U.S. patent number 3,697,670 [Application Number 05/204,023] was granted by the patent office on 1972-10-10 for electrical cable having sheath layers bonded with adhesive.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Bill Mitacek.
United States Patent |
3,697,670 |
Mitacek |
October 10, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
ELECTRICAL CABLE HAVING SHEATH LAYERS BONDED WITH ADHESIVE
Abstract
In an electrical cable having at least one polyolefin sheath
layer and an aluminum sheath layer, the polyolefin layer is bonded
to the aluminum layer with an adhesive material of 50 to 90 weight
percent amorphous polypropylene and 50 to 10 weight percent mineral
lubricating oil.
Inventors: |
Mitacek; Bill (Bartlesville,
OK) |
Assignee: |
Phillips Petroleum Company
(N/A)
|
Family
ID: |
22756291 |
Appl.
No.: |
05/204,023 |
Filed: |
December 2, 1971 |
Current U.S.
Class: |
174/107; 174/23C;
174/36; 174/110PM; 174/113R; 174/116 |
Current CPC
Class: |
H01B
7/2825 (20130101) |
Current International
Class: |
H01B
7/282 (20060101); H01B 7/17 (20060101); H01b
007/18 () |
Field of
Search: |
;174/12R,12D,23R,23C,107,12R,104,113R,116,11PM,15R,117A |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Myers; Lewis H.
Assistant Examiner: Grimley; A. T.
Claims
What is claimed is:
1. An electrical cable comprising a plurality of electrical
conductors, each of said conductors having a coating layer of
electrically insulating material, the thus insulated conductors
being positioned adjacent one another to form a core, an annular
layer of a polymer of at least one mono-1-olefin coaxial to and
surrounding said aluminum sheath, said annular layer being bonded
to said aluminum sheath by an intervening layer of adhesive
material comprising about 50 to about 90 weight percent amorphous
polypropylene and from about 50 to about 10 weight percent mineral
lubricating oil.
2. An electrical cable in accordance with claim 1 wherein a second
annular layer of a polymer of at least one mono-1-olefin is coaxial
with said core and positioned between said core and said aluminum
sheath and is bonded to said aluminum sheath by a second layer of
said adhesive material.
3. An electrical cable in accordance with claim 2 wherein said
adhesive material further comprises an antioxidant.
4. An electrical cable in accordance with claim 2 wherein said
adhesive material is about 60 to about 80 weight percent amorphous
polypropylene and about 0.05 to about 2 weight percent of at least
one antioxidant with the remainder being said mineral lubricating
oil.
5. An electrical cable in accordance with claim 4 wherein said
amorphous polypropylene has a molecular weight in the range of
about 700 to about 100,000, as determined by light scattering and a
density in the range of about 0.83 to about 0.90 gm/cc at
25.degree. C.
6. An electrical cable in accordance with claim 5 wherein said
mineral lubricating oil has a viscosity in the range of about 40 to
about 150 SUS at 210.degree. F.
7. An electrical cable in accordance with claim 6 wherein said
adhesive material comprises about 75 weight percent amorphous
polypropylene, about 25 weight percent mineral lubricating oil, and
about 0.2 weight percent of an antioxidant.
Description
This invention relates to a sheathed electrical cable. In a
specific aspect, the invention relates to a sheathed telephone
cable having polyolefin and aluminum layers in the sheath bonded
together by an adhesive material.
One of the problems encountered in designing electrical cable such
as telephone cable for utilization in underground environment is
finding a simple, economical, and yet effective, bonding material
by which the sheathing materials such as layers of aluminum and
polyolefin can be bonded to each other to form a waterproof
exterior sheath. Besides adequately bonding these layers one to
another, the bonding material should fill any voids between these
layers to prevent the entry and travel of water, and should also
allow the polyolefin to be peeled from the aluminum wrapping with
moderate effort to expose the aluminum for grounding purposes.
The present bonding composition has been found to be a suitable
alternative to other frequently more complex or expensive bonding
materials.
Accordingly, it is an object of the present invention to provide a
new and improved electrical cable. Another object of the invention
is to provide an improved waterproof sheath for an electrical
cable. Yet another object of the invention is to provide a material
for bonding together the aluminum and polyolefin layers in the
sheath of a telephone cable which polyolefin layer and adhesive
layer can be peeled from the aluminum when exposure of the aluminum
layer is desired.
Other objects, aspects and advantages of the invention will be
apparent from a study of the specification, the drawing, and the
appended claims to the invention.
In the drawing, the single FIGURE is a perspective view in cross
section of a multiconductor electrical cable embodying the present
invention. A plurality of electrical conductors 11 are provided
with individual insulation coatings 12. The insulated conductors
can be stranded or twisted to form the cable core. This core is
covered by a circumferentially continuous annular layer 13 of an
electrically insulating synthetic thermoplastic organic polymeric
material, preferably a polymer of at least one mono-1-olefin having
up to eight carbon atoms per molecule. Polyethylene, polypropylene,
and copolymers of ethylene or propylene with at least one other
mono-1-olefin having up to eight carbon atoms per molecule are
particularly suited for use as layer 13. Exemplary copolymers
include the copolymers of ethylene and propylene, the copolymers of
ethylene and butene, the copolymers of ethylene and hexene, and the
copolymers of propylene and butene. Polyethylene, particularly high
density polyethylene, is presently preferred for this core wrap
material. It can be in the form of a tape or ribbon or it can be an
extruded layer.
An annular layer 14 of aluminum is coaxial with and surrounds
polymeric layer 13 and is bonded thereto by an adhesive layer 15.
The aluminum layer 14 can be in any form known in the art, for
example spirally wound aluminum tape, braid, or a longitudinal tape
curved to tubular form.
An outer cable coating or protective jacket 16 is coaxial with and
surrounds aluminum layer 14, and is bonded thereto by an adhesive
layer 17. The cable coating 16 is an electrically insulating
synthetic thermoplastic organic, polymeric material, preferably one
of the polymers of at least one mono-1-olefin named hereinabove
with regard to layer 13. The cable coating 16 will sometimes
contain a material such as carbon black to minimize degradation of
the polymer during exposure to sunlight. It can also be in the form
of a tape or ribbon but will most often be an extruded layer.
The thickness of these various layers, namely, the core wrap, the
aluminum layer, and the outer jacket will depend upon the specific
use intended but will generally be sufficient to impart the degree
of strength, flexibility, and protection desired.
In accordance with the present invention, each of layers 15 and 17
comprises an adhesive having from about 50 to about 90 weight
percent amorphous (atactic) polypropylene, and from about 50 to
about 10 weight percent mineral lubricating oil. Other conventional
additives such as antioxidants, tackifiers, rodent repellents,
pigments, and the like can be present in amounts ranging up to
about 10 weight percent based on the adhesive. In a presently
preferred embodiment the adhesive comprises from about 60 to about
85 weight percent amorphous polypropylene and about 0.05 to about 2
weight percent of at least one antioxidant with the remainder being
the mineral lubricating oil.
In general, the amorphous polypropylene will have a molecular
weight in the range of about 700 to about 100,000, as determined by
light scattering, and preferably in the range of about 1,000 to
about 70,000. The amorphous polypropylene will have a density in
the range of about 0.83 to about 0.90 g/cc, as determined by ASTM
Test D 1505-60T. The amorphous polypropylene will generally have
less than 10, and preferably less than 5, weight percent
crystallinity as determined by X-ray diffraction patterns. The
amorphous polypropylene can be a homopolymer of propylene or a
copolymer of propylene with less than 10 weight percent of at least
one other mono-1-olefin, for example, a copolymer of propylene and
butene, a copolymer of propylene and ethylene, a copolymer of
propylene and hexene, and the like. The presently preferred
amorphous polypropylene is a homopolymer and is a material which is
well known in the polymer art. It is widely available as a
by-product in well known processes for the polymerization of
propylene to solid atactic polypropylene, a material already
described above as being suitable for conductor insulation, or core
wrap, or outer jacket material. Thus, a propylene polymerization
process, catalyzed by a catalyst system prepared from a titanium
trihalide and an organoaluminum halide, produces a polymer mixture
containing solid isotactic polypropylene and 1 to 20 weight percent
atactic polypropylene. The atactic portion is extracted with a
suitable hydrocarbon solvent and isolated. It will generally be
desirable to remove as much of the catalyst residue from the
atactic polypropylene as is economically removable to avoid adverse
effects upon the electrical properties of the adhesive materials.
This can be carried out by any suitable process such as acid
washing. Similarly, any additives for the adhesive material should
be selected to avoid any significant adverse effects upon the
electrical properties of the adhesive material.
The mineral lubricating oil will generally have a viscosity in the
range of about 40 to about 150 SUS at 210.degree. F. The
lubricating oil can be one obtained by conventional refining or by
solvent refining. The polypropylene and the mineral lubricating oil
can be blended in any manner known in the art. This is most easily
accomplished by simple mixing, preferably at slightly elevated
temperatures at which the amorphous polypropylene becomes miscible
with the mineral oil.
It will generally be desirable to incorporate a polyolefin
decomposition inhibitor, and more particularly at least one
antioxidant, into the adhesive material. Suitable inhibitors
include 2,2'-methylenebis(4-ethyl-6-tert-butyl-phenol), butylated
hydroxytoluene, dilaurylthiodipropionate,
4,4'-thiobis(6-tert-butyl-m-cresol), and the like, and admixtures
thereof.
The sheathed cables of the present invention can be assembled by
any suitable method in the electrical cable art. As an example, a
telephone cable generally contains a number of paired wire
conductors, each of which is sealed in an insulating coating such
as solid polypropylene. These coated conductor wires are suitably
twisted, gathered into a core, and encased in a core wrap such as
polyethylene tape. Prior to the wrapping, it is advantageous to
pass the core through a bath of viscous waterproofing filler such
that the wrapped core has no free or void space between the
insulated conductors.
The wrapped core is then covered by a thin layer of aluminum,
generally aluminum tape. As part of the aluminum wrapping
operation, the adhesive of the invention can be applied to the
wrapped core in an amount sufficient to provide a thin yet at least
substantially continuous film between the polyethylene wrap and the
aluminum wrap.
The final outer jacket of the cable, generally a layer of extruded
polyethylene, is then applied together with sufficient adhesive to
provide a thin but at least substantially continuous film between
the aluminum and the outer jacket.
In a specific illustration of the effectiveness of the present
invention, a bonding composition was prepared by mixing, at an
elevated temperature, a quantity of amorphous polypropylene and a
lubricating oil stock having a viscosity, at 210.degree. F, of
about 53-54. The composition contained 75 weight percent amorphous
polypropylene. Also included in the composition was 0.2 weight
percent of a commercial antioxidant identified as
4,4-thiobis(6-tert-butyl-m-cresol). A small portion of this bonding
material was placed between a sheet of aluminum foil and sheet of
high density polyethylene film. After contact, the two sheets
became adequately bonded yet could be separated by peeling without
any damage to either of the sheets. The bonded sheets of aluminum
and polyethylene were also successfully tested by flexing at
-30.degree. F. Flexing at this low temperature did not destroy the
bond between the aluminum and the polyethylene.
Reasonable variations and modifications are possible within the
scope of the foregoing disclosure, the drawing, and the appended
claims to the invention.
* * * * *