U.S. patent number 3,700,050 [Application Number 05/098,163] was granted by the patent office on 1972-10-24 for method for drilling and completing a well and a packer fluid therefor.
This patent grant is currently assigned to Atlantic Richfield Company. Invention is credited to Leon H. Miles.
United States Patent |
3,700,050 |
Miles |
October 24, 1972 |
METHOD FOR DRILLING AND COMPLETING A WELL AND A PACKER FLUID
THEREFOR
Abstract
A method for drilling and/or producing a well through a
permafrost zone which employs a thermally insulated packer fluid
which contains at least one of hollow shapes such as glass spheres,
halogenated ethane, or halogenated ethylene.
Inventors: |
Miles; Leon H. (Plano, TX) |
Assignee: |
Atlantic Richfield Company (New
York, NY)
|
Family
ID: |
22267634 |
Appl.
No.: |
05/098,163 |
Filed: |
December 14, 1970 |
Current U.S.
Class: |
175/65; 166/57;
166/901 |
Current CPC
Class: |
E21B
36/003 (20130101); C09K 8/32 (20130101); C09K
8/82 (20130101); Y10S 166/901 (20130101) |
Current International
Class: |
C09K
8/60 (20060101); C09K 8/32 (20060101); E21B
36/00 (20060101); C09K 8/82 (20060101); C09K
8/02 (20060101); E21b 043/00 () |
Field of
Search: |
;166/DIG.1,57 ;252/8.55R
;175/65 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
oil and Gas Journal, June 21, 1971, pp. 115-119..
|
Primary Examiner: Wolfe; Robert L.
Claims
The embodiments of the invention in which an exclusive property or
privilege is claimed are defined as follows:
1. In a method for drilling a well through a permafrost zone, the
improvement comprising providing at least one annulus zone in said
wellbore, said annulus zone extending at least through said
permafrost zone, and substantially filling said at least one
annulus zone during at least part of the drilling of said well with
a thermal insulating well packer fluid consisting essentially of an
effective thermal insulating amount of hollow shapes of a material
selected from the group consisting of glass and plastic, said
shapes passing through a 50 mesh sieve, said shapes having a grain
density of from about 0.2 to about 0.4 grams/cubic centimeter, said
shapes having a thermal conductivity in bulk of no greater than
about 0.08 Btu/hour sq. foot .degree. F./foot, the remainder being
essentially a hydrocarbonaceous oil.
2. A method according to claim 1 wherein said material is
glass.
3. A method according to claim 1 wherein there is additionally
present an effective insulating amount of at least one agent
selected from the group consisting of ethane and ethylene having
from 3 to 6, inclusive, halogen atoms per molecule and which is
liquid at 200.degree. F. under a pressure of at least 200 psig, has
a weight in said liquid state of at least about 7 pounds/gallon,
and a thermal conductivity in said liquid state of no greater than
about 0.08 Btu/hour sq. foot .degree. F./foot.
4. A method according to claim 3 wherein said additional insulating
agent is selected from the group consisting of
trichlorotrifluoroethane, dichlorotetrafluoroethane, and
trichloroethylene.
5. A method according to claim 1 wherein there is additionally
present an effective weighting amount of at least one agent
selected from the group consisting of ethane and ethylene having
from 3 to 6, inclusive, halogen atoms per molecule and which is
liquid at 200.degree. F. under a pressure of at least 200 psig, has
a weight in said liquid state of at least about 7 pounds/gallon,
and a thermal conductivity in said liquid state of no greater than
about 0.08 Btu/hour sq. foot .degree. F./foot.
6. A method according to claim 5 wherein said additional weighting
agent is selected from the group consisting of
trichlorotrifluoroethane, dichlorotetrafluoroethane, and
trichloroethylene present in an amount sufficient to give the
packer fluid a weight of at least about 7 pounds/gallon.
7. A method according to claim 1 wherein said shapes are present in
amounts of at least about 12 weight percent based on the total
weight of the packer fluid.
8. A method according to claim 1 wherein said shapes are spherical
and have a diameter range such that they will pass through a 50
mesh sieve but are no less than about 10 microns in diameter.
9. In a method for producing a well through a permafrost zone, the
improvement comprising providing at least one annulus zone in said
wellbore, said annulus zone extending at least through said
permafrost zone, and substantially filling said at least one
annulus zone during at least part of the producing of said well
with a thermal insulating well packer fluid consisting essentially
of an effective thermal insulating amount of hollow shapes of a
material selected from the group consisting of glass and plastic,
said shapes passing through a 50 mesh sieve, said shapes having a
grain density of from about 0.2 to about 0.4 grams/cubic
centimeter, said shapes having a thermal conductivity in bulk of no
greater than about 0.08 Btu/hour sq. foot .degree. F./foot, the
remainder being essentially a hydrocarbonaceous oil.
10. A method according to claim 9 wherein said material is
glass.
11. A method according to claim 9 wherein there is additionally
present an effective insulating amount of at least one agent
selected from the group consisting of ethane and ethylene having
from 3 to 6, inclusive, halogen atoms per molecule and which is
liquid at 200.degree. F. under a pressure of at least 200 psig, has
a weight in said liquid state of at least about 7 pounds/gallon,
and a thermal conductivity in said liquid state of no greater than
about 0.08 Btu/hour sq. foot .degree. F./foot.
12. A method according to claim 11 wherein said additional
insulating agent is selected from the group consisting of
trichlorotrifluoroethane, dichlorotetrafluoroethane, and
trichloroethylene.
13. A method according to claim 9 wherein there is additionally
present an effective weighting amount of at least one agent
selected from the group consisting of ethane and ethylene having
from 3 to 6, inclusive, halogen atoms per molecule and which is
liquid at 200.degree. F. under a pressure of at least 200 psig, has
a weight in said liquid state of at least about 7 pounds/gallon,
and a thermal conductivity in said liquid state of no greater than
about 0.08 Btu/hour sq. foot .degree. F./foot.
14. A method according to claim 13 wherein said additional
weighting agent is selected from the group consisting of
trichlorotrifluoroethane, dichlorotetrafluoroethane, and
trichloroethylene present in an amount sufficient to give the
packer fluid a weight of at least about 7 pounds/gallon.
15. A method according to claim 9 wherein said shapes are present
in amounts of at least about 12 weight percent based on the total
weight of the packer fluid.
16. A method according to claim 9 wherein said shapes are spherical
and have a diameter range such that they will pass through a 50
mesh sieve but are no less than about 10 microns in diameter.
17. A method according to claim 9 wherein there is additionally
present an effective thickening amount of at least one gelling
agent.
18. A method according to claim 17 wherein said gelling agent is
present in an amount of from about 2 to about 10 weight percent
based on the total weight of the packer fluid.
19. A method according to claim 9 wherein there is additionally
present an effective amount of at least one material selected from
the group consisting of weighting agent and viscosifier.
20. A method according to claim 9 wherein said hydrocarbonaceous
oil is Diesel oil.
Description
BACKGROUND OF THE INVENTION
Packer fluids are liquids which are pumped into annuli between a
casing and the wellbore wall or between adjacent, concentric
strings of pipe extending into a wellbore, e.g. the annuli between
9 5/8 inch and 13 3/8 inch casing, between 7 inch casing and 4 1/2
inch tubing, and the like. Generally, depending upon the
conditions, oil base or water base fluid weighted with barite have
been employed.
However, in situations where the wellbore penetrates a permafrost
zone these conventional packer fluids are unacceptable primarily
because they are good thermal conductors, particularly when the
fluid is weighted with conventional weighting agents such as
barite, barium carbonate, calcium carbonate, lead sulfide, mixtures
thereof, and the like.
It is also important that the liquid base of the packer fluid have
a freezing point below the temperatures normally prevailing in a
permafrost zone, i.e. below the temperature range of from about
14.degree. to about 32.degree. F.
SUMMARY OF THE INVENTION
It has now been found that packer fluids which do not freeze at
permafrost temperatures and which have excellent thermal insulating
characteristics as well as the capability of being weighted without
destroying these thermal insulating characteristics are obtained by
employing a hydrocarbonaceous oil base which has a freezing point
below 14.degree. F. and incorporating therein an effective thermal
insulating and/or weighting amount of at least one of hollow shapes
of glass and/or plastic and halogenated ethane and/or halogenated
ethylene as hereinafter described.
The hollow shapes of this invention are, for example, glass spheres
with air in their hollow interior. The spheres are of very small
size, i.e. from about 10 to about 250 microns in diameter and are
therefore readily dispersible in the packer fluid. When so
dispersed in the packer fluid they decrease its density and greatly
decrease the thermal conductivity of the hydrocarbonaceous oil base
thereby producing a thermally insulated well packer fluid.
The halogenated ethane and ethylene have two salient advantages in
that, when added to a hydrocarbonaceous oil base, they not only
have a thermal insulating effect due to their low thermal
conductivity but additionally have a weighting effect since they
are relatively dense liquids. T-us, the halogenated hydrocarbonas
have the distinct advantage of imparting thermal insulation while
at the same time adding weight to the packer fluid so that when a
weighted packer fluid is needed for permafrost zones, these
halogenated hydrocarbons can be used in lieu of barite and the
like, which increases thermal conductivity of the packer fluid.
Thus, these halogenated hydrocarbons can be employed as a weighting
agent if it is desired to add density to a packer fluid such as a
packer fluid employing the hollow shapes of this invention and not
only is weighting achieved when these halogenated hydrocarbons are
added, but at the same time the packer fluid is rendered even more
thermally insulating.
Accordingly, it is an object of this invention to provide a new and
improved method for drilling and/or producing a well through a
permafrost zone. It is another object to provide a new and improved
method for employing thermally insulating and/or weighted packer
fluids in permafrost zones. It is another object to provide a new
and improved well packer fluid. It is another object to provide a
new and improved packer fluid useful in permafrost zones. It is
another object to provide a new and improved thermally insulating
weighted packer fluid.
Other aspects, objects, and advantages of this invention will be
apparent to those skilled in the art from this disclosure and the
appended claims.
DETAILED DESCRIPTION OF THE INVENTION
According to one aspect of this invention, a thermal insulating
packer fluid is provided by employing a hydrocarbonaceous oil base
and incorporating in that base an effective thermal insulating
amount of hollow shapes of at least one of glass and plastic, the
shapes passing through a 50 mesh sieve, preferably being no less
than about 10 microns, said shapes having a grain density (average
density of one shape) of from about 0.2 to about 0.4 grams per
cubic centimeter, said shapes also having a thermal conductivity in
bulk form of no greater than about 0.08 Btu of heat transfer over a
square foot area with a temperature gradient in .degree. F. per
foot of thickness, i.e., Btu/hour sq. foot .degree. F./foot.
This packer fluid can have added thereto an effective insulating
and/or weighting amount of at least one of ethane and ethylene
having from 3 to 6, inclusive, halogen atoms per molecule and which
is a liquid at 200.degree. F. under pressure of at least 200 psig,
has a weight in said liquid state of at least about 7 pounds per
gallon, and has a thermal conductivity in said liquid state of no
greater than about 0.08 Btu/hour sq. foot .degree. F./foot.
The addition of the hollow shapes of this invention to a base
liquid can lighten the total liquid which is acceptable in some
situations. However, in situations where a heavier packer fluid is
desirable the halogenated hydrocarbons of this invention can be
added to that packer fluid containing the hollow shapes of this
invention to give that packer fluid the desired weight. A special
advantage of this invention is that this weighting can be achieved
with the halogenated hydrocarbon with the result that there is not
sacrifice in thermal insulation, but rather an enhancement of the
thermal insulating characteristics of the packer fluid.
According to another aspect of this invention, the
hydrocarbonaceous oil base can have added thereto an effective
insulating and/or weighting amount of at least one of the above
halogenated hydrocarbons and without the use of the above hollow
shapes and to provide a thermal insulating and weighted packer
fluid.
The hydrocarbonaceous oil base can be one or more liquids. Suitable
hydrocarbonaceous liquids have API gravities below about 30.degree.
and viscosities greater than about 25 SSF at 122.degree. F. and can
be crude petroleum oil or a distillate or residuum material
therefrom. Heavy materials such as light tar, cracked residua,
heavy extracts, and the like can also be employed. Diesel oil, fuel
oil, gas oil, kerosine, heavier petroleum refinery liquid residues
can be employed alone or in combination with heavier materials to
lighten same. Mixtures of two or more of these materials can be
employed as desired. The base oil will be the major component of
the packer fluid but can vary widely in the amount present
depending upon what other additives are employed and the desired
final characteristics of the packer fluid as a whole. Generally, at
least about 50 weight percent of the packer fluid will be the
hydrocarbonaceous oil base with the base generally being in the
range of from about 50 to about 90 weight percent based on the
total weight of the packer fluid.
The hollow shapes can be of any desired shape, but generally
spherical and can be glass or plastic. Any glass or plastic can be
employed so long as it is substantially inert to the base oil. The
hollow shape should be completely closed so that the base oil can
not penetrate the interior of the hollow shapes. Thus, the hollow
shapes will be composed of glass or plastic which can be maintained
in the base material for at least 20 years without deteriorating
and without allowing the base liquid to penetrate the interior.
The hollow shapes can be dispersed in the base oil by simply mixing
the shapes with the oil until an intimate dispersion is achieved.
Because of the small size of the shapes they will stay in this
dispersion for a matter of years.
However, in order to better maintain the dispersion of hollow
shapes in the base oil for a long period of time, and also in order
to thicken the dispersion so as to substantially prevent the
formation of convection currents in the packer fluid after it is
placed in the wellbore, one or more conventional emulsifiers can be
employed in an effective thickening amount. The thickening amount
will vary widely depending on the particular materials present and
the degree of thickening desired, but generally from about 2 to
about 10 weight percent of one or more gelling agents can be
employed based on the total weight of the packer fluid. Suitable
emulsifiers are fully and completely disclosed in "Composition and
Properties of Oil Well Drilling Fluid" by W. F. Rogers, Third
Edition, Gulf Publishing Company, Houston, Texas, 1963, page 565 et
sic. Suitable emulsifiers include alkaline metal soap or alkaline
earth metal soap of heavy metal (e.g., group IV b, V B, VI b, VII
B, VIII B of the Periodic Table, Handbook of Chemistry and Physics,
Chemical Rubber Company, 45 Edition, 1964, page B-2 (Soaps), of
tall oil, resin oil, fatty acids, disproportionated rosin as fully
and completely disclosed in U.S. Pat. No. 2,678,697, the disclosure
of which is incorporated herein by reference, and the like. The
emulsifier should be soluble in the oil base. Suitable fatty acids
are saturated, unsaturated, or mixtures thereof such as capric,
isocapric, lauric, pentadeconoic, palmitic, stearic, oleic,
linoleic, dehenic, tetracofanoic, cerotic, and fatty acid mixtures
obtained from vegetables and animals, e.g., tall oil, cotten seed,
corn, coconut oil, soya, fish oil, animal fat, and the like.
As desired, weighting agents which do not substantially adversely
affect the thermal insulating characteristics of the packer fluid,
viscosifiers such as asphalt, bentonite, or other clay, and the
like, surfactants to render the hollow shaped oil wet, and the like
can be employed in the packer fluid of this invention so long as
the materials are substantially inert as to the base oil and hollow
shapes and do not substantially adversely affect the thermal
insulating characteristics of the packer fluid.
The hollow shapes are present in the packer fluid in an amount to
give the packer fluid a thermal insulating characteristic which is
better than the thermal insulating properties of the base oil
itself. Generally, at least about 12 weight percent hollow shapes
will be employed based on the total weight of the packer fluid. To
put it another way, sufficient hollow shapes can be employed to
give the packer fluid a thermal conductivity no greater than about
0.08 Btu/hour sq. foot .degree. F./foot.
There can also be present in the hollow shape containing packer
fluid one or more halogenated hydrocarbons as above described, the
halogenated hydrocarbons being present in an effective insulating
and/or weighting amount depending upon whether the material is
added primarily as an insulating agent or a weighting agent, the
material having beneficial effects on both functions. Generally,
any halogenated ethane or ethylene meeting the above described
requirements can be employed. Suitable specific materials include
trichlorotrifluoroethane, dichlorotetrofluoroethane and
trichloroethylene these materials can be employed in effective
finite amounts up to about 50 weight percent based upon the total
weight of the packer fluid to give the packer fluid a weight of at
least about 7 pounds per gallon and a thermal conductivity no
greater than about 0.08 Btu/hour sq. foot .degree. F./foot.
The halogenated hydrocarbons of this invention can be employed with
the hydrocarbonaceous base oil in the absence of any hollow shapes
and when the base oil and halogenated hydrocarbons are thus mixed a
thermally insulating and weighted packer fluid is produced in its
own right. Therefore, a thermal insulating weighted packer fluid
according to this invention can contain an effective insulating
and/or weighting amount of at least one halogenated hydrocarbon as
above defined, the remainder being essentially the
hydrocarbonaceous base oil as above defined.
In addition, additives can be employed in the halogenated
hydrocarbon/base oil packer fluid which, include the above hollow
shapes, weighting agents, viscosifiers, surfactants, oil wetting
surfactants, and the like so long as the thermal insulating and
weighting characteristics of the packer fluid are not substantially
adversely affected.
All of the packer fluids of this invention can be prepared by
simple mixing of the ingredients under ambient conditions of
temperature and pressure for a time sufficient to provide a
homogeneous mixture of all ingredients.
The method of this invention involves using during at least one of
drilling and/or producing of the well through the permafrost zone,
one or more of the packer fluids as above described, the packer
fluid being used in the wellbore at least through the permafrost
zone by substantially filling at least one annulus zone between two
concentric pipes in the wellbore with at least one packer fluid of
this invention.
The halogenated hydrocarbons useful in this invention are desirable
additives other than their high weight and low thermal
conductivities because they have substantially no corrosivity in
steel, stainless steel, nickel based alloys, aluminum, and tin.
Consequently they have good stability in contact with steel such as
that steel from which drilling pipe and casing is made. Halogenated
hydrocarbons also have low toxicity, e.g., a threshold limit value
of 7,600 milligrams per cubic meter for trichlorotrifluoroethane,
high flash points e.g., above 900.degree. F. for
trichlorotrifluoroethane, and generally have a flash surpressing
effect on liquids such as hydrocarbons with which they are mixed.
Thus, these halogenated hydrocarbons are well suited for addition
to a packer fluid and will perform well under the conditions of
operation for a packer fluid.
EXAMPLE 1
Various packer fluids were prepared using diesel oil having an API
gravity of about 38.8.degree. and a viscosity of about 1.73
centistokes at 100.degree. F., a weight of 6.7 pounds per gallon at
100.degree. F. and a thermal conductivity of 0.08 Btu/hour sq. foot
.degree. F./foot. In packer fluid 1 trichlorotrifluoroethane (CClhd
2F-- CC1F.sub.2) having a weight of 12.8 pounds per gallon at
100.degree. F. and a thermal conductivity of 0.05 Btu/hour sq. foot
.degree. F./foot at 100.degree. F. was mixed at about 75.degree. F.
with residual fuel oil having a API gravity of about 16.9.degree.
at 60.degree. F. and a viscosity of about 150 SSF at 122.degree. F.
and an emulsifier of the calcium salt of disproportionated rosin as
fully and completely disclosed in U.S. Pat. No. 2,678,697. In
packer fluid 1 the halogenated hydrocarbon was employed in an
amount of 80 volume percent, the residual fuel oil in the amount of
10 volume percent and the emulsifier in the volume of 10 volume
percent. The resulting packer fluid at 100.degree. F. has a weight
of 11.9 pounds per gallon and a thermal conductivity of 0.055. A
packer fluid of this high a weight with such a low thermal
conductivity is highly desirable for use in permafrost
applications.
Packer fluid 2 was formed by mixing at 75.degree. F., diesel oil as
above described with the halogenated hydrocarbon of packer fluid 1,
the residual fuel oil of packer fluid 1, and the emulsifier of
packer fluid 1. The materials were mixed in the amounts of 31.4
volume percent diesel oil, 10 volume percent residual fuel oil, 10
volume percent emulsifier, and 48.6 volume halogenated hydrocarbon.
The resulting packer fluid had at 100.degree. F. a weight of 10
pounds per gallon and a thermal conductivity of 0.075. This packer
fluid also has an exceptional combination of weight and thermal
conductivity as can be seen by comparison with packer fluid 3.
Packer fluid 3 was composed of 86.4 volume percent residual fuel
oil of packer fluid 1, and 30.4 weight percent barite, the barite
having a density of 4.3 grams per cubic centimeter and a thermal
conductivity of 1.25. The resulting packer fluid at 100.degree. F.
had a weight of 10 pounds per gallon and a thermal conductivity of
0.1.
It can be seen from packer fluid 3 that although an equivalently
weighted packer fluid was achieved, the packer fluid did not have
sufficient thermal insulating characteristics with the thermal
conductivity of 0.1 and therefore was not desirable for use in
permafrost applications.
Packer fluids 1 and 2 are mixed at the drill site and just prior to
introduction of these fluids into the wellbore, about 10 pounds of
calcium oxide per barrel of packer fluid is added. The packer fluid
displaces the drilling mud in the annulus in the wellbore by first
passing down the interior of the drill pipe and then upwards into
the annulus. In about 3 hours the packer fluid has formed a grease
like gel in the drilling fluid by way of reaction of the calcium
oxide with the packer fluid. It is preferred that the packer fluid
be gelled or otherwise viscosified somewhat to help prevent the
formation of convection currents within the fluid after emplacement
in the annulus.
EXAMPLE 2
The residual fuel oil of Example 1 is employed as a base oil in the
amount of 62 volume percent to which is added 14.7 weight percent
of hollow glass spheres in the size range of from about 10 to about
250 microns, the glass being of a borosilicate composition, the
spheres being filled with air and the hollow interior closed off
from the exterior. The glass spheres had a grain density of about
0.26 grams per cubic centimeter, a thermal conductivity in bulk of
about 0.03 Btu/hour sq. foot .degree. F./foot. The glass spheres
are commercially available from Emerson and Cuming, Inc. and
Minnesota Mining and Manufacturing Company.
The spheres were mixed with the base oil at 75.degree. F. until an
homogeneous mixture was formed.
The resulting packer fluid had a weight of 5.95 pounds per gallon
and a thermal conductivity of 0.07 Btu/hour sq. foot .degree.
F./foot.
This packer fluid can also be thickened by the addition thereto of
6 volume percent of the emulsifier of Example 1.
Reasonable variations and modifications are possible within the
scope of this disclosure without departing from the spirit and
scope of this invention.
* * * * *