U.S. patent number 3,698,202 [Application Number 05/171,874] was granted by the patent office on 1972-10-17 for control system for low temperature refrigeration system.
This patent grant is currently assigned to Gulf & Western Industries, Inc.. Invention is credited to Dale J. Missimer.
United States Patent |
3,698,202 |
Missimer |
October 17, 1972 |
CONTROL SYSTEM FOR LOW TEMPERATURE REFRIGERATION SYSTEM
Abstract
In a compression refrigeration cycle employing a mixture of
refrigerants and a single compressor wherein low temperatures are
reached by one or more vapor-liquid separations in which the
expanded and cooled liquid from each separation stage is evaporated
and used to condense the vapors from that stage, high starting
discharge pressures are avoided and rapid cool down to low
temperature is achieved by incorporating a by-pass system for the
throttling device feeding the evaporator which is responsive to
predetermined operating characteristics of the cycle.
Inventors: |
Missimer; Dale J. (San Anselmo,
CA) |
Assignee: |
Gulf & Western Industries,
Inc. (New York, NY)
|
Family
ID: |
22625477 |
Appl.
No.: |
05/171,874 |
Filed: |
August 16, 1971 |
Current U.S.
Class: |
62/114; 62/197;
62/502 |
Current CPC
Class: |
F25B
9/006 (20130101); F25B 2500/26 (20130101) |
Current International
Class: |
F25B
9/00 (20060101); F25b 001/00 () |
Field of
Search: |
;62/114,197,198,502 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: O'Dea; William F.
Assistant Examiner: Ferguson; P. D.
Claims
What is claimed is:
1. In a compression process for refrigeration using a mixture of
refrigerants having different boiling points which process
comprises the steps of compressing a vaporous mixture of
refrigerants, partially condensing the compressed refrigerant
vapors in a first condensation stage, separating the condensate
into first liquid and first vapor phases, throttling said first
liquid phase to a lower pressure, evaporating said throttled first
liquid phase to absorb heat from and at least partially condense
said separated first vapor phase, throttling the at least partially
condensed vapors to a lower pressure, at least partially
evaporating said throttled condensed vapors in an evaporator to
produce the final refrigerating temperatures, mixing the
refrigerant leaving said evaporator with the said throttled first
liquid phase and closing the circuit by recycling the mixture of
refrigerants to the compressing step, the improvement comprising
by-passing the final throttling step feeding the evaporator when
compression is commenced and continuing by by-pass said throttling
step until the said refrigerants reach a predetermined operating
condition.
2. The process of claim 1 wherein said final throttling step is
by-passed until the discharge pressure is 10 to 150 psi more than
the final discharge pressure of said process.
3. The process of claim 1 wherein said final throttling step is
by-passed until the temperature of the refrigerant in said
evaporator is within 5.degree. to 100.degree. F. of the lowest
evaporator temperature for said process.
4. The process of claim 1 including at least one additional
intermediate cooling stage subsequent to said first condensation
stage and prior to separating the condensate into first liquid and
first vapor phases, each said intermediate cooling step comprising
the steps of separating the condensate from said first condensation
stage into a vapor phase and a liquid phase, throttling the liquid
phase to a lower pressure; evaporating the throttled liquid phase
to absorb heat from and at least partially condense the separated
vapor phase and mixing the evaporated liquid phase with said
mixture of refrigerants being recycled from said final evaporator
to said compressing step.
5. The process of claim 1 wherein said refrigerant mixture
comprises two to six individual refrigerants.
6. The process of claim 1 in which any separated liquid phase is
cooled by an exchange of heat with said recycling refrigerant
returning to the compressing step prior to said evaporation of said
separated and throttled liquid.
7. A compression refrigeration apparatus comprising:
a. compression means for compressing a vaporous mixture of
refrigerants having different boiling points;
b. condenser means for at least partially condensing said
compressed refrigerant vapors;
c. at least one intermediate cooling stage, said stage comprising
vapor-liquid separating means, throttling means for reducing the
pressure on the separated liquid phase, heat exchanger means for at
least partially condensing said separated vapor and evaporating
said throttled liquid phase, circulation means for passing said at
least partially condensed vapor to the next succeeding cooling
stage, and circulation means for returning said evaporated liquid
phase to said compressor means;
d. final throttling means for reducing the pressure of the at least
partially condensed vapors from said intermediate cooling
stage;
e. evaporator means for at least partially evaporating said
throttled condensed vapors to produce the final refrigerating
temperature;
f. by-pass means interposed between said intermediate cooling stage
and said evaporator said by-pass means having an open position and
a closed position and adapted to move between said positions in
response to predetermined operating characteristics of the
refrigerants; and
g. recycling means for returning the at least partially evaporated
refrigerant mixture to said compressor means.
8. The apparatus of claim 7 wherein said by-pass means is a
pressure actuated valve.
9. The apparatus of claim 8 wherein said valve is responsive to the
discharge pressure of said apparatus.
10. The apparatus of claim 7 wherein said by-pass means is a
temperature responsive valve.
11. The apparatus of claim 10 wherein said valve is a thermal
expansion valve which is actuated by the evaporator temperature and
pressure.
12. The apparatus of claim 7 which includes two to five successive
intermediate cooling stages.
13. The apparatus of claim 7 including a series of mixing means for
joining the recycling refrigerant mixture emanating from said
evaporator means with the throttled separated liquid from each of
said successive intermediate cooling stages prior to reaching said
compression means.
14. The apparatus of claim 7 further including at least one
auxiliary condenser means for permitting heat exchange between said
recycling refrigerant mixture and said at least partially condensed
vapors.
15. The apparatus of claim 7 further including at least one heat
exchange means for permitting an exchange of heat between said
separated liquid and said recycling refrigerant mixture.
Description
This invention relates to compression refrigeration systems. More
particularly, the present invention is concerned with a novel
control system for rapidly achieving ultra-low temperatures in
compression refrigeration systems.
U.S. Pat. No. 3,203,194 issued Aug. 31, 1965 to A. Fuderer
describes a compression refrigeration system involving the use of a
mixture of refrigerants circulating in a single refrigeration
circuit employing a single compressor. In this system, the
compressed mixture of refrigerant gasses undergoes a partial
condensation in a first condensation stage and a liquid fraction,
rich in the higher boiling refrigerant, is formed. Thereafter, the
liquid fraction is separated from the remaining vapors and the
vapors are transferred to a second condensation stage where they
are condensed using the cold produced by the expansion and
evaporation of the liquid component from the first condensation
stage and by cold vapors returning to the compressor from the final
evaporator. The final refrigeration temperature is achieved by
throttling and at least partially evaporating the condensate from
the second stage of condensation. The refrigeration circuit is
closed by mixing the vapors, and any residual liquid leaving the
final evaporator with the vapor formed by throttling the liquid
rich in the higher boiling refrigerant and returning the vaporous
mixture to the compressor.
Co-pending commonly assigned U.S. Pat. application, Ser. No. 43,108
filed June 3, 1970 and now abandoned, in the name of Dale Missimer
and Daniel Lieberman and entitled "Low Temperature Refrigeration
System", also describes a compression refrigeration system
utilizing a single refrigeration circuit which circulates a mixture
of refrigerants. In that application, multiple intermediate cooling
stages and multiple vapor liquid separation steps are employed to
achieve ultimate low temperatures in the cryogenic range with
conventional compression equipment operating at compression ratios
of less than 10:1.
While the above-described systems are effective in achieving
temperatures approaching the cryogenic range at low pressures and
compression ratios when operating normally after having achieved
temperatures in the range for which they were designed, a problem
has existed with regard to the commercial packaging and design of
sealed systems incorporating the above refrigeration concepts.
Specifically, it has been found that when these systems operate at
higher temperatures, for example during start-up from room
temperature or during power off and standby conditions, the
refrigerants employed exert substantially higher vapor pressures
and there is an increased likelihood of reaching compressor
discharge pressures and compression ratios which would damage the
compressor. In experimental systems, such a result is avoided by
staging the refrigerant charge to the system, thereby limiting the
volume of refrigerant flow until such time as lower temperatures
are achieved and the system develops the capacity for accepting
additional refrigerant. The use of staged charging techniques is
obviously impractical in commercial systems which require that the
full charge of refrigerant be permanently sealed into the
system.
An alternative method for controlling vapor discharge pressures is
described in the Fuderer patent and involves the use of a pressure
regulated vapor tank on the discharge side of the compressor. This
vapor tank serves to take low boiling refrigerant vapors out of
circulation when the pressure on the discharge side of the
compressor becomes too high and to return some of those vapors to
the refrigeration cycle as the pressure is reduced. The use of
vapor tanks is unacceptable in many commercial operations since it
severely reduces refrigerant flow through the system and thereby
greatly increases the time required to reach the optimum
temperature range for which the system is designed.
It is an object of the present invention to provide a novel control
system for maintaining the compressor discharge pressures and
compression ratios of compression refrigeration systems within the
safe limits of the compressor being employed.
It is another object of this invention to provide a by-pass system
for rapid start-up of compression refrigeration systems employing
multiple refrigerants and intermediate cooling stages.
Yet another object of the present invention is to provide a sealed
compression refrigeration system containing a full refrigerant
charge which is capable of rapidly achieving low temperatures
without damage to compression equipment or other system
components.
It has now been discovered that excessive compressor discharge
pressures and compression ratios can be avoided during periods of
start-up and temperature pull-down by permitting uncondensed
refrigerant vapors to return to the low pressure side of the
refrigeration system without passing through the primary throttling
device feeding the low temperature evaporator of the refrigeration
cycle. It has also been discovered that the utilization of such
by-pass systems results in the more rapid attainment of the normal
operating conditions of the system.
While not wishing to be limited to any particular theory, it is
presently believed that the by-pass system of the invention avoids
excessive discharge pressures and results in more rapid cooling for
several reasons. First, the volume on the low pressure or suction
side of the refrigeration cycle is greater than the volume on the
high pressure or discharge side of the compressor. Thus,
eliminating the final throttling step, the vapors are permitted to
more easily flow to the low pressure or suction side of the cycle
thereby increasing the pressure on the side of the system which has
more volume. As a result, a larger amount of the non-condensed low
boiling point vapor fractions can be retained in the system at a
lower discharge pressure. Second, the by-pass system allows the
partially condensed low boiling point vapors on the high pressure
side of the cycle to flow at a higher rate than the flow rates
which can be achieved when the final throttling device is not
by-passed, thereby resulting in quicker cooling of the final
evaporator. Moreover, since the larger flow of suction vapors to
the compressor can more readily absorb the low boiling point rich
vapors from the high pressure side of the system, the system
appears to lower the partial vapor pressure of the evaporating
condensate employed in the high pressure side of the cascade
condenser. The lower partial pressure results in lower evaporating
temperatures for the liquid and thus, condensation on the high
pressure side of the cascade condenser commences sooner and at
lower temperatures.
The invention will be further understood by reference to the
accompanying drawings where:
FIG. 1 is a schematic representation of a refrigeration system
employing one form of the by-pass system of the invention; and
FIG. 2 is a schematic representation of a modified form of the
by-pass system shown in FIG. 1.
Referring specifically to FIG. 1, a mixture of two or more
refrigerants having different boiling points is charged into a
single closed refrigeration circuit generally identified as 10
through a service valve 12 or other conventional charging means
such as a tube, pipe, or the like which will be sealed after the
charging step. The amount of each refrigerant charged to the system
may be predetermined by weight or, in the case of lower boiling
point refrigerants, by allowing each refrigerant gas to circulate
through the system until a predetermined partial pressure and a
predetermined total pressure for the system are reached.
Subsequent to the charging step the vapors are aspirated by a
compressor 14 and pass through line 16 to condenser 18 where
partial condensation occurs. Condensation occurs by heat exchange
with ambient air forced over condenser pipes 20 by a fan 22, or
alternatively, condensation may be carried out using a readily
available source of water. The partially condensed refrigerant
mixture flows through line 24 to an optional auxiliary condenser 26
where, after the system is in operation, further condensation may
occur by heat exchange with the cooler vapors returning to
compressor 14 from the final evaporator 28 through line 30. The
utilization of an auxiliary condenser is not critical to the
refrigeration system but such additional heat exchange at this
point and at other similar points throughout the system serve to
improve thermodynamic efficiency. The partially condensed
refrigerant mixture leaves auxiliary condenser 26 through line 32
and passes to a vapor-liquid separator 34. The liquid at this point
is rich in the higher boiling refrigerant or refrigerants of the
mixture. Nevertheless, each fraction will contain at least minor
amounts of each of the refrigerants in the mixture.
The liquid separated in separator 34 passes through an optional
dryer-strainer 36 where particulate matter is filtered from the
stream and residual moisture is removed and then through a
capillary tube 38 which throttles the liquid, i.e., the pressure on
the liquid drops from the discharge pressure to the suction
pressure. The use of a capillary tube is not critical and any
expansion or throttling device such as a float valve, thermal
expansion valve, or other device well known in the refrigeration
art may be employed in lieu of capillary tube 38. A portion of
capillary tube 38 may be disposed in a heating exchange
relationship at point 40 with line 30 through which cold vapors are
returning to the compressor from the final evaporator 28. As noted
previously, such an arrangement is not critical but serves to
further cool the condensate and improve thermodynamic efficiency.
In lieu of the heat exchange between capillary tube 38 and line 30
a heat exchanger could be employed at point 40. Such an exchanger
would be particularly useful where expansion or throttling was
achieved by means of a valve or other throttling device located
below strainer 36, rather than the capillary tube as shown.
The throttled, low pressure liquid emanating from capillary 38 is
intermixed at point 42 with the cold returning vapors in line 30.
This liquid is evaporated in cascade condenser 44 and the
absorption of heat causes the condensation of the low-boiling point
vapor fraction which leaves separator 34 and passes through line 43
to cascade condenser 44.
When the system is operating normally, the by-pass systems of the
invention are closed and the final liquid fraction from cascade
condenser 44 passes through a second optional dryer strainer 46, is
throttled in capillary tube or other throttling device 48 and, if
desired, further cooled by heat exchange with returning vapors in
line 30 at exchange point 50. The liquid at evaporator inlet 52 is
at the coldest system temperature and essentially at the suction
pressure and is partially or completely evaporated in evaporator 28
to achieve the final refrigeration temperature of the system. The
refrigeration circuit is closed by returning the vapors and any
residual liquid from evaporator 28 through line 30 back to
compressor 14, the vapor being mixed with additional refrigerant
fractions, e.g., the expanded and evaporated higher boiling liquid
fraction emanating from capillary 38, along its path of travel as
previously described and the cycle is repeated.
The refrigeration system as described above is substantially
identical to the system described in U.S. Pat. No. 3,203,194. It is
capable of producing low refrigeration temperatures, when
operating, utilizing mixtures of refrigerants having different
boiling points with conventional compressors operating at
compression ratios of less than 10:1.
FIG. 1 also illustrates one form of the by-pass system of the
invention. This system includes valve 54 positioned near the outlet
end of optional dryer-strainer 46 and line 56 which runs from valve
54 to the inlet 52 of evaporator 28. During normal operation, valve
54 is closed and the refrigeration cycle operates as previously
described. Thus, the condensate leaving cascade condenser 44 passes
through expansion device 48 and then through final evaporator 28.
However, during start-up of the refrigeration cycle, valve 54 will
be open and the vapors and condensate from cascade condenser 44
will pass through valve 54 and line 56 to the inlet end 52 of
evaporator 28 thereby by-passing expansion device 48.
The selection of a particular flow control device for the by-pass
system is not critical so long as it meets certain functional
characteristics. Thus valve 54 may be either a temperature or
pressure actuated valve of a construction generally well known to
persons skilled in the art.
A typical pressure actuated valve which is useful in the system of
the invention is designed to sense the upstream or compressor
discharge pressure and open as this pressure increases above a
pre-set level. In a typical pressure actuated valve the discharge
pressure of the system which acts to open the valve will be
counterbalanced by a spring and atmospheric pressure acting in a
downward or closing direction. Moreover, the port size of the valve
will be selected so as to handle the vapor flow without permitting
the outlet pressure from the valve to influence its operating
characteristics while being small enough to avoid chattering. In
preferred valve arrangements, the valve seat and plug shape may be
designed to permit a modulated flow rather than merely operating
only at the full open or full closed position although the pressure
range between the full open and pre-set shut-off positions will be
relatively small, e.g., 10 to 50 psi. While the operating range for
the valve is not critical it may function to by-pass the final
throttling step, as least in part, until the discharge pressure
reaches a level of within 10 to 150 psi of the final discharge
pressure of the system.
A typical temperature actuated valve which is useful in the system
of the invention is designed to sense the refrigerant temperature
leaving the final evaporator and shut-off when this temperature
reaches within a pre-determined level, e.g., within 5.degree. to
100.degree. F., preferably 10.degree. to 20.degree. F. of the final
evaporator temperature for which the system is designed. The
thermal expansion valve will normally be installed in parallel with
the capillary tube or other expansion device feeding the final
evaporator and will have an oversized port or orifice, e.g., 3 to 5
times the size required for a standard duty thermal expansion
valve.
Irrespective of which type of by-pass valve is selected the valve
will be set to function at a predetermined level based upon the
operating characteristics of the refrigeration system in which it
is employed. These characteristics will vary depending upon the
nature of the refrigerants employed and the maximum safe operating
pressure and compressor ratios for the compressor employed in the
system. Typically a pressure actuated type would be wide open at
discharge pressures above 300 psig and will close tight below 250
psig with a compressor suitable for air-conditioning with R-22
refrigerant (about 2.5 cfm displacement per h.p.). For an
air-conditioning range R-12 compressor having about 4 cfm
displacement per h.p., the actuation range would be full open at
200 psig and closed at 160 psig discharge pressure.
Temperature actuated valves, or more suitably temperature-suction
pressure thermal expansion valves which sense and control from
superheat have a charge such that they remain open until the
suction line leaving the evaporator is reduced to within 10.degree.
to 20.degree. F. of the final low temperature. Such a valve, when
installed in parallel with a thermal expansion valve used for final
control of feed to the evaporator, will have a charge in the power
assembly having a boiling point about 10.degree. to 30.degree. F.
higher than that of the refrigerants exiting from the evaporator,
when compared at the same suction pressures. This may involve the
use of a mixed or "cross" charge in the by-pass valve power
assembly.
FIG. 2 illustrates a slightly modified form of the by-pass system.
In this arrangement a pair of complimentary temperature and/or
pressure controlled solenoid actuated or modulating type valves 60
and 62 function as a by-pass control system. During normal
operation valve 62 will be closed and valve 60 will be open so that
the condensate leaving cascade condenser 44 travels through
expansion device 48 and final evaporator 28 in the normal fashion.
However, during start-up, valve 60 will be closed and valve 62 will
remain open until such time as the solenoid operating valves 60 and
62 are energized, depending upon the operating characteristics of
the refrigeration cycle as previously discussed at which time valve
62 will close and valve 60 will open. With valve 62 in the open
position and valve 60 in the closed position, the condensate
leaving cascade condenser 44 will by-pass both expansion device 48
and final evaporator 28 and pass immediately to return line 30 at
junction 64. It will be evident to those persons skilled in the art
that the solenoid valves may be actuated by the action of a
temperature or pressure controller or by a suitable timing circuit.
It is also evident that in lieu of two solenoid actuated valves a
single three-way valve may be employed.
While the by-pass system of the invention has been schematically
represented with respect to the refrigeration cycle illustrated in
Fuderer U.S. Pat. No. 3,203,194 it will be obvious to those persons
skilled in the art that the system is equally applicable to
refrigeration systems utilizing multiple vapor-liquid separators,
multiple cascade condensers, and any desired number of refrigerants
provided only that the boiling points of the individual
refrigerants in the mixture are sufficiently far apart to permit a
reasonable separation into distinct liquid and vapor phases at each
stage of the system. Such systems and refrigerants are described in
co-pending commonly assigned U.S. application, Ser. No. 43,108,
filed June 30, 1970 and include refrigerant mixtures wherein each
refrigerant in the mixture will differ in boiling point from the
next closest boiling refrigerant by 40.degree. to 250.degree. F.,
preferably 90.degree. F. Any of the well-known refrigerants set
forth in standard refrigerant tables and charts may be
employed.
The invention will be further understood by reference to the
following illustrative example:
A storage freezer having a 4.5 cubic foot workspace volume and a
capability of reaching -100.degree. F. was operated for the purpose
of determining the effect of the by-pass system of the invention.
The freezer was first tested with a refrigeration cycle similar to
that illustrated in FIG. 1 but not including the by-pass system.
The refrigerants employed were R-503, an azeotrope of
trifluoromethane (R-23) and chlorotrifluoromethane (R-13) and
R-114, dichlorotetrafluoroethane. The start-up pressure of the
system was 350 psig and it took 90 minutes to reach a final
evaporator temperature of -100.degree. F. In addition, in repeated
tests the system had difficulty in starting up after each "off"
cycle and on one occasion the cascade condenser went into
self-refrigeration.
The system described above was subsequently operated with a by-pass
control system including a thermal expansion valve having a
suitably selected port size and a power assembly set up for 55 psig
miximum operating pressure, and a "cross-charged" R-13 charge, in
parallel with the capillary tube feeding the final evaporator. The
maximum starting discharge pressure was normally only 280 psig. The
chamber reached -100.degree. F. in 45 minutes.
Similar tests on the same system with a by-pass system comprising a
pressure actuated valve resulted in pull-down to -100.degree. F. in
60 minutes at starting discharge pressures up to approximately 300
psig.
Having thus described the general nature as well as preferred
embodiments of the invention and true scope will now be pointed out
in the appended claims:
* * * * *