U.S. patent number 3,698,095 [Application Number 05/082,239] was granted by the patent office on 1972-10-17 for fiber conditioning article.
This patent grant is currently assigned to Colgate-Palmolive Company. Invention is credited to Pasquale Joseph Falivene, Henry P. Furgal, Paul S. Grand.
United States Patent |
3,698,095 |
Grand , et al. |
October 17, 1972 |
FIBER CONDITIONING ARTICLE
Abstract
An article for conditioning fibrous materials by contact
includes a form-retaining base and, held to an outside surface of
the base in form-retaining relationship with it, a flexible
material which has an outer surface thereof containing a fiber
conditioning agent. Conditioning effected is preferably fabric
softening and may take place in an automatic laundry dryer wherein
damp laundry is brought into tumbling contact with the conditioning
article while being dried. Such contact causes the transfer to the
laundry of softening agent and the dried laundry is satisfactorily
soft, non-static and unwrinkled, upon removal from the dryer. Also
disclosed are packages for the articles wherein the form-retaining
base is a paperboard cylinder and is employed as a container for
the flexible material coated with softening agent.
Inventors: |
Grand; Paul S. (South Bound
Brook, NJ), Falivene; Pasquale Joseph (Union City, NJ),
Furgal; Henry P. (Bernardsville, NJ) |
Assignee: |
Colgate-Palmolive Company (New
York, NY)
|
Family
ID: |
22169921 |
Appl.
No.: |
05/082,239 |
Filed: |
October 20, 1970 |
Current U.S.
Class: |
34/333; 206/.5;
34/60; 427/242 |
Current CPC
Class: |
D06F
58/30 (20200201); D06B 1/00 (20130101); D06F
58/203 (20130101); D06M 23/02 (20130101); D06M
23/00 (20130101); D06C 2700/135 (20130101) |
Current International
Class: |
D06B
1/00 (20060101); D06M 23/02 (20060101); D06M
23/00 (20060101); D06F 58/20 (20060101); F26b
003/00 () |
Field of
Search: |
;34/9,12,60,71 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Camby; John J.
Claims
What is claimed is:
1. An article for conditioning fibrous materials making contact
with it which comprises a form-retaining base and, held to an
outside surface of such base, in form-retaining relationship with
it, a flexible material having an outer surface containing thereon
a fiber conditioning agent which, during a tumbling operation, is
transferable to the fibrous materials contacted, to condition them,
said flexible material being in thin sheet or strip form and
conforms closely to the outer surface of at least a portion of the
form-retaining base, said fiber conditioning agent being a fabric
softener or antistatic agent.
2. An article according to claim 1 wherein the fabric softener is a
waxy composition which extends beyond the surface of the flexible
paper and which comprises, as an active fabric softening
constituent, an organic nonionic, anionic, cationic or mixed
anionic-nonionic or cationic-nonionic surface active softening
agent.
3. An article according to claim 2 wherein the form-retaining base
is tubular and the flexible material is fastened to the exterior of
the tube by fastening means and is removable from the tube after
use and consumption of substantially all the fabric softening agent
at the outer surface thereof.
4. An article according to claim 5 wherein the form-retaining
tubular base is of paperboard, cardboard or corrugated board
construction and the thin sheet or strip of flexible material is of
paper.
5. An article according to claim 4 wherein the paper is coated on
both sides with fabric softener so as to be reversible on the
tubular base after consumption of the softener from one side
thereof.
6. An article according to claim 4 wherein the means for holding
the flexible material to the form-retaining base comprises end
sections of the paper which extend beyond the length of the tubular
base and are capable of being folded into the ends of the tubular
portion thereof, to hold the rest of the sheet or strip in
form-retaining relationship with the outer surface of the tube.
7. An article according to claim 6 wherein the end sections of the
paper are uncoated in the portions thereof which extend beyond the
length of the tubular base.
8. An article according to claim 3 wherein the tubular base is a
cylinder which is telescopic with a roll of paper containing the
conditioning agent.
9. A package of materials of a fiber conditioning article which
comprises a form-retaining tubular base and a quantity of flexible
material having an outer surface containing thereon a fiber
conditioning agent for the treatment of fibrous materials by
contact therewith, which quantity is sufficient for making a
plurality of covers for the base, with the quantity of flexible
material being packed in telescopic relationship with the base,
whereby the base performs the function of a packaging element for
the quantity of flexible material containing fiber conditioning
agent.
10. A package according to claim 9, wherein the form-retaining
tubular base is an outer cylinder and the quantity of flexible
material having an outer surface thereof containing a fiber
conditioning agent is in roll form, packed in the base
cylinder.
11. An article for conditioning fibrous materials making contact
with it which comprises a form-retaining base and, held to an
outside surface of such base, in form-retaining relationship with
it, a flexible material having an outer surface containing thereon
a fiber conditioning agent which, during a tumbling operation, is
transferable to the fibrous materials contacted, to condition them,
said fiber conditioning agent being a fabric softener or antistatic
agent.
12. A method for conditioning fibrous materials which comprises
contacting such materials with a fiber conditioning article
comprising a form-retaining base, and held to an outer surface of
such base in form-retaining relationship with it, a flexible
material having an outer surface containing thereon a fiber
conditioning agent, and tumbling fibrous materials to be
conditioned in contact with the article until a sufficient quantity
of fiber conditioning agent is transferred to the fibrous materials
to condition them, the fibrous materials being conditioned being
items of laundry in a damp state, the fiber conditioning agent
being a fabric softener and the contacting occurring in an
automatic laundry dryer during tumbling contact of the damp laundry
being dried with the conditioning article.
Description
SUBJECT OF THE INVENTION
This invention relates to the conditioning of fibrous materials by
contact with a form-retaining base having on an outer surface
thereof a conditioning agent which is transferable to the contacted
fibrous materials. More particularly, the invention relates to
certain structures of such form-retaining conditioning articles
wherein flexible substrates are employable despite the
disadvantages which it has been discovered are often associated
with their use.
BACKGROUND OF THE INVENTION
It is well known that conditioning agents may be employed to
improve the characteristics of fibrous materials. The most
important of such conditioning operations undertaken on a large
scale today during the washing of fibrous articles and materials is
the softening of such materials by addition of treating chemicals
in the last rinse. Substantive chemicals employed adhere to the
laundry so that after drying it has the desired properties
conditioned into it. Thus, cotton and synthetic organic polymeric
fibrous materials are made soft to the touch, static-free and
wrinkle-resistant by treatment with substantive softeners. Of
course, a problem with such treatment is in the necessity for the
softening agent or other conditioning compound to be highly
substantive to the fibers being treated. Otherwise, the
conditioning chemical is largely wasted, being discharged with the
rinse water.
When attempts have been made to condition laundry by a treatment
which will not require addition of a chemical to the rinse water,
such as in treatments in the dryer, other problems have been
encountered. For example, conditioning sprays or other applications
of liquid to the laundry in the dryer require somewhat complicated
and accordingly, expensive installations and even with these,
staining or other detrimental effects due to local over-application
of conditioning agent may be caused. Also, when a flexible paper or
cloth sheet is impregnated with cationic conditioning agent and the
product is tumbled with laundry in the dryer, staining is sometimes
experienced, apparently due to temporary entrapments of the
flexible conditioning article in the laundry being treated, causing
the application of more conditioning agent than is desirable at a
particular location on the treated material. Local over-application
of conditioning agents may also be caused by cracking and flaking
off of such compositions when the flexible substrate is folded,
creased, twisted, bent or otherwise distorted, straining the
conditioning material to a breaking point. In the case of cationic
conditioning agents, such as quaternary ammonium salts, severe
staining may result if there is also present a sufficient quantity
of materials containing color bodies or heavy metal ions, such as
ferric or ferrous ions. Such stains are difficult to remove from
the laundered articles, often requiring dry cleaning, which
sometimes is not completely successful. Thus, even the possibility
of only occasional adverse effects of this type will prevent the
satisfactory marketing of such a product. In attempts to counteract
this objectionable characteristic, the concentration of
conditioning agent may be diminished or its nature may be changed,
so as to avoid the most severe staining but such action may also
have a detrimental effect on the conditioning power of the
product.
Although the disadvantages of the use of flexible substrates for
conditioning substances have been ascertained, it is often
advantageous from a manufacturing standpoint to utilize films or
sheets of flexible materials as the means of applying conditioning
agent. This is largely so because they lend themselves to
continuous and mass production coating operations, which may not
adapt as well to the coating of solid or form-retaining articles.
Furthermore, flexible substrates such as paper may be rolled and
packaged automatically and large quantities of effective
conditioning surfaces may be contained in packages of comparatively
small volume.
DESCRIPTION OF THE INVENTION
The products, packages and methods of this invention allow the
commercial production of fiber conditioning articles and the
treatment of fabrics with them in efficient and commercially
adaptable ways and permit advantage to be taken of the better
transfer properties of conditioning materials from form-retaining
substrates, while at the same time permitting use of the
manufacturing and packaging techniques best applicable to flexible
materials.
In accordance with the present invention, an article for
conditioning fibrous materials making contact with it comprises a
form-retaining base and, held to an outside surface of such base,
in form-retaining relationship with it, a flexible material having
an outer surface containing thereon a fabric conditioning agent
which, during a tumbling operation, is transferable to the fibrous
materials contacted, thereby conditioning them. In particularly
preferred embodiments of the invention, the base of the
conditioning article is a paperboard cylindrical tube and the
flexible material is paper, wrapped around the tube and held to it,
with the outer surface of the paper being coated with a
conditioning agent for the fibrous materials to be contacted.
Various details, constructions, operations, uses and advantages of
the invention will be apparent from the following description,
taken in conjunction with the illustrative drawing of some
embodiments thereof, in which drawing:
THE DRAWING
FIG. 1 is a perspective view of a cylindrical fabric conditioning
article, illustrating holding of the flexible sheet portion thereof
to the form-retaining base by folding in of the sheet ends;
FIG. 2 is a perspective view of the cylindrical base of the article
of FIG. 1;
FIG. 3 is a developed plan view of the flexible sheet employed in
making the article of FIG. 1;
FIG. 4 is a vertical section along plane 4--4 of FIG. 3;
FIG. 5 is a corresponding vertical section of a flexible sheet
coated on both sides with fiber conditioning agents;
FIG. 6 is a top plan view of another form of fabric conditioning
article;
FIG. 7 is a vertical sectional view along plane 7--7 of FIG. 6;
and
FIG. 8 is a cutaway view of a part of a tubular package containing
a roll of flexible sheet material coated with conditioning
agent.
DETAILED DESCRIPTION OF THE INVENTION:
Fabric conditioning article 11 includes a base portion of
form-retaining material, a cylindrical paperboard tube 14, the
interior of which is shown at 13, plus a flexible covering sheet 15
having a coating of conditioning agent or composition 17 thereon.
The ends of such sheet, one of which is illustrated at 19, are
uncoated and are folded in to hold the sheet to the form-retaining
cylindrical base 13. The base is shown in FIG. 2. Wall 21 is of
sufficient thickness to make the paperboard cylindrical tube
form-retaining. The flexible sheet 15 of paper, coated with fabric
conditioning composition 17 is shown in FIGS. 3 and 4, before being
rolled around the outside of tube 13 to form the product of FIG. 1.
As will be noted from FIG. 4, the coating 17 of conditioning agent
penetrates slightly below the surface 27 of sheet 15, but does not
completely impregnate the paper. The thickness 23 of the
conditioning material external to the surface of sheet 15 is
generally sufficient to allow a plurality of conditioning uses in
softening or otherwise treating charges of laundry or other fibrous
material in an automatic dryer. In FIG. 5 there is illustrated a
different form of cover for a base, flexible sheet material 25,
coated on both sides with conditioning compositions 29 and 30,
respectively. In the articles of both FIGS. 4 and 5 the thicknesses
31 and 33 of the flexible bases and their flexibilities are such
that when the ends of the flexible sheet materials are folded
inwardly over a cylindrical form-retaining base 13, they hold the
coated sheet in place thereon.
In FIGS. 6 and 7 there is shown a disc shaped fiber conditioning
article 35 having coatings 37 and 38 of fabric conditioning
composition on the surfaces 41 and 43 of flexible substrates 42 and
44, respectively, with these held to form-retaining base 39.
Substrates 42 and 44 are fastened to form-retaining base 39 by
suitable means, e.g., staples, cement.
In FIG. 8 a cylindrical tubular outer package 49 comprises tubular
wall portion 51 and end 53. The tube is similarly closed at the
opposite end and the ends may be punched out, if so desired, when
the tubular portion 51 thereof is to be employed as a
form-retaining base to be covered with a strip of flexible sheet
material coated with conditioning agent. Such flexible sheet
material is shown at 55, in a continuous sheet rolled about mandrel
tube 57. In the packages illustrated in the drawing the roll of
flexible sheeting coated with conditioning agent is long enough to
cover form-retaining cylinder 51 about 10 to 25 times.
The present articles for conditioning fibrous materials may be made
of any of the wide variety of suitable components. Thus, the
form-retaining base, while preferably of paperboard, cardboard or
corrugated board or other cellulosic product, may also be of any of
various suitable synthetic organic polymeric plastics, in foam,
solid or hollow form, wood, metal, mineral, or vegetable. Thus,
polyvinyl chloride, polystyrene, foamed polystyrene, either open or
closed cell, rigid polyurethane foam, glass-reinforced polyester,
balsawood, coconut shells, asbestos-foamed concrete, talc, pumice
or other bases may be used. They may be perforated or continuous at
the surfaces thereof. They may be of various forms, such as the
preferred cylinders or other rounded tubular shapes. However,
discs, parallelograms, such as rectangles, parallelepipeds, such as
cubes, ellipsoids, spheres, and many other shapes, which may also
be symbolic or decorative, e.g., figures, flowers, etc., are also
useful, providing only that they may be adequately covered with a
thin flexible material having conditioning agent on a surface
thereof. Of course, characteristics of the base material chosen
should be such that under the conditions of operation, usually in
an automatic laundry dryer with from 5 to 10 pounds of laundry
tumbling about it, the base will maintain its shape and thereby
will prevent distortion of the coated flexible material about
it.
A preferred base is a tube, most preferably a cylinder of
paperboard, and the thickness thereof will usually be from 0.1 cm.
to 0.4 cm. Its diameter may be variable but will usually be between
2 and 15 cm. with the length usually being from 2 to 30 cm.
Generally, the important measurement with respect to the base is
the total surface thereof which will be covered with the coated
flexible material. This should usually be from 10 to 5,000 sq. cm.
preferably from 100 to 2,000 sq. cm. and most preferably about 250
to 1,500 sq. cm. In some embodiments of the invention, the
form-retaining base will also be used as an outer container for a
roll of coated flexible paper. In such cases, it may be desirable
for the ends of the tube to be closed in, as by paper, plastic or
metal caps. Alternatively, other container structures may be used,
such as telescoping tube portions, each of which has one closed end
and one of which fits inside the other. Various other package
designs that lend themselves to the present use are apparent and
will not be discussed further here. Of course, when the
form-retaining base is not to be used as a package, it may be solid
or have internal reinforcing members present, because in such cases
space need not be allowed for storage of the flexible sheet
material.
The thin flexible substrate to be coated with conditioning agent
and used to cover at least a portion of the form-retaining base may
also be any of a wide variety of suitable materials, including
papers, plastics, rubbers, metals, cloths, sponges, fibers, felts
or non-woven fabrics. The various fibrous materials may be natural
or synthetic and usually will preferably be cellulosic. However,
they may also be of resilient foamed plastics, such as
polyurethanes. The shape of the flexible substrate material will
necessarily be such as to be conformable to the form-retaining
base. Generally, it will be preferred to utilize comparatively thin
sheeting, usually from 0.001 to 0.1 cm. thick but in some cases, as
when flexible foams or sponges are employed, the thickness may be
increased to as much as about 1 cm. without detrimental effects.
The main consideration is that the material have the desired
flexible properties to make it readily processable when coating
agent is employed and to make it readily storable before use. In
both such cases it is desired that it be capable of being formed
into a roll in which the sheet material is usually comparatively
thin. Of course, instead of using a rolled sheet, sections can be
cut from it into various shapes and employed on flat or partially
curved bases.
Among the fabric softeners and antistatic agents that are usable in
accord with the present invention are the nonionic surface active
materials, including higher fatty acid mono-lower alkanolamides,
higher fatty acid di-lower alkanolamides, block copolymers of
ethylene oxide and propylene oxide, having balanced hydrophilic and
lipophilic groups, alkyl (preferably middle alkyl) phenol
poly-lower alkylene oxide lower alkanols, polymers of lower
alkylene glycols, polyalkylene glycol ethers of higher fatty
alcohols and polyalkylene glycol esters of higher fatty acids.
Among the anionic agents are the higher fatty acid soaps of water
soluble bases, higher fatty alcohol sulfates, higher fatty acid
monoglyceride sulfates, sarcosides, taurides, isethionates and
linear higher alkyl aryl sulfonates. Cationic compounds include the
higher alkyl di-lower alkyl amines, di-higher alkyl lower alkyl
amines and quaternary compounds, especially quaternary ammonium
salts, e.g., quaternary ammonium halides. In the preceding
description, lower, as applied to various hydrocarbyl-containing
groups, indicates a carbon content of from 1 to 6, preferably from
2 to 3. Similarly, higher includes compounds having from 10 to 20
carbon atoms, preferably from 12 to 18. Of course, since it is
important to the present invention that the conditioning
composition be in a solid form, so that it can have conditioning
agent gradually removed from it by contact with tumbling laundry
fabrics in a dryer or similar machine, the fabric softening and/or
antistatic agents will be chosen to be in the solid state. Mixtures
of nonionic conditioning agents with either cationics or anionics
of the types mentioned above may also be used and generally, the
proportions of components of such mixtures will be chosen so as to
have the final product in most desired waxy condition and
satisfactorily removable by a combination of moisture, heat and
abrading contact with laundry that exists in an automatic
dryer.
Specific examples of surface active materials of the types
described above are given in the text Synthetic Detergents by
Schwartz, Perry and Berch, published in 1958 by Interscience
Publishers, New York. See pages 25 to 143. Among the more preferred
of these are:
Nonionic -- nonylphenoxy polyethoxy ethanol; stearic
monoethanolamide; lauric diethanolamide; block copolymers of
ethylene oxide and propylene oxide (Pluronics);
Anionic -- sodium soap of mixed coconut oil and tallow fatty acids;
sodium stearate; potassium stearate; sodium laurate; tallow
alcohols sulfate;
Cationic -- dilauryl dimethyl quaternary ammonium chloride;
hydrogenated tallow alkyl trimethyl ammonium bromide and
benzethionium chloride.
The above list is only illustrative of some of the compounds useful
in accordance with the present invention. Conditioning agents of
these types are well known in the art and others than those
mentioned above may also be used satisfactorily.
In addition to the fabric softening and/or antistatic and
anti-wrinkling agents which are the principal conditioning
compounds, other components may also be present in these
conditioning compositions for their adjuvant effects. Thus, other
conditioning agents may be used, including those designed to treat
the fabrics in other ways than in softening. For example, perfumes,
brighteners, bactericides, solvents, thickening or hardening
agents, stabilizers and other materials may be incorporated in the
conditioning compositions. In some cases, small quantities of water
may be present, especially when the components form hydrates.
Plasticizers and release agents may be employed to assist in having
the conditioning compounds satisfactorily coat the flexible
substrate and to facilitate release of the conditioning agent from
the treated articles upon subsequent laundering. Solvents and
dispersants may be used to assist in applying the conditioning
compositions to the flexible base, principally in those cases where
a flexible material, such as paper, is being impregnated with the
conditioning composition. The types and proportions of the various
adjuvants used will be chosen so to make them readily applied with
the softening agents and so as not to interfere with the operations
of the conditioning compounds.
The final conditioning composition is preferably waxy in appearance
and is capable of being stored at room temperature without melting,
while yet being satisfactorily picked up by fabrics in the
operation of an automatic laundry dryer, when the fabrics tumble
into contact with the conditioning composition. The conditioning
composition will be form-retaining at temperatures below 30.degree.
C. and preferably, also at all temperatures below 40.degree. C. It
may tend to fuse or melt under the higher temperatures obtaining in
the dryer, such as 70.degree. to 90.degree. C. but usually will be
only sufficiently softened, even in the presence of the
plasticizers, to be abraded off a treating article onto the surface
of material to be conditioned, at dryer conditions, including the
presence of moisture and drying gas at an elevated temperature. The
conditioning composition should be removable from a substrate
rather slowly but in sufficient quantity to condition fabrics, at a
temperature from 40.degree. to 90.degree. C., preferably from
50.degree. to 80.degree. C. Normally, to effect these purposes, the
fabric softener and/or antistatic agent, the surface active
conditioning agent mentioned previously, will be a major proportion
of the conditioning composition, usually from 51 to 100 percent
thereof. Preferably it will comprise from 75 to 100 percent of the
composition. The various adjuvants will normally constitute any
remainder of the composition.
When the conditioning composition is employed as a coating on the
substrate, the thickness of the coating applied will normally be
within the range of 0.0005 to 0.5 centimeter, generally from 0.001
to 0.3 cm. and preferably from 0.005 or 0.05 to 0.2 cm. The
thickness given is that external to the outer surface of the thin
flexible material coated. A somewhat porous or rough surfaced
substrate or one having indentations will normally be preferred so
that the coating composition may penetrate below the outer surface
to a sufficient depth to hold the external coating firmly to the
surface and prevent its cracking or flaking off from the surface
during use. As an example of such a substrate may be mentioned the
flexible polyurethane foams or paper toweling, having a crinkled or
roughened appearance, as contrasted to a smooth sheet of paper. A
minor proportion of the external thickness of coating agent may be
below the surface. This will usually be held to 10 to 30 percent of
that external to the base. In terms of weights applied, the
conditioning composition will normally be employed in the range of
0.0005 to 0.5 g./sq. cm., preferably from 0.001 to 0.3 g./sq.cm.
and most preferably from 0.005 to 0.2 g./sq. cm.
The preparation of the conditioning compositions is easy, usually
requiring only the melting together of the various components or
the dissolving of them in a solvent such as ethanol, water,
acetone, ether or other suitable medium. Such solutions are
normally employed if it is desired to impregnate a porous material,
such as paper, cloth or sponge. Normally however, it is most
desirable to have a major proportion of the coating agent external
to the flexible base so that it will all be available for transfer
to the laundry to be conditioned. In such cases, although solutions
can be used, it will generally be desirable to employ melts.
Methods for coating flexible articles which are especially
adaptable to coating such materials as they are unwound from and
wound onto rolls are described in an application for patent Ser.
No. 82,238, filed Oct. 20, 1970 entitled PROCESS FOR THE
MANUFACTURE OF FABRIC CONDITIONING ARTICLE, filed by P. J.
Falivene, one of the present inventors. Usually, the flexible base
will be drawn through a bath of conditioning composition, will be
passed under rollers or a spreader which coats a surface thereof or
will be sprayed with a melt or a solution of the treating
composition. In such manner, a coating of the type described
previously can be deposited on the flexible base and the coated
sheet can be rolled up or otherwise stored, ready for subsequent
use.
If it is desired to coat both sides of the flexible sheet, as will
often be the case, this may be done by the application of sprays or
spreading of conditioning composition on both sides simultaneously
or sequentially. If only one side is to be treated, it will usually
be preferred to accomplish this with a roller, doctor blade or
spray application, rather than by drawing of the sheet or film
substrate through a melt and removing one side coating. Of course,
it is a simple matter to coat the central portion of the sheet,
leaving the ends free of conditioning composition and this can be
accomplished by utilizing masking means or by squeezing out or
scraping off coating composition from the ends, after application.
Where both sides of a substrate are covered, the conditioning
materials may be the same or different on the major faces. Also,
one of them may incorporate another coating thereon to aid in
preventing adhesion of portions of the sheet which come into
contact with each other after rolling up of the coated substrate.
Thus, a thin layer of wax can be applied on top of one side of the
sheet coated with conditioning agent or an interleaf of waxed
paper, foil or other protective barrier can be used. Although it
will be strongly preferred to employ continuous, automatic
machinery, of the type used to make waxed paper, for the coating of
the present flexible substrates, other means may also be used,
including printing equipment. Also, the conditioning compounds can
be deposited from emulsions or dispersions and their fusion can be
promoted by flame, plasma arcs, lasers, or sonic means. Individual
pre-cut pieces of substrate may be made. Although the material
treated may be removed from a roll, it may be cut immediately after
coating. Evaporation means may be employed to remove solvent after
coating, or cooling means, such as an air blast, may be used to
lower the temperature to solidify the coating melt.
In preferred embodiments of the invention, after coating of the
sheet of substrate it will be wound on a spool or mandrel on which
it is to be sold or it may be subsequently rewound from a larger
spool onto the final one. If the product is to be packed on a
cylindrical roll, such as a roll of the type used to support wax
paper, this, in turn, may be boxed or packaged in a tube or
comforming container. It is not necessary that such container be
used as the form-retaining base but this is generally preferable,
in the interest of utilizing each part to the fullest extent and
avoiding unnecessary elements. If desired, the supporting
form-retaining tube or base may be packed inside the mandrel,
rather than outside it. Instructions for use may be printed on the
base. The sheets of flexible substrate may be scored or marked for
cutting or tearing at such lengths as to most efficiently cover the
form-retaining base. Means may be supplied in the package for
fastening the coated flexible substrate to the base.
To assemble the conditioning article, it is necessary only to apply
the coated flexible sheet to the form-retaining base. In some
cases, this may be done beforehand by the manufacturer. Most of the
time, however, in the interest of making less bulky packages and
producing a more economical product, the housewife will tear off a
length of sheet material, apply it to or wrap it around the base
and fasten it thereto. The fastening means employed, while they may
include conventional adhesives, elastic bands, snaps, clips, etc.,
will very often most economically be merely the uncoated ends of
the flexible sheet, which will be folded in at the ends of a tube
and will be held in place there by the confining or bending forces
created. Of course, after use, the consumed sheet may be removed,
turned over, if coated on both sides, re-used and ultimately
discarded, when all the conditioning composition has been consumed.
Then, another sheet may be placed on the base. Such use will
continue until the entire package is consumed.
The present articles are simple to employ and the treating methods
are effective for conditioning fabrics without special care being
necessary on the part of the user. The conditioning article is
placed in the automatic dryer or other tumbling device immediately
before a drying or treating operation commences. In tumbling, the
laundry and the conditioning article are in relative movement and
the combination of heat and moisture with the abrading action due
to contact causes the deposit of conditioning agent on the fabrics.
These then, by repeated contact with other fabrics, further even
out the depositing of conditioning agent. Although it is preferred
to employ an automatic laundry dryer, equivalent machines may be
used and in some instances the heat and drying air may be omitted
for part or all of the cycle. Generally, air will be employed and
will be circulated frequently. Normally there will be about 5 to 50
changes of drying gas in the dryer drum per minute and the gas
temperature will be from 10.degree. to 90.degree. C., preferably
from 50.degree. to 80.degree. C. The dryer will usually revolve at
about 20 to 100 revolutions per minute, preferably 40 to 80 r.p.m.
The weight of laundry employed will usually be from 4 to 12 pounds,
preferably from 5 to 10 pounds, dry weight. This will fill 10 to 70
percent of the volume of the dryer, preferably about 30 to 60
percent thereof. Drying will usually take from 5 minutes to 2 hours
and generally from 20 minutes to 1 hour will be sufficient, with
synthetic fabrics, such as nylon, polyesters and synthetic-natural
blends requiring shorter periods of time than cotton laundry. The
synthetics may often be dried satisfactorily in from 3 to 10
minutes and resin-treated fabrics of the permanently pressed or
non-wrinkling types may be dried in from 10 minutes to 1/2
hour.
After completion of the drying of the laundry or the softening
operation, the conditioning article is removed and examined. If
sufficient softener remains, the article may be employed again
until complete removal of the coating. If the laundry is not
satisfactorily conditioned, additional tumbling may be in order. To
obtain different levels of conditioning activity or different
effects there may be employed several treating articles or a
plurality of different treating articles. Of course, after the
coating is consumed the form-retaining base may be covered with a
new treated flexible substrate. Other details about the use of the
present compositions, articles and methods may be found in an
application for patent entitled FABRIC CONDITIONING METHODS,
ARTICLES AND COMPOSITIONS, Ser. No. 82,357, filed by G. T. Hewitt
on the same day of the present application, as well as in my other
patent application previously mentioned.
The advantages of the present invention have been mentioned
previously. In summary, it is considered most important that the
conditioning agent should not be employed on a flexible substrate
which is free to be distorted and trapped in the tumbling laundry
or fabrics being treated, thereby being apt to deposit excessive
treating composition which can stain or spot the fabrics being
conditioned. Yet, the advantages of a coated flexible material, in
that it is readily manufactured by continuous mass production
techniques, is easy to store and lends itself to efficient
packaging, are retained by having the coated flexible substrate
held to a form-retaining article and used to treat fibrous
materials to be conditioned. By use of such an article, the
tendency toward entrapment is minimized and staining, due to such
entrapment or cracking off of particles of conditioning agent due
to distortion of the flexible substrate, is minimized. Although the
highly preferred embodiments of the invention utilize conditioning
agents designed to soften textiles, such as cotton, and to make
them antistatic, an effect most desirable with respect to the
synthetic organic fibrous materials, such as nylons and polyesters,
or to make them wrinkle resistant, other conditioning agents may
also be employed and suitable bases for their application, such as
waxes, hydrophilic solids, fats, carriers or other depositable
media may be used.
The following examples illustrate various embodiments of the
invention. Unless otherwise indicated, all parts are by weight,
temperatures are in degrees Centigrade and the measurements are in
the metric system. The examples are not intended to be limiting
because it is evident that various modifications may be made and
equivalents may be substituted without departing from the spirit or
scope of the invention.
EXAMPLE 1
A melt is prepared by heating 70 parts of stearic monoethanolamide
and 30 parts of stearic diethanolamide to a temperature of about
90.degree. C., while mixing to maintain uniformity of the
composition. The melt is then applied to a sheet of toweling paper,
which is creped and has a thickness of approximately 0.1 cm.
Application is by means of a roller, dipping into a bath of the
melt and depositing a uniform layer of coating composition on a
central portion of the toweling, leaving the ends free of coating
composition, as illustrated in FIG. 3 of the drawing. Also, as
illustrated in FIG. 4, the toweling is covered with the softening
and antistatic conditioning composition on only one side thereof.
The deposit of conditioning composition is to a depth of about 0.05
cm. above the surface of the paper and the penetration is about
0.015 cm. below the surface. Penetration is limited by the rapid
cooling of the melt effected by air flow directed onto the coated
paper immediately after withdrawal from contact with the coating
roller.
After coating of the paper with conditioning composition, it is
rolled onto a paperboard spool having a diameter of about 6 cm. and
being 35 cm. long. The spool is of ordinary paperboard tubing
material, about 0.4 cm. thick. Enough of the treated paper is
rolled onto such a spool for 50 sheets, 35 .times. 20 cm., to be
obtained therefrom. Thus, each roll is 25 cm. wide and 10 meters
long.
The roll of conditioning paper wrapped around the base or mandrel
spool, is approximately 15 cm. in diameter, when wrapped tightly.
Another tube, this one having a closure at one end and a cover,
removable from the other end, and being of internal diameter of
about 17 cm., with an external diameter of about 18 cm., is
employed as a packaging enclosure for the tube of conditioning
paper. The roll of paper is slid into the tube and the cover is
slipped on and held thereto by suitable means, such as transparent
adhesive tape. The tube is covered then with an overwrap of
decorative and descriptive paper, containing instructions for use
of the product or such decorations and instructions are printed
directly on it.
In use, a 20 cm. length of paper coated with conditioning agent is
drawn off from the roll and is cut, either with scissors or by
means of pre-perforations. It is wrapped around the external
surface of the paperboard cylinder which also serves as a package
for the roll of conditioning material. Because the coated paper is
35 cm. wide with 5 cm. uncoated strips along the edges, the coated
portion thereof just covers the entire width of the 25 cm. long
cover portion. Note that the tubular package for containing the
roll of coated material is about 37 cm. long, with the separable
cover being approximately 17 cm. long, giving a 5 cm. overlap with
the portion thereof being used as a form-retaining base for the
flexible coated conditioning paper. The conditioning paper is held
to the base by pressing in of the uncoated ends thereof so that
they appear as shown in FIG. 1 of the drawing.
The conditioning action of the conditioning article made is tested
by employing it in treating a dryer load of 8 pounds of mixed
laundry in an automatic laundry dryer. The laundry treated is a
mixture of wearing apparel and household articles, including
cotton, synthetic fibers, especially polyesters, polyacetates and
blends of these plastics with each other or with cotton, nylons,
rayons and resin-treated, permanently pressed and wrinkle resistant
fabrics. The wash comprises approximately 50 percent of cotton
articles, 20 percent of polyester-cotton blends, 10 percent
permanently pressed items, 10 percent nylon articles and the
balance of rayon, acetate, etc. The dryer employed is of the
horizontal drum type, having longitudinal flights or ridges to
assist in creating a tumbling action. After loading the damp
laundry, just removed from a washing machine after having been spun
"dry," the conditioning article is placed on top of the laundry,
which occupies 40 percent of the dryer volume, and the dryer
operation is commenced. Drying air is blown through the dryer at
the rate of about 200 cubic feet per minute and with an initial
temperature of about 70.degree. C. The drum rotates at about a
speed of 60 r.p.m. Initially the temperature of the damp laundry is
low, approximately 20.degree. C., but as drying continues, it
increases to almost 70.degree. C. The conditioning agent on the
surface of the article is abraded off onto the surface of the
fabric being treated, so that when, after 50 minutes of drying, the
machine is turned off and the laundry is removed, it is static-free
and soft to touch, compared to a similar load in which the
conditioning article is not used. Of course, no softening agent is
employed in the rinse water during the wash cycle. The clothing
treated exhibits so spots or stains and periodic examination of the
conditioning article during the operation of the dryer shows that
the coating is held satisfactorily to the base. There is no flaking
or cracking of the conditioning composition evident.
Upon removal of the treating cylinder and examination of it, it is
found that approximately 3 grams of conditioning composition have
been abraded from the surface onto the articles to be treated.
Therefore, the coated paper contains at least an additional 2 grams
of available conditioning material and can be used again. When it
is reused with another load of laundry and all the coating is
abraded from the surface, only about 1.5 grams of the original 6.5
grams of conditioning composition remains in the conditioning
paper. At that time, the paper is replaced with a fresh sheet and
the conditioning operation is repeated with another laundry
load.
In other runs, using the same type of base and with the same coated
paper, nylon articles are removed after 5 minutes and permanently
pressed articles are withdrawn after 15 minutes and are found to be
satisfactorily conditioned, being soft, static-free and
wrinkle-free.
When, instead of employing the formula described above there is
used a melt of lauric monoethanolamide and stearic diethanolamide,
also in 30:70 portions, comparable results are obtained. Similarly,
when a solution comprising 30 percent ethanol, 55 percent distearyl
dimethyl ammonium chloride and 15 percent water is employed to
impregnate the same type of paper over the same area at
approximately the same weight of conditioning compound per unit
area, and the article covered with treated paper is used in the
described conditioning operation, good softening of cotton and
antistatic action on synthetic organic polymeric textiles are
obtained. In manufacturing such a product, an air blast is employed
to evaporate solvent immediately upon removal of the coated paper
from contact with the coating roll. When synthetic organic anionic
surface active agents such as sodium lauryl sulfate and soap are
also used, applied either as melts or solutions to toweling of the
type described above and wrapped around the form-retaining base,
they are also found to be satisfactory in conditioning of the
tested laundry. It is generally observed that the additions of
plasticizing agents, such as those described in a patent
application filed by P. J. Falivene on the same day as this
application and entitled FABRIC CONDITIONING WITH IMPROVED
COMPOSITION CONTAINING A PLASTICIZER, are useful in improving even
further the adaptability of the coated toweling to be rolled onto
and rolled from a cylindrical mandrel, without exhibiting any
cracking or flaking off of the coating.
EXAMPLE 2
The experiments reported in Example 1 are repeated, this time using
various other tubular shapes, including those of elliptical, square
and rectangular cross-section, but with equivalent surface areas
and covered with similarly coated papers. Those tubes having sharp
corners have strips of conditioning paper cut to fit each face and
these are applied thereto by stapling or cementing, so as to avoid
creating sharp bends which could cause the conditioning composition
to flake off and spot the treated clothing. When such precautions
are followed, the conditioning results are comparable to those of
Example 1.
EXAMPLE 3
The procedure described in Example 1 is followed but the base
material, rather than being a paper towel, is a thin layer of
polyurethane foam, approximately 0.5 cm. thick. It is cemented to a
form-retaining base which is a paperboard box in the shape of a
cube, having a side of approximately 10 cm. when employed to treat
similar laundry, satisfactory conditioning results, following the
test procedures in Example 1, but the softening and antistatic
effects are not as good as those observed with the product of
Example 1.
EXAMPLE 4
The preparation of a coating paper follows the procedure described
in Example 1 with respect to the stearic monoethanolamide-stearic
diethanolamide coating on paper toweling, with the exception that
entire sheet of paper is coated on both sides at approximately the
same weight of conditioning agent per unit area. Clothing is
softened by the same method but after consumption of the exposed
conditioning agent on the paper, the tucked in paper is removed and
reversed, so that a fresh surface of conditioning agent is
available. It is then used over again, until the coating is
consumed. Then, the ends, previously tucked in to hold the sheet
onto the form-retaining base, are cut off and are stapled to the
base, together with other such ends, so that the coating thereon
can be utilized. By following this method, it is not necessary to
make any special effort to prevent the coating of the ends of the
sheets, which would normally be inaccessible for application of
coating composition from them to the laundry or fibrous materials
being treated.
Instead of being stapled to the tubes, the coating compositions may
be fastened, as by staples, cement, or other fastening means, even
paper clips, to other form-retaining bases, even to discs or other
flat items. Of course, articles of such shapes do not roll as
satisfactorily in the automatic dryer as do the rounded tubular
items, but, providing that an equivalent weight of conditioning
composition is present on a comparable surface area, useful
conditioning results.
If, instead of the nonionic conditioning agents, a cationic
material, such as the distearyl dimethyl ammonium chloride
conditioner of U.S. Pat. No. 3,442,692 is employed and is used to
coat a flexible substrate, in the manner described in that patent,
with the substrate then being made form-retaining by being affixed
to a form-retaining base, useful conditioning of laundry results.
However, in such cases, contact with metals, especially heavy metal
ions, such as ferric or ferrous ions, and color bodies should be
avoided to prevent staining. Thus, staples and paper clips will not
ordinarily be used to fasten the flexible substrates to the bases
when cationic materials are employed. For similar reasons, where
contact with metals or rusted materials is possible, one will
preferably employ the nonionic or anionic conditioning agents. If
the cationics are used, some staining problems therewith are
obviated by having the flexible base made form-retaining and
thereby less apt to have large quantities of conditioning agent
broken off and deposited on the fibrous materials being
treated.
Other embodiments of the invention will be apparent to those of
skill in the art from this description. For example, the
form-retaining cylinder may be of a springy nature, made of plastic
or metal, with a longitudinal slit running the length thereof. The
springing together of the plastic at the slit may be used to hold a
sheet of coated paper wrapped around the cylinder. Also, the coated
sheets and base materials may be in pad form, with the pad support,
being a plastic or other material which is flexible, yet
form-retaining when rolled into a tubular shape. The form-retaining
support which may be of polyurethane foam, paper, Mylar, nylon,
etc., can be rolled into a cylindrical shape and held in this shape
by rubber bands or other suitable fasteners. The coated sheets from
the pad may then be wrapped around the cylinder and employed in a
conventional automatic dryer for softening purposes. With respect
to the form-retaining base, it may even be made from a plurality of
layers of flexible material, such as paper, which are wound
sufficiently to become essentially form-retaining. In such an
embodiment, a coating may be applied to the outer portion of the
strip of paper, with the section thereof forming the base portion
being uncoated. All such embodiments are fairly within the concept
of the present invention. These and other equivalents are intended
to be encompassed by the claims appended hereto.
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