that difficulty can be encountered when attempting to totally remove the material with a non-corrosive leaching medium. Other cores used for forming hollow cast articles have included soluble metal halide salts mixed with borax, magnesium oxide or talc. Such compositions have been disclosed in the U.S. Pat. to Anderko, No. 3,407,864. Disclosed in the U.S. Pat. to Rose, No. 3,473,599, is the use of a mixture of magnesium oxide and calcium phosphate. In the case of the halide-containing core, we have found that the halogen can react undesirably with the superalloy during casting. In the case of the magnesium oxide-calcium phosphate core, we have found that is is gassy, brittle and difficult to use when making castings of superalloys. SUMMARY OF THE INVENTION We have found that cores of essentially pure magnesium oxide are quite advantageous in investment casting, especially in the so-called directionally solidified casting of superalloys. Alloys which can be cast and used with our magnesium oxide cores are disclosed in the Ver Snyder U. S. Pat., No. 3,260,505. Because magnesium oxide dissolves in hot water and is readily soluble in organic acids, we have found that a core of this material is easily dissolved from even the most narrow and small crevices inside of a casting. Moreover, the thermal expansion rate for magnesium oxide is quite close to that of the superalloys which are used in directionally solidified casting processes. Thus, much of the stresses due to gross mismatches in thermal expansion rates which could cause cracking is eliminated and castings having extremely complicated configurations with re-entrant features can be easily made. In the practice of the present invention, a mixture is made of essentially pure magnesium oxide and an evanescent resinous binder. The mixture is then poured or injected into a mold and allowed to harden according to conventional techniques. The core is then removed from the mold and slowly heated in air to burn off the carbonaceous material from the binder and form a carbonaceous material-free structure. Generally, temperatures in the range of 1,000.degree. F. are sufficient to remove the resin and form the "green" structure of essentially pure magnesium oxide. The "green" core is then heated to above about 2,000.degree. F. to sinter the magnesium oxide particles and form a rigid, self-supporting structure which can subsequently be used in investment casting. Because the core is heated slowly during the early stages of firing, generally less than about 10.degree. F./hour, no significant shrinkage occurs. With this process, cores have been made which have exceedingly complex shapes and cross sections as thin as 0.015 to 0.25 inch. These molded and fired cores can sustain the rigors of casting temperatures as high as 2,800.degree. to 3,000.degree. F. In the present process, 40 to 70 w/o magnesium oxide is mixed in a solution of an evanescent, resinous binder to form a thick slurry. Suitable thermosetting and thermoplastic resins, for example, include polyethylene, polystyrene, carbowax, phenolformaldehyde and polyvinyl alcohols. The magnesium oxide-resin mixture is transferred into a die having the configuration that is desired and the binder dries to form a solid body having the shape of the core, The body is then removed from the die and transferred to a furnace for slow heating to burn off and volatilize the evanescent, resinous binder. The heating should be sufficiently slow to remove the carbonaceous material without disrupting the integrity of the core while the gas is leaving. Preferably, the magnesium oxide has a particle size between about 25 and 150 microns since below about 25 microns the magnesium oxide wets only with great difficulty while above about 150 microns the particles are too coarse to produce a quality casting. The method by which the core is formed will depend upon the configuration which is required. However, the methods of forming which may be used include extrusion, injection molding, transfer molding, compression molding, ramming, isostatic pressing, and slip casting or pouring. To form a core, the preferred process involves mixing a thermoplastic resin dissolved in a solvent, with magnesium oxide and conventional die lubricants. The solvent is volatilized and an appropriate quantity of the resulting resin-MgO paste is placed in a transfer cavity of a transfer press. Heat and pressure, in the order of 10,000 to 20,000 p.s.i., is applied to the resin-MgO paste to inject the material (while hot) into the die and fill it. The die is then split apart and a core is removed. We have found that it is quite important to use essentially pure magnesium oxide, since contamination with other materials can lead to deterioration of the casting. For demonstration, a core was made of 5 percent calcium phosphate and 95 percent magnesium oxide. This core was compared to a core made of 100 percent magnesium oxide. When a casting was made and tested using the impure core, matrix oxidation of the surface of the casting occurred to a depth of 0.0,007 inch and alloy depletion occurred to 0.0,005 inch. With the essentially pure magnesium oxide core, matrix oxidation only occurred to a depth of 0.0,002 inch and alloy depletion only occurred to 0.0,003 inch. While the microsections indicated a reaction between the core and the casting with both the magnesium oxide core and the magnesium oxide-calcium phosphate core, the extent of the reaction in the first mentioned core was less than with the latter. In general, the process further includes the conventional casting steps of pouring a molten metal or alloy into a shell-mold of the desired shape in which the magnesium oxide core of the present invention is disposed so as to form the apertures and internal passages when the casting cools. When the magnesium oxide core is washed out from the casting, apertures and passageways remain in the casting. According to the preferred practice of the present invention, the alloy to be cast is melted in a vacuum furnace with a vacuum of 50.mu. or better, and after having been held at a temperature of from 100.degree. to 250.degree. F. above its melting point for a short period of time, it is cast in a mold. Generally the shell-mold has the shape of a gas turbine or gas-contacting blade and is preferably formed of ceramic or siliceous material, such as a shell-mold formed of alternate layers of finely divided siliceous material, such as silicates, zirconia, or other argillaceous or refractory material and finely divided sand or like material, there usually being several layers of each of the two materials. Such shell-molds are usually formed on a wax pattern, and after drying, the shell-mold is fired to remove the wax as is customary in the "lost wax" molding method. The magnesium oxide core of the present invention is conventionally mounted within the wax assembly and becomes permanently fixed in the shell-mold after the wax has been removed. It is disposed so as to allow the molten metal to flow around it, whereby the hollow portions can be formed when the metal cools. In the vacuum casting furnace apparatus, the shell-mold is provided with the electrical heating means so that its upper portion can be heated to a temperature, preferably at least 100.degree. F. above the melting point of the alloy, prior to the pouring of the metal into the mold. When in casting position, the mold is supported with its open bottom end on a support member which can be chilled and will remain substantially colder than the body of the shell-mold during the casting operation, thereby chilling the cast metal in the shell-mold at its lower end. The chilling of the cast metal at one end causes the casting to crystallize in a columnar structure having unidirectionally oriented crystals aligned substantially parallel to the axis of the casting and with almost complete avoidance of grain boundaries normal to the stress axis. When the casting has cooled to room temperature, or sufficiently so that it does not react with the atmosphere, the vacuum may be destroyed and the casting and its shell-mold are removed from the apparatus, after which the shell-mold is removed, usually destructively, from the casting, and the core is then ready to be removed. To remove the core, the part is dipped in water or preferably an organic acid solution, such as acetic acid less than about 10 normal. Agitating the solution around the casting will quickly dissolve the magnesium oxide and provide a casting which is then suitable for finish-machining.
Inventors: | Fassler; Michael H. (Middletown, CT), Brinker; Norman E. (Gardena, CA) |
---|---|
Assignee: | United Aircraft Corporation
(East Hartford, CT) |
Family ID: | 22575863 |
Appl. No.: | 05/160,184 |
Filed: | July 6, 1971 |
Current U.S. Class: | 164/132; 164/526 |
Current CPC Class: | B22C 9/106 (20130101); B22C 9/10 (20130101); B22C 9/101 (20130101); B22D 29/002 (20130101) |
Current International Class: | B22C 9/10 (20060101); B22D 29/00 (20060101); B22d 029/00 () |
Field of Search: | ;164/41,43,132 |
3407864 | October 1968 | Anderko et al. |
3473599 | October 1969 | Rose |
3645491 | February 1972 | Brown et al. |
uspto.report is an independent third-party trademark research tool that is not affiliated, endorsed, or sponsored by the United States Patent and Trademark Office (USPTO) or any other governmental organization. The information provided by uspto.report is based on publicly available data at the time of writing and is intended for informational purposes only.
While we strive to provide accurate and up-to-date information, we do not guarantee the accuracy, completeness, reliability, or suitability of the information displayed on this site. The use of this site is at your own risk. Any reliance you place on such information is therefore strictly at your own risk.
All official trademark data, including owner information, should be verified by visiting the official USPTO website at www.uspto.gov. This site is not intended to replace professional legal advice and should not be used as a substitute for consulting with a legal professional who is knowledgeable about trademark law.